Прямий синтез гетероядерних комплексів міді та свинцю з аміноспиртами: Автореф. дис… канд. хім. наук / Л.А. Ковбасюк, Київ. ун-т ім. Т.Шевченка. — К

EE?ANUeEEE IAOe?IIAEUeIEE OI?AA?NEOAO ?iai? OA?ANA OAA*AIEA

EIAAANTHE EA?ENA AIAOIE??AIA

OAeE 546.386-56-815

I?ssIEE NEIOAC AAOA?IssAeA?IEO EIIIEAEN?A I?Ae? OA NAEIOeTH C
AI?IINIE?OAIE

02.00.01 — iai?aai?/ia o?i?y

AAOI?AOA?AO

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?i?/ieo iaoe

EE?A — 1999

Aeena?oaoe??th ? ?oeiien.

?iaioa aeeiiaia ia eaoaae?? iai?aai?/ii? o?i?? Ee?anueeiai
Iaoe?iiaeueiiai oi?aa?neoaoo ?iai? Oa?ana Oaa/aiea.

Iaoeiaee ea??aiee aeieoi? o?i?/ieo iaoe,

noa?oee
iaoeiaee ni?a?ia?oiee

Eieicae Aieiaeeie? Ieeieaeiae/,

Ee?anueeee Iaoe?iiaeueiee oi?aa?neoao

?iai? Oa?ana Oaa/aiea,

caa?aeoth/ee eaai?aoi???th IAe*

Io?oe?ei? iiiiaioe: aeieoi? o?i?/ieo iaoe, i?ioani?

Eae?aaa/oe Aaeaioeia Ieaenaiae??aia,

Iaoe?iiaeueiee iaaee/iee oi?aa?neoao

?i. I.I. Aiaiiieueoey,

caa?aeoth/a eaoaae?ith caaaeueii? o?i??

eaiaeeaeao o?i?/ieo iaoe, aeioeaio

?aeoa? E?ii A?eai?iae/,

Iaoe?iiaeueiee oaoi?/iee oi?aa?neoao

Oe?a?ie “Ee?anueeee iie?oaoi?/iee ?inoeooo”

I?ia?aeia onoaiiaa ?inoeooo caaaeueii? oa iai?aai?/ii? o?i??

?i.
A.?.Aa?iaaenueeiai IAI Oe?a?ie, i.Ee?a

Caoeno aeena?oaoe?? a?aeaoaeaoueny 24 o?aaiy 1999 ?ieo i 1400 ia
can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee Ae26.001.03 i?e Ee?anueeiio
Iaoe?iiaeueiiio oi?aa?neoao? ?iai? Oa?ana Oaa/aiea (252033, i. Ee?a,
aoe. Aieiaeeie?nueea, 60).

C aeena?oaoe??th iiaeia iciaeiieoenue o a?ae?ioaoe? Ee?anueeiai
Iaoe?iiaeueiiai oi?aa?neoaoo ?iai? Oa?ana Oaa/aiea, 252033, i. Ee?a,
aoe. Aieiaeeie?nueea, 58.

Aaoi?aoa?ao ?ic?neaiee 21 ea?oiy 1999 ?.

A/aiee nae?aoa?

niaoe?ae?ciaaii? a/aii? ?aaee
Ieaenaiei E.I.

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeuei?noue oaie. Aaoa?iyaea?i? eiiieaene caaaeaee i?eaa?oaee oaaao
aeine?aeiee?a. I?enooi?noue e?eueeio oeaio?aeueieo aoii?a, ?icoaoiaaieo
ia iaaaeeeeo a?aenoaiyo, noai?th? ni?eyoeea? oiiae aeey iai?iii?
aca?iiae?? oa i?iyao iiaeo o?ceei-o?i?/ieo (eaoae?oe/ieo,
aeaeo?io?i?/ieo, aeaeo?iiieo, iaai?oieo) oa a?ieia?/ieo aeanoeainoae.
?acii c oei, neioac aaoa?iyaea?ieo eiiieaen?a ? aeineoue neeaaeiei.

Iaoiae i?yiiai neioaco eii?aeeiaoe?eieo niieoe c aeei?enoaiiyi
i?ioiiiaeiii?ieo ?aaaaio?a, caii/aoeiaaiee ia eaoaae?? iai?aai?/ii?
o?i?? Ee?anueeiai Iaoe?iiaeueiiai oi?aa?neoaoo ?iai? Oa?ana Oaa/aiea,
iiaeia aaaaeaoe iaeiei c ia?niaeoeaieo iai?yie?a no/anii? neioaoe/ii?
eii?aeeiaoe?eii? o?i??. Iaaoo? ciaiiy oa aeina?ae uiaei ?aaeoe?e ca
o/anoth iaoae?/ieo ii?ioe?a oa ieneae?a iaoae?a aeaee i?aenoaae
i?iaiicoaaoe ooai?aiiy aaoa?iyaea?ieo eiiieaen?a a oiiaao i?yiiai
neioaco. C’ynoaaiiy oaei? i?eioeeiiai? iiaeeeaino? iio?aaoaaei ie?aiiai
aeine?aeaeaiiy, aeooaeuei?noue yeiai iieyaa? o ?ic?iaoe? iiaeo iaoiae?a
neioaco aaoa?iyaea?ieo eiiieaen?a.

Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie. Aea?aiee
iai?yiie iia’ycaiee ?c oaiaoe/iei ieaiii iaoeiai-aeine?aeieo ?ia?o
Ee?anueeiai Iaoe?iiaeueiiai oi?aa?neoaoo ?iai? Oa?ana Oaa/aiea (oaia ?
168 ”Neioac oa aeine?aeaeaiiy a?ieia?/ii-aeoeaieo eii?aeeiaoe?eieo
niieoe” oa ? 97071 ”Ia?niaeoeae i?yiiai neioaco eii?aeeiaoe?eieo
niieoe”) oa i?ia?aiith ?a?iiaenueeiai Nithco ”O?i?y iaoae?a a
iaaeeoeei?”.

Iaoa ? caaea/? aeine?aeaeaiiy. Iaoith aeaii? ?iaioe aoea ?ic?iaea iiaiai
i?aeoiaeo aei iaea?aeaiiy aaoa?iyaea?ieo eiiieaen?a i?ae? oa naeioeth c
ai?iinie?oaie.

Aeey aeinyaiaiiy iinoaaeaii? iaoe aoei i?iaaaeaii iiooe nenoai,
iaea?eueo i?eaeaoieo aeey neioaco aaoa?iyaea?ieo eiiieaen?a, yeeie
aeyaeeenue oae?, ui i?noyoue ii?ioie iaeiiai iaoaeo oa n?eue ?ioiai. Ie
aea/eee aca?iiae?th ii?ioeo i?ae? c nieyie naeioeth (oei?eae, a?ii?ae,
eiaeeae, o?ioe?aiao, i?o?ao, aoeaoao) a iaaiaeieo (aeeiaoeeoi?iai?ae,
aeeiaoeenoeueoieneae, iaoaiie, aoeaoii?o?ee) ?ic/eiao ai?iinie?o?a
(iiiiaoaiieai?i, 2-aeeiaoeeai?iiaoaiie, ae?aoaiieai?i, o?eaoaiieai?i)
aai ?o a?ae?ioei?eae?a oa c’ynoaaee iniiai? caeiiii??iino?
ia?aoai?aiiue a aeine?aeaeaieo nenoaiao.

