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Изучение антиоксидантной активности растений

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ФЕДЕРАЛЬНОЕ АГЕНСТВО ПО ОБРАЗОВАНИЮ ГОСУДАРСТВЕННОЕ ОБРАЗОВАТЕЛЬНОЕ
УЧРЕЖДЕНИЕ ВЫСШЕГО

ПРОФЕССИНАЛЬНОГО ОБРАЗОВАНИЯ

СЛАВЯНСКИЙ-НА-КУБАНИ ГОСУДАРСТВЕННЫЙ ПЕДАГОГИЧЕСКИЙ ИНСТИТУТ

Факультет биологии и химии

Специальность биология

Кафедра естественно-биологических

и медицинских дисциплин

Выпускная квалификационная работа.

Изучение антиоксидантной активности растений

Выполнила Научный руководитель

Студентка 5 курса доцент,к.т.н.

Ольшанская Елена Петровна Избранова Светлана Иосифовна

_______________ __________________

Подпись Подпись

г. Славянск – на – Кубани

2008 г

Оглавление

Введение

Глава 1. Антиоксидантная активность растительных материалов

1.1 Антиоксиданты растительных материалов

1.1.1 Общая характеристика растительных антиоксидантов

1.1.2 Аскорбиновая кислота как антиоксидант

1.2 Биологическое описание растений, обладающих антиоксидантной
активностью

1.2.1 Лимон обыкновенный (Citrus limon)

1.2.2 Калина обыкновенная (Viburnuv opulus L.)

1.2.3 Шиповник коричный (Rosa majalis)

1.3 Растения чая (Thea)

Глава 2. Материалы и методы исследования

2.1 Объекты

2.2 Материалы исследования

2.3 Методы исследования

Глава 3. Результаты исследования и их обсуждение. Изучение
антиоксидантной активности растений

3.1 Определение содержания витамина С в калине обыкновенной в период
созревания

3.2 Определение антиоксидантной активности растительных материалов

3.3 Определение содержания полифенольных соединений в различных сортах
чая

3.4 Влияние компонентов чая на антиоксидантную активность

Методическая часть. Урок биологии в 8-м классе по теме: “Витамины”

Выводы

Список литературы

Приложения

Введение

Кислород является мощным окислителем, реакции окисления с его участием –
источник энергии для многих живых организмов. С другой стороны, в
процессе метаболизма образуются соединения кислорода, которые разрушают
структуру и вещества клетки. В результате в клетке и во всем организме
нарушается обмен веществ. Роль антиоксидантов – связать и вывести из
организма свободные радикалы.

В организме имеется собственная система борьбы с излишним количеством
свободных радикалов, но она ослабляется под воздействием неблагоприятных
факторов окружающей среды. Известно, что многие растения содержат
вещества, обладающие антиоксидантной активностью.

Большое внимание в настоящее время уделяется биофлавоноидам – большой
группе соединений с полифенольной структурой. Имеются сведения о их
антиоксидантной активности. Антиоксиданты растительного происхождения
широко используют в медицине и пищевой промышленности в виде экстрактов
и натуральных масел.

Объектом изучения являются плоды калины обыкновенной, шиповника
коричного и лимона обыкновенного, различные сорта чая.

Предметом изучения является антиоксидантная активность исследуемых
материалов.

Целью нашей работы явилось изучение антиоксидантной активности растений.

Для реализации цели были поставлены следующие задачи:

1. Изучить особенности калины обыкновенной, лимона, шиповника, чая и их
антиоксидантную активность;

2. Определить содержание аскорбиновой кислоты в настоях плодов калины
обыкновенной в период созревания;

3. Определить содержание аскорбиновой кислоты в плодах лимона
обыкновенного, шиповника коричного и различных сортов чая;

4. Определить содержание полифенольных соединений в различных сортах
чая;

5. Изучить влияние компонентов чая на антиоксидантную активность.

Гипотеза работы – если исследуемые растения обладают антиоксидантной
активностью, то количество антиоксидантов зависит от вида растения.

Теоретическая значимость – в результате проделанной работы определено
содержание аскорбиновой кислоты в калине обыкновенной, лимоне
обыкновенном, шиповнике коричном, различных сортах чая.

Практическая значимость – установлено, что компоненты чая снижают
антиоксидантную активность, поэтому не рекомендуется употреблять чай
после приема пищи.

Глава 1. Литературный обзор. Изучение антиоксидантной активности
растительных материалов

Антиоксиданты — вещества, замедляющие или предотвращающие окисление
органических соединений. Они защищают организм от негативных воздействий
свободных радикалов. Антиоксидант соединяется со свободным радикалом и
ставит заслон разрушительному действию лишнего электрона. С помощью
ферментной защитной системы организм преобразует клеточный оксидант в
воду и кислород (нерадикал) [1].

1.1 Антиоксиданты растительных материалов

В организме имеется собственная система борьбы с излишним количеством
свободных радикалов, но она ослабляется под воздействием загрязненной
среды, курения, прямых солнечных лучей и нуждается в поддержке. Было
обнаружено, что многие растения содержат вещества флавоноиды – большую
группу соединений с полифенольной структурой, которые связывают
свободные радикалы, т.е. являются антиоксидантами.

1.1.1 Общая характеристика растительных антиоксидантов

В организме постоянно образуются свободные радикалы, поэтому от них
должна существовать антиоксидантная защита, являющаяся одним из
важнейших компонентов иммунитета в целом. Важно дополнять свой пищевой
рацион природными веществами – антиоксидантами , которые усиливают
защиту от свободных радикалов, повышают тем самым иммунитет,
устойчивость организма к воздействию неблагоприятных внешних факторов,
замедляют процессы старения [8].

Важнейшими антиоксидантами являются: витамины С, Е, в-каротин, селен,
биофлавоноиды (витаминоподобные вещества, содержащиеся в кожуре растений
– апельсины, лимоны, томаты и прочее). Многие растительные экстракты,
витамины, аминокислоты, минералы, микроэлементы обладают
антиоксидантными свойствами или непосредственно, или опосредованно, так
как входят в состав ферментов-антиоксидантов[3].

В растениях было обнаружено около 5000 флавоноидов – антиоксидантов с
широким спектром целебного воздействия. Они обладают сосудорасширяющими,
противоопухолевыми, противовоспалительными, бактерицидными,
иммуностимулирующими и противоаллергическими свойствами [1].

