EUeA?ANUeEEE AeA?AEAAIEE OI?AA?NEOAO

?IAI? ?AAIA O?AIEA

II?IC

??eia ?aaai?aia

OAeE 535.37+536.361

OIIIII? NIAEO?E IAE?I?EIIIIOE*IEO

E?ENOAE?A

LiB3O5, b-BaB2O4, Li2B4O7

01.04.10 – O?ceea iai?ai?ia?aeiee?a ? ae?aeaeo?ee?a

A a o i ? a o a ? a o

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?ceei-iaoaiaoe/ieo iaoe

EUeA?A – 1999

Aeena?oaoe??th ? ?oeiien.

?iaioa aeeiiaia ia eaoaae?? aenia?eiaioaeueii? o?ceee Euea?anueeiai
aea?aeaaiiai oi?aa?neoaoo ?iai? ?aaia O?aiea.

Iaoeiaee ea??aiee: aeieoi? o?ceei-iaoaiaoe/ieo iaoe,

i?ioani? Aeiaaee ss?ineaa
Inoaiiae/,

Euea?anueeee aea?aeaaiee
oi?aa?neoao ?iai? ?aaia O?aiea,

i?ioani? eaoaae?e
aenia?eiaioaeueii? o?ceee.

Io?oe?ei? iiiiaioe: aeieoi? o?ceei-iaoaiaoe/ieo iaoe,

i?ioani? Iinaiei Aiaoie?e
??io?eiae/,

Euea?anueeee aea?aeaaiee
oi?aa?neoao ?iai? ?aaia O?aiea,

i?ioani? eaoaae?e o?ceee
iai?ai?ia?aeiee?a;

aeieoi? o?ceei-iaoaiaoe/ieo iaoe,

??cae Aaneeue Ieoaeeiae/,

Oaeai?iaenueeee aea?aeaaiee
oi?aa?neoao,

i?ioani? eaoaae?e o?ceee
iai?ai?ia?aeiee?a.

I?ia?aeia onoaiiaa: ?inoeooo o?ceee Iaoe?iiaeueii? aeaaeai?? iaoe
Oe?a?ie,

a?aeae?e iioe/ieo aeanoeainoae
e?enoae?a, i.Ee?a.

Caoeno a?aeaoaeaoueny 8 aa?aniy 1999 ?. i 15 aiae. 30 oa. ia can?aeaii?
niaoe?ae?ciaaii? a/aii? ?aaee Ae.35.051.09 i?e Euea?anueeiio
aea?aeaaiiio oi?aa?neoao? ?iai? ?aaia O?aiea (290005, i.Euea?a, aoe.
Ae?aaiiaiiaa, 50, aoae. ?1).

C aeena?oaoe??th iiaeia iciaeiieoeny a iaoeia?e a?ae?ioaoe?
Euea?anueeiai aea?-aeaaiiai oi?aa?neoaoo ?iai? ?aaia O?aiea (290005,
i.Euea?a, aoe. Ae?aaiiaiiaa, 5).

Aaoi?aoa?ao ?ic?neaii 21 eeiiy 1999 ?ieo.

A/aiee nae?aoa?

niaoe?ae?ciaaii? a/aii? ?aaee,

aeieoi? o?ceei-iaoaiaoe/ieo iaoe,

i?ioani?
Aeaaee?anueeee E.O.

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeuei?noue oaie. Na?aae iaaeaaii neioaciaaieo iae?i?eiiiioe/ieo
iaoa??ae?a iniaeeaee ?ioa?an i?aaenoaaeythoue niieoee eeano ai?ao?a.
Aiie i?i-ci?? o oe?ieiio ae?aiacii? aeiaaeei oaeeue (a?ae aaeooiiiai
oeueo?ao?ieaoo aei aeecueei? ?io?a/a?aiii? iaeano?), ?aae?aoe?eii no?ee?
oa oa?aeoa?ecothoueny aenieei ii?iaii iioe/ii? no?eeino?. Iiiie?enoaee
LiB3O5 oa b-BaB2O4 ? ia?niae-oeaieie aeey aeei?enoaiiy o i?eno?iyo
iae?i?eii? iioeee, aea aiie ca aa-ee/eiaie iae?i?eieo ni?eeiyoeeainoae
ia?aaa?oothoue oae? o?aaeeoe?ei? iaoa??aee ye KD?, DKDP oa KTP. ?ioee
i?aaenoaaiee ai?ao?a – oao?aai?ao e?o?th Li2B4O7 — ? i’?ciaeaeo?eeii,
i?eaeaoiei aeey aeei?enoaiiy a aeonoi-aeaeo?ii?oe?.

Iacaaaeath/e ia cia/io e?euee?noue iaoeiaeo ioae?eaoe?e, i?enay/aieo
aea/aiith o?ceei-o?i?/ieo oa iae?i?eiiiioe/ieo aeanoeainoae ieene?a
ai?ao?a, aaaaoi caaea/ caeeoathoueny ua ia ae??oaieie. Ianaiia?aae oea
noino?oueny aeine?aeaeaiiy oiiiiieo niaeo??a oa aieeao aeeiai?ee a?aoee
ia iae?i?ei? ia?aiao?e.

E?enoaee LiB3O5, b-BaB2O4 oa Li2B4O7 neeaaeathoueny c oa?aeoa?ieo
ai?-eeniaaeo no?oeoo?ieo o?aaiaio?a, aecia/aeueieo o oi?ioaaii?
no?oeoo?e oi-iiiieo niaeo??a, ? a?ae??ciythoueny eeoa eao?iiiith
i?aenenoaiith. Naia eeanoa?e (A3I6)3-, (A3I7)5- oa (A4I9)6-
a?aeiia?aeathoue ca iniiai? aeanoeaino? aeacaieo iaoa-??ae?a. Ca ?o
aeeiai?/ieie oa?aeoa?enoeeaie iiaeia ioe?ieoe ia?aiao?e o?i?/ieo
ca’yce?a ? ia oe?e iniia? ae?iaeoe iaai? ?aeiiaiaeaoe?? uiaei ea?oaaiiy
?o aeanoe-ainoyie ia noaae?? neioaco.

O ca’yceo c oeei aeine?aeaeaiiy oiiiiieo niaeo??a ? aeeiai?ee a?aoee
e?enoa-e?a LiB3O5, b-BaB2O4 oa Li2B4O7 ? aeooaeueieie ye c i?aeoe/ii?
oi/ee ci?o, oae ? c i??eoaaiue ?icoeo?oaaiiy no?oeoo?e ?o iioe/ieo
ooieoe?e.

Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie. Aeena?oaoe?eia ?iaioa aeei-iaia
ia eaoaae?? aenia?eiaioaeueii? o?ceee Euea?anueeiai aea?aeaaiiai
oi?aa?neoaoo ?iai? ?aaia O?aiea o ?aieao aea?aeaaiiai i?iaeoo
07.01.01./009-92 «?ic?iaea oaoiieia??, neioac oa aeine?aeaeaiiy iiaiai
eeano iaoa??ae?a aeey eaca?ieo ia?aoai-?thaa/?a».

Iaoa ? caaea/? aeine?aeaeaiiy. C’ynoaaiiy ?ie? oiiiiii? i?aenenoaie o
oi?ioaaii? iae?i?eiiiioe/iiai a?aeaoeo iiiie?enoae?a LiB3O5, b-BaB2O4 oa
Li2B4O7 oa ae?iaeaiiy aeayeeo ?aeiiaiaeaoe?e aeey i?iaiicoaaiiy
iae?i?eii-iioe/ieo ia?aiao??a oeeo iaoa??ae?a.

Aeey aeinyaiaiiy iaoe ?ica’ycoaaeeny oae? caaea/?:

1. Aea/aiiy no?oeoo?e ?* niaeo??a a?aeaeaaiiy oa niaeo??a
eiia?iaoe?eiiai ?icn?thaaiiy iiiie?enoae?a LiB3O5, b-BaB2O4 oa Li2B4O7.

2. ?ic?aooiie oa?aeoa?enoe/ieo /anoio oiiiiieo niaeo??a
aeine?aeaeoaa-ieo e?enoae?a.

3. Aecia/aiiy aianeo iniiaieo no?oeoo?ieo ai?-eeniaaeo o?aaiaio?a
ii-iie?enoae?a ieene?a ai?ao?a o aeeiai?eo a?aoee.

4. Aeine?aeaeaiiy aieeao aeii?oie ia oiiiiiee niaeo? oao?aai?aoo e?o?th.

Iaoeiaa iiaecia iaea?aeaieo ?acoeueoao?a.

1. Aei??yii oa ?icoeo?iaaii niaeo?e eiia?iaoe?eiiai ?icn?thaaiiy
na?o-ea oa niaeo?e ?io?a/a?aiiiai iiaeeiaiiy aeey iiiie?enoae?a LiB3O5,
b-BaB2O4, Li2B4O7.