Iaoeiaa iiaecia iaea?aeaieo ?acoeueoao?a. Aoei anoaiiaeaii i?eioeeiiao
iiaeeea?noue iaea?aeaiiy aaoa?iyaea?ieo niieoe a oiiaao i?yiiai neioaco
oa cai?iiiiiaaii iia? iaoiaeeee neioaco aaoa?iyaea?ieo eiiieaen?a i?ae?
oa naeioeth c ai?iinie?oaie. ?ic?iaeai? i?ea?iaeuei? iaoiaeeee
a?ae??ciythoueny a?ae a?aeiieo i?inoioith aenia?eiaioaeueiiai aeeiiaiiy
oa aeinooii?noth aeo?aeieo ?a/iaei. Aia?oa neioaciaaii 63 aaoa?iyaea?i?
eiiieaene c ai?iinie?oaie, anoaiiaeai? ?o neeaae oa aoaeiaa. I?iaaaeaii
iiaiee ?aioaaiino?oeoo?iee aiae?c 12 iiaeo eii?aeeiaoe?eieo niieoe.
Iieacaii, ui canoinoaaiiy i?yiiai neioaco a?aee?eaa? iiaee iai?yiie a
o?i?? aaoa?iyaea?ieo eiiieaen?a.

I?aeoe/ia oe?ii?noue iaea?aeaieo ?acoeueoao?a. Iaea?aeai? ?acoeueoaoe
iiaeooue aooe aeei?enoai? aeey oe?eani?yiiaaiiai neioaco aaoa?iyaea?ieo
eiiieaen?a ?ioeo iaoae?a. Neioaciaai? niieoee aeyaeythoue i?ioeiooeeiio
aeoeai?noue ? iiaeooue aooe canoiniaai? i?e ?ic?iaoe? e?ea?nueeeo
i?aia?ao?a. ?acoeueoaoe aeine?aeaeaiiy iiaeooue aooe aeei?enoai? i?e
i?aeaioiaoe? i?ae?o/iee?a oa eaeoe?eieo eo?n?a aeey nooaeaio?a o?i?/ieo
niaoe?aeueiinoae.

Iniaenoee aianie caeiaoaa/a. A iniiao aeaii? aeena?oaoe?? iieeaaeai?
?aea? i?yiiai neioaco aaoa?iyaea?ieo niieoe, noi?ioeueiaai? iaoeiaei
ea??aieeii ?iaioe ae.o.i. A.I.Eieica?i oa iaoeiaei eiinoeueoaioii
I.TH.Aaneeue?aith. Iniiaiee ianya aenia?eiaioaeueii? ?iaioe oa ia?iaea
iaea?aeaieo ?acoeueoao?a aeeiiai? iniaenoi caeiaoaa/ai. Iinoaiiaea
caaea/?, aiae?c iaea?aeaieo ?acoeueoao?a ?iaioe oa oi?ioethaaiiy
aeniiae?a i?iaiaeeeenue ca o/anoth iaoeiaiai ea??aieea A.I. Eieicay oa
iaoeiaiai eiinoeueoaioa I.TH. Aaneeue?ai?. ?aioaaiino?oeoo?i?
aeine?aeaeaiiy aeeiiai? o ni?aaaoi?noa? c ?onaiiaei A.A. (?IO IAIO,
i.Ee?a), Neaeoiiii A.A. (Oi?aa?neoao Cao?aeii? Aano?ae??, i Ia?o) oa
?aca? I. (Eaia??aeaenueeee Oi?aa?neoao, Aaeeeia?eoai?y).

Ai?iaaoe?y ?acoeueoao?a aeena?oaoe??. ?acoeueoaoe aeena?oaoe?eii? ?iaioe
aoee ii?eethaeiai? ia XIV Oe?a?inuee?e eiioa?aioe?? c iai?aai?/ii? o?i??
(Ee?a, 1996), XVII Congress and General Assembly of IUCr (USA, 1996),
Fifth Eurasia Conference on Chemical Sciences (China, 1996), Fifth
International School and Workshop of Crystallography: Teaching and
Applications (Egypt, 1997), Anglo/German Inorganic Chemistry Meeting
(Germany, 1997), 7th International Symposium on Macromolecule-Metal
Complexes (The Netherlands, 1997), 32nd International Conference on
Coordination Chemistry (Chile, 1997), International workshop on
Intermolecular Interactions (South Africa, 1997), 2nd International
conference “Progress in inorganic and organometallic chemistry” (Poland,
1997), Seventeenth European Crystallographic Meeting (Portugal, 1997),
Iaoeeiiaeueiie e?enoaeeioeie/aneie eiioa?aioeee (?inney, 1998), XXXIII
International conference on coordination chemistry (Italy, 1998), Annual
Meeting of American Crystallographic Association (USA, 1998), 3rd
Conference of the Asian Crystallographic Association (Malaysia, 1998).

Ioae?eaoe??. Ca iaoa??aeaie aeena?oaoe?eii? ?iaioe iioae?eiaaii 6 noaoae
oa 14 oac aeiiia?aeae ia i?aeia?iaeieo oa iaoe?iiaeueieo eiioa?aioe?yo.
?ic?iaeaiee niin?a iaea?aeaiiy aaoa?iyaea?ieo eiiieaen?a caoeuaiee
iaoaioii Oe?a?ie.

No?oeoo?a oa ia’?i aeena?oaoe??. Aeena?oaoe?y neeaaea?oueny c anooio,
3-o ?icae?e?a, aeniiae?a, nieneo oeeoiaaii? e?oa?aoo?e (69 iaeiaioaaiue)
oa aeiaeaoeo. ?iaioa aeeeaaeaia ia 159 noi?. ae?oeiaaiiai oaenoo ?
i?noeoue 55 ?enoie?a oa 31 oaaeeoeth.

INIIAIEE CI?NO ?IAIOE

Ia?oee ?icae?e i?noeoue iaeyae e?oa?aoo?ieo aeaieo i?i i?yiee neioac
eii?aeeiaoe?eieo niieoe i?ae? aai naeioeth c ai?iinie?oaie a iaaiaeieo
?ic/eiao. Oeae ?icae?e oaeiae i?noeoue iaeyae e?oa?aoo?e i?i iaoiaee
neioaco oa e?enoae?/io aoaeiao aaoa?iyaea?ieo eiiieaen?a 3d — iaoae?a.
Iniaeeao oaaao a?aeaaaeaii ?icaeyaeo aoaeiae aaoa?iyaea?ieo eiiieaen?a,
ui i?noyoue i?aeue oa naeiaoeue. Ia i?aenoaa? i?iaaaeaiiai iaeyaeo
e?oa?aoo?e c?iaeaii aeniiaie i?i iiaeeea?noue aeei?enoaiiy ?aaeoe?e
i?yiiai neioaco aeey iaea?aeaiiy aaoa?iyaea?ieo eiiieaen?a.

O ae?oaiio ?icae?e? iienai? iniaeeaino? aca?iiae?? ii?ioeo i?ae? c
nieyie naeioeth (oei?eae, a?ii?ae, eiaeeae, o?ioe?aiao, aoeaoao) a
iaaiaeieo ?ic/eiao (aeeiaoeenoeueoieneae, aeeiaoeeoi?iai?ae, iaoaiie,
aoeaoii?o?ee) ai?iinie?o?a (iiiiaoaiieai?io — HEa,
2-aeeiaoeeai?iiaoaiieo — HMe2Ea, ae?aoaiieai?io — H2Dea oa
o?eaoaiieai?io — H3Tea) ? ?o a?ae?ioei?eae?a, iaoiaeeee neioaco oa
?acoeueoaoe ?*-niaeo?aeueieo aeine?aeaeaiue aaoa?iyaea?ieo eiiieaen?a.
Iieacaia i?eioeeiiaa iiaeeea?noue i?yiiai neioaco aaoa?iyaea?ieo oa
aaoa?iai?iiieo aaoa?iyaea?ieo eiiieaen?a ? anoaiiaeaii ooai?aiiy o?ueio
oei?a niieoe, ye? a?ae??ciythoueny ni?aa?aeiioaiiyi Cu : Pb (oaae. 1).