Антиоксиданты, обнаруженные в растениях, являются полифенолами. Многие
травяные добавки — сибирский женьшень (адаптоген), гингко билоба
(стимулятор умственной деятельности), чертополох морской (защищает
печень), куркума длинная (противовоспалительное действие) и черника
(зрение, ревматоидный артрит) — помимо своих основных свойств, являются
еще и антиоксидантами. В травяных экстрактах биоактивные ингредиенты
освобождены от клеточных стенок – за счет этого они легче усваиваются
организмом. Чтобы добавка давала максимальный эффект, она должна
содержать строго стандартизированное количество биоактивных веществ:
сибирский женьшень — 0,5% элеутерозида Е, гингко билоба — 24%
флавокгликозидов, морской чертополох – 80% силимарина, куркума длинная —
как минимум 80% куркуминоидов, черника — 25% антоцианидинов. Необходимо
выбирать только такие травяные добавки, в которых точно соблюдены все
эти показатели [31].

Характеристика антиоксидантов.

Бета-каротин. Каратиноидный предшественник витамина А. Связывает
атомарный кислород и пероксильные радикалы. Защищает уязвимую (липидную)
оболочку клетки. Содержится в апельсинах, желтых овощах, тыкве, моркови,
в сладком картофеле и темно-зеленых овощах, например, в брокколи [50].

Витамин Е (d-альфа токоферол). Главный жирорастворимый антиоксидант.
Защищает жирные кислоты внутри и вокруг клеток от свободных радикалов и
липидного окисления. Содержится в растительном масле, приготовленном
методом холодного прессования; в пшеничных ростках, хлебе и крупах из
цельного зерна. [50]

Экстракт зеленого чая. Полифеноловый антиоксидант, богатый катехинами,
связывает анионные радикалы, супероксиды, перекись водорода. Экстракт
должен содержать как минимум 50 процентов катехинов и полифенолов.
Рекомендуемая доза — 300-700 мг в день [50].

Экстракт чертополоха морского. Главный защитник печени. Экстракт должен
содержать 70 или больше процентов силимарина. Рекомендуемая доза —
300-600 мг в день [50].

Экстракт гингко билоба. Защищает клеточные мембраны от липидного
окисления, особенно миелиновую оболочку нервов и клеток мозга. Экстракт,
полученный из листьев дерева гингко билоба, содержит 24 процента
флавогликозидов. Рекомендуемая доза — 120мг в день [50].

Экстракт виноградных косточек. Мощный антиоксидант, содержащий 95%
процианидов (полифеноловые олигомеры), которые обладают свойством
связывать свободные радикалы и подавлять активность коантиновой
оксидазы, фермента, включающего цепное производство кислородных
радикалов. Экстрагируется из косточек красного винограда. Рекомендуемая
доза 50-100 мг в день [50].

Экстракт китайского лимонника. Растение с ярко выраженной способностью
защищать печень и обладающее антиоксидантным свойством. Рекомендуемая
доза — 200-300 мг в день [50].

Ликопен. Мощный картиноид, связывающий атомарный кислород и пероксильные
радикалы. Защищает липидную оболочку клетки. Содержится в помидорах.
Рекомендуемая доза — 5-10 мг в день [50].

Альфа-липоидная кислота. Липоикная кислота не является витамином, но она
существенна для жизнедеятельности организма. Она защищает клетки и
преобразует окисленный глютатион в его более функциональную форму.
Рекомендуемая доза — 50-100 мг в день [50].

Селен. Основной минеральный антиоксидант и дезактиватор свободных
радикалов. Участвует в синтезе фермента глютатионной перексидазы.
Рекомендуемая доза — 200-400 мг в день (I-селенометионинная форма) [50].

Любой организм можно рассматривать как образец работы сбалансированной и
отлаженной антиоксидантной системы, состоящей из многих компонентов –
это и витамины (витамины С, Е, Р), и ферменты (глутатионпероксидаза,
супероксиддисмутаза), и микроэлементы (селен, цинк), и полифенольные
соединения (флавоноиды), и серосодержащие аминокислоты (цистеин,
метионин), а также трипептид глутатион. Это только некоторые соединения,
обладающие антиокислительным действием. Химическая природа этих
соединений разнообразна, среди них есть как водо- так и жирорастворимые
компоненты. Основной принцип, на котором строится действие
антиоксидантной системы живого организма – это синергизм. Он заключается
в том, что компоненты системы работают сообща, восстанавливая друг друга
и усиливая эффективность действия [1] .

Природные антиоксидантные системы, выработанные в ходе эволюции, прошли
испытание “на прочность” в течение многих миллионов лет. Поэтому
выглядит вполне логичным учесть опыт природы и использовать в
косметических средствах естественные антиоксидантные комплексы,
выделенные, например, из растений. Причин тому несколько:

1. Широкий выбор растений, обладающих не только антиоксидантным
действием, но и другими полезными для кожи свойствами. Поэтому из
растительного сырья можно готовить полифункциональные препараты;

2. При использовании растений нет риска инфекционного заражения, как в
случае использования животного сырья;

3. Доступность растительного сырья [1].

1.1.2 Аскорбиновая кислота как антиоксидант

б-Лактон 2,3-дегидро-L-гулоновой кислоты

Витамин С – мощный антиоксидант. Он играет важную роль в регуляции
окислительно-восстановительных процессов, участвует в синтезе коллагена
и проколлагена, обмене фолиевой кислоты и железа, а также синтезе
стероидных гормонов и катехоламинов. Аскорбиновая кислота также
регулирует свертываемость крови, нормализует проницаемость капилляров,
необходима для кроветворения, оказывает противовоспалительное и
потивоаллергическое действие [3].

Витамин С является фактором защиты организма oт последствий стресса.
Усиливает репаративные процессы, увеличивает устойчивость к инфекциям.
Уменьшает эффекты воздействия различных аллергенов. Имеется много
теоретических и экспериментальных предпосылок для применения витамина С
с целью профилактики раковых заболеваний. Известно, что у онкологических
больных из-за истощения его запасов в тканях нередко развиваются
симптомы витаминной недостаточности, что требует дополнительного их
введения [41].

Витамин С улучшает способность организма усваивать кальций и железо,
выводить токсичные медь, свинец и ртуть.

Важно, что в присутствии адекватного количества витамина С значительно
увеличивается устойчивость витаминов В1, В2, A, E, пантотеновой и
фолиевой кислот. Витамин С предохраняет холестерин липопротеидов низкой
плотности от окисления и, соответственно, стенки сосудов от отложения
окисленных форм холестерина [3].

Способность успешно справляться с эмоциональным и физическим стрессом в
большей степени зависит от витамина С, чем от какого-либо другого
витамина. Надпочечники, которые выделяют гормоны, необходимые, чтобы
действовать в стрессовых ситуациях, содержат больше аскорбата, чем любая
другая часть тела. Витамин С помогает выработке этих стрессовых гормонов
и защищает организм от токсинов, образующихся в процессе их метаболизма.