2. I?iaaaeaii ioe?ieo oei?a o?i?/ieo ca’yce?a iiiie?enoae?a ieene?a
ai?ao?a.

3. Aeine?aeaeaii aieea aeii?oee n??aea ia no?oeoo?o ?*-niaeo?a
iiiie?en-oaea Li2B4O7, ca aeiiiiiaith /iai aia?oa i?iaaaeaii
?aeaioeo?eaoe?th aeniei/an-oioieo nioa oiiiiiiai niaeo?a.

4. ?ic?aoiaaii eieeai? /anoioe aaoa-ai?aoo aa??th. Ii??aiyiiy io?eiaieo
?acoeueoao?a c aenia?eiaioaeueieie aeaieie na?ae/eoue ia ei?enoue
eeanoa?iiai i?ae-oiaeo o ieoaii? aea/aiiy aeeiai?ee a?aoee neeaaeieo
no?oeoo?.

5. Ioe?iaii aianie aeaeo?iiii? oa oiiiiii? eiiiiiaio o iae?i?ei?
ni?ee-iyoeeaino? iiiie?enoae?a LiB3O5, b-BaB2O4 oa Li2B4O7.

I?aeoe/ia cia/aiiy iaea?aeaieo ?acoeueoao?a. ?icaeiooi i?aeo?ae aei
?ic-?aooieo eieeaieo /anoio neeaaeieo niieoe oeio ieene?a ai?ao?a, ui
aaco?oueny ia eeanoa?i?e iiaeae?. ?acoeueoaoe ?iaioe aeathoue ciiao
aeeaoa c?icoi?oe ?ieue aianeo oiiiiii? neeaaeiai? o iae?i?eiiiioe/i?
ni?eeiyoeeaino? iiiie?enoae?a LiB3O5, b-BaB2O4 oa Li2B4O7. Io?eiaii
?ioi?iaoe?th aeey i?iaiicoaaiiy iae?i?eiiii-oe/ieo ia?aiao??a oeeo
iaoa??ae?a ia iniia? eeanoa?ii? iiaeae?.

Iniaenoee aianie caeiaoaa/a. Iniaenoee aianie aeena?oaioa iieyaa? o
aei??thaaii? ?*- oa E?- niaeo??a iiiie?enoae?a LiB3O5, b-BaB2O4,
Li2B4O7 oa ?*-niaeo??a Li2B4O7, eaaiaaiiai n??aeii; ?ic?aooieao eieeaieo
/anoio b-BaB2O4 iaoiaeii FG-iao?eoeue; noai?aii? i?ia?aie ?ic?aooieo
iae?i?eiiiioe/ieo ni?eeiyoeeainoae oa i?iaaaeaii? a?aeiia?aeieo
ia/eneaiue. Iieiaeaiiy, ui aeii-nyoueny ia caoeno, a oaeiae aeniiaee
aeaii? ?iaioe iaeaaeaoue aaoi?o. O i?aoeyo, aeeiiaieo ?acii c ?ioeie
ni?aaaoi?aie, /anoea o/ano? aeena?oaioa ??aiicia/ia o/ano? ?ioeo
aaoi??a.

Ai?iaaoe?y ?acoeueoao?a aeena?oaoe??. ?acoeueoaoe ?iaioe aeiiia?aeaeeny
? ia-aiai?thaaeeny ia O?O I?aeia?iaei?e eiioa?aioe?? c eiaa?aioii? oa
iae?i?eii? iioeee EEII’91 (i.Naieo-Iaoa?ao?a, 1991?.), ia
Oe?a?inueei-iieuenueeiio iaoeiaiio nai?ia?? (Euea?a, 1998?.), ia
ui??/ieo iaoeiaeo eiioa?aioe?yo Euea?anueeiai aea?aeaaiiai oi?aa?neoaoo
?iai? ?aaia O?aiea o 1992, 1995, 1996, 1998 oa 1999 ?ieao.

Ioae?eaoe??. Iaoa??aee aeena?oaoe?? aeeeaaeai? o 8 ae?oeiaaieo i?aoeyo,
nienie yeeo iiaeaiee iai?ee?ioe? aaoi?aoa?aoo.

No?oeoo?a oa ia’?i aeena?oaoe??. Aeena?oaoe?y neeaaea?oueny ?c anooio,
/ioe-?ueio ?icae?e?a, aeniiae?a, nieneo aeei?enoaieo aeaea?ae oa o?ueio
aeiaeaoe?a. Ianya aeena?oaoe?? 150 noi??iie, aeeth/ii c? nieneii
aeei?enoaieo aeaea?ae, ui i?noeoue 112 iaeiaioaaiue, oa aeiaeaoeaie.
?iaioa i?noeoue 67 ?ethno?aoe?e oa 35 oaaeeoeue.

INIIAIEE CI?NO ?IAIOE

O anooi? a?aecia/a?oueny aeooaeuei?noue oaie, iiaecia, iaoeiaa ?
i?aeoe/ia oe?ii?noue caaea/, ui ?ica’ycai? i?e aeeiiaii? aeena?oaoe?eii?
?iaioe.

Ia?oee ?icae?e – iaeyaeiaee. O iueiio ?icaeyiooi oaoiieia?/i?
iniaeeaino? ae?iuoaaiiy iiiie?enoae?a LiB3O5, b-BaB2O4 oa Li2B4O7.
Iiaeaii aiae?oe/iee iaeyae iaoeiai? e?oa?aoo?e, i?enay/aiee o?ce/iei oa
iioe/iei aeanoeainoyi aeine?aeaeoaaieo ai?ao?a. Ie?aii aeaiaeyoueny
oiiae noi?niino? oa i?aaeea a?aeai?o. ?icaeyaeathoueny aeaeo?iiia
aia?aaoe/ia no?oeoo?a, e?i?ei? oa iae?i?ei? iioe/i? oa?aeoa?enoeee
iiiie?enoae?a ieene?a ai?ao?a. Iiaeaii oaeiae iaeiia?o? a?aeiiino? uiaei
aeei?enoaiiy aeine?aeaeoaaieo e?enoae?a aeey aaia?aoe?? 2-i? oa 3-i?
aa?iii?e ?AA:Nd-eaca??a, aeey noai?aiiy ia?aiao?e/ieo aaia?aoi??a
na?oea, aeey oi/ieo aaoiei?aeyoe?eieo aei??thaaiue oe?eie ?iioeuen?a o
oaioinaeoiaeiiio ?aaeei?, aeey noai?aiiy oaeeaaiae?a (LiB3O5); aeey
ia?aoai?aiiy /anoioe eaca?iiai aei?ii?ithaaiiy aeaeeiiai ae?aiaciio a
OO-eaca?ia aei?ii?ithaaiiy (b-BaB2O4). Iiaa?oiaa? aeonoe/i? oaee? oa
oaee? ao?ao, ui iioe?ththoueny ia iiaa?oi? Li2B4O7, coiiaeththoue
canoinoaaiiy oeueiai iaoa??aeo o o?eueo?ao, ?aciiainieo nenoaiao,
eiiaieueaa?ao ? ei?aeyoi?ao.

O ae?oaiio ?icae?e? ?icaeyiooi e?enoaeio?i?th iiiie?enoae?a LiB3O5
(i?.a?.
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01000000020002001053796D626F6C0002040000002D01000004000000F0010100080000
00320AA001F802010000003D000A00000026060F000A00FFFFFFFF010000000000100000
00FB021000070000000000BC02000000CC0102022253797374656D00CC040000002D0101
0004000000F0010000040000002701FFFF030000000000), b-BaB2O4 (i?. a?.
wmetafile80100090000034C0100000200150000000000050000000B0200000000050000
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000400000002010100050000000102FFFFFF00040000002E011800050000003102010000
00050000000C026002C006050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFB7FFFFFF80060000170200000B00000026060F000C004D61746854
7970650000600015000000FB0280FE0000000000009001010000000402001054696D6573
204E657720526F6D616E00007A040000002D01000008000000320AA001CA050100000063
0008000000320AA001260401000000520008000000320AA0012E00010000004300150000
00FB0220FF0000000000009001010000000402001054696D6573204E657720526F6D616E
00007A040000002D01010004000000F001000008000000320A00029F0101000000560015
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616E00007A040000002D01000004000000F001010008000000320AA00116050100000033
0015000000FB0220FF0000000000009001000000000402001054696D6573204E65772052
6F6D616E00007A040000002D01010004000000F001000008000000320AF4005F01010000
00360008000000320A00023B0101000000330010000000FB0280FE000000000000900100
0000020002001053796D626F6C0002040000002D01000004000000F00101000800000032
0AA001E202010000003D000A00000026060F000A00FFFFFFFF01000000000010000000FB
021000070000000000BC02000000CC0102022253797374656D00CC040000002D01010004
000000F0010000040000002701FFFF030000000000) oa Li2B4O7 (i?. a?.
wmetafile80100090000034C0100000200150000000000050000000B0200000000050000
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000400000002010100050000000102FFFFFF00040000002E011800050000003102010000
00050000000C0260024007050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFB7FFFFFF00070000170200000B00000026060F000C004D61746854
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01000008000000320A0002AD0101000000560015000000FB0220FF000000000000900100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). Ni?eueiith ?enith an?o oeeo
iaoa??ae?a ? iayai?noue o ?o no?oeoo?? ai?-eeniaaiai e?eueoey, aoaeiaa
yeiai iinooiiai oneeaaeith?oueny: o b-BaB2O4 e?eueoea ooai?ththoue o?e
aoiie ai?o, ui ia?aaoaathoue o o?eeooi?e eeniaa?e eii?aeeiaoe??, a
LiB3O5 e?eueoea oaea noai?thth?oueny aeaiia o?eeooieeaie ? iaeiei
oao?aaae?ii ai?o, a o Li2B4O7 ai?-eeniaaee eiiieaen neeaaeathoue aeaa
o?eeooieee ? aeaa oao?aaae?e ai?o.

