EE?ANUeEEE OI?AA?NEOAO ?IAI? OA?ANA OAA*AIEA
Ia i?aaao ?oeiieno
IINEA?I Iaaei Iao?iae/
OAeE 621.315.59: 548.52: 546.681
OA?IIAeEIAI?EA ? E?IAOEEA OACIOOAI?AIIss
A AAAAOIEIIIIIAIOIEO IAI?AI?IA?AeIEEIAEO NENOAIAO
01.04.07 – o?ceea oaa?aeiai o?ea
Aaoi?aoa?ao
aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy aeieoi?a
o?ceei-iaoaiaoe/ieo iaoe
Ee?a–1999
Aeena?oaoe??th ? ?oeiien
?iaioa aeeiiaia a
Naieo-Iaoa?ao?cueeiio aea?aeaaiiio aeaeo?ioaoi?/iiio oi?aa?neoao? (EAO?)
oa AEeoiie?nueeiio ?iaeaia?ii-oaoiieia?/iiio ?inoeooo?
Io?oe?ei? iiiiaioe:
1. Eenia Aieiaeeie? ?aaiiae/, aeieoi? o?ceei-iaoaiaoe/ieo iaoe, aeioeaio
eaoaae?e caaaeueii? o?ceee, noa?oee iaoeiaee ni?a?ia?oiee, canooiiee
aeaeaia c iaoeiai? ?iaioe Ee?anueeiai oi?aa?neoaoo ?iai? Oa?ana
Oaa/aiea.
2. Iaeai?iaea Aieiaeeie? Iao?iae/, aeieoi? o?ceei-iaoaiaoe/ieo iaoe,
noa?oee iaoeiaee ni?a?ia?oiee, caa?aeoaa/ a?aeae?eii ?inoeoooo i?iaeai
iaoa??aeiciaanoaa ?iai? ?.I. O?aioeaae/a IAI Oe?a?ie.
3. Eiiaeiaa ?a?na Aanee?aia, aeieoi? oaoi?/ieo iaoe, i?ioani?,
i?ia?aeiee iaoeiaee ni?a?ia?oiee ?inoeoooo iai?ai?ia?aeiee?a IAI
Oe?a?ie, aea?/? Eao?aao aea?aeaaii? i?ai?? Oe?a?ie.
I?ia?aeia onoaiiaa:
Iaeanueeee aea?aeaaiee oi?aa?neoao ?iai? ?.?. Ia/i?eiaa.
Caoeno aeena?oaoe?? a?aeaoaeaoueny “21” /a?aiy 1999 ?. ia 14:30 aiae. ia
can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee Ae 26.001.23 a Ee?anueeiio
oi?aa?neoao? ?iai? Oa?ana Oaa/aiea ca aae?anith: 252650 INI, Ee?a,
i?iniaeo Aeaaeai?ea Aeooeiaa, 6.
C aeena?oaoe??th iiaeia iciaeiieoeny a a?ae?ioaoe? Ee?anueeiai
oi?aa?neoaoo ?iai? Oa?ana Oaa/aiea.
Aaoi?aoa?ao ?ic?neaiee “17” o?aaiy 1999 ?.
A/aiee nae?aoa?
niaoe?ae?ciaaii? ?aaee,
i?ioani?
A.A. Io?eiaiei
CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE
AEOOAEUeI?NOUe OAIE. Aeinyaiaiiy aeaeo?iiii? oaoi?ee o?nii iia’ycai? c
?ic?iaeaie iiaeo oa oaeineiiaeaiiyi no/anieo oyaeaiue i?i o?ce/i?
i?ioeane, ui i?io?eathoue i?e c?iuoaaii? neeaaeieo iai?ai?ia?aeieeiaeo
oaa?aeeo ?ic/ei?a. Io?eiaiiy caaeaieo aeaeo?i-o?ce/ieo aeanoeainoae
no?oeoo? i?eionea? ca?eueoaiiy /enea eiiiiiaio?a oaa?aeiai ?ic/eio c
iaiaei?iiei i?aoeec?eiei aeai?ii eiai eiiiiiaioiiai oa
eiioeaio?aoe?eiiai neeaaeo i?e aenie?e no?oeoo?i?e aeineiiaeino?. C
?inoii /enea eiiiiiaio?a iai?ai?ia?aeieea ?, ioaea, ?c ca?eueoaiiyi
oa?iiaeeiai?/ieo nooiai?a naiaiaee nenoaie, c?inoathoue neeaaeiiu? ia
o?eueee a aia?aoo?iiio ioi?ieaii? i?ioeano oaciooai?aiiy, aea e iiooeo
iaoiae?a ea?oaaiiy i?ioeanii inaaeaeaiiy iaoa??ae?a ?c caaeaieie
aeanoeainoyie.
Iaea?eueo? ia?niaeoeae a ??oaii? oe??? i?iaeaie o?ceee iai?ai?ia?aeiee?a
iia’ycothoueny c ?? oa?iiaeeiai?/iei iienii oa ianooiiei iaoaiaoe/iei
iiaeaethaaiiyi i?ioeano oaciooai?aiiy. ??oaiiy oaei? caaea/? a ?aieao
oaiaiieia?/ii? oa?iiaeeiai?ee i?eionea? noi?nia i?iaaaeaiiy oai?aoe/ieo
aeine?aeaeaiue oa oe?eani?yiiaaieo aenia?eiaio?a i?e iaia?a?aiiio
ei?aeooaaii? ye o?ce/ieo oyaeaiue i?i i?ioeane, ui i?io?eathoue, oae ?
oiia i?iaaaeaiiy iio??aieo aenia?eiaio?a.
Aeinyaioo? oni?oe a ia/enethaaeuei?e oaoi?oe? oa ia/enethaaeuei?e
iaoaiaoeoe? noi?nii c aeinyaiaiiyie a ?ic?iaeao aenia?eiaioaeueii? aace
a?aee?eee ia?niaeoeae a ?aae?caoe?? oaeiai aeaeo iiaeaethaaiiy noiniaii
neeaaeieo iai?ai?ia?aeieeiaeo nenoai. A oeueiio a?aeiioaii? oaiaoeea
?iaioe, ui iia’ycaia c oai?aoe/iei iienii i?ioean?a oaciooai?aiiy i?e
io?eiaii? iaea?eueo aaaeeeaeo oaa?aeeo ?ic/ei?a aeey i?eeaae?a
aeaeo?iiii? oaoi?ee, ? AEOOAEUeIITH.
Iaea?eueo oe?iei canoiniaoaaiei ? ia?niaeoeaiei ? can?a ae?iuoaaiiy
e?enoae?a oa ie?aie ?c ??aeei? oace. Aeinoaoiuei iecuee? oaiia?aoo?e
?inoo, a?aeiiaethaaeueia aoiinoa?a i?ioeano, a oaeiae, ye i?aaeei,
iacia/ia a?aeoeeaiiy ?inoiai? nenoaie a?ae oa?iiaeeiai?/ii ??aiiaaaeiiai
noaio, yea aeicaiey? aoaeoeaii ea?oaaoe i?ioeanii, noaaeyoue oaeiai
aeaeo iaoiaee a ?yae iaea?eueo oe?iei aeei?enoiaoaaieo ? ia?niaeoeaieo.