Организм человека не может запасать витамин С, поэтому необходимо
постоянно получать его дополнительно. Поскольку он водорастворим и
подвержен действию температуры, приготовление пищи с термической
обработкой его разрушает [32].

Источники растительные: цитрусовые, овощи листовые зеленые, дыня,
брокколи, брюссельская капуста, цветная и кочанная капуста, черная
смородина, болгарский перец, земляника, помидоры, яблоки, абрикосы,
персики, хурма, облепиха, шиповник, рябина, печеный картофель в
“мундире” [41].

Травы, богатые витамином С: люцерна, коровяк, корень лопуха, песчанка,
очанка, семя фенхеля, пажитник сенной, хмель, хвощ, ламинария, мята
перечная, крапива, овес, кайенский перец, красный перец, петрушка,
сосновые иглы, тысячелистник, подорожник, лист малины, красный клевер,
плоды шиповника, шлемник, листья фиалки, щавель [30] .

Полное и длительное отсутствие витамина С в рационе или прекращение его
усвоения вследствие болезни ведет к возникновению заболевания,
известного под названием цинги. Возникновению С-авитаминоза способствуют
энергетическая и белковая недостаточность питания, суровые климатические
условия и изнуряющий, непосильный труд. Начальные формы дефицита
витамина С явление достаточно распространенное. Чаще и в большей степени
при аскорбиновом гиповитаминозе отмечаются утомление, снижение
устойчивости к холоду и возрастание подверженности к заболеваниям
верхних дыхательных путей. Обнаруживается кровоточивость десен при
чистке зубов. На коже голени, бедер и спины возникают мелкие
кровоизлияния вокруг волосяных фолликулов, отмечается их приподнятость,
что воспринимается как гусиная кожа при ознобе. Состояние С –
витаминозного дефицита может длительно протекать в скрытой форме,
создавая благоприятный фон для формирования атеросклероза, астенического
состояния, неврозов, стрессовых реакций. Имеются наблюдения,
свидетельствующие о том, что скрытая форма С-витаминной недостаточности
является предрасполагающим фактором формирования избыточной массы тела.
Возникающие в таком состоянии болезни протекают более тяжело и
длительно, чаще возникают осложнения [25].

Важнейшие источники витамина С приведены в приложении 1.

Ученые говорят, что уже давно известно, что для растений витамин С очень
важен – он выступает как антиоксидант, помогающий растениям
противостоять засухе, озону и активному ультрафиолетовому излучению.
Однако до сих пор было неизвестно, что витамин С также форсирует и рост
растительных культур [23] .

При длительном хранении овощей, фруктов и ягод их витаминная ценность
снижается. Сохранность витамина С зависит также от способа кулинарной
обработки продуктов [41].

Суточная потребность взрослого здорового человека в аскорбиновой кислоте
колеблется в пределах 70-100 мг [41].

1.2 Биологическое описание растений, обладающих антиоксидантной
активностью

1.2.1 Лимон обыкновенный (Citrus limon)

Вечнозеленое дерево семейства рутовых высотой до 5 м. Крона раскидистая,
пирамидальная. Листья темно-зеленые, овальной формы, длиной 7-15 см. Они
плотные и кожистые, с короткими черешками. На просвет можно увидеть
светлые точки – железки, выделяющие эфирные масла. Если слегка потереть
поверхность листьев, можно почувствовать легкий цитрусовый запах. Лимон
– хорошо известное культурное растение, выращиваемое уже несколько
тысячелетий. Происхождение его неизвестно; некоторые ученые считают, что
его родина – Северо-Западная Индия. Примерно в начале III века н.э.
лимон начали выращивать на юге Италии, в VIII веке – в Египте и Ираке, в
конце первого тысячелетия – в Китае. К началу второго тысячелетия арабы
распространили его по всему средиземноморскому региону. Христофор Колумб
в одной из своих экспедиций привез семена этого растения в Новый Свет.
Сейчас лимоны выращиваются во многих странах мира. В России их
выращивают в субтропических областях Черноморского побережья. Ветви
искривленные, листья глянцевые овальной формы, цветы очень душистые,
белого или розового цвета. Белые цветы диаметром 2-3 см появляются в
пазухах листьев или на кончиках ветвей, одиночные или собраны в
соцветия. Лепестки, а их бывает 4 или 5, обычно слегка закручиваются
назад. Запах цветов похож на жасминовый и имеет специфический оттенок,
агрессивный у некоторых экземпляров. Каждый цветок держится несколько
дней. Опавшие лепестки продолжают пахнуть, поэтому их можно собирать и
использовать для ароматизации. Плоды, у некоторых культиваров
достигающие диаметра 10 см, окрашены в цвета зеленоватых или желтоватых
оттенков. Кожура может быть тонкой или толстой (до 10 мм), с железками,
выделяющими эфирные масла.

Селекционерами выведено множество культиваров и получены гибриды с
родственными видами. Они отличаются размером и формой, цветом кожуры и
мякоти, балансом сладкого и кислого вкуса, количеством семян или их
отсутствием, лежкостью и некоторыми другими свойствами [35].

Лимон обыкновенный выращивают в Грузии, на Северном Кавказе, в Молдавии
и Средней Азии. Широко культивируют как комнатное растение. В диком виде
неизвестен[4].

Используют в пищевой и кондитерской промышленности. Соком мякоти лимона
выводят пятна на одежде и других вещах, им чистят ножи, металлические
ложки и вилки. Из плодов готовят соки и безалкогольные напитки,
применяют в качестве приправы к диетическим блюдам. В косметической
практике применяют для удаления веснушек и пигментных пятен, в
парфюмерии – для отдушки лосьонов и мазей[22].

Лекарственным сырьем служат свежие плоды.

Из плодов лимона получают эфирное масло, в состав которого входят
лимонен (90%), альфа-пинен, гамма-терпинен, фалландерн, метилгептенон, а
также октиловый, каприловый и нониловый альдегиды. Лимонный сок содержит
лимонную кислоту, сахара, витамины С, А, В и D. В мякоти плода
Обнаружены пектиновые вещества, соли калия, меди и другие микроэлементы.
В кожуре содержатся витамин Р, флавоновые гликозиды, кумарины и
ситостерол [10], [14].

1.2.2 Калина обыкновенная (Viburnuv opulus L.)

Родовое название растения viburnum – от “viere” – вить, плести; “opulus”
– древнее латинское название одного из видов клена – из-за сходства с
его листьями [16].