Aaoa?iyaea?i? eiiieaene ?c na?aa?aeiioaiiyi Cu : Pb = 1 : 1 caaaeueiiai
neeaaeo CuPbO2L2(nSolv ( X = Cl, Br, I, SCN; n = 0; 1, L = Ea, Me2Ea,
HDea; Solv = AeINI, HEa, H2Dea, I2I) ooai?ththoueny o an?o aea/aieo
nenoaiao ca aeiyoeii nenoai c o?eaoaiieai?iii ca ?aaeoe??th:

Cu ( PbX2 ( 2HL ( 0,5O2 ( nSolv ( CuPbX2L2·nSolv ( H2O.

Aaoa?iyaea?i? eiiieaene c o?eaoaiieai?iii neeaaeo CuPbCl3(H2Tea)(H3Tea)n
(n = 0; 1) ooai?th?oueny eeoa a nenoaiao, ui i?noyoue a?ae?ioei?eae
o?eaoaiieai?io. Aeey ae?aoaiieai?io oa?aeoa?ii ooai?aiiy aoeaoaoiiai
eiiieaeno CuPb(Ac)(Dea)(HDea), ui i?noeoue iaeii- oa aeaiaeai?ioiiiaai?
caeeoee ai?iinie?oo. Anoaiiaeaii, ui aei neeaaeo

a?ii?aeieo oa eiaeeaeieo eiiieaen?a c iiiiaoaiieai?iii aai
2-aeeiaoeeai?iiaoaiieii aoiaeeoue AeINI.

Aca?iiae??th iaoae?/ii? i?ae? oa nieae naeioeth c iaaiaeieie ?ic/eiaie
a?ae?ioei?eae?a ai?iinie?o?a io?eiai? aaoa?iai?iii? aaoa?iyaea?i?
eiiieaene ?c ni?aa?aeiioaiiyi Cu : Pb = 1 : 1 aeaio oei?a:

Oaaeeoey 1

Aaoa?iyaea?i? eiiieaene c ai?iinie?oaie, ui i?noyoue i?aeue oa
naeiaoeue, ye? ooai?ththoueny a aeine?aeaeaieo nenoaiao.

Nenoaia Neeaae niieoee

Cu-PbX2-HEa-Solv,

Solv — AeIOA, AeINI, NI3II,

2(nSolv X = Cl, Br, I; n = 0; 1;

3 X = Cl, I

Cu-PbX2-HMe2Ea-Solv,

Solv — AeIOA, AeINI, NI3II,

2(nSolv X = Cl, Br, I, SCN; n = 0; 1;

3 X = Cl, I, SCN

Cu2PbX2(Me2Ea)4 X = Br, I

CuPb2X3(Me2Ea)3 X = Br, I

Cu-PbX2-H2Dea- Solv,

Solv — AeIOA, AeINI, NI3II,

NI3CN CuPbX2(HDea)2·n(H2Dea) X = Cl, Br, I; n = 0; 1

Cu2PbCl(Dea)(HDea)3

CuPb(Ac)(Dea)(HDea)

Cu-PbX2-HEa·HCl-Solv,

Solv — AeIOA, AeINI Cu2Pb2I3Cl(Ea)4

Cu2PbX3Cl(Ea)2 X = Br, I

Cu-PbX12-PbX22-HMe2Ea- Solv,

Solv — AeIOA, AeINI
CuPbBrI(Me2Ea)2

Cu2Pb2Cl3(NCS)(Me2Ea)4

CuPb2I(SCN)(Me2Ea)4

Cu-PbX2-H2Dea·HCl-Solv,

Solv — AeIOA, AeINI

CuPbClI(HDea)2

Cu-PbCl2-H3Tea(HCl-Solv,

Solv — AeIOA, AeINI, NI3II,

NI3CN CuPbCl3(H2Tea)(H3Tea)n n = 0; 1

Cu2PbCl(NCS)(HTea)2

2Cu + 2Pb?2 + 4HEa(HCl + O2 = Cu2Pb2ClI3(Ea)4 + 3HCl + HI + 2H2O,

Cu + Pb?2 + 2H2Dea(HCl + 0,5O2 = CuPbClI(HDea)2 + HCl + HI + H2O.

Iieacaia iiaeeea?noue neioaco aaoa?iai?iiieo aaoa?iyaea?ieo eiiieaen?a
ca o/anoth aeaio nieae c ??cieie ai?iiaie:

2Cu2Pb2Cl3(SCN)(Me2Ea)4

+ 4H2O,

2CuPbBrI(Me2Ea)2 + 2H2O.

?*-niaeo?e niieoe CuPbI2(Ea)2(AeINI oa CuPbBr2(Me2Ea)2(AeINI i?noyoue
aeineoue ?ioaineai? nioae eieeaaiue (SO iaeii?aeeiiaaiiai (1070 ni-1) oa
eii?aeeiiaaiiai /a?ac aoii eenith (995 ni-1) ?ic/eiieea. A ?*-niaeo??
niieoee CuPbI2(Me2Ea)2(2AeINI i?enooi? iaeii/anii (SO iaeii?aeeiiaaieo
(1090 ni-1) oa eii?aeeiiaaieo /a?ac aoii eenith (990 ni-1) iieaeoe
?ic/eiieea. Ca aeaieie ?*-niaeo??a o?ioe?aiaoi? a?oie a niieoeao
CuPb(NCS)2(Me2Ea)2 oa CuPb(NCS)(Me2Ea)3 eii?aeeiiaai? /a?ac aoii acioo
((CN = 2080 ni-1,(CS = 850 ni-1 oa (CN = 2080 ni-1, (CS = 830 ni-1,
a?aeiia?aeii).

Aaoa?iyaea?i? eiiieaene ?c ni?aa?aeiioaiiyi Cu : Pb = 2 : 1
ooai?ththoueny a on?o ?ic/eiieeao ca aeiyoeii NI3II:

2Cu ( PbX2 ( O2 ( 4HL ( Cu2PbX2L4 ( 2H2O,

X = Cl, Br, I; L = Ea, Me2Ea;

4Cu ( 3PbO2 ( 8HMe2Ea ( 2O2 ( 2Cu2PbO3(Me2Ea)3 ( Pb(Me2Ea)2 + 4H2O,

X = Cl, I, SCN.

Aaoa?iai?iii? aaoa?iyaea?i? eiiieaene ?c ni?aa?aeiioaiiyi Cu : Pb = 2 :
1 aoee io?eiai? a nenoaiao, ui i?noeee a?ae?ioei?eae iiiiaoaiieai?io, ca
?aaeoe??th:

4Cu + 3PbO2 + 4HEa(HCl + 2O2 = 2Cu2PbO3Cl(Ea)2 + PbCl2 + 4H2O.

Ooai?aiiy eiiieaeno Cu2PbCl(NCS)(HTea)2 cao?eniaaii a CH3CN i?e
iieueiiio ni?aa?aeiioaii? aeo?aeieo ?a/iaei Cu : Pb(SCN)2 : H3Tea(HCl =
2 : 1 : 1 oa a AeINI i?e ni?aa?aeiioaii? Cu : Pb(SCN)2 : H3Tea(HCl = 3 :
1 : 1. C eiai ?*-niaeo?o iiaeia c?iaeoe aeniiaie, ui o?ioe?aiaoia a?oia
eii?aeeiiaaia /a?ac aoii acioo ((CN = 2020 oa (CS = 770 ni-1).
Iieiaeaiiy /anoio aaeaioieo eieeaaiue (CN (2110, 2060 ni-1) oa (CS (820,
775 ni-1) a ?*-niaeo?? niieoee [Cu2Pb(NCS)3(Me2Ea)3] aea? iiaeeea?noue
c?iaeoe aeniiaie i?i i?enooi?noue ?cio?ioe?aiaoii? oa i?noeiai?
o?ioe?aiaoii? a?oi.