O?oaeiiu? a ea?oaaii? i?ioeanii e?enoae?caoe?? a aeaiee /an a iniiaiiio
ia?aai?ththoueny aii??e/iei oeyoii. Oea noa? iiaeeeaei, i?eeiath/e aei
oaaae oe?ieo aenia?eiaioaeueio ?ioi?iaoe?th, yea iaeiie/aia oaoiieiaaie.
A oie aea /an aecia/aiiy oiia io?eiaiiy iaoa??aeo aeecueeeo aei
iioeiaeueieo cae?enith?oueny ia i?aeoeoe? aeaeaei ia caaaeaee ii
iaeei?iooiio oeyoo. Oaea neooaoe?y noa? oe?eeii c?icoi?eith, yeui
caaaeaoe, ui aaaaoieiiiiiaioi? nenoaie aaaeooue naaa a aaaaoueio
aeiaaeeao aeaeaei ia oae, ye niieoee, ui ?o ooai?ththoue. Oea iaoiiaeaii
aaaaoueia oa?iiaeeiai?/ieie i?e/eiaie. Aei ieo, a ia?oo /a?ao,
iaiao?aeii a?aeianoe aiiiae?? a iiaaae?ioe? oa?aeoa?enoe/ieo iiaa?oiiue
oaciaeo ??aiiaaa a aaaaoii??iiio i?inoi?? ia?aiao??a, ui caaeathoueny,
iiaeeeaino? iiyae iaeanoae iano?eeino?, cia/iee aieea ia i?ioeane ?inoo
e?iaoe/ieo oaeoi??a oiui. O oeueiio a?aeiioaii? i?iaaaeaiiy
o?ceei-iaoaiaoe/iiai iiaeaethaaiiy i?ioean?a ?inoo oaa?aeeo ?ic/ei?a
aeyaey?oueny iaaecae/aeii ei?eniei o I?AEOE*IIIO A?AeIIOAII?.
Oaeei /eiii, IAOITH aeaii? ?iaiou ? i?iaaaeaiiy oai?aoe/ieo
oa?iiaeeiai?/ieo aeine?aeaeaiue i?ioean?a oaciooai?aiiy a
aaaaoieiiiiiaioieo iai?ai?ia?aeieeiaeo nenoaiao, ?ic?iaea ia ?o iniia?
?aeeii? iaoaiaoe/ii? iiaeae? aca?iiae?? oac, a oaeiae cae?eniaiiy ia
oeueiio aacen? ioe?iie aieeao ??ciiiai?oieo oa?iiaeeiai?/ieo oaeoi??a ia
aeanoeaino? iaoa??ae?a c ianooiiei ae?iaeaiiyi ?aeiiaiaeaoe?e c
iioei?caoe?? oiia io?eiaiiy aenieiye?nieo iai?ai?ia?aeieeiaeo oaa?aeeo
?ic/ei?a.
Aeey aeinyaiaiiy iinoaaeaii? a ?iaio? iaoe iaiao?aeii aoei ?ica’ycaoe
ianooii? aenia?eiaioaeuei? oa oai?aoe/i? AeINE?AeI? CAAeA*?:
– cae?enieoe oai?aoe/ia ? aenia?eiaioaeueia aeine?aeaeaiiy oiia
oa?iiaeeiai?/ii? ??aiiaaae ??aeeia–oaa?aea–aac a aaaaoieiiiiiaioieo
iai?ai?ia?aeieeiaeo nenoaiao aeey aecia/aiiy ye iaea?eueo aeinoia??ieo
oa?iiaeeiai?/ieo iiaeaeae ? ooieoe?e noaio nenoai, oae ? ?ie? oaciaeo
??aiiaaa a iaoaieci? i?io?eaiiy i?ioeano oaciooai?aiiy a
aaaaoieiiiiiaioieo nenoaiao;
– oai?aoe/ii i?iaiae?coaaoe ianiia?aiin eiiiiiaio?a a iae?ineii?/iiio
iaaeeaeaii? aeey ??cieo oiia oaciooai?aiiy ? ?ic?iaeoe iaoaiaoe/i?
iiaeaeuei? oyaeaiiy, ui iienothoue oea yaeua noiniaii aaaaoieiiiiiaioieo
nenoai;
– aeeiiaoe oai?aoe/iee aiae?c aeeaaeaiiy aia?a?? iaoai?/ieo iai?oa a
caaaeueiee aia?aaoe/iee aaeain nenoai, ioe?ieoe ?o ?ieue a e?iaoeoe?
i?ioeano oaciooai?aiiy ia ??cieo noaae?yo i?aeoacii? aca?iiae?? oa
?ic?iaeoe iaoaiaoe/io iiaeaeue ai?oaen??, ui a?aoiao? i?oaei?
aeaoi?iaoe?? oa??a aaaaoieiiiiiaioieo oaa?aeeo ?ic/ei?a;
– ?ic?iaeoe aoaeoeai? i?ia?aii? oa iaoaiaoe/i? aeai?eoie ?ica’ycoaaiiy
caaea/, ui iiaeaeththoue i?ioeane oaciooai?aiiy, ye? aeicaieythoue
io?eiaoe ?ioi?iaoe?th ye i?i ia?aiao?e iaoa??ae?a, ui ae?iuothoueny o
aea?aieo oiiaao, oae ? cae?enithaaoe iiooe oaoiieia?/ieo oiia, ui
caaacia/othoue c?inoaiiy aaaaoieiiiiiaioieo oaa?aeeo ?ic/ei?a caaeaiiai
neeaaeo.
IAOEIAA IIAECIA ?iaioe iieyaa? a ?icaeoeo ? ocaaaeueiaii?
oa?iiaeeiai?/ieo oyaeaiue i?i i?ioeane, ui i?io?eathoue i?e aca?iiae??
oac ??ciiai eiiiiiaioiiai neeaaeo, a ?ic?iaoe? oai?aoe/ieo i?eioeei?a
ea?oaaiiy ?inoiaeie nenoaiaie i?e io?eiaii? aaaaoieiiiiiaioieo oaa?aeeo
?ic/ei?a. Aei iaea?eueo nooo?aeo iiaeo iaoeiaeo ?acoeueoao?a ?iaioe
iaiao?aeii a?aeianoe ianooii?:
– ?acoeueoaoe oai?aoe/iiai ? aenia?eiaioaeueiiai aea/aiiy aaoa?ioacii?
??aiiaaae aeey oe?ieiai eeano aaaaoieiiiiiaioieo iai?ai?ia?aeieeiaeo
aeiaciiiae?aieo iaoa??ae?a ? iaoa??ae?a ?c no?oeoo?ith oi?iae? a
oe?ieiio oaiia?aoo?ii-eiioeaio?aoe?eiiio ?ioa?aae? oaciaiai i?inoi?o;
– ?ic?iaea oa?iiaeeiai?/ieo oyaeaiue i?i aieea i?oaeieo iaoai?/ieo
aeaoi?iaoe?e, iaoiiaeaieo iaa?aeiia?aei?noth ia??iae?a e?enoae?/ieo
a?aoie ni?yaeaieo iaoa??ae?a, ia ci?uaiiy oaciaeo ??aiiaaa
?icieaa–e?enoae i?e ai?oaen?? oa??a o aaaaoieiiiiiaioieo nenoaiao;
– ?ic?iaea e?iaoe/ieo iiaeaeae oaciooai?aiiy a aaaaoieiiiiiaioieo
nenoaiao ye aeey ??cieo i?eiouaiue i?i oaeaeeino? ianiia?aiino o
??aeeiio na?aaeiaeu?, oae ? i?i ??ci? oa?iiaeeiai?/i? noaie
aaaaoieiiiiiaioii? oaa?aei? oace;
– i?iaaaeaiiy oa?iiaeeiai?/iiai aiae?co ? ?ic?iaea oai?aoe/ieo iiaeaeae,
ui iienothoue i?ioeane ?aeaenaoe?? iieiaeaiiy i?aeoacii? iaae?