Ветвистый кустарник или небольшое дерево семейства жимолостных высотой
1,5-4 м с морщинистой буровато-серой корой, усеянной коричневыми
бородавками, и голыми молодыми побегами. Листья супротивные, длиной и
шириной 5-10 см, черешковые, широкояйцевидные или округлые, трех- и
пятилопастные, сверху почти голые, снизу пушистые, летом зеленые, осенью
пурпурные, красные. Цветки белые или бело-розовые, ароматные, собраны в
щитковидные соцветия – метелки. Метелки шириной 5-10 см, плоские,
находятся наверху облиственных веточек. Краевые цветки соцветия
бесплодные, на тонких цветоножках, длиной 1-2 см, белые, плоские шириной
1,3-2,5 см, колосовидный венчик с 5 неравными лопастями служит для
привлечения насекомых; остальные срединные цветки обоеполые, сидячие или
почти сидячие, белые или розовато-белые, колокольчатые, мелкие (до 0,5
см в диаметре), с широкими тупыми лопастями. Тычинок 5, они в 1,5 раза
длиннее венчика [21],[29].

Плоды красные, шаровидные, внутри с одной плоской косточкой диаметром
0,8-1,2 см. На одной кисти бывает 80-100 плодов. Цветет в мае-июне.
Созревают в августе-сентябре. Калина плодоносит на 3-4-м году. После
созревания плоды калины имеют горьковато-сладкий вкус, поэтому есть
поговорка “Не быть калине малиной”. Но после первых морозов (или после
варки) горечь исчезает и калина становится “малиной”, отсюда –
“калинка-малинка”. Однако по своей полезности калина превосходит малину:
железа в ее плодах больше в 1,5 раза, витамина С – в 2, сахаров – даже в
3 раза [21] .

В мире насчитывается около 125 видов калины, в России растет 10, из них
самая распространенная калина обыкновенная. Она распространена в
европейской части России, особенно в средней полосе, лесной и
лесостепной зонах, на Урале и в Сибири. Встречается также в горно-лесных
районах Кавказа, Крыма и Восточного Казахстана. В степные районы
проникает только по долинам рек. Растет рассеянно в сырых лесах,
преимущественно на опушках, полянах, среди зарослей кустарников, на
вырубках, по берегам водоемов. Наиболее обильна в долинах рек. Разводят
в садах и парках как декоративный кустарник [6].

В коре калины содержатся гликозид вибурнин, дубильные вещества
пирокатехиновой группы (около 2%), а также до 6,5% смолы, в состав
омыляемой части которой входят органические кислоты: муравьиная,
уксусная, изовалериановая, каприновая, каприловая, масляная, линолевая,
церотиновая, пальмитиновая, в состав неомыляемой – фитостеролин,
фитостерин, тритерпеновые сапонины (около 6%). Содержит иридоидные
гликозиды (опулусиридоид, ацетилопулусиридоид), хлорогеновую,
неохлорогеновую, кофейную, урсоловую и олеаноловую кислоты, соли
валериановой и каприловой кислот, витамины, сахара [2].

Плоды содержат до 32% инвертного сахара, дубильные вещества (до 3%),
пектиновые вещества, эфирное масло, фитостерины, аминокислоты, танниды
(3%), провитамин А, витамины Р, К, изовалериановую, уксусную и
аскорбиновую кислоты. Кроме того, есть пектиновые вещества и
органические кислоты. В семенах содержится до 21% жирного масла. Калина
выделяет много фитонцидов, убивающих болезнетворные организмы [2].

Плоды калины усиливают работу сердца, оказывают вяжущее,
антисептическое, кровоостанавливающее, желчегонное, мочегонное действие,
понижают кровяное давление, ускоряют заживление ран, язв, останавливают
кровотечения при язвенной болезни желудка и двенадцатиперстной кишки
[34].

Кора калины улучшает функции желудка, кишечника, понижает кровяное
давление, оказывает противоспазматическое, успокаивающее,
кровоостанавливающее, противовоспалительное, антисептическое действие,
тонизирует, повышает трудоспособность. Кора калины усиливает также тонус
мускулатуры матки и оказывает сосудосуживающее действие, связанное с
гликозидом вибурнином, находящимся в коре растения [34].

1.2.3 Шиповник коричный (Rosa majalis)

С конца мая до июля на лесных опушках среди кустарниковых зарослей и по
речным поймам зацветает привлекающий нас крупными душистыми цветками
шиповник. Название растения уже говорит о том, что оно покрыто шипами.
Особенно много шипов на молодых ветвях, которые этим защищаются от
поедания их травоядными животными. На одеревеневших стеблях шиповника
шипов меньше, так как он достаточно хорошо защищен корой [5].

Шиповник был первым растением, которое еще в глубокой древности человек
стал разводить для красоты и за многие века вырастил из него большое
количество видов роз [11].

В России произрастает свыше 60 видов шиповника. Шиповник представляет
собой красивый колючий кустарник. Для заготовок большое значение имеют
два вида: шиповник иглистый и шиповник коричный [12].

Шиповник иглистый имеет буроватые ветви, густо усаженные тонкими,
прямыми, равномерными щетинками. Цветет в июне — июле розовыми цветками.
Плоды яйцевидной формы, гладкие, блестящие. Шиповник иглистый
произрастает в лесной зоне, заходит в тундру от Тихого океана до
Ленинграда, но к западу, от Онежского озера, изреживается [11].

Шиповник коричный в отличие от шиповника иглистого растет по поймам рек,
среди кустарников и в лесах. Ветви блестящие, красно-коричневые.
Цветоносные стебли снабжены загнутыми книзу шипами, расположенными
попарно у основания черешка, а листоносные побеги, кроме того, усажены
тонкими прямыми шипами неравной длины. Шиповник коричный произрастает
почти по всей Европейской территории России, особенно на севере [21].

Неприхотливый колючий кустарник — дикая роза.

Витамина С в плодах шиповника больше, чем в смородине и лимоне. Имеются
витамины группы В, К, Р, каротин, сахара, дубильные вещества,
органические кислоты, пектины, микроэлементы. В семенах содержится
витамин Е. Препараты плодов этого природного поливитаминного концентрата
используют для профилактики и лечения цинги, куриной слепоты и других
авитаминозов, при малокровии, хлорозе, атеросклерозе, гипертонии,
различных кровотечениях, других заболеваниях. Собирают плоды шиповника
до заморозков [20], [34].

В корнях много дубильных веществ, поэтому их используют в качестве
вяжущего средства.

Из семян шиповника получают масло, содержащее жирные кислоты и витамины.
Оно обладает противовоспалитёльными и ранозаживляющими свойствами [22].

1.2.4 Биология чайного листа (Thea)

Большинство потребителей привыкло различать чаи в основном по району
произрастания: китайский, индийский, цейлонский, грузинский,
краснодарский и т.д.