O?ce/i? aeanoeaino? ai?ao?a cia/iith i??ith aecia/athoueny iayai?noth
naia oeeo ai?-eeniaaeo o?aaiaio?a oa ?o ?icoaooaaiiyi o e?enoae?/i?e
no?oeoo??.

C iaoith ?ic?aooieo eieeaieo niaeo??a aeine?aeaeoaaieo no?oeoo?
i?iaaaeaii neiao??eio eeaneo?eaoe?th eieeaieo iiae iiiie?enoae?a
b-BaB2O4, LiB3O5, L?2B4O7 o
wmetafile8010009000003BD0000000200120000000000050000000B0200000000050000
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02000000000400000002010100050000000102FFFFFF00040000002E0118000500000031
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000000BC02000000CC0102022253797374656D00CC040000002D01010004000000F00100
00040000002701FFFF040000002701FFFF030000000000-oi/oe? ciie A??eethaia.
Ciaeaeaii ?iciiae?e eieeaaiue aeine?aeaeoaaieo iiiie?enoae?a ca eeanaie
neiao???, a oaeiae aecia/aii i?aaeea a?aeai?o aeey eieeaaiue ?*- oa
E?-niaeo??a:

LiB3O5 —
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00040000002701FFFF030000000000(?*,
E?)+24wmetafile8010009000003CA0000000200150000000000050000000B0200000000
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FFFF000010000000C0FFFFFFA6FFFFFFA0010000C60100000B00000026060F000C004D61
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0100000041000A00000026060F000A00FFFFFFFF01000000000010000000FB0210000700
00000000BC02000000CC0102022253797374656D00CC040000002D01000004000000F001
0100040000002701FFFF030000000000(E?)+26wmetafile8010009000003CA000000020
0150000000000050000000B0200000000050000000C024B02EA01030000001E000700000
016044B02EA0100000000050000000902000000000400000002010100050000000102FFF
FFF00040000002E01180005000000310201000000050000000C022002C001050000000B0
2000000001200000026060F001A00FFFFFFFF000010000000C0FFFFFFA6FFFFFF8001000
0C60100000B00000026060F000C004D617468547970650000500015000000FB0220FF000
0000000009001000000000402001054696D6573204E657720526F6D616E0000AB0400000
02D01000008000000320AE0011C0101000000310015000000FB0280FE000000000000900
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F01000000000010000000FB021000070000000000BC02000000CC0102022253797374656
D00CC040000002D01000004000000F0010100040000002701FFFF030000000000(?*,E?)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(?*,E?);

b-BaB2O4 —
A=42wmetafile8010009000003CA0000000200150000000000050000000B020000000005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(?*,E?)+42wmetafile8010009000003A500000002
00150000000000050000000B0200000000050000000C02B301F401030000001E00070000
001604B301F40100000000050000000902000000000400000002010100050000000102FF
FFFF00040000002E01180005000000310201000000050000000C02A0018001050000000B
02000000001200000026060F001A00FFFFFFFF000010000000C0FFFFFFC6FFFFFF400100
00660100000B00000026060F000C004D617468547970650000200015000000FB0280FE00
00000000009001010000000402001054696D6573204E657720526F6D616E0000B4040000
002D01000008000000320A600146000100000045000A00000026060F000A00FFFFFFFF01
000000000010000000FB021000070000000000BC02000000CC0102022253797374656D00
CC040000002D01010004000000F0010000040000002701FFFF030000000000(?*,E?);

L?2B4O7 —
A=19wmetafile8010009000003CA0000000200150000000000050000000B020000000005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(?*,E?)+19wmetafile8010009000003CA00000002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(E?)+1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(E?)+40wmetafile8010009000003A500000002001500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(?*,E?).

?ic?aooiie oa?aeoa?enoe/ieo /anoio eieeaieo iiae iniiaiiai no?oeoo?iiai
o?aaiaioo aaoa-ai?aoo aa??th – ai?iiii? a?oie (A3I6)3- -i?iaaaeaii
iaoiaeii FG-iao?eoeue. I?ney iiaoaeiae iao?eoe? e?iaoe/ii? aia?a??
(G-iao?eoe?) oa iao?eoe? neeiaeo iino?eieo (F-iao?eoe?), aeeiai?/ia
caaea/a caaaeaia aei a?eiaiai ??aiyiiy

wmetafile80100090000033B0100000300150000000000050000000B0200000000050000
000C024E03690B030000001E000700000016044E03690B00000000050000000902000000
000400000002010100050000000102FFFFFF00040000002E011800050000003102010000
00050000000C0280028008050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFA6FFFFFF40080000260200000B00000026060F000C004D61746854
7970650000700009000000FA02000010000000000000002200040000002D010000050000
0014025A004800050000001302260248000500000014025A00E6050500000013022602E6
0515000000FB0280FE0000000000009001000000000402001054696D6573204E65772052
6F6D616E0000DA040000002D01010008000000320AA001820701000000300010000000FB
0280FE0000000000009001000000020002001053796D626F6C0002040000002D01020004
000000F001010008000000320AA0015806010000003D0008000000320AA001CC02010000
002D0010000000FB0280FE0000000000009001010000020002001053796D626F6C000204
0000002D01010004000000F001020008000000320AA001E204010000006C0015000000FB
0280FE0000000000009001010000000402001054696D6573204E657720526F6D616E0000
DA040000002D01020004000000F001010008000000320AA001F803010000004500080000
00320AA0015C000200000047460A00000026060F000A00FFFFFFFF010000000000100000
00FB021000070000000000BC02000000CC0102022253797374656D00CC040000002D0101
0004000000F0010200040000002701FFFF030000000000,
(1)

(wmetafile8010009000003C20000000200150000000000050000000B020000000005000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-
iaeeie/ia iao?eoey), ?ica’ycee yeiai aeathoue niaeo? /anoio ii?iaeueieo
eieeaaiue
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008C0505000000140280022D030500000013028002AC0515000000FB0280FE0000000000
009001010000000402001054696D6573204E657720526F6D616E000072040000002D0102
0008000000320A0804D50401000000630015000000FB0220FF0000000000009001010000
000402001054696D6573204E657720526F6D616E000072040000002D01030004000000F0
01020008000000320A3502110501000000690008000000320A4003320101000000690010
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01020004000000F001030008000000320A0804030401000000700008000000320AD50145
04010000006C0008000000320AE0021C0001000000770015000000FB0280FE0000000000
009001000000000402001054696D6573204E657720526F6D616E000072040000002D0103
0004000000F001020008000000320A08045B0301000000320010000000FB0280FE000000
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0008000000320AE002F701010000003D000A00000026060F000A00FFFFFFFF0100000000
0010000000FB021000070000000000BC02000000CC0102022253797374656D00CC040000
002D01030004000000F001020004000000F0010100040000002701FFFF030000000000
(2)

Oiiae neiao??? oa aaaaeaiiy aioo??oi?o eii?aeeiao aeicaieythoue iiieceoe
ii?yaeie ??aiyiiy (2) oa ciaioeoe /enei iacaeaaeieo eiiiiiaio
G-iao?eoe?.

?en. 1. Cia?aaeaiiy aioo??oi?o eii?aeeiao (A3I6)3 — e?eueoey.