??aeeia–oaa?aea ia noaae?? oi?ioaaiiy iane/aii? ??aeei? oace a
caeaaeiino? a?ae oiia i?iaaaeaiiy i?ioeano aca?iiae?? oa
oa?iiaeeiai?/ieo aeanoeainoae eiioaeooth/eo na?aaeiaeu.
I?AEOE*IA CIA*AIIss aeeiiaii? ?iaioe iieyaa? a ianooiiiio:
1. ?ic?iaeai? oai?aoe/i? iiaeae? e?enoae?caoe?? ye aaaaoieiiiiiaioieo
ai?oaen?aeueieo oa??a, oae ? ia’?iieo iiiie?enoae?a aeicaieythoue c
aenieith aoaeoeai?noth ea?oaaoe ia?aiao?aie iaoa??ae?a, ui ?inoooue, a
oiiaao neeaaeiiai aaaaoioaeoi?iiai oaoiieia?/iiai i?ioeano.
Cai?iiiiiaai? ia/enethaaeuei? i?ia?aie iiaeooue aeei?enoiaoaaoeny aeey
iaoeiaiai i?iaiicoaaiiy ?acoeueoao?a eiie?aoiiai e?enoae?caoe?eiiai
i?ioeano aai ae, iaaiaee, canoiniaoaaoeny aeey iiooeo oiia
e?enoae?caoe??, ui caaacia/othoue ae?iuoaaiiy e?enoae?a ?c caaeaieie
aeanoeainoyie.
2. I?iaaaeaii anaa?/ia aenia?eiaioaeueia aeine?aeaeaiiy i?ioeano
??aeeioaciai? aaoa?iai?oaen?? oaa?aeeo ?ic/ei?a nenoaie Ga–In–P–As oa
aeo?aeieo ooai?thth/eo niieoe. Ia iniia? ?ic?iaeaieo oai?aoe/ieo
oyaeaiue iioei?ciaai? ?aaeeie ae?iuoaaiiy iiaea?eieo aaoa?ino?oeoo?
GaoIn1-oPyAs1-y/InP, ui aei?ii?iththoue a ae?aiacii? aeiaaeei oaeeue
1,3–1,55 iei, GaoIn1-oP/GaAs, GaoIn1-oP/GaP, GaoIn1-oP/InP,
GaoIn1-oAs/InP.
3. Oai?aoe/ii ia?aaeaa/aii ? ?aae?ciaaii i?eioeeiiai iiaee iaoiae
?cioa?i?/ii? ??aeeiiioaciai? ai?oaen??, yeee ?icoe?th? iaa??
oaoiieia?/ieo i?eeii?a ? aeicaiey? aoaeoeaii ea?oaaoe oiiaaie oi?ioaaiiy
ai?oaen?aeueii? aaoa?ino?oeoo?e (A.N. ? 1232078) i?e nooo?aiio ni?iuaii?
ai?oaen?aeueiiai i?ioeano.
4. I?iaaaeaii aenia?eiaioaeueia ? oai?aoe/ia aeine?aeaeaiiy i?ioeano
io?eiaiiy iiiie?enoae?a ia?aaiaoeue-oeeieiaeo oa?eo?a a oiiaao
i?iieneiaiai ae?iaieoeoaa. ?ic?iaeai? ?aeiiaiaeaoe?? ii iioei?caoe??
oaiia?aoo?ii-/aniaeo ?aaeei?a ?iaioe onoaiiaee aeicaieeee aeiaanoe
aeo?ae i?eaeaoiiai iaeii??aeiiai ca neeaaeii iaoa??aeo aei 95 % ii ian?.
5. ?ic?iaeai? iaoaiaoe/i? iiaeae? oaciooai?aiiy aeei?enoiaothoueny a
i?aeoe/ieo ?ic?iaeao I?iaeaiii? eaai?aoi??? aeaeo?io?ce/ieo i?ioean?a a
ae?aeaeo?eeao ? iai?ai?ia?aeieeao EAO? ?i. A.?. Oe’yiiaa (Eai?ia),
eaai?aoi??? eiioaeoieo yaeu OO? ?i. A.O. ?iooa ? IAe? “Aeiiai” (i.
Naieo-Iaoa?ao?a).
INIIAI? IAOEIA? IIEIAEAIIss
1. Ae??oaia i?iaeaia oa?iiaeeiai?/iiai iieno i?ioeano oaciooai?aiiy a
aaaaoieiiiiiaioieo iai?ai?ia?aeieeiaeo nenoaiao i?e io?eiaii? iaoa??ae?a
aaaaoiooieoe?iiaeueiiai i?ecia/aiiy.
2. Aeei?enoaiiy e?i?eii caeaaeieo a?ae oaiia?aoo?e iaaeeeoeiaeo aia?a?e
ci?uaiiy a ??aeeiio oa oaa?aeiio noai? aeicaiey? aeinyaiooe iieno
oaciaeo ??aiiaaa epenoae–picieaa a aaaaoieiiiiiaioieo
iai?ai?ia?aeieeiaeo nenoaiao A3A5 a oe?ieiio ?ioa?aae? oaiiapaoop.
3. Aia?oa iieacaii, ui canoinoaaiiy oai??? anioe?eiaaieo ?ic/ei?a c
i?aeaeuaiith e?euee?noth eiiieaen?a neeaaeiiai neeaaeo a ??aee?e oac?
aeicaiey? iienaoe oacia? ??aiiaaae aac–picieaa–epenoae a
aaaaoieiiiiiaioieo ieneaeieo nenoaiao.
4. Ciaeaeai? aiae?oe/i? ??oaiiy e?iaoe/ieo ??aiyiue aeeooc?eiiai
ianiia?aiino eiiiiiaio?a a aaaaoieiiiiiaioi?e ??aee?e oac? ? iieacaia
aoaeoeai?noue ?o canoinoaaiiy i?e iieno i?ioean?a oaciooai?aiiy.
5. Aecia/aii aca?iica’ycie i?ae oa?aeoa?ii oaciaeo ??aiiaaa ?
ia?aiao?aie ianiia?aiino a ??aee?e oac?, ui caaacia/o? inaaeaeaiiy oa??a
iaeiiai ? oiai ae neeaaeo a ?cioa?i?/ieo oiiaao ?c ?icieaao c ??ciei
ii/aoeiaei ci?noii iniiaieo eiiiiiaio?a.