Все многообразие чаев делится на три основные типа: черный, зеленый,
оолонги (красные и желтые чаи). Цвет является лишь внешним отражением
различий в биохимических процессах обработки чайного листа, что в
конечном счете оказывает влияние на химический состав и основные
вкусовые и ароматические признаки каждого типа чая [28], [38], [42],
[44].

Красный и желтый чаи являются промежуточными типами между черным и
зеленым. Красные чаи ближе стоят к черным, а желтые – к зеленым [44].

Биологическое название чая каркаде – гибискус сабдарифа. Гибискус
сабдарифа относится к семейству мальвовых (Malvaceae).

В мире насчитывается более 150 видов гибискуса. Гибискус сабдарифа
представляет собой кустарниковое однолетнее, высотой до 3.5 м, растение
разветвленной формы, с глубоко внедренной в грунт корневой системой
[46].

Стебель и листья – зеленого цвета, с красноватыми оттенками. Листья
верхней части кустарника гладкие, пальмообразные, разделенные на 3-7
долей с зубчатыми опушками; в нижней части растения форма листьев –
овальная. Цветки очень крупные, (5-7) cм в диаметре, с короткой
цветоножкой и толстыми лепестками. По цвету они ярко-красные с
темно-фиолетовым венчиком снаружи и темно-пурпурным внутри. У основания
лепестков встречается желтое, иногда коричневое пятно. Чашечки цветков
гибискуса (та часть, которая высушивается и используется в качестве чая)
красноватого, иногда зеленоватого цвета. После окончания цветения,
чашечка приобретает светло-красный оттенок, увеличивается в размерах,
становятся мясистой и сочной [46].

Мате – чаеподобный напиток, который получается из сухих листьев
вечнозеленого тропического дерева Illex Paraguariensis. Оно представляет
собой ветвистое дерево-кустарник, которое в диких условиях живет до 50
лет и достигает в высоту до 15 метров [39].

Доля белков и аминокислот в составе чая — 16-25%, доля сахаров и
углеводов — 10-16%.

Белков в чайном листе больше, чем всего остального, т.к. именно из них
состоит в основном клетчатка чайного листа. Кроме того, в чае много
разных белковосодеращих соединений, например, ферментов [47].

Основными растворимыми белками чая являются альбумины, которых в зеленом
чае до 10% (в черном поменьше).

В экстремальных ситуациях чай является комплексной диетической пищей,
которая полноценно восполняет в организме нехватку белков и витаминов.

В чае содержится также более 17 аминокислот, часть из которых находится
в свободном состоянии. Аминокислоты вносят значительный вклад в создание
своеобразного аромата чая [38].

До 12% полисахаридов, содержащихся в чае (крахмал, целлюлоза,
гемицеллюлоза и др.), нерастворимы, и потому бесполезны. Мало того, чем
больше сахаров и углеводов в чае, тем хуже его качество.1) Сахара (такие
как фруктоза, глюкоза, мальтоза) — 0,73-1,41%. 2) Крахмал — 0,82 – 2,96
%.

3) Пектины — 6,1% [47].

Пектины способствуют заживлению ран, снижают содержание холестерина в
крови, улучшают обмен желчных кислот, нейтрализуют токсичность и
побочные эффекты антибиотиков. Пектины благотворно влияют на слизистые
оболочки носоглотки, горла, пищевода, желудка и т.д., обволакивая их
своеобразным защитным слоем [47].

Например, обжечься горячим чаем сложнее, чем голым кипятком, т.к. именно
пектины защищают слизистые от ожога. Это свойство, в сочетании с
дубильными способностями танинов делает чай отличным противоожоговым и
противовоспалительным средством [15].

От содержания пектинов напрямую зависит и гигроскопичность сухой
заварки. Чем больше пектинов, тем лучше чай защищен от посторонних
запахов, тем дольше он сохраняет свой аромат и тем дольше хранится [47].

Минеральных веществ в чае 4-7%. Но в общем, можно выделить макро- и
микроэлементы [48].

Макроэлементы чая, мг/г: калий–17,90, кальций–4,70, магний–2,20, железо
– 0,20.

Про макроэлементы. С одной стороны нормальная концентрация калия в крови
является обязательным условием функционирования сердечной мышцы; с
другой стороны, в нервных клетках существует такая вещь как
калиево-натриевый баланс, без которого невозможно нормальное ее
функционирование [48].

ЭлементСодержаниеЭлемент СодержаниеАлюминий

Марганец

Сера

Натрий

Бор

Барий

Цинк

Медь 843,40.

828,00.

650,0

210,00.

95,00

56,08.

22,90

11,60Стронций

Никель

Свинец

Кобальт

Молибден

Хром

Селен

Йод 5,84

5,20.

2,48

1,68.

0,40.

0,40

0,12.

0,10

Таблица 1

Микроэлементы чая, мкг/г

Есть также данные о большом содержании в чае – примерно 0,3% от сухого
веса – фосфора. Фосфор – это незаменимое вещество для активизации работы
мозга. Также есть данные о весьма значительном содержании фтора в чае –
около 0,2% от сухого веса [48].

Кроме этого чай преимущественно накапливает в себе и является ценным
носителем таких элементов: алюминий, марганец, бор, барий, цинк, медь,
никель. Очень хорошо из чая организмом усваиваются прежде всего
марганец, цинк, медь, никель [40].

Доля пигментов в химическом составе чая – 1-12%. Пигменты – это
красители. В чайном настое можно увидеть желто-зелено-красно-фиолетово –
коричнево-бурые цвета и оттенки, которые задаются немногочисленными
пигментами. Причем первые два более актуальны для неферментированных
чаев, а вторые два – для улунов и черных [36].

1) Хлорофилл. Этот пигмент дает зеленую окраску живому растущему чайному
листу. При термических обработках он в значительной мере разрушается и в
большей мере остается лишь в неферментированных чаях (белом, зеленом и
т.п.)

2) Каротин и ксантофилл. При термической обработке темнеют, отчасти
участвуют в придании чаю красновато-бурого цвета. Хотя их в чае немного.

3) Теофлавин. В чае около 1-2%. Придает чайному настою золотисто-желтую
гамму. Высокое содержание теофлавина характерно для качественных
сортовых чаев. Если его мало, чай тусклый, блеклый, производит
впечатление слегка мутноватого.

4) Теарубигин. В чае 10-20%. Придает чайному настою красно-коричневую
гамму. В идийском агротипе чая теарубигин более темный (коричневый,
бурый), в китайском – более светлый (красный) [36].

Теофлавин и теарубигин являются производными от чайных полифенолов. Оба
пигмента образуются в процессе ферментации. Их химические структуры
весьма похожи, но при этом теофлавин является более химически активным
(соответственно – легче разрушается) и легко переходит в теарубигин.