?c caaaeueiiai /enea 27 eieeaieo iiae ai?iiii? a?oie (A3I6)3- 15
a?aeiia?aeathoue eieeaaiiyi A-I o ieiuei? eeanoa?a
(wmetafile8010009000003A50000000200150000000000050000000B020000000005000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-iiaee), 6 – iica ieiueiith
(wmetafile8010009000003A50000000200150000000000050000000B020000000005000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-iiaee); 3 eieeaaiiy ? o?aineyoe?yie (ci?uaiiy
oeaio?a ian,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-iiaee), a 3 – e?a?aoe?eieie iiaeaie (l-iiaee).
Eieaeueia neiao??y eeanoa?a (A3I6)3- a?aeiia?aea?
wmetafile80100090000035B0100000300150000000000050000000B0200000000050000
000C029C02C507030000001E000700000016049C02C50700000000050000000902000000
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00000000009001000000000402001054696D6573204E657720526F6D616E0000EA040000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, oiio ?iceeaae ca iaca?aeieie
i?aaenoaaeaiiyie ia? aeaeyae:

A=3A’1+2A’2+5E’+2A2»+2E»+A2»+E’+A2’+E» (3)

p — iiaee a? — iiaee l — iiaee l —
iiaee

aioo??oi? eieeaaiiy

Oi?ie ii?iaeueieo eieeaaiue ai?iiii? a?oie (A3I6)3- iaaaaeaii ia ?en.2.

?en.2. Oi?ie ii?iaeueieo eieeaaiue ai?iiii? a?oie (A3I6)3.

Io?eiaii ianooii? cia/aiiy oa?aeoa?enoe/ieo /anoio eieeaieo iiae:
A1/(163, 718, 806 ni-1); A2/(645, 1677 ni-1); A2//(255, 1520 ni-1);
A/(398, 965, 1185, 1236 ni-1); A» (498 ni-1).

O o?aoueiio ?icae?e? iiaeathoueny ?acoeueoaoe i?iaaaeaieo iaie
aenia?eiaioaeueieo aeine?aeaeaiue oiiiiieo niaeo??a e?enoae?a L?A3O5,
aaoa-AaA2I4 oa Li2A4I7.

?*-niaeo?e a?aeaeaaiiy iiiie?enoae?a L?A3O5, aaoa-AaA2I4 oa Li2A4I7
aei??yii o niaeo?aeueiiio ae?aiacii? 200-1800 ni-1. C aeei?enoaiiyi
oai?aoeei-a?oiiaiai aiae?co, ioe?iie neeiaeo eiinoaio oa eeanoa?iiai
iiaeaethaaiiy i?iaaaeaii ?aeaioeo?eaoe?th io?eiaii? no?oeoo?e niaeo??a.
Iieacaii, ui eieeaaiiy ai?aoieo e?eaoeue i?iyaeythoueny i?e 250-280,

990-1500ni-1(L?A3O5), 200-240, 1190-1500ni-1 (aaoa-AaA2I4) oa 650-750
ni-1 (Li2A4I7); eieeaaiiy I-Li-I niinoa??aathoueny i?e 354, 358 ni-1
(L?A3O5) i?e 200-350, 780-800, 900-1150 ni-1 (Li2A4I7), a ci?oaiei
eieeaaiiyi (A3I7) oa i?noea I-Li-I a?aeiia?aeathoue nioae a iaeano?
650-900 ni-1 (Li2A4I7). Noia?iiceoe?y eieeaaiue a?oi (LiO4) oa (AI4) a
(Li2A4I7) i?iyaey?oueny o ae?aiacii? 400-600 ni-1.

Oiiea no?oeoo?a, ui i?i?iaey?oueny aeey aaeaioieo eieeaaiue (A3I6)3- a
iaeano? 1300-1400 ni-1 na?ae/eoue i?i ?aciianio aca?iiae?th 4-o
iaaea?aaeaioieo e?eaoeue (A3I6)3- a aeaiaioa?i?e eii??oe? aaoa-AaA2I4
yea i?ecaiaeeoue aei aeaaeaeianueeiai ?icuaieaiiy.

Ia iniia? ?ic?aoiaaieo ooieoe?e
wmetafile80100090000030D0100000200150000000000050000000B0200000000050000
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000400000002010100050000000102FFFFFF00040000002E011800050000003102010000
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0010000000C0FFFFFFA6FFFFFF20030000C60100000B00000026060F000C004D61746854
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0A8001A501010000006E0008000000320A8001280001000000650015000000FB0220FF00
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2253797374656D00CC040000002D01000004000000F0010100040000002701FFFF030000
000000 oa
wmetafile80100090000030D0100000200150000000000050000000B0200000000050000
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000400000002010100050000000102FFFFFF00040000002E011800050000003102010000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 aecia/aii oa?aeoa?enoe/i? /anoioe iiia?a/ieo OI oa iicaeiaaei?o
LI iioe/ieo oiiii?a L?A3O5, aaoa-AaA2I4 oa Li2A4I7, ui aeicaieeei
anoaiiaeoe aaee/eie iicaeiaaeiuei-iiia?a/ieo (LI-OI) ?icuaieaiue.

Iacia/ia ai?cio?ii?y aeey a?eueoino? iiae L?A3O5; oa?aeoa?eco?oueny
ni?aa?aeiioaiiyi

wmetafile8010009000003B00200000400150000000000050000000B0200000000050000
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000400000002010100050000000102FFFFFF00040000002E011800050000003102010000
00050000000C024003E01B050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFA2FFFFFFA01B0000E20200000B00000026060F000C004D61746854
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0509000000FA02000010000000000000002200040000002D0101000500000014025E0048
00050000001302E20248000500000014025E002206050000001302E2022206040000002D
0100000500000014027E00890B0500000013028801890B0500000014027E00320C050000
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018A1A040000002D0101000500000014025E004815050000001302E20248150500000014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 (4)

a iicaeiaaeiuei-iiia?a/ia ?icuaieaiiy o oeeo e?enoaeao ci?ith?oueny a
iaaeao 3-101 ni-1. Oa?oaao?noue no?oeoo?e aaoa-AaA2I4 coiiaeth? aaeeeo
ai?cio?ii?th,
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 (5)

oiio LI-OI ?icuaieaiiy ia ia?aaeuo? 10 ni-1

Iicaeiaaeiuei-iiia?a/ia ?icuaieaiiy o e?enoaeao Li2A4I7 ci?ith?oueny a
iaaeao

2-63 ni-1, a eiai oa?aeoa? oaeee:
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 (6)

Ca aaee/eiaie iicaeiaaeiuei-iiia?a/ieo ?icuaieaiue ?ic?aoiaai? aoaeoeai?
ca?yaee ? ioe?iaii oeie o?i?/ieo ca’yce?a aeine?aeaeoaaieo ai?ao?a.
Anoaiiaeaii, ui a Li2A4I7 iaea?eueoa ?iii?noue i?eoaiaiia ca’yceia?
Li-I, aea aoaeoeaiee ca?yae: eT /e neeaaea? aaee/eio 1.2, oiae? ye aeey
ca’yce?a A-I a eeanoa?ao [AI3] oa [AI4] oey aaee/eia noaiiaeoue 0,2.
Ona?aaeiai? aoaeoeai? ca?yaee o aeiaaeeo L?A3O5 iathoue aeoaea iecuee?
cia/aiiy. Oae, aeey eieeaaiue I-Li-I, cia/aiiy eT2 neeaaea? 0.012, a
aeey eieeaaiue [A3I7]5- — 0,079; aeey o?aineyoe?e ai?-eeniaaeo e?eaoeue
— 0,036.

Oiio ?iiia neeaaeiaa aea? iacia/iee aianie o eieeaaiiy ye A-I, oae ?
Li-I. Aeey aaoa-AaA2I4 ?iiia neeaaeiaa aeii?io? eeoa aeey eieeaaiue oeio
I-Aa-I.

Oaaeeoey 2

Iniiai? ia?aiao?e (ni-1) oiiii?a L?A3O5
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3B08000000320AE0011D0401000000280008000000320AE0011000010000003100150000
00FB0220FF0000000000009001000000000402001054696D6573204E657720526F6D616E
000069040000002D01050004000000F001040008000000320A4002FD1A01000000320008
000000320A4002C91301000000310008000000320A4002BF0C0100000032000800000032
0A40028A0501000000310015000000FB0280FE0000000000009001010000000402001054
696D6573204E657720526F6D616E000069040000002D01040004000000F0010500080000
00320AE001FD2501000000630008000000320AE001DE2301000000450008000000320AE0
019C2001000000630008000000320AE001B01E01000000450008000000320AE0010D1A01
000000420008000000320AE001F21201000000420008000000320AE001E10B0100000041
0008000000320AE001C50401000000410015000000FB0220FF0000000000009001010000
000402001054696D6573204E657720526F6D616E000069040000002D01050004000000F0
01040008000000320A40027C1802000000797A08000000320A4002611102000000787A08
000000320A4002330A02000000787908000000320A40021B0302000000787810000000FB
0280FE0000000000009001000000020002001053796D626F6C0002040000002D01040004
000000F001050008000000320AE001B222010000002D0008000000320AE0019A1F010000
005E0008000000320AE001841D010000002D0008000000320AE0015116010000002D0008
000000320AE001400F010000002D0008000000320AE0011208010000002D000800000032
0AE001FA00010000002D0010000000FB0280FE0000000000009001010000020002001053
796D626F6C0002040000002D01050004000000F001040008000000320AE0014D17010000
00610008000000320AE0013C1001000000610008000000320AE0010E0901000000610008
000000320AE001F6010100000061000A00000026060F000A00FFFFFFFF01000000000010
000000FB021000070000000000BC02000000CC0102022253797374656D00CC040000002D
01040004000000F001050004000000F001010004000000F0010200040000002701FFFF03
0000000000