6. ?ic?iaeaia aoaeoeaia iaoiaeeea iae?eo aieeao aia?a?? i?oaeieo
aeaoi?iaoe?e, ui aeieeathoue ?c-ca iaa?aeiia?aeiino? ia??iae?a
e?enoae?/ieo a?aoie (IEA), ia ci?uaiiy o?i?/ieo ??aiiaaa i?e
oaciooai?aii? c aaaaoieiiiiiaioiiai ?icieaao niieoe A3A5.
7. Ci?uaiiy o?i?/ieo oaciaeo p?aiiaaa ca ?aooiie iayaiino? a nenoai?
iaoai?/ieo iai?oa aeinyaa? naiai iaeneiaeueiiai cia/aiiy aeey neeaae?a
aaaaoieiiiiiaioiiai epenoaea iaea?eueo aeecueeeo aei iaae?
ni?iiaeaeueiiai piciaaeo.
?acoeueoaoe aeena?oaoe?eii? ?iaioe, ?? iniiai? iieiaeaiiy, aeniiaee ?
?ic?iaeai? o?ceei-iaoaiaoe/i? iiaeae? o nai?io eiiieaen?
i?aaenoaaeythoue niaith ??oaiiy i?eioeeiiai? caaea/? iaoa??aeiciaanoaa
oaa?aeeo ?ic/ei?a, iia’ycaii? c ?ic?iaeith oai?aoe/ieo iniia ea?oaaiiy
i?ioeanaie io?eiaiiy aaaaoieiiiiiaioieo iaoa??ae?a ?c cacaeaeaa?aeue
caaeaieie aeanoeainoyie.
AI?IAAOe?ss ?IAIOE. Iniiai? ?acoeueoaoe ?iaioe oa ?? iaoeia? iieiaeaiiy
aeiiia?aeaeenue ? iaaiai?thaaeenue ia ianooiieo eiioa?aioe?yo, ia?aaeao
? nai?ia?ao: VI Ananithci?e ia?aae? ii oaoiieia?? oa oa?iiaeeiai?oe?
oa?eo?a (i. ?aaii-O?aie?anuee, 1988); III Ananithci?e eiioa?aioe?? ii
o?ce/ieo i?ioeanao a iai?ai?ia?aeieeiaeo aaoa?ino?oeoo?ao (i. Iaeanna,
1982); eiioa?aioe?? “O?ceei-o?i?/i? iniiae io?eiaiiy ? aeine?aeaeaiiy
iai?ai?ia?aeiee?a o oaa?aeiio ? ??aeeiio noai?” (i. Eoeya, 1989);
Ananithciiio nai?ia?? “O?ceei-o?i?/i? aeanoeaino? aaaaoieiiiiiaioieo
iai?ai?ia?aeieeiaeo nenoai. Aenia?eiaio ? iiaeaethaaiiy” (i. Iaeana,
1990); Ananithci?e eiioa?aioe?? c iaoa??aeiciaanoaa iai?ai?ia?aeiee?a
(i. Iineaa, 1987); I?aeia?iaei?e iaoeiai-oaoi?/i?e eiioa?aioe??
“Aa?ieini?/iee eiiieaen: eiiaa?n?y ? oaoiieia??” (i. AEeoiie?, 1995,
1997); Ananithciiio nai?ia?? c oa?iiaeeiai?ee ? iao?aaeeoe?eieo iaoiae?a
io?eiaiiy oa?eo?a (i. Aei?i?iiao?ianuee, 1989); VI Ananithci?e
eiioa?aioe?? c ?inoo e?enoae?a ? ie?aie (i. Iiainea??nuee, 1982);
II Ananithci?e eiioa?aioe?? c o?ceee ? oaoiieia?? oiieeo ie?aie
(i. ?aaii-O?aie?anuee, 1984); eiioa?aioe?? c oaoiieia?? io?eiaiiy,
aeine?aeaeaiiy aeanoeainoae, canoinoaaiiy ??aeeeo iaoae?a, ?o niieoe ?
iai?ai?ia?aeieeiaeo iaoa??ae?a. A??AAeIAO (i. Iineaa, 1984);
VII eiioa?aioe?? c i?ioean?a ?inoo ? neioaco iai?ai?ia?aeieeiaeo
e?enoae?a ? ie?aie (i. Iiainea??nuee, 1986); III Ananithci?e
eiioa?aioe?? “Oa?iiaeeiaieea e iaoa?eaeiaaaeaiea iieoi?iaiaeieeia”
(i. Iineaa, 1986), a oaeiae ia ui??/ieo iaoeiai-oaoi?/ieo eiioa?aioe?yo
i?ioani?nueei-aeeeaaeaoeueeiai neeaaeo EAO? ?i. A.?. Oe’yiiaa (Eai?ia),
(1980–1988); oaoi?/ieo ia?aaeao ni?a?ia?oiee?a IAe? “Aeiiai” (i.
Eai?ia?aae, 1989–1994) ? OO? ?i. A.O. ?iooa AI N?N? (i. Eaieia?aae,
1983–1988).
IOAE?EAOe??. Ca iaoa??aeaie aeena?oaoe?? iioae?eiaaii a?eueoa 50 ?ia?o,
na?aae ieo 4 – o aaaeo/eo ca?oa?aeieo aeo?iaeao, 22 ioae?eaoe?? – a
aeo?iaeao AI. ? iiiia?ao?y ? iaeia aaoi?nueea na?aeioeoai ia aeiao?ae.
Nienie iniiaieo ?ia?o iaaaaeaii a e?ioe? aaoi?aoa?aoo.
NO?OEOO?A ? IANssA AeENA?OAOe??. Aeena?oaoe?y neeaaea?oueny ?c anooio,
oanoe ?icae?e?a, caeeth/aiiy, nieneo e?oa?aoo?e ?c 329 iaca.
Aeena?oaoe?y i?noeoue 328 noi??iie (?c ieo 256 noi??iie iaoeiiieniiai
oaenoo), a oiio /ene? 6 oaaeeoeue, 92 ?ethno?aoe??).
EI?IOEEE CI?NO ?IAIOE.
Ia’?eoii aeine?aeaeaiue aeaii? ?iaioe ? o?ce/i? i?ioeane, ui
i?io?eathoue i?e oaciooai?aii? a aaaaoieiiiiiaioieo iai?ai?ia?aeieeiaeo
nenoaiao.
Aeoeaio a aeine?aeaeaiiyo ci?uaii ia oaa?ae? ?ic/eie niieoe A3A5 ?
/ioe?eeiiiiiaioi? iaoa??aee ?c no?oeoo?ith oi?iae?.
Aea?? naia oaeeo ia’?eo?a aeine?aeaeaiue iaoiiaeaiee ye aeinoaoiueith
caaaeuei?noth iinoaaeaieo ia?aae ?iaioith oai?aoe/ieo ieoaiue, oae ?
oe?ieei canoinoaaiiyi iaoa??ae?a oeueiai eeano ye aeoeaieo na?aaeiaeu
aaaaoiooieoe?iiaeueieo i?eeaae?a aeaeo?iiii? oaoi?ee.