Ooai?aiiy aaoa?iyaea?ieo eiiieaen?a ?c ni?aa?aeiioaiiyi Cu : Pb = 1 : 2
oa?aeoa?ia aeey iiiiaoaiieai?io oa 2-aeeiaoeeai?iiaoaiieo a NI3II aai
AeINI:

Cu ( 2PbO2 ( 3HL ( 0,5O2 ( CuPb2O3L3 ( IO ( H2O,

X = Cl, Br, I.

A o?aoueiio ?icae?e? i?aaenoaaeai? ?acoeueoaoe AI?-niaeo?aeueieo,
?aioaaiino?oeoo?ieo oa iaaiaoio?i?/ieo aeine?aeaeaiue, a oaeiae
?acoeueoaoe aeine?aeaeaiiy i?ioeiooeeiii? aeoeaiino? neioaciaaieo
niieoe.

Niaeo?e AI? aeeiaoeeoi?iai?aeieo ?ic/ei?a aeine?aeaeoaaieo eiiieaen?a
i?e oaiia?aoo?? 20(N iiae?ai? ? iathoue oeiiaee aeaeyae aeey niaeo??a
?ic/ei?a niieoe i?ae?(??). I?e oaiia?aoo?? ??aeeiai acioo AI?-niaeo?e
aeeiaoeeoi?iai?aeieo ?ic/ei?a an?o oei?a aeine?aeaeoaaieo eiiieaen?a
iathoue aen?aeueiee aeaeyae. A iaeano? ia?aeaeueii? i???ioaoe?? niaeo?o
niinoa??aathoueny eiiiiiaioe iaaeoiiei? no?oeoo?e a?ae yae?a aoiio
i?ae?. A AI?-niaeo?ao eiiieaen?a ?c ni?aa?aeiioaiiyi Cu : Pb =
1 : 1 oa 1 : 2 a iaeano?

Oaaeeoey 2

Ia?aiao?e niaeo??a AI? aeeiaoeeoi?iai?aeieo ?ic/ei?a neioaciaaieo
niieoe.

Oi?ioea eiiieaeno

g0 a0·10-4,

ni-1 gII

g( AII·10-4,

ni-1 A(·10-4,

ni-1 aN,

An

293 E 77 K

[CuPbI2(Me2Ea)2] 2,116 71 2,262 2,040 178 17,0 11

[CuPbI2(Ea)2AeINI] 2,118 70 2,263 2,044 173 18,0 14

[Cu2Pb(SCN)3(Me2Ea)3] 2,132 72 2,273 2,061 176 19,5

[CuPb2I3(Me2Ea)3] 2,117 69 2,264 2,042 172 17,0 11

[CuPbI2(Dea)2] 2,114 70 2,262 2,038 175 18,0

.

Iniiai? e?enoaeia?ao?/i? oa?aeoa?enoeee niieoe, aeine?aeaeaieo
?aioaaiino?oeoo?ii, iaaaaeai? a oaae. 3.

A caeaaeiino? a?ae i?enooiino? eii?aeeiiaaieo iieaeoe AeINI,
aeine?aeaeai? aaoa?iyaea?i? eiiieaene iathoue iieaeoey?io aai iie?ia?io
(eaioethaiao aai oa?oaaoo) aoaeiao. Oaaeeoey 3

Iniiaii e?enoaeia?aoi/ii oa?aeoa?enoeee neioaciaaieo eiiieaenia

Oi?ioea

Neia.

I?.

Ia?aiao?e aeaiaioa?ii? eiii?ee

Z

R

a?. a (A) b (A) c (A) ((0) ( (0) ( (0)

[CuPbI2(Ea)2]2·2AeINI o?eee. P(1 7,713(2) 10,789(2) 11,923(2) 63,08(3)
74,70(3) 89,41(3) 2 0,039

[CuPbCl2(Me2Ea)2]2·H2O iii. P21/n 7,995(3) 15,008(7) 13,255(7) 90
105,88(4) 90 4 0,061

[CuPbBr2(Me2Ea)2AeINI]2 o?eee. P(1 8,266(2)
11,800(2) 11,882(2) 62,51(3) 72,87(3) 87,86(3) 2 0,040

[CuPbI2(Me2Ea)2]2 iii. P21/c 12,485(1) 8,490(1)
15,494(4) 90 93,68(2) 90 4 0,030

[CuPbI2(Me2Ea)2AeINI]2 ·2AeINI o?eee. P(1 8,305(3) 12,132(3) 12,755(3)
84,86(2) 80,79(3) 73,26(3) 2 0,044

[Cu2Pb2Cl3(NCS)(Me2Ea)4] iii. P21/n 7,917(2) 15,326(1) 13,005(3) 90
104,277(5) 90 4 0,032

[CuPbBrI(Me2Ea)2]2 iii. P21/c 12,316(5) 8,380(2) 15,312(2) 90 93,94(3)
90 4 0,048

[Cu2Pb(NCS)3(Me2Ea)3] iii. P21/c 14,726(3) 17,529(4) 10,498(2) 90
105,40(3) 90 4 0,061

[CuCl(H2Tea)][CuCl(H3Tea)]2 aaen. ?-3 8,144(2) 8,144(2) 8,225(1) 90 90
120 6 0,033

[Cu(NCS)(H2Tea)] ?iia. Pnma 10,605(2) 8,050(2) 12,538(3) 90 90 90 4
0,035

[Cu(NCS)((H2Tea)]2·AeINI oao?. ?4(1)/a 18,550(9)
18,550(7) 48,760(1) 90 90 90 4 0,076

[(CuL)2](SO4)2·(i-C3H7OH)2·3,5H2O ?iia. P21 14,015(3) 14,939(3)
16,941(3) 90 90 90 4 0,051

A iniia? e?enoae?/ii? aoaeiae eiiieaen?a iieaeoey?ii? aoaeiae
[CuPbBr2(Me2Ea)2AeINI]2, [CuPbI2(Me2Ea)2AeINI]2·2AeINI eaaeaoue
aeeia?i? oeaio?ineiao?e/i? iieaeoee [CuPbX2(Me2Ea)2AeINI]2 (?en.1).
Aeaa aoiie eenith oa aeaa aoiie acioo 2-aeeiaoeeai?iiaoaiieueieo a?oi
oi?iothoue o?ioe aee?eaeaiee ieinei-eaaae?aoiee eii?aeeiaoe?eiee
iie?aae? i?ae?. Iaeaeeae/? aei aoiio naeioeth aoiie eenith o?ueio
2-aeeiaoeeai?iiaoaiieueieo a?oi oa aoii eenith AeINI ooai?ththoue
neeueii aee?eaeaio eaaae?aoio i??ai?aeo c aoiiii naeioeth o aa?oei?.
A?eueo a?aeaeaeai? aoiie eiaeo aai a?iio, ?icoaoiaai? ia a?aenoaiiyo
3,285(1) — 3,390(1) (eiae), 3,068(1)-3,193(2)A (a?ii) a?ae aoiia
naeioeth, aeiiiaiththoue eiai eii?aeeiaoe?eia ioi/aiiy aei aee?eaeaiiai
ieoaaae?e/iiai. Iaeia c a?aenoaiae naeiaoeue-aaeiaai o?ioe iiaeiaaeaia a
ii??aiyii? c ?ioith, aiane?aeie aeiaeaoeiaiai eiioaeoo aoiia aaeiaaio c
aoiiii i?ae? ae?oai? iieiaeie aeeia?ii? iieaeoee.

Eiiieaen [CuPbI2(Ea)2]2·2AeINI — /ioe?eyaea?iee anioe?ao aeeia?ii?
aoaeiae. Aaiiao??y iaeaeeae/iai eii?aeeiaoe?eiiai ioi/aiiy i?ae?
(CuI2N2) ieinei-eaaae?aoia. Iaeaeeae/a eii?aeeiaoe?eia ioi/aiiy naeioeth
neeaaea?oueny c o?ueio aoii?a eenith 2-aeeiaoeeai?iiaoaiieueieo
a?oi oa aeaio aoii?a eiaeo.