E? ?* ?aeaioeo?eaoe?y

1 2 3 4 5 6

TO LO TO LO TO LO TO LO TO LO TO LO

60 72 59 72 11 59 30 58 E?a?aoe?y e?eaoeue (A3I7)3-

90 113 149 101 123 161 86 113 150 102 121 160 86 122 94 145 86 122 95
143 O?aineyoe?ei? eieeaaiiy Li+

188 205 189 201 179 201 180 200 Ca’ycee [BO4] — oao?aaae??a

243 307 222 245 250 281 O?aineyoe?? e?eaoeue (A3I7)3-

304 339 Eieeaaiiy ea?ean?a [LiO6]

348 392 354 358 Eieeaaiiy O-Li-O

381 389 381 420 390 458 383 479 Caeii? eieeaaiiy O-Li-O

480 489 480 490 457 482 Neiao?e/iee ?icoya [BO4] — oao?aaae??a

547 597 589 597 517 589 528 621 Eieeaaiiy e?eaoeue (A3I7)3-

619 637 619 637 638 664 637 663 670 674 Ci?oai? eieeaaiiy (A3I7)3- oa
O-Li-O

685 711 Eieeaaiiy [BO4]

779 788 781 788 721 788 753 788 Aneiao?e/ia aeaoi?iaoe?y [BO3]

892 893 Ci?oai? eieeaaiiy (A3I7)3- oa i?noea O-Li-O

964 1094 968 1118 998 1080 1040 1116 Aneiao?e/i? eieeaaiiy
(A3I7)3-

1256 1511 1273 1536 1240 1341 Neiao?e/i? eieeaaiiy (A3I7)3-

Aei??yii niaeo?e eiia?iaoe?eiiai ?icn?thaaiiy na?oea iiiie?enoae?a
L?A3O5, aaoa-AaA2I4 oa Li2A4I7, aeey ??cieo aaiiao??e aeine?aeo, ye?
aeaiiino?othoue aeia?a ocaiaeaeaiiy oai?aoe/ii ia?aaeaa/aieo oa
aenia?eiaioaeueii aeyaeaieo iiae. Aeine?aeaeaii oaiia?aoo?i? caeaaeiino?
?ioaineaiino? niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy iiiie?enoae?a L?A3O5
oa Li2A4I7 a iaeano? oaiia?aoo? 77-273 E. Oaiia?aoo?ia caeaaei?noue,
io?eiaia aeey aaiiao??? ?icn?thaaiiy Z(OO)Y e?enoaea oao?aai?aoo e?o?th
Li2A4I7 aeicaieeea aecia/eoe iiaee A1 oa A1 ye? iaea?eueo nooo?ai
caeaaeaoue a?ae oaiia?aoo?e, a oiio iiaeooue aooe iia’ycai? c iiaeeeaeie
oaciaeie ia?aoiaeaie.

?en.3 Oaiia?aoo?ia caeaaei?noue (77-290 E) niaeo??a eiia?iaoe?eiiai
?icn?thaaiiy iiiie?enoae?a Li2A4I7, aei??yieo a aaiiao??? Z(XX)Y.

Aeoiaey/e c ii??aiyiiy oiiiiieo niaeo??a, a oaeiae a?aoiaoth/e
e?enoaeio?i?/ia i?aaeei, ui iia’yco? iae?i?eiiiioe/i? aeanoeaino? c
oa?aeoa?ii o?i?/ieo ca’yce?a, aaeaeiny anoaiiaeoe, ye? no?oeoo?i?
o?a?iaioe e?enoae?a L?A3O5, aaoa-AaA2I4 oa Li2A4I7 ? a?aeiia?aeaeueieie
ca iae?i?eiiiioe/i? aeanoeaino?. Cie?aia, o aeiaaeeo L?A3O5 oa
aaoa-AaA2I4 aecia/aeueieie ? eeanoa?e .(A3I7)5- oa (A3 I6 )3-.
Aeonoineaeo?iiiei aoaeoai o Li2A4I7 ni?eythoue o?a?iaioe (LiI4) oa
(AI4).

Aeine?aeaeaii aieea aeii?oee n??aea (5%) ia oiiiiiee niaeo? Li2A4I7.
Aeyaeaii, ui nioae 690, 760, 1710, 2880, 2940, 2980 oa 3245 ni-1 ?
/ooeeaeie aei ai?noo aeii?oee. O e?enoae? aac aeii?oee n??aea niooa 3245
ni-1 a?aenooiy, sse iieacaa aiae?c, aiia aeieea? aiane?aeie aeaoi?iaoe??
ai?-eeniaaiai e?eueoey oa ciyooy neiao??eii? caai?iie aeey A2-iiaee. Ca
ci?iaie ?ioaineaiinoae iecee nioa i?iaaaeaii ?o ?aeaioeo?eaoe?th: nioaa
654 ni-1 a?aeiia?aea? eieeaaiiyi eeanoa?a (LiO4), a aeniei/anoioi? nioae
2875, 2940 oa 2975 ni-1 — eieeaaiiyi eeanoa?a (LiO6). Nioae 760 oa 1700
ni-1 ?ioaineai?noue yeeo i?e eaaoaaii? n??aeii iaeaea ia ci?ith?oueny,
a??ia?aeii iia’ycaoe c ai?-eeniaaei eeanoa?ii [A4I9]6-.

?en.4. ?*-niaeo?e iiaeeiaiiy Li2A4I7, (a) oa Li2A4I7 Ag (a)

*aoaa?oee ?icae?e i?enay/aiee ?icaeyaeo aeaeo?iiii? oa oiiiiii?
neeaaeiaeo iae?i?eieo ni?eeiyoeeainoae iiiie?enoae?a eeano ai?ao?a. Aeey
i?iaiicoaaiiy ? iiooeo iiaeo aoaeoeaieo iae?i?eiiiioe/ieo iaoa??ae?a
iaiao?aeia aea/aiiy ca’yceo ?o iioe/ieo ni?eeiyoeeainoae c? no?oeoo?ith
aeaeo?iiieo oa oiiiiieo niaeo??a.

Ia iniia? iaoiaeo ca?yaeo ia ca’ycao ia/eneaii iae?i?eiiiioe/i?
ni?eeiyoeeaino? aeine?aeaeoaaieo iaoa??ae?a. Eiiiiiaioe oaici?a
iae?i?eii? ni?eeiyoeeaino? o?eai?aoo e?o?th L?A3O5;, aeyaeeeny oaeeie:

wmetafile8010009000003AC0100000200150000000000050000000B020000000005000
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0000400000002010100050000000102FFFFFF00040000002E01180005000000310201000
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00010000000C0FFFFFFB7FFFFFFE00D0000170200000B00000026060F000C004D6174685
47970650000600015000000FB0280FE0000000000009001000000000402001054696D657
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000320AA001CE0402000000313808000000320AA0016E04010000002E0008000000320AA
001AE0301000000310015000000FB0220FF0000000000009001000000000402001054696
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20AF400760902000000313208000000320A00023B0102000000333115000000FB0280FE0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wmetafile8010009000003A40100000200150000000000050000000B0200000000050000
000C029C02230F030000001E000700000016049C02230F00000000050000000902000000
000400000002010100050000000102FFFFFF00040000002E011800050000003102010000
00050000000C026002E00D050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFB7FFFFFFA00D0000170200000B00000026060F000C004D61746854
7970650000600015000000FB0280FE0000000000009001010000000402001054696D6573
204E657720526F6D616E0000EE040000002D01000008000000320AA001B10C0100000042
0015000000FB0280FE0000000000009001010000CC0402001054696D6573204E65772052
6F6D616E00CCEE040000002D01010004000000F001000008000000320AA001C50A010000
00EC0015000000FB0280FE0000000000009001000000000402001054696D6573204E6577
20526F6D616E0000EE040000002D01000004000000F001010008000000320AA001F70B01
0000002F0008000000320AA0017B0702000000313008000000320AA001E1040200000033
3408000000320AA0018104010000002E0008000000320AA001C103010000003100150000
00FB0220FF0000000000009001000000000402001054696D6573204E657720526F6D616E
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0000000000 — aeeaae k — oi? iiaee a iecueei/anoioio ni?eeiyoeea?noue, ui
i?iii?oe?eiee aoaeoeaiiio ca?yaeo,
wmetafile8010009000003000100000200150000000000050000000B0200000000050000
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0000002701FFFF030000000000 — ?ioaineai?noue na?oea c iiey?ecaoe??th ?,
?icn?yiiai a o?eaniiio eoo?
wmetafile8010009000003A00000000200120000000000050000000B0200000000050000
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00 ia aeiaaeei? e?enoaea l, iiae?eaia ia ?ioaineai?noue caoaeaeaiiy c
iiey?ecaoe??th j. Aaee/eie
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000000 caaeathoueny ae?acaie

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aea
wmetafile8010009000003EA0000000200150000000000050000000B0200000000050000
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0000000000 — nooi?iue oiiiiii? canaeaiino? ca noaoenoeeith Aica;

wmetafile8010009000003FB0000000200150000000000050000000B0200000000050000
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000000 — iiey?eciai?noue;

wmetafile8010009000003170100000200150000000000050000000B0200000000050000
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0004000000F0010100040000002701FFFF030000000000- neeiaa noaea aeey k -oi?
neeaaeiai? o -oi? iiaee.