Oa?iiaeeiai?ea ??aiiaaaeiiai noaio aaaaoieiiiiiaioieo nenoai
Iniiaith iiaoaeiae oa?iiaeeiai?/ii? iiaeae? i?ioean?a, ui i?io?eathoue
i?e ae?iuoaaii? aaaaoieiiiiiaioieo oaa?aeeo ?ic/ei?a, ? oyaeaiiy
??aiiaaaeii? oa?iiaeeiai?ee. Oiio ia?oee ?icae?e ?iaioe i?enay/aiee
?icaeyaeo oa?iiaeeiai?/ieo aniaeo?a iieno ae?aa?ai noaio
aaaaoieiiiiiaioieo eiaaeaioieo iai?ai?ia?aeiee?a ? iai?ai?ia?aeiee?a ?c
no?oeoo?ith oi?iae?.
Iaea?eueo ie?aeiei i?aeoiaeii i?e iieno oaciaeo ??aiiaaa a nenoaiao
eeano A3A5 ? i?aeo?ae, iia’ycaiee c oai???th ?aaoey?ieo ?ic/ei?a.
Ca?aeii oe??? oai??? neeaaee ??aiiaaaeieo oac ?ic?aoiaothoueny ca
ae?acaie:
, (1)
– eiao?oe??ioe aeoeaiino? oa aoiiia aeiey eiiiiiaioa i /e ij a ??aee?e
oa oaa?ae?e oac? a?aeiia?aeii; ?ij – ia?aiao?e i?aeaoiiii? aca?iiae??
i?ae eiiiiiaioaie i oa j; aij, bij – ooeai? eiinoaioe iiaeae?.
Iniaeeao oaaao a ?iaio? i?eae?eaii aecia/aiith a??ia?aeieo, a ?aieao
aea?aii? iiaeae?, oa?iiaeeiai?/ieo ooieoe?e ci?uaiiy ?icaeyaeoaaieo
nenoai (?ij). Iiia?aaei? ?ic?aooiee iieiaeaiue oa?aeoa?enoe/ieo e?i?e
aaaaoii??ieo ae?aa?ai noaio nenoai A3A5 a oe?ieiio ?ioa?aae? oaiia?aoo?
iieacaee, ui aeinyaiooe iieno noeoiiino? aenia?eiaioaeueieo aeaieo, i?e
aeei?enoaii? noai?i ?aaoey?iiai iaaeeaeaiiy oai??? ?aaoey?ieo ?ic/ei?a
iaiiaeeeai. Oiio a ?iaio? aeey iiaoaeiae ae?aa?ai noaio nenoai a
oe?ieiio ?ioa?aae? oaiia?aoo? aeei?enoiaoaaeinue eaac??aaoey?ia
iaaeeaeaiiy oai??? ?aaoey?ieo ?ic/ei?a c e?i?eii caeaaeieie a?ae
oaiia?aoo?e ia?aiao?aie aca?iiae?? eiiiiiaio?a a ??aee?e oa oaa?ae?e
oacao.
Iiooe /enaeueieo cia/aiue iaaaaeaieo a?eueieo aia?a?e ci?uaiiy
cae?enithaaany oeyoii iaeiie/aiiy oa?iiaeeiai?/ii? ?ioi?iaoe?? i?e
iine?aeiai?e ia?iaoe? aenia?eiaioaeueieo aeaieo ii aca?iiae?? oac a?ae
a?ia?ieo nenoai aei a?eueo neeaaeieo. Iiia?aaei? ni?iae aecia/aiiy
iaaaaeaieo aia?a?e ci?oaiiy, ui a?oioothoueny ia o?aeooaaii?
aenia?eiaioaeueieo aeaieo ii ai?oaen?? ye i?i i?ioean aeecueeee aei
oa?iiaeeiai?/ii ??aiiaaaeiiai noaio iieacaee o?ce/io ia?aaeuei?noue
io?eiaii? e?euee?nii? ?ioi?iaoe?? i?i ooeai? oa?iiaeeiai?/i? ooieoe??
ci?oaiiy. Oiio a ?iaio? aeey aiae?co oaciaeo ??aiiaaa ? iiooeo
oa?iiaeeiai?/ieo ooieoe?e nenoai aoa aeei?enoaiee i?eioeeiiai a?aei?iiee
a?ae a?aeiieo iaoiae?a iieno ?icaeyaeoaaieo i?ioean?a i?aeo?ae, ui
a?aoiao? ia??aiiaaaeiee oa?aeoa? i?ioean?a aca?iiae?? oac a
aaaaoieiiiiiaioieo nenoaiao. Oea icia/a?, ui a ?iaio? ?icoe?thaaeenue
o?ce/i? oyaeaiiy i?i i?ioean aca?iiae?? oac, a ia ianeoaaeenue ia
a?aoiaai? o?ce/i? yaeua a oa?iiaeeiai?/ii iaiaa?oioiaaieo ??aiiaaaeieo
ia?aiao?ao nenoai. Iaiao?aei?noue ? ia?niaeoeai?noue oaeiai i?aeoiaeo
aei iieno i?ioean?a i?aeoaa?aeaeo?oueny ianooiieie aenia?eiaioaeueieie
oaeoaie ? oai?aoe/ieie ?icoi?iiyie. A ia?oo /a?ao, oea – aeniea
oaeaee?noue e?enoae?caoe?? oa??a oaa?aeeo ?ic/ei?a (ii?yaeeo 1 iei/oa.),
caeaaeiino? ia?aiao??a oa??a a?ae ?o e?enoaeia?ao?/ii? i???ioaoe??,
??cia e?euee?noue eiiiiiaio?a oa??a oaa?aeiai ?ic/eio oa i?aeeiaeee i?e
oi?ioaaii? aaoa?iia?aoiae?a, i?iaiice i?i ?nioaaiiy iaeanoae
ianoaa?eueiino? oac. Oea ? aeicaieyei noaa?aeaeoaaoe, ui e?i?? oaciaeo
ae?aa?ai aaaaoieiiiiiaioieo nenoai, iiaoaeiaai? ca aeaieie
aaoa?iai?oaen?? ia ?noeiii ??aiiaaaei?, ine?eueee aiie ceiiooeueiaai?
iiiaeeiith ia??aiiaaaeieo aoaeo?a, ? aeey io?eiaiiy ?noeiii ?aaiiaaaeii?
?ioi?iaoe?? i?i noai nenoai aenia?eiaioaeuei? aeai? ii ai?oaen?? iiaeii?
aooe cei?aaiaai? c a?aooaaiiyi iaoiaeee ?o io?eiaiiy ? iniaeeainoae
oa?iiaeeiai?/iiai noaio nenoai. I?e oaeiio i?aeoiae? ciaeaeai?
??aiiaaaei? oa?iiaeeiai?/i? ooieoe?? iaiao?aeii i?eciaoe o?ce/ii
iaa?oioiaaieie ? aeei?enoiaoaaoe ?o aeey aiae?co oaciaeo ??aiiaaa a
aaaaoieiiiiiaioieo nenoaiao A3A5. Oaeee niin?a iiooeo oa?iiaeeiai?/ieo
ooieoe?e ? i?eioeeiiaei ? iiaei a o?aeooaaii? ? ia?iaoe?
aenia?eiaioaeueieo ?acoeueoao?a.