Aeiaeaoeiaee eiioaeo aoiia naeioeth c aoiiii eiaeo non?aeiuei? iieaeoee
eiiieaeno ia?aoai?th? eiai eii?aeeiaoe?eiee iie?aae? o aee?eaeaiee
ieoaaae?. Oeae aea aoii eiaeo aeoaea neaaei aca?iiae?? c aoiiii
i?ae? ae?oai? iieiaeie aeeia?ii? iieaeoee eiiieaeno, aeiiiaithth/e
eii?aeeiaoe?eia ioi/aiiy i?ae? aei eaaae?aoii-i??ai?aeaeueiiai.
Aiane?aeie oaei? aeiaeaoeiai? aca?iiae?? aoii?a iaoae?a aeieea?
eaioethaiaa aoaeiaa aaoa?iyaea?iiai eiiieaeno (?en. 2). Iaeii?aeeiiaai?
iieaeoee AeINI caeiathoue ionoioe e?enoae?/ii? a?aoee.

Aaoa?iyaea?i? eiiieaene [Cu2Pb2Cl3(NCS)(Me2Ea)4] ?
[CuPbCl2(Me2Ea)2]2(H2O ?cino?oeoo?i? ? a?ae??ciythoueny iayai?noth
o?ioe?aiaoii? a?oie cai?noue iaeiiai c aoii?a oei?o (?en.3). A iniia?
aoaeiae iaio eiiieaen?a eaaeeoue oeaio?ineiao?e/iee /ioe?eyaea?iee
aeeia?, ui neeaaea?oueny c aeaio iaeeieoeue CuPbO2(Me2Ea)2 (aea O = Cl,
Cl/NCS), niieo/aieo eeniaaeie i?noeaie, a ?ie? yeeo aenooiathoue aoiie
eenith 2-aeeiaoeeai?iiaoaiieueieo a?oi. A eiiieaen?
[Cu2Pb2Cl3(NCS)(Me2Ea)4] i?noeiao ooieoe?th oaeiae aeeiio? aoii acioo
o?ioe?aiaoii? a?oie. Ca aeaiieie Eaia??aeaenueeiai e?enoaeia?ao?/iiai
aaieo, ia nueiaiaei? a?aeiii ia a?eueo ye 20 no?oeoo? eiiieaen?a, a yeeo
i?enooi?e (-NNCS-aoii acioo. Iienoaaia niieoea ? ia?oei i?eeeaaeii
eiiieaeno, aea i?aeue oa naeiaoeue aoee a ca’ycai? oaeei /eiii.
*ioe?eyaea?i? oa?oioaaiiy a iaio eiiieaenao ca aeiiiiiaith iiaea?eieo
i?noe?a Pb-Cl-Pb ca’ycai? a iane?i/aii? eaioethae (?en.4), ye? iiaeia
?icaeyaeaoe ye no?ae/ano? iie?ia?e c eooii aeecueei 33( i?ae non?aei?ie
ieiueiaie Pb2O2 oa Pb2Cl2.

Eiiieaene [CuPbI2(Me2Ea)2]2 oa [CuPbBrI(Me2Ea)2]2 ?cino?oeoo?i?. A
eiiieaen? [CuPbBrI(Me2Ea)2]2 iieiaeaiiy aaeiaai?aeieo aoii?a caeiathoue
aoiie eiaeo oa a?iio o ni?aa?aeiioaii? 3 : 2 oa 2 : 3, a?aeiia?aeii,
aeey aeaio iacaeaaeieo iiceoe?e (?en.5). Aeiaaeeie ca’yce?a
naeiaoeue — aaeiaai a eiiieaen? [CuPbBrI(Me2Ea)2]2 aeaui ei?ioo?, a
ii??aiyii? c aeiaaeeiaie ca’yce?a naeiaoeue — eiae a eiiieaen?
[CuPbI2(Me2Ea)2]2. Oeae oaeo i?aeoaa?aeaeo? i?enooi?noue a niieooe?
iaeii/anii ye aoii?a eiaeo, oae ? aoii?a a?iio, ui aeineoue aaaeei
aecia/eoe aiae?oe/ii. Aoiie aaeiaai?a, aenooiath/e a ?ie? i?noe?a
i?ae o?ueiia aoiiaie iaoae?a, iia’ycothoue eiiieaeni? iieaeoee a oa?e
(?en.6), ui ?icoaoiaai? ia?aeaeueii ieiuei? e?enoaeo bc.

A o?eyaea?iiio eiiieaen? [Cu2Pb(NCS)3(Me2Ea)3] i?enooi? aeaa no?oeoo?ii
a?aei?ii? aoiie i?ae? (?en.7). Eii?aeeiaoe?eiee iie?aae? aoiia Cu(1)
yaey? niaith eaaae?aoio i??ai?aeo, aacenio ieiueio yei? oi?iothoue
aeaa aoiie

eenith oa aoii acioo 2-aeeiaoeeai?iiaoaiieueieo a?oi ? aoii acioo
o?ioe?aiaoii? a?oie. Aen?aeueio iiceoe?th a eaaae?aoi?e i??ai?ae?
caeia? aoii acioo ?ioi? o?ioe?aiaoii? a?oie. Aoii Cu(2) ioi/aiee aeaiia
aoiieie eenith, aoiiii acioo 2-aeeiaoeeai?iiaoaiieueieo a?oi oa aoiiii
acioo o?ioe?aiaoii? a?oie, ye? ooai?ththoue iaieineee /ioe?eeooiee.
?icaeyaeath/e eii?aeeiaoe?eia ioi/aiiy Cu(2), ne?ae a?aoe aei
oaaae neaaeo aca?iiae?th aeaiiai aoiia c aoiiii n??ee o?ioe?aiaoii?
a?oie non?aeiuei? iieaeoee oa aoiiii eenith 2-aeeiaoeeai?iiaoaiieueii?
a?oie, ui ?icoaoiaaiee ia a?aenoai? 2,71 A. O?ioe?aiaoi? a?oie,
eii?aeeioth/enue aei aoii?a i?ae? ca ?aooiie n??ee oa
acioo, ia’?aeiothoue non?aei? o?eyaea?i? iieaeoee a aeeia?e. Iaeaeeae/o
eii?aeeiaoe?eio noa?o aoiia naeioeth ooai?ththoue o?e aoiie
eenith ? aoii acioo 2-aeeiaoeeai?iiaoaiieueieo a?oi oa aoii acioo
o?ioe?aiaoii? a?oie. A?eueo a?aeaeaeai? eiioaeoe c aoiiaie n??ee
o?ioe?aiaoieo a?oi non?aei?o iieaeoe (Pb(((S = 3,266(5); 3,452(5) A)
ca?eueoothoue eii?aeeiaoe?eia /enei naeioeth aei naie. Oey aeiaeaoeiaa
i?aeiieaeoey?ia aca?iiae?y ca ?aooiie neaaeeo ca’yce?a aoii?a
naeioeth c a?eueo a?aeaeaeaieie aoiiaie n??ee i?ecaiaeeoue aei
ooai?aiiy oa??a aeeia?ieo iieaeoe, ui ?ici?uothoueny acaeiaae in?
e?enoaeo b (?en.8).