Aeey ciaoiaeaeaiiy aeeaaeo oiiiiii? eiiiiiaioe o aaee/eio

aeaeo?iiioe/iiai eiao?oe??ioa e?enoaea Li2A4I7, ?ic?aooaaeeny aaee/eie
rijk ca aeiiiiiaith a?aeiieo aoaeoeaieo ca?yae?a aeey o -i? eieeaii?
iiaee :

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1)

aea f(m) ?ioaineai?noue o -ai ?*-inoeeeyoi?a c /anoioith
wmetafile8010009000003C50000000200150000000000050000000B0200000000050000
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000000. Io?eiaii cia/aiiy

r33=1.3×10-14 i/A. A?aeiia?aeia cia/aiiy, io?eiaia c aenia?eiaioo
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(wmetafile8010009000003A00000000200120000000000050000000B020000000005000
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000=632.8 ii), aeyaeeiny ??aiei 2.1×10-14 i/A, ui iaiiaaii
ocaiaeaeo?oueny ?c ?ic?aoiaaiei.

Ia iniia? ni?aa?aeiioaiiy (11) i?iaaaeaii ?ic?aooiie aaee/eie
aeaeo?iiii-a?aoeiaiai aianeo a iae?i?eiiiioe/i? ia?aiao?e aaoa-AaA2I4
cie?aia, a aeaeo?iiioe/iee eiao?oe??io. Io?eiaii ianooii? ?acoeueoaoe:

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A ?acoeueoao? aeine?aeaeaiue aeenia?n?? aeaeo?iiioe/iiai eiao?oe??ioa
aeey r11 oa r52 (?en.5) aeyaeaii, ui ?o cia/aiiy ia aeiaaeei? oaee?
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00=632.8 ii a?aeiia?aeii aei??aiththoue: ^=^.52±0.31′)-
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01000000020002001053796D626F6C0002040000002D01010004000000F0010000080000
00320A6A03A70D010000002D0008000000320AF3007D0D010000002D0010000000FB0280
FE0000000000009001000000020002001053796D626F6C0002040000002D010000040000
00F001010008000000320A1604220B01000000B40008000000320A1604B40601000000B1
0008000000320A16041C02010000003D0008000000320A9F01F80A01000000B400080000
00320A9F01A20601000000B10008000000320A9F010A02010000003D000A00000026060F
000A00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC010202
2253797374656D00CC040000002D01010004000000F0010000040000002701FFFF030000
000000

Oaeee nooo?aee aianie ??aoeiai? eiiiiiaioe iiaeia iiynieoe a?aeiinii
neeueiith ?iii?noth nioa, iia’ycaieo c I-Aa-I eieeaaiiyie.

?en. 5. Aeenia?n?y aeaeo?iiioe/ieo eiao?oe??io?a r11 (1) oa r51 (2)
e?enoaeaa aaoa-AaA2I4

I?iaaaeai? aei??thaaiiy aeenia?n?? aeaeo?iiioe/iiai eiao?oe??ioa r51
iiiie?enoaea L?A3O5 iieacaee, ui eiai cia/aiiy ia aeiaaeei? oaee?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632.8 ii noaiiaeoue

(6.28±0.15)o10-14i/A. ?ic?aoiaaia ae cia/aiiy ca oi?ioeith (11)
noaiiaeei

(0.79±0.15)o10-14 i/A. Oaeei /eiii, anoaiiaeaii, ui, ia a?aei?io a?ae
aaoa-AaA2I4 oiiiiia neeaaeiaa ?iaeoue iacia/iee aeeaae o aaee/eio
aeaeo?iiioe/iiai eiao?oe??ioa r51 iiiie?enoaea L?A3O5.

AENIIAEE

1. I?iaaaeaii oai?aoeei??oiiao eeaneo?eaoeei oiiiiieo iiae iiiie?enoae?a
L?A3O5, aaoa-AaA2I4 oa Li2A4I7. Ia i?eeeaae? ai?iiii? a?oie (A3I6)3-
-iniiaiiai no?oeoo?iiai o?aaiaioa aaoa-AaA2I4 — iieacaii aoaeoeai?noue
eeanoa?iiai i?aeoiaeo. I?aeoaa?aeaeaiiyi oeueiai ? ocaiaeaeaiiy
?ic?aoiaaieo /anoio ?c aenia?eiaioaeueii aei??yieie.

2. Ca iiey?ecaoe?eieie aei??thaaiiyie ?* niaeo??a iiiie?enoae?a L?A3O5,
aaoa-AaA2I4 oa Li2A4I7 ca aeiiiiiaith ni?aa?aeiioaiue E?aia?na-E?ii?aa
aia?oa i?iaaaeaii ?ic?aooiie iioe/ieo ooieoe?e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 oa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 aeine?aeaeoaaieo iaoa??ae?a. Oea aeicaieeei aecia/eoe oa?aeoa?enoe/i?
/anoioe iiia?a/ieo oa iicaeiaaei?o iioe/ieo oiiii?a.

3. Aia?oa aei??yi? oa ?aeaioeo?eiaai? niaeo?e eiia?iaoe?eiiai
?icn?thaaiiy na?oea aeey iniiaieo aaiiao??e ?icn?thaaiiy iiiie?enoae?a
L?A3O5, aaoa-AaA2I4 oa Li2A4I7. Aeyaeaii i?aeoe/ii an? ia?aaeaa/oaai?
iiaee. Aeine?aeaeaii oaiia?aoo?i? ci?ie E?-niaeo??a Li2A4I7.

4. Ia iniia? ?ic?aooieo aoaeoeaieo ca?yae?a oa iicaeiaaeiuei-iiia?a/ieo
LI-‘?’I ?icuaieaiue i?iaaaeaii ioe?ieo oei?a o?i?/ieo ca’yce?a.
Anoaiiaeaii, ui a Li2A4I7 iaea?eueoa ?iii?noue i?eoaiaiia ca’yceo Li-I,
aea aoaeoeaiee ca?yae neeaaea? aaee/eio 1.2, oiae? ye aeey ca’yce?a A-I
a eeanoa?ao [AI3] ? [BI4] oey aaee/eia noaiiaeoue 0.2. Ona?aaeiai?
aoaeoeai? ca?yaee o aeiaaeeo L?A3O5 iathoue aeoaea iecuee? cia/aiiy.
Oae, o aeiaaeeo eieeaaiue I-Li-I, cia/aiiy eT2 neeaaea? 0.012, aeey
eieeaaiue (A3I7)5- — 0.079, aeey o?aineyoe?e ai?-eeniaaeo e?eaoeue
0.036. Oiio ?iiia neeaaeiaa ?iaeoue iacia/iee aianie o eieeaaiiy ye A-I,
oae ? Li-I. Aeey aaoa-AaA2I4 ?iiia neeaaeiaa aeii?io? eeoa aeey
eieeaaiue oeio I-Aa-I.

5. Ia iniia? ii??aiyiiy oa?aeoa?enoee oiiiiieo niaeo??a i?e o?aooaaii?
e?enoaeio?i?/iiai i?aaeea, yea iia’yco? iae?i?eiiiioe/i? aeanoeaino? c
oa?aeoa?ii o?i?/ieo ca’yce?a, ia i?eeeaae? e?enoae?a L?A3O5, aaoa-AaA2I4
oa Li2A4I7 aaeaeiny anoaiiaeoe, ye? no?oeoo?i? o?aaiaioe ?
a?aeiia?aeaeueieie ca iae?i?eiiiioe/i? aeanoeaino?. Cie?aia, o aeiaaeeo
L?A3O5, aaoa-AaA2I4 aecia/aeueieie eeanoa?aie ? o?aaiaioe (B3O6)3- oa
(B3O7)5- a?aeiia?aeii. Aeonoiaeaeo?iiiei aoaeoai o Li2A4I7 ni?eythoue
o?aaiaioe (L?I4) oa (AI4).

6. Aeine?aeaeaii aieea aeii?oee n??aea ia oiiiiiee niaeo? Li2A4I7 , ui
aeaei iiaeeea?noue aia?oa ?aeaioeo?eoaaoe aeniei/anoioi? iiaee 654,
2875, 2940 oa 2975 ni-1. Iieacaii, ui eieeaaiiy 654 ni-1 coiiaeaia
(LiO4) eeanoa?ii, a ?aooa aeniei/anoioieo nioa iia’ycai? c eieeaaiiyie
eeanoa?a (L?O6).