?ioa neooaoe?y neeaaea?oueny i?e aiae?c? oaciaeo ??aiiaaa i?e io?eiaii?
oaa?aeeo ?ic/ei?a iaai?oieo iai?ai?ia?aeiee?a, ui e?enoae?cothoueny a
no?oeoo?? oi?iae?, aea /anoea ?iiiiai ca’yceo a e?enoae?/i?e a?aooe?
nooo?aa. Iniaeea?noth nenoai oaeiai aeaeo iaiao?aeii aeciaoe oa, ui aeey
iiaoaeiae ? aeai?o oa?iiaeeiai?/ii? iiaeae? i?e aiae?c?
aenia?eiaioaeueieo aeaieo ii oaciaeo ??aiiaaaao iaiao?aeii a?aoiaoaaoe
?ioaineaio aca?iiae?th ?icieaao c aaciaei na?aaeiaeuai ii neeueii
eaoeiio eiiiiiaioo – eenith. ?ioeie neiaaie oea icia/a?, ui ai?no eecith
a ?icieaa? aecia/a?oueny eiai ia?oe?aeueiei oeneii a nenoai? ? noai
?icieaao iaiiaeia ?icaeyaeaoe a iacaeaaeiino? a?ae noaio aaciaiai
na?aaeiaeua. Oiio a ioe?ioe? aeinoia??iino? e?oa?aoo?ieo aeaieo ii
oaciaeo ??aiiaaaao aeey ?o ianooiii? oai?aoe/ii? ia?iaee caaaeaee
a?aeanue aei oaaae ?ioi?iaoe?y i?i oa, yea nenoaia aiae?co?oueny
(cae?eoa /e a?aee?eoa) ? ye eiio?ieth?oueny aai yeei niiniaii
caaea?oueny oene eenith iaae aca?iiae?th/eie oacaie.
Iiaeaeueiith nenoaiith i?e iaa?oiooaaii? aeai?o oa?iiaeeiai?/ii? aoaeiae
ieneaeiiai ?icieaao neoaoaaea iaea?eueo aenia?eiaioaeueii aeine?aeaeaia
nenoaia cae?ci–eenaiue. Iniaeea?noue ae?aa?aie noaio iaei?ino?oi?
oi?iae? – iaaiaoeoo i?e aenieeo oaiia?aoo?ao ? a?aeiinii iacia/iee oene
eenith i?e aaeeeiio eiai ai?noo a ??aee?e oac? (iae. 1). Aoei
cai?iiiiiaaii niinoa??aa?iee aenia?eiaioaeueiee oaeo iiynithaaoe
neeueiei ca’yceii eenith c iaoae?/ieie eiiiiiaioaie ?icieaao, oiae? eiai
iacia/iee oene a nenoai? iia’ycoaaoe o?eueee ?c a?eueieie
iaanioe?eiaaieie aoiiaie eenith. O?ce/ii oea a?aeiia?aeaei ia?aoiaeo
a?ae oyaeaiue oai??? ?aaoey?ieo ?ic/ei?a aei iiaeae? anioe?aoeaii?
aoaeiae oace.
Cai?iiiiiaai? a ?iaio? ??aiyiiy oai??? anioe?eiaaieo ?ic/ei?a aeey noaio
aaaaoieiiiiiaioii? ??aeei? oace c eiiieaenaie ??ciiai neeaaeo iathoue
aeaeyae:
;
,
– oene iane/aiiy eenith.
Nenoaia ??aiyiue aeey iieno ?–O–O ??aiiaaa a ia?aiiio iaaeeaeaii? ?
caieiaiith i?e aeei?enoaii? ia?oeo ae?ac?a nenoaie (1).
Aieiaiei e?eoa???i i?e iaa?oiooaaii? neeaaeo anioe?ao?a a ?icieaa?
neoaoaaea a?aeiia?aei?noue ?ic?aooie?a aenia?eiaioo ii oaiaaino eooa
iaoeeo caeaaeiino? ia?oe?aeueiiai oeneo eenith a?ae eiai eiioeaio?aoe??
a ??aee?e oac?. Oaeee ?acoeueoao a nenoai? Fe–O aeinyaaany, eiee a
?ic?aooieao a?aoiaoaaeinue ye i?i?ioi o?e eiiieaene, ye? i?noyoue
eenaiue (FeO, Fe2O3, Fe3I4) (iae. 1). Aeacaiee i?aeo?ae i?e aiaeec?
oaciaeo ??aiiaaa a ieneaeieo iai?ai?ia?aeieeiaeo nenoaiao ?
i?ea?iaeueiei ? aia?oa cai?iiiiiaaiee a aeai?e ?iaio?.
Oai?aoe/ia iiaoaeiaa ae?aa?aie noaio ieneaeii? nenoaie Zn–Mn–Fe–O
cae?enithaaeanue, ye ? ?ai?oa aeey niieoe oeio A3A5, iine?aeiaiei
iiooeii oa?iiaeeiai?/ieo ooieoe?e a?ae a?ia?ieo nenoai aei a?eueo
neeaaeieo.
Iae. 1: 1 – oene eenith iaae ?icieaaii i?e O = 1873 E;
2 – oene eenith acaeiaae e?ea?aeono Iae. 2: 1– nie?aeon nenoaie
Ga–In–As; 2, 3 – eaac???aiiaaaeiee nie?aeon i?oaeii-aeaoi?iiaaiee
oa? – ??aeea oaca nenoaie
Aeey iiaeaethaaiiy aia?aaoe/iiai noaio oaa?aei? oace, yea ooai?th?
no?oeoo?o oi?iae? ZnxMnyFe3-x-yO4, ??aiyiiy oai??? ?aaoey?ieo ?ic/ei?a
aoee iiaea?i?ciaai?. Iaiao?aei?noue oaei? iiaea?i?caoe?? iaoiiaeaia oei,
ui aia?aaoe/iee noai ?ii?a a ??cieo e?enoaeia?ao?/ieo iiceoe?yo
oi?iaeueii? no?oeoo?e ??ciee. Aeey iaea?eueo aaaeeeaeo a i?aeoe/iiio
a?aeiioaii? neeaae?a oaa?aeiai ?ic/eio Zn~0,3Mn~0,6Fe~2,1O4 neacaia, a
ia?oo /a?ao, a?aeiineoueny aei ?ii?a cae?ca, ye? ?icoaoiaothoueny ye a
oao?a-, oae ? a ieoaaae?e/ieo iiceoe?yo. I?e oeueiio ca?aeii c
aenia?eiaioaie ?iie oeeieo ? ia?aaioeth, ye i?aaeei, naia? aaeaioiino?
ia ci?iththoue. Oiio aeey aecia/aiiy caaaeueii? oaa?aeioacii? aeoeaiino?
cae?ca aeei?enoiaoaaeenue oyaeaiiy i?i ia?oeeaeueio aeoeai?noue ?ii?a a
caeaaeiino a?ae ?o e?enoaeia?aoe/ii? iiceoe??. A oaeiio iaaeeaeaii?
??aiyiiy aeey ?ic?aooieo neeaae?a ??aiiaaaeieo oac a ieneaeieo
iai?ai?ia?aeieeao c? no?oeoo?ith oi?iae? io?eiai? a aeai?e ?iaio?.