Iaaiaoio?i?/i? aeanoe- aino? aaoa?iyaea?ieo eiiieaen?a aoee
aeine?aeaeai? a oaa?aeiio noai? (iaoiae Oa?aaeay) oa a ?ic/ei? (iaoiae
Aaaina). Iiia?aaei? aeine?aeaeaiiy iieacaee, ui iaaiaoio?i?/ia
iiaaae?iea aaoa?iyaea?ieo eiiieaen?a ?c ni?aa?aeiioaiiyi Cu : Pb = 1 : 1
oa 1 : 2 iiae?aia. Aaee/eie iaai?oiiai iiiaioo aeey eiiieaeno
[CuPbI2(Me2Ea)2]2 a ?ioa?aae? oaiia?aoo? 121-293 E i?aeoe/ii ia
ci?iththoueny ?c cieaeaiiyi oaiia?aoo?e. Na?aaeiy aaee/eia (ao neeaaea?
1,77 I.A. ia iaeei aoii i?ae?, ui a?aeiia?aea? /enoi ni?iiaiio
cia/aiith iaai?oiiai iiiaioo aeey nenoai c iaeei iania?aiei aeaeo?iiii.
I?e e?iiaoi?e oaiia?aoo?? iaai?oiee iiiaio eiiieaeno
[Cu2Pb(NCS)3(Me2Ea)3] ia iaeei aoii i?ae? neeaaea? 1,85 I.A. I?e
cieaeaii? oaiia?aoo?e cia/aiiy iaai?oiiai iiiaioo ciaioo?oueny,
aeinyaath/e i?e 5 E aaee/eie 1,0 I.A. (?en.9), ui aeaco? ia iayai?noue
neaaei? aioeoa?iiaai?oii? aca?iiae??, iai?iiee ia?aiao? yei? (J = — 5,0
ci-1) aoa ?ic?aoiaaiee ca ??aiyiiyi Ae?i?-Aaoa?na aeey a?yaea?ieo
nenoai.

Aaee/eie iaai?oieo iiiaio?a aeine?aeaeaieo niieoe o ?ic/eiao iaiiaaii
ocaiaeaeothoueny c aaee/eiaie iaai?oieo iiiaio?a aeey oaa?aeeo c?ace?a.
Oea aea? iiaeeea?noue c?iaeoe aeniiaie, ui aoaeiaa o?aaiaio?a niieoe,
ye? i?noyoue ia?aiaai?oi? oeaio?e, i?e ?ic/eiaii? i?eioeeiiai ia
ci?ith?oueny.

Aeine?aeaeaiiy aino?i? oiene/iino? aaoa?iyaea?ieo eiiieaen?a iieacaee,
ui ?o EAe50 noaiiaeoue 30-40 ia/ea ? ciaoiaeeoueny ia ??ai? EAe50
eii?aeeiaoe?eieo niieoe i?ae?(??). Aeine?aeaeaiiy iieacaee, ui na?aae
neioaciaaieo eiiieaen?a iaea?eueoo i?ioeiooeeiio aeoeai?noue ii
a?aeiioaiith aei ee?oei anoeeoiiai ?aeo A?e?oa aeyaeee eiiieaene c HEa
oa HMe2Ea. ?o i?ioeiooeeiia ae?y i?iyaey?oueny aaea /a?ac 3 aiaeeie ?
i?eaiaeeoue aei caaeaae? 44 — 70 % ee?oei. Iiaia caaeaaeue ?aeiaeo
ee?oei ianoa?, ye i?aaeei, /a?ac 24 aiaeeie.

AENIIAEE

Cai?iiiiiaaii iiaee i?aeo?ae aei neioaco aaoa?iyaea?ieo eiiieaen?a, a
iniia? yeiai eaaeeoue aca?iiae?y ii?ioeo iaeiiai iaoaeo c n?eeth ?ioiai
a i?enooiino? i?ioiiiaeiii?iiai eiiieaeniooai?thth/iai ?aaaaioo. Oeae
i?aeo?ae ?aae?ciaaii ia iiaeaeuei?e nenoai?, ui i?noeoue iaoae?/io
i?aeue, n?eue naeioeth oa iaaiaeiee ?ic/ei ai?iinie?oo.

Aea/aia aca?iiae?y ii?ioeo i?ae? c nieyie (oei?eae, a?ii?ae, eiaeeae,
o?ioe?aiao, aoeaoao) naeioeth a iaaiaeieo ?ic/eiao (AeIOA, AeINI, NI3II,
NI3NN) ai?iinie?o?a (HEa, HMe2Ea, H2Dea, H3Tea) oa ?o a?ae?ioei?eae?a ?
anoaiiaeaii ooai?aiiy o?ueio oei?a aaoa?iyaea?ieo eiiieaen?a, ye?
a?ae??ciythoueny ni?aa?aeiioaiiyi Cu : Pb:

— aaoa?iyaea?i? eiiieaene ?c ni?aa?aeiioaiiyi Cu : Pb = 1 : 1
ooai?ththoueny

o an?o aea/aieo nenoaiao ca aeiyoeii nenoai c o?eaoaiieai?iii;

— ooai?aiiy aaoa?iyaea?ieo eiiieaen?a ?c ni?aa?aeiioaiiyi Cu : Pb = 1 :
2

oa?aeoa?ia aeey iiiiaoaiieai?io oa 2-aeeiaoeeai?iiaoaiieo a NI3II oa

AeINI;

— aaoa?iyaea?i? eiiieaene ?c ni?aa?aeiioaiiyi Cu : Pb = 2 : 1
ooai?ththoueny

a on?o aea/aieo nenoaiao ca aeiyoeii NI3II.

Iieacaia iiaeeea?noue i?yiiai neioaco aaoa?iai?iiieo eiiieaen?a, ui
i?noyoue i?aeue oa naeiaoeue.

?ic?iaeaii iaoiaee i?yiiai neioaco, ca yeeie aia?oa iaea?aeaii 63
aaoa?iyaea?ieo eiiieaene, ui i?noyoue i?aeue oa naeiaoeue. ?o aoaeiaa
aea/aia iaoiaeaie ?*-, AI?-niaeo?ineii??, iaaiaoio?i?? oa
?aioaaiino?oeoo?iiai aiae?co.

I?iaaaeaiee iiaiee ?aioaaiino?oeoo?iee aiae?c 12 neioaciaaieo eiiieaen?a
? iieacaii, ui:

— oiiae i?yiiai neioaco ni?eythoue ooai?aiith iie?yaea?ieo
eiiieaen?a

iieaeoey?ii? oa iie?ia?ii? aoaeiae, ui i?noyoue no?oeoo?i?
o?aaiaioe

I1I2I2, a yeeo aoiie iaoae?a ca’ycai? ca ?aooiie i?noeiaeo aoii?a
eenith

caeeoe?a ai?iinie?o?a;

— ooai?aiiy eiiieaen?a iieaeoey?ii? aoaeiae oa?aeoa?ii aeey niieoe, ui

i?noyoue iieaeoee eii?aeeiiaaiiai ?ic/eiieea;

— eaioethaiaa oa oa?oaaoa aoaeiaa aaoa?iyaea?ieo eiiieaen?a
?aae?co?oueny

ca ?aooiie i?noeiai? ooieoe?? aoii?a aaeiaai?a oa n??ee o?ioe?aiaoieo
a?oi.

?acoeueoaoe iaaiaoio?i?/ieo aeine?aeaeaiue iieacaee iayai?noue iai?iii?
aca?iiae?? aioeoa?iiaai?oiiai oeio, yea oa?aeoa?ia aeey aaoa?iyaea?ieo
eiiieaen?a ?c ni?aa?aeiioaiiyi Cu : Pb = 2 : 1, ui i?noyoue no?oeoo?iee
o?aaiaio Cu2O2.

Aeine?aeaeaia i?ioeiooeeiia ae?y neioaciaaieo aaoa?iyaea?ieo eiiieaen?a
? anoaiiaeaia ?o aeniea aeoeai?noue ii a?aeiioaiith aei ee?oei
anoeeoiiai ?aeo A?e?oa iaa?oue i?e eiioeaio?aoe?? 5(10-8 iieue/e.