7. I?iaiae?ciaaii aeeaae oiiiiieo iiae o iae?i?ei? ni?eeiyoeeaino?
aeine?aeaeoaaieo e?enoae?a. Anoaiiaeaii, ui aeey aaoa-AaA2I4 oiiiiia
neeaaeiaa aea? ?noioiee aianie a aeaeo?iiioe/iee aoaeo. Aianie ??aoeiai?
eiiiiiaioe o aaee/eio aeaeo?iiioe/iiai eiao?oe??ioa r51 L?A3O5, ia
a?aei?io a?ae aaoa-AaA2I4 ? cia/ii iaioei.

INIIAI? ?ACOEUeOAOE EENA?OAOe?? IIOAE?EIAAI? A ?IAIOAO;

1. Aeiaaee ss.I., Eeoue E.A., Ii?ic E.A., ssieiiianeay I.A. Oiiiiiua
niaeo?u e?enoaeeia Li2A4I7 // Aeeyeaeo?eee e iieoi?iaiaeieee. — 1990. —
Aui.38. -N.10-13.

2. Aaeai?a A.O., Aa?ei O.E., E?oee ?.A., Ao?ae ss.A., Aeaeaea A.?.,
Aeiaaee ss.I., Ii?ic ?.?. I?i oiiiii? niaeo?e iiiie?enoae?a ai?ao?a //
Oe?. o?c. aeo?e. — 1992. -O.37, ?3. — N.368-373.

3. Ao?ae ss.A., Aeiaaee ss.I., Aeaeaea A.?., E?oee ?.A., Ii?ic ?.?.
Niaeo?e eiia?iaoe?eiiai ?icn?thaaiiy L?A3O5// Oe?. o?c. aeo?i. — 1992. —
‘A .37, ?7. — N.983-986.

4. Dovgii Ya.O.,Kityk I.V., Moroz I.E., Burak Ya.O. Phonon Spectra and
nonlinear features of
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00050000000C0200028001050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFC6FFFFFF40010000C60100000B00000026060F000C004D61746854
7970650000500010000000FB0280FE0000000000009001010000020002001053796D626F
6C0002040000002D01000008000000320A600146000100000062000A00000026060F000A
00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC0102022253
797374656D00CC040000002D01010004000000F0010000040000002701FFFF0300000000
00-AaA2I4 single crystals // Phys. Stat. Sol.B. — 1992 — 172, K45. — P.
K45-K49.

5. Aa?ei O.E., Aeiaaee ss.I., E?oee O.A., Ao?ae ss.A., Aeaeaea A.?.,
Ii?ic ?.?. Niaeo?e eiia?iaoe?eiiai ?icn?thaaiiy na?oea iiiie?enoae?a
oao?aai?aoo e?o?th // Oe?. o?c. aeo?i. — 1993. ~O.38,?1.-N.39-43.

6. Ao?ae ss.A., Aeiaaee ss.I., E?oee O.A., Ii?ic ?.?. ?*-niaeo?e
iae?i?eieo e?enoae?a L?A3O5// Oe?. o?c. aeo?i. — 1995. — O. 40, ?3. — N.
191-193.

7. A?eaiueea I.A., Iaiueeianueea 1.A., Ii?ic ?.?. Ia?aiao?e o?i?/ieo
ca’yce?a oa iae?i?ei? ni?eeiyoeeaino? aoeaio?e/ieo e?enoae?a. I?aaeei
Aeiaaiai-E?oeea // Oe?. o?c.aeo?i. — 1997, — O. 42. ?5- n. 544-547.

8, Ii?ic ?.?. Oiiiiiee niaeo? aaoa-AaA2I4 // A?niee EAeO. — 1998. —
Aei.6. -N.15-19.

Ii?ic ?.?. Oiiiii? niaeo?e iae?i?eiiiioe/ieo e?enoae?a L?A3O5,
aaoa-AaA2I4 oa Li2A4I7. — ?oeiien.

Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa
o?ceei-iaoaiaoe/ieo iaoe ca niaoe?aeuei?noth 01.04.10 — o?ceea
iai?ai?ia?aeiee?a ? .ae?aeaeo?ee?a. — Euea?anueeee aea?aeaaiee
oi?aa?neoao ?iai? ?aaia O?aiea, Euea?a, 1999,

Aeena?oaoe?y i?enay/aia aeine?aeaeaiith ?ie? oiiiiii? i?aenenoaie o
oi?ioaaii? iae?i?eiiiioe/iiai a?aeaoeo iiiie?enoae?a L?A3O5, aaoa-AaA2I4
oa Li2A4I7. C aeei?enoaiiyi oai?aoeei-a?oiiaiai aiae?co, ioe?iie neeiaeo
eiinoaio oa eeanoa?iiai iiaeaethaaiiy ?icoeo?iaaii no?oeoo?o ?*-niaeo??a
a?aeaeaaiiy oa niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea
aeine?aeaeoaaieo iaoa??ae?a. ?ic?aoiaaii iioe/i? ooieoe??, aaee/eie
iicaeiaaeiuei-iiia?a/ieo ?icuaieaiue, aoaeoeai? ca ?yaee oa ia oe?e
iniia? i?iaaaeaii ioe?ieo oei?a o?i?/ieo ca’yce?a. ?ic?aoiaaii eieeai?
/anoioe aaoa-ai?aoo aa??th, ?o ii??aiyiiy c aenia?eiaioaeueieie aeaieie
i?aeoaa?aeeei i?eaeaoi?noue eeanoa?ii? iiaeae? o aeiaaeeo ?ic?aooieo
eieeaiiai niaeo?a neeaaeieo niieoe. Aeine?aeaeaii aieea aeii?oee n??aea
ia oiiiiiee niaeo? oao?aai?aoo e?o?th ‘[‘a ?aeaioeo?eiaaii
aeniei/anoioi? nioae Li2A4I7 . I?iaiae?ciaaii aianie oiiiiieo iiae o
iae?i?ei? ni?eeiyoeeaino? iiiie?enoae?a ieene?a ai?ao?a.

Eeth/ia? neiaa; oiiiii? (?*- aa E?-) niaeo?e, iae?i?ei? ni?eeiyoeeaino?
(aeaeo?iiia ? oiiiiia eiiiiiaioa), iicaeiaaeiuei-iiia?a/i? ?icuaieaiiy,
oeie o?ica’yce?a, aoaeoeai? ca?yaee, oai?aoeei-a?oiiaee aiae?c, aieea
eaaoaaiiy ia oiiiii? niaeo?e.

Ii?ic E.A. Oiiiiiua niaeo?u iaeeiaeiiiioe/aneeo e?enoaeeia L?A3O5,
aaoa-AaA2I4, Li2A4I7 — ?oeiienue.

Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa
oeceei-iaoaiaoe/aneeo iaoe ii niaoeeaeueiinoe 01.04.10 — oeceea
iieoi?iaiaeieeia e aeeyeaeo?eeia.—Eueaianeee ainoaea?noaaiiue
oieaa?neoao eiaie Eaaia O?aiei, Eueaia, 1999.

Aeenna?oaoeey iinayuaia enneaaeiaaieth ?iee oiiiiiie iiaenenoaiu a
oi?ie?iaaiee iaeeiaeiiiioe/aneiai ioeeeea iiiie?enoaeeia L?A3O5,
aaoa-AaA2I4 e Li2A4I7. N eniieueciaaieai oai?aoeei-a?oiiiaiai aiaeeca,
ioeaiie neeiauo iinoiyiiuo e eeanoa?iiai iiaeaee?iaaiey i?iecaaaeaia
?anoeo?iaea no?oeoo?u EE-niaeo?ia io?aaeaiey e niaeo?ia eiiaeiaoeeiiiiai
?annayiey naaoa enneaaeoaiuo iaoa?eaeia. ?ann/eoaiu iioe/aneea ooieoeee,
aaee/eiu i?iaeieueii-iiia?a/iuo ?anuaieaiee, yooaeoeaiua ca?yaee, ia
iniiaaiee /aai i?iecaaaeaia ioeaiea oeiia oeie/aneeo naycae. ?ann/eoaiu
eieaaaoaeueiua /anoiou aaoa-ai?aoa aa?ey. Eo n?aaiaiea n
yenia?eiaioaeueiuie aeaiiuie iiaeoaa?aeaeaao i?eaiaeiinoue eeanoa?iie
iiaeaee a neo/aa ?an/aoa eieaaaoaeueiiai niaeo?a neiaeiuo niaaeeiaiee.
Enneaaeiaaii aeeyiea i?eiane na?aa?a ia oiiiiiue niaeo? oao?aai?aoa
eeoey e eaeaioeoeoee?iaaii auniei/anoioiua iieinu Li2A4I7.
I?iaiaeece?iaai aeeaae oiiiiiuo iiae a iaeeiaeiua aini?eei/eainoe
iiiie?enoaeeia ieneaeia ai?aoia.