Aeey iiooeo an??? noeoiiino? oa?iiaeeiai?/ieo ooieoe?e iiaeaeueii?
nenoaie Zn–Mn–Fe–O aenia?eiaioaeueieo aeaieo, ye? ?, ii oaciaeo
??aiiaaaao o aeo?aeieo nenoaiao aeyaeeinue iaaeinoaoiuei. Oiio aeey
i?aeaeuaiiy oi/iino? oa?iiaeeiai?/ii? ?ioi?iaoe?? caeo/aeenue
aenia?eiaioaeuei? e?iaoe/i? aeai? i?i ??no e?enoae?a. Aeey ?ica’yceo
iiae?aiiai aeaeo caaea/?, ye ? o aeiaaeeo nenoai A3A5, c’yaeyeanue
iaiao?aei?noue i?iaaaeaiiy aiae?co i?ioean?a, ui a?aeaiaeyoue
aaaaoieiiiiiaioi? nenoaie ?c oa?iiaeeiai?/ii ??aiiaaaeiiai noaio.
Oa?iiaeeiai?ea oaciaeo ??aiiaaa i?oaeii-aeaoi?iiaaiee oa?
oaa?aeiai ?ic/eio – aeaniee ?icieaa
Iaei??th ?c iniiaieo i?e/ei, ui a?aeaiaeyoue ai?oaen?aeueio nenoaio a?ae
noaio o?i?/ii? oaciai? ??aiiaaae i?e ?OA, ? iayai?noue iaa?aeiia?aeiino?
IEA i?ae oa?ii ? i?aeeiaeeith. Ae?enii, a aaaaoioaeoi?iiio i?ioean? ?OA
oi/ii ?aae?coaaoe oiiao ?ciia??iaeiiai cai?uaiiy i?aeoe/ii iaaecae/aeii
neeaaeii. Oea icia/a?, ui i?ioean oaciooai?aiiy aaaaoieiiiiiaioiiai
oaa?aeiai ?ic/eio i?ioiaeeoue a iie? i?oaeieo iai?oa.
I?e iaeeo aaee/eiao iaa?aeiia?aeiino? IEA ai?oaen?aeueiee oa?
e?enoae?co?oueny ii iaoai?cio inaaaeiii?o?cio, a iaa?aeiia?aei?noue IEA
eiiiaino?oueny iiyaith iie?a i?oaeieo aeaoi?iaoe?e a nenoai?. A ?iaio? a
?aieao e?i?eii? ai?cio?iiii? oai??? i?oaeiino? io?eiai? ae?ace, ui
iia’ycothoue iaoai?/i? aeaoi?iaoe?? oa iai?oae a nenoai? c ieoiiith
a?eueiith aia?a??th aeey oiieeo oa??a, IEA yeeo iaia?a?aiei /eiii
ni?yaeaiee c ianeaiith iiaeeiaeeith.
Iiyaa iaoai?/ii? eiiiiiaioe a?eueii? aia?a?? a nenoai? ci?uo? o?i?/i?,
oacia? ??aiiaaae. Oea i?iyaey?oueny a ci?i? oaiia?aoo?e oaciaiai
ia?aoiaeo ??aeeia–oaa?aea (eiioaeoia ia?aioieiaeaeaiiy), yeui
eiioaeooth/? oace iiaeia ?icaeyaeaoe ye eiina?aaoeai?, aai ae aeeeeea?
ia?ane/aiiy aca?iiae?th/i? c i?aeeiaeeith ??aeei? oace ca ?aooiie
?ic/eio inoaiiuei?. Aia?a?y i?oaeii? aeaoi?iaoe?? caaaeaee iiceoeaia,
oiio i?e aoaeue-yeiio aeae? aeaoi?iaoe?? caaaeueia aia?a?y nenoaie
ia?aaeuo? ?noeiii ??aiiaaaeio, o?i?/io. Oaeee ??aiiaaaeiee noai ?
eaac?noaa?eueiei ? aeey eiai iieno a ?iaio? a ?aieao oai??? ?aaoey?ieo
?ic/ei?a cai?iiiiiaai? a?aeiia?aei? ??aiyiiy.
??aiyiiy aeey aiae?co ?icaeyaeoaaii? ??aiiaaae aoee io?eiai? oeyoii
ei?aaoaaiiy a eeane/ieo oi?ioeao ?ic?aooie?a ae?aa?ai noaio ae?ac?a aeey
ioe?iee aeoeaiinoae eiiiiiaio?a a oaa?ae?e oac?. C o?aooaaiiyi
aeanoeaino? aaeeoeaiino? a?eueii? aia?a?? A?aana eiao?oe??ioe aeoeaiino?
iai?oaeaiiai oaa?aeiai noaio o ae?acao (1) ia?aioe?ithaaeenue
a?aeiia?aeii aei ae?ac?a:
, nij – eiao?oe??ioe aeoeaiino? oa e?euee?noue iieae inaaaeieiiiiiaioo
ij a iai?oaeaiiio noai?; Gex, Gel – a?eueia aia?a?? ci?ooaaiiy ?
i?oaeieo aeaoi?iaoe?e iaeiiai iiey oaa?aeiai ?ic/eio.
I?e oeueiio ooieoe?? noaio ??aeei? oace caeeoaeenue iaci?iieie. Oeae
o?aaiaio ?iaioe ? iiaei ? eiai iaiao?aeii ?icaeyaeaoe ye iiaeaeueoee
?icaeoie oai?aoe/ieo oyaeaiue i?i i?aeoacio aca?iiae?th noiniaii aei
ai?oaen?aeueii? e?enoae?caoe?? a aaaaoieiiiiiaioieo nenoaiao.
O a?aeiia?aeiino? aei io?eiaieo ae?ac?a a ?iaio? aoei cae?eniaii
iiaeaethaaiiy eaac???aiiaaaeiiai noaio i?ae ai?oaen?aeueieie oa?aie
/ioe?eeiiiiiaioieo oaa?aeeo ?ic/ei?a niieoe A3A5, ni?yaeaieo aei
a?ia?ieo i?aeeiaeie, ? a?aeiia?aeieie aaaaoieiiiiiaioieie ??aeeeie
oacaie aeey iaea?eueo aaaeeeaeo nenoai ? oaiia?aoo?ieo oiia aca?iiae??.
I?aeoe/ii aeey an?o ?icaeyiooeo eiioaeoieo ia? iiaeeco e?i?e
?ciia??iaee/iiai cai?uaiiy a?aei?/aii iayai?noue aaeeeeo iaeanoae c
iacia/iith aaee/eiith eiioaeoiiai ia?aioieiaeaeaiiy, ?i?oe?eiaaiiai
iaoai?/ieie iai?oaaie (?O Caeiiii??iino? oaciooai?aiiy
a aaaaoieiiiiiaioieo iai?ai?ia?aeieeiaeo nenoaiao
Ca aeiiiaith ?ic?iaeaieo a ?iaio? iaoaiaoe/ieo oyaeaiue cae?eniaii
iiaeaethaaiiy i?ioeano ??aeeioaciai? ai?oaen?? a nenoaiao Ga–In–P–As,
Ga–In–As–Sb ? aeo?aeieo o?eeiiiiiaioieo oaa?aeeo ?ic/eiao aeey an?o
i?aeoe/ii aaaeeeaeo ?ioa?aae?a neeaae?a iaoa??ae?a. Niinoa??aa?ia oi?ioa
a?aeiia?aei?noue ?ic?aooie?a aenia?eiaioo aeey caeaaeiino? neeaaeo
oaa?aeeo ?ic/ei?a a?ae oaiia?aoo?e ?inoo, neeaaeo iaoi/iiai ??aeeiiiai
na?aaeiaeua, ia?aioieiaeaeaiiy nenoaie, oiui aeicaiey? noaa?aeaeoaaoe
aaeaeaaoi?noue oyaeaiue i?i aeeooc?eii-iaiaaeaio e?enoae?caoe?th
?aaeueiei i?ioeanai, ui i?io?eathoue i?e oaciooai?aii?.