Nienie ioae?eaoe?e

Vassilyeva Olga Yu., Kokozay Vladimir N., Zhukova Nadezhda I. and
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containing 2-dimethylaminoethanol: direct synthesis and structure //
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Kovbasyuk Larisa A., Vassilyeva Olga Yu., Kokozay Vladimir N. and Linert
Wolfgang. Crystal structure of di-bromo-bis(2-dimethylaminoethanolato)
(dimethylsulfoxide)-copper(II)-lead(II) dimer obtained by direct
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Vassilyeva Olga Yu., Kovbasyuk Larisa A., Kokozay Vladimir N., Skelton
Brian W. and Linert Wolfgang. Mixed-metal copper(II) and lead(II)
complexes due to (- and (3-bridging alkoxo groups from
2-dimethylaminoethanol. Chains and layers in
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Polyhedron. — 1998. — V.17. — ? 1.- ?. 85-91.

Vassilyeva O.Yu., Kovbasyuk L.A., Kokozay V.N. and Linert W. Crystal
structure of bis(aminoethanolato)-di-iodo-copper(II)-lead(II)dimer
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Kovbasyuk L.A., Vassilyeva O.Yu., Kokozay V.N., Linert W. and Reedijk J.
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Kovbasyuk Larisa A., Vassilyeva Olga Yu., Kokozay Volodymyr N., Linert
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iieo/aiiiai i?yiui neioacii // Nai?iee oacenia Iaoeeiiaeueiie
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from zerovalent metal // Book of Abstracts. Anglo/German Inorganic
Chemistry Meeting. — Marburg (Germano). — 1997. — P.72.

Kokozay V.N., Vassilyeva O.Yu., Kovbasyuk-Mokhir L.A., Makhankova V.O.,
Linert W. and Weinberger P. An approach to mixed-metal compounds with
aminoalcohols // Book of Abstracts. 32nd International Conference on
Coordination Chemistry . — Santiago (Chile). — 1997. — P. 55.

Vassilyeva O.Yu., Kovbasyuk L.A., Kokozay V.N.. Crystal Structure of
Di-iodo- bis(aminoethanolato)-copper (II)-lead(II)dimer
dimethylsulfoxide solvate // Book of Abstracts. Seventeenth European
Crystallographic Meeting. — Lisbon (Portugal). — 1997. — P.121.

Kokozay V.N., Manskaya J.A., Domasevitch K.V., Kovbasyuk L.A.,
Vassilyeva O.Yu., Makhankova V.G., Linert W. and Weinberger P.. New
synthetic strategy for coordination compounds involving zero valent
metals as starting materials // Book of Abstracts. XXXIII International
conference on coordination chemistry. — Florence (Italy). — 1998. —
P.178.

Vassilyeva Olga Yu., Kovbasyuk Larisa A., Kokozay Volodymyr N. and
Skelton Brian W. A novel Cu/Pb mixed-metal polymeric complex with
unusual N-bonded, bridging thiocyanate // Book of Abstracts. Annual
Meeting of American Crystallographic Association. — Arlington (USA). —
1998. — P.169.

Eiaaanthe E.A. I?yiee neioac aaoa?iyaea?ieo eiiieaen?a i?ae? oa naeioeth
c ai?iinie?oaie. — ?oeiien.

Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa o?i?/ieo iaoe ca
niaoe?aeuei?noth 02.00.01 — iai?aai?/ia o?i?y. — Ee?anueeee
Iaoe?iiaeueiee oi?aa?neoao ?iai? Oa?ana Oaa/aiea, Ee?a, 1999.

Aeena?oaoe?th i?enay/aii ?ic?iaoe? iiaiai i?aeoiaeo aei iaea?aeaiiy
aaoa?iyaea?ieo eiiieaen?a a oiiaao i?yiiai neioaco. C’yniaai? iniiai?
caeiiii??iino? aca?iiae?? ii?ioeo i?ae? c nieyie naeioeth a iaaiaeieo
?ic/eiao ai?iinie?o?a oa ?o a?ae?ioei?eae?a ? anoaiiaeaii ooai?aiiy
o?ueio oei?a aaoa?iyaea?ieo eiiieaen?a, ye? a?ae??ciythoueny
ni?aa?aeiioaiiyi Cu : Pb. ?ic?iaeaii iia? iaoiaeeee iaea?aeaiiy
aaoa?iyaea?ieo niieoe, ca yeeie aia?oa neioaciaaii 63 aaoa?iyaea?i?
eiiieaene. ?o aoaeiaa aea/aia iaoiaeaie ?*-, AI?-niaeo?ineii?? oa
iaaiaoio?i??. I?iaaaeaii iiaiee ?aioaaiino?oeoo?iee aiae?c 12
eii?aeeiaoe?eieo niieoe. Aeyaeaia aeniea i?ioeiooeeiia aeoeai?noue
neioaciaaieo eiiieaen?a ii a?aeiioaiith aei ee?oei anoeeoiiai ?aeo
A?e?oa. Iieacaii, ui canoinoaaiiy i?yiiai neioaco a?aee?eaa? iiaee
iai?yiie a iaeano? o?i?? aaoa?iyaea?ieo eiiieaen?a.

Eeth/ia? neiaa: i?yiee neioac, aaoa?iyaea?i? eiiieaene, i?aeue,
naeiaoeue, ai?iinie?o, e?enoae?/ia aoaeiaa, ?*-niaeo?e, AI?-niaeo?e,
iaaiaoio?i?/i? aeine?aeaeaiiy, i?ioeiooeeiia aeoeai?noue.

Eiaaanthe E.A. I?yiie neioac aaoa?iyaea?iuo eiiieaenia iaaee e naeioea n
aieiinie?oaie. — ?oeiienue.

Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa oeie/aneeo iaoe ii
niaoeeaeueiinoe 02.00.01 — iai?aaie/aneay oeiey. — Eeaaneee
Iaoeeiiaeueiue oieaa?neoao eiaie Oa?ana Oaa/aiei, Eeaa, 1999.

Aeenna?oaoeey iinayuaia ?ac?aaioea iiaiai iiaeoiaea e iieo/aieth
aaoa?iyaea?iuo eiiieaenia a oneiaeyo i?yiiai neioaca.

Aeey aeinoeaeaiey iinoaaeaiiie oeaee aue i?iaaaeai iiene nenoai,
iaeaieaa iiaeoiaeyueo aeey neioaca aaoa?iyaea?iuo eiiieaenia, eioi?uie
ieacaeenue nenoaiu, aeeth/athuea ii?ioie iaeiiai iaoaeea e nieue
ae?oaiai. Auyaeaiu iniiaiua caeiiiia?iinoe acaeiiaeaenoaey ii?ioea
iaaee n nieyie naeioea (oei?eae, a?iieae, eiaeeae, oeioeeaiao, ieo?ao,
aoeaoao) e iaaiaeiuie (aeeiaoeeoi?iaieae, aeeiaoeenoeueoieneae, iaoaiie,
aoeaoiieo?ee) ?anoai?aie aieiinie?oia (iiiiyoaiieaiei,
2-aeeiaoeeaieiiyoaiie, aeeyoaiieaiei, o?eyoaiieaiei), a oaeaea eo
aeae?ioei?eaeia. Auei onoaiiaeaii, /oi acaeiiaeaenoaea a enneaaeiaaiiuo
nenoaiao i?eaiaeeo e ia?aciaaieth o?ao oeiia aaoa?iyaea?iuo eiiieaenia n
?acee/iui niioiioaieai Cu : Pb. Aaoa?iyaea?iua eiiieaenu ia?aiai oeia
(Cu : Pb = 1 : 1) ia?acothony ai anao eco/aiiuo nenoaiao ca eneeth/aieai
nenoai n o?eyoaiieaieiii. Ia?aciaaiea eiiieaenia aoi?iai oeia (Cu : Pb
= 2 : 1) oa?aeoa?ii aeey anao eco/aiiuo nenoaiao e?iia iaoaiieueiuo
?anoai?ia. Eiiieaenu o?aoueaai oeia (Cu : Pb = 1 : 2) ia?acothony a
nenoaiao n iiiiyoaiieaieiii e 2-aeeiaoeeaieiiyoaiieii a NI3II e AeINI.
Aeey nenoai, eioi?ua niaea?aeao iiiiyoaiieaiei eee 2-aeeiaoeeaieiiyoaiie
e a?iieae eee eiaeeae naeioea, oa?aeoa?ii ia?aciaaiea aaoa?iyaea?iuo
eiiieaenia, a ninoaa eioi?uo aoiaeeo AeINI.