Eeth/aaua neiaa: oiiiiiua (EE- e E?-) niaeo?u, iaeeiaeiua
aini?eei/eainoe (yeaeo?iiiay e oiiiiiay eiiiiiaioa),
i?iaeieueii-iiia?a/iua ?anuaieaiey, oeiu oeinaycae, yooaeoeaiua ca?yaeu,
oai?aoeei-a?oiiiaie aiaeec, aeeyiea eaae?iaaiey ia oiiiiiua niaeo?u.

Moroz I.E. Phonon spectra of nonlinear optical crystals LiB3O5,
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00-BaB2O4, Li2B4O7 — Manuscript

Thesis for the Degree of Candidate of Physical and Mathematical Sciences
in speciality 01-04.10 — Physics of Semiconductors and Dielectric s.-
Lviv Ivan Franko State University, Lviv, 1999.

This thesis is devoted to the investigation of the role of phonon
subsystem in nonlinear optical response formation of LiB3O5,
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0010000000C0FFFFFFC6FFFFFF40010000C60100000B00000026060F000C004D61746854
7970650000500010000000FB0280FE0000000000009001010000020002001053796D626F
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00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC0102022253
797374656D00CC040000002D01010004000000F0010000040000002701FFFF0300000000
00-BaB2O4, Li2B4O7 single-crystals. These materials arc transparent in a
wide range of wave length (from vacuum ultraviolet to near infrared
region); they arc radiation resistant and possess high threshold of
optical stability. Single crystals LiB3O5and
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0010000000C0FFFFFFC6FFFFFF40010000C60100000B00000026060F000C004D61746854
7970650000500010000000FB0280FE0000000000009001010000020002001053796D626F
6C0002040000002D01000008000000320A600146000100000062000A00000026060F000A
00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC0102022253
797374656D00CC040000002D01010004000000F0010000040000002701FFFF0300000000
00-BaB2O4are of great interest due to the possibility of using them in
various nonlinear optical devices such as phase and amplitude
modulators, frequency mixing generators, parametric light generators and
for the second and highest harmonics generation. The other borate single
crystal — Li2B4O7 — is perspective for usage in acoustoelectronic
devices, e.g. in filtres, correlators, convolvers and resonance systems.

For calculation of vibrattonai spectra of the investigated crystals the
symmetry classification uf vibratiun modes of LiB3O5,
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00-BaB2O4, Li2B4O7 single crystals in F-point of Brillouin zone has been
realized. The dustribution of vibrations of oxide borates on symmetry
classes has been found out, and selection rules for vibration IR and
Raman spectra have been determined as well.

The boraies’ physical properties arc determined to a grate extent by the
presence of B-O fragments (B3 O6 )3- (B3 O7)5- and (B4 O9 )6- in LiB3O5,
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00-BaB2O4, Li2B4O7 crystal structures. That is why using FG-matrix
method we calculated the characteristic frequencies of the vibration
modes of the main structural fragment of
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7970650000500010000000FB0280FE0000000000009001010000020002001053796D626F
6C0002040000002D01000008000000320A600146000100000062000A00000026060F000A
00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC0102022253
797374656D00CC040000002D01010004000000F0010000040000002701FFFF0300000000
00-BaB2O4single crystals — (B3 O6 )3- anion group. The correspondence
between theoretically determined and experimentally obtained frequencies
confirms the usefulness of cluster model for calculation of vibrational
spectra of complex structures.

The identification of IR reflectivity and Raman scattering spectra of
the investigated crystals have been realized using theoretical group
analysis, estimation of the forse constants and cluster simulation. The
vibration of the borate rings reveals at 250-280, 990-1500 cm-1
(wmetafile8010009000003A00000000200120000000000050000000B020000000005000
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000050000000C0200028001050000000B02000000001200000026060F001A00FFFFFFFF0
00010000000C0FFFFFFC6FFFFFF40010000C60100000B00000026060F000C004D6174685
47970650000500010000000FB0280FE0000000000009001010000020002001053796D626
F6C0002040000002D01000008000000320A600146000100000062000A00000026060F000
A00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC010202225
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000-BaB2O4), 200-240, 1190-1500 cm-1(LiB3O5) and 650-750 cm-1 (Li2B4O7),
vibration O-Li-O is observed at

354,358 cm-1(LiB3O5), 200-350, 780-800, 900-1150 cm-1 (Li2B4O7). The
mixed vibration (A3 I7 )5— and O-Li-O reveals at 650-900 cm-1;
superposition (LiO4) and (BO4) is observed at range

400-600 cm-1 (Li2B4O7).

Thin structure of the (B3 O4 ) valence vibration at 1300-1400 cm-1
testifies the resonance interaction of 4 non-equivalent (B3 O4 ) rings
in the unit cell of
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000400000002010100050000000102FFFFFF00040000002E011800050000003102010000
00050000000C0200028001050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFC6FFFFFF40010000C60100000B00000026060F000C004D61746854
7970650000500010000000FB0280FE0000000000009001010000020002001053796D626F
6C0002040000002D01000008000000320A600146000100000062000A00000026060F000A
00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC0102022253
797374656D00CC040000002D01010004000000F0010000040000002701FFFF0300000000
00-BaB2O4 which results in Davydov splitting.

The characteristic frequencies of transversal TO and longitudinal LO
optical phonons were defined on the basis of the calculated by
Kramers-Kronig relations optical functions
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00050000000C022002A003050000000B02000000001200000026060F001A00FFFFFFFF00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,wmetafile8010009000003FA0000000200150000000000050000000B0200000000050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. Due to the calculated values of LO-TO splitting the effective
charges of the investigated single crystals were determined and chemical
bonds types were estimated too. It has been determined that in Li2B4O7
structure the largest ionicity is characteristic for Li-O bond. The
ionic component makes a small contribution to B-O and Li-O vibration in
the case of LiB3O5 .It prevails only for O-Ba-O vibration in
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000C023202A501030000001E000700000016043202A50100000000050000000902000000
000400000002010100050000000102FFFFFF00040000002E011800050000003102010000
00050000000C0200028001050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFC6FFFFFF40010000C60100000B00000026060F000C004D61746854
7970650000500010000000FB0280FE0000000000009001010000020002001053796D626F
6C0002040000002D01000008000000320A600146000100000062000A00000026060F000A
00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC0102022253
797374656D00CC040000002D01010004000000F0010000040000002701FFFF0300000000
00-BaB2O4

The measurements of the Raman spectra of investigated crystals for main
scattering geometries have been made. These spectra demonstrates a good
agreement between theoretically determined and experimentally obtained
modes. We obtained the temperature dependencies (77-230 E) of the Raman
scattering spectra of lithium tetraborate for scattering geometry Z(XX)Y
where A, and B^ modes are observed. These modes strongly depend on
temperature lherefore they could be connected with phase transitions in
Li2B4O7.

The influence of Ag impurity (5%) on the phonon spectrum of Li2B4O7 were
investigated and high-frequency bands of this material were identified:
mode at 654 cm-1 corresponds to LiO4 cluster vibration, and modes at
2875, 2940 and 2975 cm-1 -corresponds to LiO6 vibration.

The 760 and 1700 cm-1 modes intensity don’t change with doping, thus
one can connect ones with (B4O9)6- claster vibration. The discovered
band at 3245 cm-1 in Li2B4O7 -Ag spectra arises because of deformation
B-O ring and symmetry forbidden take off for the A2 mode.

The contribution of the electron and phonon components of nonlinear
susceptibilities of borate oxides were estimated. The components of
nonlinear susceptibilities tenser were determined by bond charge method.
It has been determined that the phonon component makes essential
contribution to electro optical effects for
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00050000000C0200028001050000000B02000000001200000026060F001A00FFFFFFFF00
0010000000C0FFFFFFC6FFFFFF40010000C60100000B00000026060F000C004D61746854
7970650000500010000000FB0280FE0000000000009001010000020002001053796D626F
6C0002040000002D01000008000000320A600146000100000062000A00000026060F000A
00FFFFFFFF01000000000010000000FB021000070000000000BC02000000CC0102022253
797374656D00CC040000002D01010004000000F0010000040000002701FFFF0300000000
00-BaB2O4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0.46xl0-12 m/b; r51=2.88xl0-12 i/A. The lattice counterpart
contributes vanishingly to the value of the electro-optical coefficient
of LiB3O5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0.75xl0-12 m/b; r51=0.79xl0-14m/b.

Key words: phonon (IR- and Raman-) spectra, nonlinear susceptibilities
(electron and phonon components), transversal-longitudinal splitting,
chemical bonds types, effective charges, group theory analysis,
influence of impurity on the phonon spectra.

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