В хорошем черном чае соотношение теафлавина и теарубигина должно быть
1/10 [36].

Наиболее важной составной частью чайного листа и готового чая является
комплекс дубильных веществ, или так называемый чайный танин,
обуславливающий не только органолептические свойства, но и биологическую
ценность продукта. Теотанин – белое вещество вяжущего вкуса растворимое
в воде и сообщающее напитку специфическую терпкость и крепость, выделил
голландский химик Деусс. Установлено, что основными аккумуляторами
танина служат двух-трехлетние побеги, а еще точнее – почка и первый
лист, где его накапливается до 30%. В огрубевшем листе запасы дубильных
веществ резко снижаются. Чем выше сорт сырья, тем больше танина в
готовой продукции – до 18%. Окислительные во время ферментации
лимонно-желтые танины придают настою характерную темно-золотую окраску,
дополняют аромат [38].

Танин – полимерное фенольное соединение. Вместе с полифенолами в
растении присутствуют и разнообразные мономерные соединения фенола.
Среди них – группа окислительных кислот (галловая, салициловая и
протокатехиновая), производные коричной кислоты и лактоны (кумарины,
теогалин, кофейная, хлорогеновая, и кумаричная кислоты). В создании
вкуса байхового чая участвуют также красящие вещества – антоцианы с их
красно-фиолетовой палитрой [31].

Вопрос образования, превращения и условий накопления фенольных
соединений – центральный в биохимии и физиологии чая. Основным
компонентом сложного танинового комплекса являются катехины. Эти
бесцветные кристаллические вещества впервые выявлены в 30-х годах
прошлого века Ф. Руже. Хорошо растворимые в горячей воде, легко
окисляются, они теряют при этом горький вкус и приобретают
красновато-коричневый оттенок. Их экстракт применяют не только для
дубления кож, но и для крашения х/б тканей, ароматизации какао, кофе,
чая, вина, пива и табака. Сегодня известно более чем двести видов
растений – носителей катехина, выполняющего функции передатчиков
водорода в процессе дыхания [31].

Являясь составной частью дубильных веществ, катехины во многом
превосходят те свойства, которыми славятся танины. Как и танины,
катехины обладают антимикробными свойствами. Отваром зеленого чая
успешно излечивают больных дизентерией. Чайные катехины способны
увеличивать отложение витамина C, задержать его выведение из организма,
предохранить от заболевания цингой [27].

Доля полифенолов в составе чая колеблется от 9 до 35% .Фенольные
соединения — один из наиболее распространенных и многочисленных классов
природных соединений, обладающих биологической активностью. Активность
обеспечивается наличием свободного или связанного фенольного гидроксила.
Фенольные соединения делятся на три группы:

1) Простые фенолы (фенилы, фенолоспирты, фенолокислоты, кумарины и др.)
с одним ароматическим кольцом;

2) Фенолы с двумя ароматическими кольцами (флавоноиды, флавоны,
изофлавоноиды и др.);

3) Полимерные фенолы (полифенолы).

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Эпикатехин. Один из полифенолов чая. Молекулярный вес — 290.

Более активными являются фенольные соединения первой и второй групп,
которые обладают широчайшим спектром фармакологического действия
(антимикробное, адаптогенное и стимулирующее, мочегонное, Р-витаминное,
кровоостанавливающее, гипотензивное, протиивораковое), и которые в
незначительном количестве содержатся и в чае. К сожалению, многие
фенольные соединения 1 и 2 групп, которые в значительной мере
присутствуют в растущем чайном листе, при изготовлении чая в
значительной мере утрачиваются, остаются преимущественно полифенолы.
Следует отметить, что наиболее богаты активными фенольными соединениями
белый и зеленый чаи [36].

В чае содержится более 30 полифенолов, которые по традиции называют
дубильными веществами или танинами. Дело в том, что полифенолы способны
образовывать весьма устойчивые химические соединения с белками, что и
приводит к «дубильному эффекту». Данный эффект имеет хорошее
фармацевтическое применение — полифенолы чая действуют как
кровоостанавливающие, ранозаживляющие, вяжущие, противовоспалительные и
бактерицидные средства [44].

Преобладающими водорастворимыми полифенолами чая являются:
галлокатехингаллат, l-эпикатехингаллат, l-эпигаллокатехин,
dl-галлокатехин, l-галлокатехингаллат, l-эпикатехин, свободная галловая
кислота. Некоторые дубильные вещества находятся в связанном состоянии с
протеинами и алкалоидами [26].

Некоторые из полифенолов обладают свойствами витамина Р: улучшают
пищеварение, укрепляют кровеносные сосуды и мелкие капилляры, снижают
проницаемость их стенок. В соединении с кофеином придают чаю значение
уникального стимулятора мозга. Следует также отметить, что полный набор
кахетинов характерен лишь для зеленого чая, в черном их весьма мало
[26].

При заваривани чая необходимо учитывать, что танины активно реагируют с
железом. При заваривании чая в железной посуде (или с использованием
богатой железом воды) получается мутная бурая («ржавая») заварка. Кислая
среда, напротив, осветляет заварку (всем известно действие на чай
лимона) [28].

Полифенолы хорошо растворяются только в горячей воде. Именно поэтому чай
заваривают кипятком. После того, как заварка остывает, она зачастую
мутнеет — это также свойство полифенолов. Если при охлаждении заварка не
мутнеет — это показатель того, что содержание полифенолов в сырье явно
недостаточно. Если помутневшую заварку подогреть на несильном огне, то
она вновь станет прозрачной [36].

Чем больше в чае танинов, тем более терпким и вяжущим вкусом он обладает
[36].

Полифенолы чая сейчас активно исследуются, т.к. среди них еще многие не
изучены; также исследуется химический синтез новых фенольных соединений
в ходе ферментации [26].

Глава 2. Материалы и методы исследования

2.1 Объекты

Объектом изучения являются плоды калины обыкновенной, шиповника
коричного и лимона обыкновенного, различные сорта чая. Предметом
изучения является антиоксидантная активность исследуемых материалов.

В период с 12.09.2007 г. по 31.10.2007 г. отбирали 3 раза в неделю по
10-15 ягод с калины обыкновенной г. Славянска – на – Кубани, п. Кубрис.
Ягоды срывали вместе с плодоножками, чтобы не повредить их
герметичность, по несколько штук с разных кистей для большей
достоверности опыта.

Для исследования содержания танинов в чае выбрали следующие сорта: мате
зеленый, красный чай «Ройбуш», белый ч? «Ветер поднебесный», зеленый чай
«Лазурная россыпь» и черный чай «Лисма».