Iieacaii, /oi i?e eniieueciaaiee aeae?ioei?eaea aieiinie?oa eee aeaoo
nieae naeioea n ?aciuie aieiiaie iiaeia a iaeio noaaeeth iieo/eoue
aaoa?iaieiiiua aaoa?iyaea?iua eiiieaenu.

A neo/aa AeIOA e AeINI, eae i?aaeei, nouanoaoao i?yiay caaeneiinoue
iaaeaeo niioiioaieai Cu : Pb a enoiaeiie niane e ia?acothuainy
niaaeeiaiee.

Iieo/aiiua eiiieaenu auee eco/aiiu iaoiaeaie EE- e AI?-niaeo?ineiiee, a
oaeaea iaaiaoioeie/anee — a oaa?aeii ninoiyiee (iaoiae Oa?aaeay) e a
?anoai?ao (iaoiae Yaaina). Onoaiiaeaii, /oi a aieueoeinoaa neo/aaa
oeioeeaiaoiay a?oiia eii?aeeie?oaony e aoiio iaoaeea /a?ac aoii acioa, a
aoeaoaoiay a?oiia yaeyaony iinoeeiaie. Ec aeaiiuo AI?-niaeo?ia auei
ii?aaeaeaii iniiaiia ninoiyiea aoiia iaaee a aaoa?iyaea?iuo eiiieaenao.
Aaee/eie iaaieoiuo iiiaioia eco/aiiuo niaaeeiaiee a ?anoai?a eiatho
aeeceea cia/aiey e aaee/eiaie iaaieoiuo iiiaioia aeey oaa?aeuo
ia?acoeia. Yoi iicaieyao naeaeaoue auaiae, i oii, /oi no?iaiea o?aaiaioa
niaaeeiaiey, niaea?aeauaai ia?aiaaieoiue oeaio?, i?e ?anoai?aiee
i?eioeeieaeueii ia eciaiyaony.

Iieiue ?aioaaiino?oeoo?iue aiaeec 12 neioace?iaaiiuo eiiieaenia iieacae,
/oi oneiaey i?yiiai neioaca niinianoaotho ia?aciaaieth iieeyaea?iuo
eiiieaenia, niaea?aeaueo no?oeoo?iua o?aaiaiou I’I’’I2, a eioi?uo aoiiu
iaaee e naeioea naycaiu ca n/ao iinoeeiauo eenei?iaeiuo aoiiia inoaoeia
aieiinie?oia. O?aaiaio Pb2I2 eiaao ieineia ?iiae/aneia no?iaiea.
Ioeeiiaiea io ieaia?iinoe o?aaiaioa Cu2I2 i?eaiaeeo e oiaiueoaieth
ia?ae?uaaiey aoiiiuo i?aeoaeae iaaee, /oi ineaaeyao iaiaiiia
acaeiiaeaenoaea aioeoa??iiaaieoiiai oeia iaaeaeo aoiiaie iaoaeea. A
?yaeo Cl — Br — I no?iaiea ea?eana Cu2Pb2L4 iieaeoe eiiieaenia
i?eioeeieaeueii ia eciaiyaony, /oi naeaeaoaeuenoaoao i aai iiauoaiiie
no?oeoo?iie aeanoeinoe, nio?aiythuaeny e i?e /anoe/iie caiaia
oei?eaeiiai aieiia ia oeioeeaiaoiue. Iieiia caiauaiea aaeiaaieaea ia
oeioeeaiao i?eaiaeeo e ia?aciaaieth o?aouyaea?iiai eiiieaena e e
nouanoaaiiiio eciaiaieth no?iaiey iieaeoeu.

Oiaaea eae no?oeoo?iay eaeaioe/iinoue aaeeieoe Cu2Pb2L4 nio?aiyaony
iacaaeneii io i?e?iaeu aaeiaaieaeiiai aoiia e aieiinie?oa,
e?enoaeee/aneay no?oeoo?a eiiieaenia a oeaeii ioee/aaony. A caaeneiinoe
io i?enoonoaey iieaeoe AeINI a eii?aeeiaoeeiiiie noa?a aoiia naeioea,
?aaeecoaony iieaeoey?iia ([CuPbBr2(Me2Ea)2AeINI]2,
[CuPbI2(Me2Ea)2AeINI]2·2AeINI) eeai iieeia?iia ([CuPbI2(Ea)2]2·2AeINI,
[CuPbCl2(Me2Ea)2]2·H2O, [Cu2Pb2Cl3(NCS)(Me2Ea)4], [CuPbI2(Me2Ea)2]2,
[Cu2Pb(NCS)3(Me2Ea)3], [CuPbBrI(Me2Ea)2]2) no?iaiea eiiieaenia.
Oeaii/a/iay eee neienoay no?oeoo?a aaoa?iyaea?iuo eiiieaenia
ia?acoaony ca n/ao iinoeeiaie ooieoeee aoiiia aaeiaaiia eee na?u
oeioeeaiaoiuo a?oii, eioi?ua niaaeeiytho aoiiu iaaee e naeioea ninaaeieo
iieaeoe a neie eee oeaie, ninoiyuea ec /a?aaeothueony o?aaiaioia Pb2X2
(X = Cl, I) e Pb2I2.

Onoaiiaeaia aunieay i?ioeaiiiooieaaay aeoeaiinoue aaoa?iyaea?iuo
eiiieaenia ii ioiioaieth e eeaoeai anoeeoiiai ?aea Y?eeoa.

Eeth/aaua neiaa: i?yiie neioac, aaoa?iyaea?iua eiiieaenu, iaaeue,
naeiaoe, aieiinie?o, e?enoaee/aneia no?iaiea, EE-niaeo?u, AI?-niaeo?u,
iaaiaoioeie/aneea enneaaeiaaiey, i?ioeaiiiooieaaay aeoeaiinoue.

Kovbasyuk L.A. Direct synthesis of the Cu/Pb heteronuclear complexes
with aminoalcohols. — Manuscript.

Thesis for a candidate’s degree by speciality 02.00.01 — inorganic
chemistry. — Kyiv National Taras Shevchenko University, Kyiv, 1999.

The dissertation is devoted to development of a new approach to obtain
heteronuclear complexes by direct synthesis. The interaction of copper
powder with lead salts in non-aqueous solutions of aminoalcohols as well
as aminoalcohol hydrochlorides has been studied and complexes with
different Cu : Pb ratio have been obtained. The new synthetic procedures
to heteronuclear compounds have been elaborated and 63 novel Cu/Pb
heteronuclear complexes have been prepared using those. The compounds
were studied by IR-, EPR-spectroscopy, magnetochemistry and also tested
for antitumour activity. The crystal structures of the 12 new complexes
have been determined by X-Ray single crystal analysis. Direct synthesis
is shown to be a new promising area of research in chemistry of
heteronuclear compounds.

Key words: direct synthesis, heteronuclear complexes, copper, lead,
aminoalcohol, crystal structure, IR-spectra, EPR-spectra, magnetic
measurements, antitumours activity.

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