2.2 Материалы исследования

Реактивы и оборудование: бюксы, эксикатор, ступка с пестиком, вата,
стеклянная воронка, установка для титрования, дистиллированная вода,
0,5% раствор крахмала, раствор 0,003 Н йода.

Приготовление растворов

1. 0,5 % раствор крахмала. В дистиллированную воду объёмом 30 мл
прибавили 0,5 г порошка крахмала, тщательно перемешали и нагрели до
кипения. В полученный раствор прилили 70 мл холодной дистиллированной
воды и охладили.

2. Раствор 0,003 н йода. К 97 мл дистиллированной воды прилили 3 мл 0,1
н раствора йода.

3. Подготовка пробы чая к анализу для определения содержания танина.

2,5 г предварительно измельченной навески чая, взятой из средней пробы,
с погрешностью взвешивания не более 0,0002 г, помещают в колбу
вместимостью 250 см3, приливают 200 см3 кипящей дистиллированной воды и
ставят на водяную баню. Экстракцию ведут в течение 45 минут. Экстракт
фильтруют под вакуумом через воронку Бюхнера в колбу вместимостью 500
см3, фильтрат переносят в мерную колбу вместимостью 250 см3, охлаждают и
доводят дистиллированной водой до метки.

2.3 Методы исследования

Определение влажности плодов

Растереть в ступке 2 г плодов. Полученную массу поместить в бюкс, массу
которого определить заранее. Бюкс поставить в эксикатор при температуре
70єС на сутки. По истечении времени измерить массу бюкса. Вычислить
абсолютно сухое вещество по формуле:

Mа.с.в.= m1-m2,

Где: Mа.с.в- – масса абсолютно сухого вещества;

m1 – масса пустого бюкса;

m2 – масса бюкса с плодами после высушивания.

Влажность вычислить по формуле:

W= ((а 1 – а 2 ) а1) • 100%,

Где:

W- влажность,%;

а 1- масса навески до высушивания, г;

а 2 – масса навески после высушивания, г [33].

Определение витамина С в исследуемых материалах

2 г плодов растереть в ступке. Полученную массу перенести в стаканчик и
добавить 10 мл 2% раствора HCl. Тщательно перемешать и отфильтровать
через стеклянную воронку с ватой в коническую колбу на 50-100 мл. Массу
на фильтре промыть несколькими каплями воды. В фильтрат прилить 1 мл
0,5% раствора крахмала и оттитровать рабочим раствором 0.003 Н йода до
появления синего окрашивания.

При расчете содержания витамина С в продукте использовать формулу
определения массы:

М= ((н•Э)1000)•V,

Где : н- молярная концентрация эквивалента йода;

Э- молярная концентрация эквивалента витамина С, равная 88 г;

V- объем пошедшего на титрование йода, мл.

Для более точного количественного определения витамина С проводить
параллельные опыты [33].

Определение содержания танина в чае [36]

Определение проводилось согласно ГОСТ 19885-74.

Метод основан на окислении танина чая марганцевокислым калием в
присутствии индигокармина в качестве индикатора.

Пипеткой отбирают 10 см3 экстракта и помещают в выпарительную чашу,
добавляют 750 см3 водопроводной воды, 25 см3 раствора индигокармина и
титруют 0,1 моль/дм3 раствором марганцовокислого калия при постоянном
перемешивании стеклянной палочкой. Синяя окраска при этом постепенно
переходит через сине-зеленую, темно- и светло-зеленую, желто-зеленую в
желтую золотистого оттенка.

Конец реакции определяют по исчезновению зеленого оттенка и появлению
чистого желтого цвета. Затем подсчитывают количество 0,1 моль/дм3
раствора марганцовокислого калия в см3, израсходованное на окисление
танина.

Аналогичным образом устанавливают количество марганцовокислого калия,
израсходованное на титрование раствора воды и индигокармина.

Количество танина (А1) в процентах определяют по формуле:
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,

где а – количество 0,1 моль/дм3 раствора марганцовокислого калия,
израсходованное на окисление танина, см3;

а1 – количество 0,1 моль/дм3 раствора марганцовокислого калия,
израсходованное на титрование раствора воды и индигокармина, см3;

0,004157 – количество танина, окисляемое 1 см3 0,1 моль/дм3 раствора
марганцовокислого калия, г;

х – количество полученного экстракта чая, см3;

х1 – количество экстракта чая, взятое для испытания, см3;

m – масса навески абсолютно сухого чая, г;

За результат анализа принимают среднее арифметическое двух параллельных
определений, расхождение между которыми не должно превышать 0,5% для
р=0,95.

Если результат анализа попадает вблизи значения нормы содержания танина
для соответствующего вида чая, то необходимо проведение двух
дополнительных определений. В этом случае за результат анализа принимают
среднее арифметическое двух параллельных определений, расхождение между
которыми не должно превышать 0,7% для р=0,95. [9]

Определение влияния компонентов чая на антиоксидантную активность

Количество витамина С в лимоне обыкновенном определяют по методике.

В экстракт чая каждого из сортов добавить 2 мл сока лимона, определить
содержание витамина С. Через 1 час находят содержание аскорбиновой
кислоты в каждом из сортов. Сравнивают содержание витамина С до и после
выдерживаемого времени [33].

Глава 3. Результаты исследования и их обсуждение. Изучение
антиоксидантной активности растений

3.1 Определение содержания витамина С в калине обыкновенной в период
созревания

В измельченной массе плодов калины обыкновенной определили влажность
всех отбираемых образцов. Влажность плодов калины обыкновенной во время
созревания в период с 12.09 по 31.10 варьирует в пределах от 60% до
78,5%. Наибольшая влажность в плодах калины обыкновенной отмечмна в
период созревания с 12 по 19 октября.

W,%
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Рисунок 1. Влажность плодов калины обыкновенной в период созревания

Общеизвестно, что в калине высокое содержание витамина С. Плоды калины
обыкновенной широко используют в качестве источника этого витамина.

С 12.03.2007 г по 31. 10. 2007 г с периодичностью в 3 дня были отобраны
плоды калины обыкновенной, произрастающей в п. Кубрис Славянского
района.

Используя метод йодиметрического титрования, определили содержание
витамина С в каждой пробе согласно методике.

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ffff030000001e00030000001e00040000002c010000070000001604b502e20207000700
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ffff030000001e00030000001e00040000002c010000070000001604b502e20207000700
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6d616e003f3f003f003f003f00003f3f3f303f30040000002d010300040000002e011800
04000000020101000500000009020000000209000000320afb00450001000000338f0900
040000002d01060004000000f0010300040000002701ffff040000002701ffff03000000
1e00030000001e00040000002c010000070000001604b502e202070007001c000000fb02
eeff0000000000009001000000cc0400061254696d6573204e657720526f6d616e00003f
003f003f003f00003f3f3f303f30040000002d010300040000002e011800040000000201
0100050000000902000000020c000000320ac800370003000000332c35000a0004000900
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1e00030000001e00040000002c010000070000001604720269002d0255001c000000fb02
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003f003f003f00003f3f3f303f30040000002d010300040000002e011800040000000201
01000500000009020000000208000000320a3702590001000000313208000000320a4002
590001000000322e08000000320a4a025900010000002ef108000000320a4e0259000100
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1e00030000001e00040000002c0100000700000016047202c1002d02ac001c000000fb02
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003f003f003f00003f3f3f303f30040000002d010300040000002e011800040000000201
01000500000009020000000208000000320a3702b00001000000313908000000320a4002
b00001000000392e08000000320a4a02b000010000002ef108000000320a4e02b0000100
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01000500000009020000000208000000320a3702070101000000323608000000320a4002
070101000000362e08000000320a4a020701010000002ef108000000320a4e0207010100
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1e00030000001e00040000002c010000070000001604720270012d025a011c000000fb02
eeff0000000000009001000000cc0400061254696d6573204e657720526f6d616e00003f
003f003f003f00003f3f3f303f30040000002d010300040000002e011800040000000201
01000500000009020000000208000000320a37025f0101000000303308000000320a4002
5f0101000000332e08000000320a4a025f01010000002eee08000000320a4e025f010100
0000eeea08000000320a57025f0101000000eaf208000000320a5f025f0101000000f2f1
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1e00030000001e00040000002c0100000700000016047202c6012d02b2011c000000fb02
eeff0000000000009001000000cc0400061254696d6573204e657720526f6d616e00003f
003f003f003f00003f3f3f303f30040000002d010300040000002e011800040000000201
01000500000009020000000208000000320a3702b60101000000313008000000320a4002
b60101000000302e08000000320a4a02b601010000002eee08000000320a4e02b6010100
0000eeea08000000320a5702b60101000000eaf208000000320a5f02b60101000000f2f1
040000002d01060004000000f0010300040000002701ffff040000002701ffff03000000
1e00030000001e00040000002c01000007000000160472021e022d0209021c000000fb02
eeff0000000000009001000000cc0400061254696d6573204e657720526f6d616e00003f
003f003f003f00003f3f3f303f30040000002d010300040000002e011800040000000201
01000500000009020000000208000000320a37020d0201000000313708000000320a4002
0d0201000000372e08000000320a4a020d02010000002eee08000000320a4e020d020100
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1e00030000001e00040000002c010000070000001604720275022d0261021c000000fb02
eeff0000000000009001000000cc0400061254696d6573204e657720526f6d616e00003f
003f003f003f00003f3f3f303f30040000002d010300040000002e011800040000000201
01000500000009020000000208000000320a3702640201000000323408000000320a4002
640201000000342e08000000320a4a026402010000002eee08000000320a4e0264020100
0000eeea08000000320a5702640201000000eaf208000000320a5f02640201000000f2f1
040000002d01060004000000f0010300040000002701ffff040000002701ffff03000000
1e00030000001e00040000002c0100000700000016044b02c600260007001c000000fb02
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003f003f003f00003f3f3f303f30040000002d010300040000002e011800040000000201
01000500000009020000000218000000320a3f0014000b000000d1eee4e5f0e6e0ede8e5
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2c0100000700000016044b02c600260007001c000000fb02e6ff00000000000090010000
00cc0400061254696d6573204e657720526f6d616e000000003f003f003f00003f3f3f30
3f30040000002d010300040000002e011800040000000201010005000000090200000002
15000000320a5d00230009000000e2e8f2e0ece8ede020e50c000e000a000d0010000d00
0e000c000400040000002d01060004000000f0010300040000002701ffff040000002701
ffff030000001e00030000001e00040000002c0100000700000016044b02c60026000700
1c000000fb02e6ff0000000000009001000000cc0400061254696d6573204e657720526f
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0400000002010100050000000902000000020d000000320a7900140004000000d12c20e3
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07001c000000fb02e6ff0000000000009001000000cc0400061254696d6573204e657720
526f6d616e00003f003f003f003f00003f3f3f303f30040000002d010300040000002e01
180004000000020101000500000009020000000209000000320a79003b00010000005c8f
0700040000002d01060004000000f0010300040000002701ffff040000002701ffff0300
00001e00030000001e00040000002c0100000700000016044b02c600260007001c000000
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1604b502b6026e0250001c000000fb02e6ff0000000000009001000000cc040006125469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Анализ результатов показал, что содержание витамина С меняется в период
созревания и зависит от срока созревания плодов калины обыкновенной. В
период с 12 сентября по 12 октября содержание аскорбиновой кислоты
изменяется с 1,44г по 2,78г на 100 г а.с.в. В период с 12 по 19 октября
отмечена наибольшая интенсивность накопления витамина С, что составляет
3,1г кислоты на 100г сухого вещества. В период с 19 по 31 октября
содержание падает до 2,37г на 100г сухого вещества.

Проследив динамику изменения витамина С можно сделать вывод о том, что
оптимальным временем сбора калины является период с 12 по 19 октября,
так как в этот период происходит максимальное накопление аскорбиновой
кислоты в плодах калины обыкновенной.

3.2 Определение антиоксидантной активности лимона обыкновенного,
шиповника коричного и различных сортов чая

Антиоксидантную активность растительных материалов определяли по
содержанию витамина С методом йодиметрического титрования аналогично
определению содержания витамина С в калине обыкновенной. Для
исследования были взяты следующие растительные материалы: лимон
обыкновенный, калину обыкновенная, шиповник коричный и сорта чая: мате
зеленый, красный чай «Ройбуш», белый ?й «Ветер поднебесный», зеленый чай
«Лазурная россыпь» и черный чай «Лисма».

Полученные результаты представлены на рисунках 3,4.
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00000000

Из полученных результатов видно, что самое высокое содержание витамина С
в калине обыкновенной – 3,1 г/ 100 г а.с.в., в шиповнике витамина меньше
по сравнению с содержанием его в калине и составляет 1,2 г/ 100 г а.с.в.
Содержание аскорбиновой кислоты в лимоне обыкновенном – 0,04 г/ 100 г
а.с.в., что по значению меньше, чем содержание витамина в калине и
шиповнике.

Для анализа антиоксидантной активности сортов чая было определено
содержание витамина С в мате зеленом, красном чае «Ройбуш», белом ?е
«Ветер поднебесный», зеленом чае «Лазурная россыпь» и черном чае
«Лисма». Полученные результаты исследования приведены на рисунке 4.

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