I?eioeeiiaei ?acoeueoaoii, ui aeo?ea? ?c ?ic?iaeaii? iiaeae?
e?enoae?caoe??, ? iiaeeea?noue inaaeaeaiiy aaaaoieiiiiiaioieo oaa?aeeo
?ic/ei?a iaeiiai ? oiai ae neeaaeo c ?icieaao ?c ??ciei ai?noii iniiaieo
eiiiiiaio?a. Oaea yaeua ia i?ioe??/eoue oacia?e ae?aa?ai?, aea ?nio?
iaeiicia/iee ca’ycie i?ae neeaaeaie eiioaeooth/eo oac, a ?
a?aeia?aaeaiiyi aieeao oaeaeeino? ?inoo ia eiao?oe??ioe ?iciiae?eo
iae?ieiiiiiaio?a o nooo?ai ia??aiiaaaei?e nenoai?. Neacaia noaa?aeaeaiiy
? ocaaaeueiaiiyi iaaeeaeaiiy Aa?oiia–I?eia–Neeooa?a ia i?ioeane ?inoo
oaa?aeeo ?ic/ei?a ?c aaaaoieiiiiiaioii? ??aeei? oace. Iaiao?aeii
a?aei?oeoe, ui, yeui a eeane/iiio iaaeeaeaii? Aa?oiia–I?eia–Neeooa?a,
neeaae aai ae aoaeoeai? eiao?oe?aioe ?iciiae?eo ? ?iaa??aioith a?aeiinii
noaei? oaeaeeino? e?enoae?caoe??, oi o aeiaaeeo ?cioa?i?/ii?
aaoa?iai?oaen?? oaeei ia?aiao?ii aenooia? noaea aaee/eia – ia?aiao?
oaeaeeino? ?inoo ?.
Aeey eiaeiiai neeaaeo oaa?aei? oace ?niothoue nai? caeaaeiino?
ii/aoeiaeo eiioeaio?aoe?e eiiiiiaio?a a?ae ia?aiao?a oaeaeeino? ?inoo,
ye? ca o?ce/iei ci?noii ne?ae o?aeooaaoe e?iaoe/ieie iii?aaeaie ia
ia?ane/aiiy aei ae?aa?aie noaio i?e aeai?? oiia oaciooai?aiiy a
?cioa?i?/iiio ?aaeei?. Canoinoaaiiy a oai?aoe/iiio ?icaeyae? oaeeo
iii?aaie nooo?ai i?aeaeueei oi/i?noue iieno aenia?iaioaeueieo aeaieo c
?OA a nenoaiao A3A5 ii anueiio iieth ae?aa?aie neeaae?a.
I?e iiaeaethaaii? e?iaoeee oaciooai?aiiy ca a?aie/i? oiiae aeey
?ic?aooieo eiioeaio?aoe?eieo iie?a iiaeeco o?iioa e?enoae?caoe??
aeei?enoiaoaaeinue ye ??aiiaaaeia, oae ? a?aoiaoth/a iayai?noue
iaoai?/ieo iai?oa iaaeeaeaiiy aeey ioe?iie eiioeaio?aoe?e eiiiiiaio?a ia
iiaa?oi? ?inoo. A?aei?/aii, ui aieea iaoai?/ieo iai?oa iniaeeai neeueii
a?aeaeaa?oueny ia i?ioean? ai?oaen?? a i??o iaaeeaeaiiy
oa?iiaeeiai?/ieiai noaio nenoaie aei iaae? ni?iiaeaeueiiai ?iciaaeo. A
oe?eiio iaoai?/i? aeaoi?iaoe?? a aaoa?ino?oeoo?? a?aeiia?aeathoue ca
cieaeaiiy /ooeeaino? ia?aiao??a oa??a aei oiia ae?iuoaaiiy, ui
a?aeia?aaea?oueny ia ciaioaii? aaee/ei /anoeiieo iio?aeieo a?ae neeaaeo
oaa?aeiai ?ic/eio ca aoaeue-yeei ?c ciai?oi?o ia?aiao??a i?ioeano
oaciooai?aiiy.
a?ae neeaaeo oaa?aeiai ?ic/eio GaxIn1-xPyAs1-y. ?ic?aooiee aeeiiai? ye
c iayai?noth iaoai?/ieo iai?oaeaiue a iaeano? aaoa?iiaae? (2), oae ? a
iaaeeaeaii? o?i?/ii? ??aiiaaae (1, 3) i?e ??cieo oaeaeeinoyo
ianiia?aiino a ??aee?e oac?.
Iae. 3: 1, 2 – aeeooc?eia iiaeaeue;
3 – iiaeaeue iiaiiai ia?ai?ooaaiiy Iae. 4: 1,2 – iaae? ianoaa?eueiiai oa
iaoanoaa?eueiiai noaio nenoaie Ga–In–P–As i?e O = 900 E;
- - – eiiiaee ?iciaaeo;
n – e?eoe/iee neeaae ?iciaaeo
Aaaaeaiiy a ?icaeyae aia?a?e i?oaeieo aeaoi?iaoe?e a?aeia?aaea?oueny
o?eueee ia e?euee?nieo ioe?ieao oiai /e ?ioiai ia?aiao?a ?inoo/i? oace,
oiae? ye ye?nia oa?iiaeeiai?/ia ea?oeia nenoaie caeeoa?oueny iaci?iiith.
Aeeiiaiee aiae?c aeicaieea io?eiaoe e?euee?ni? aeai? i?i aieea
oa?iiaeeiai?/ieo aeanoeainoae (iieiaeaiiy ? oi?ia oa?aeoa?enoe/ieo e?i?e
ae?aa?aie noaio) ? e?iaoe/ieo ia?aiao??a ia i?ioean oaciooai?aiiy a
aaaaoieiiiiiaioieo nenoaiao. Aeey oeueiai a ?iaio? aeeiiaii
iiaeaethaaiiy i?ioeano ae?iuoaaiiy /ioe?eeiiiiiaioieo oaa?aeeo ?ic/ei?a
a iaaeeaeaii? iiaiiai ia?ai?ooaaiiy aeo?aeii? ??aeeiai na?aaeiaeua.
Ni?anoaaeaiiy oaeiai aeaeo ?acoeueoao?a ?ic?aooie?a, c aiaeia?/ieie
aeaieie, io?eiaieie a iaaeeaeaii? aeeooc?eii-iaiaaeaiiai ?inoo iieacaei,
ui aa??aoe?y oaeaeeino? inaaeaeaiiy a?ae iane?i/aiii aaeeei? (iiaia
ia?ai?ooaaiiy) aei aenia?eiaioaeueii niinoa??aa?ii? ia nooo?ai ci?ith?
?aaeoe?? nenoaie (iae. 3). Oiio noaa?aeaeo?oueny, ui naia
ooieoe?iiaeueia caeaaei?noue a?eueieo aia?a?e A?anna oac a?ae neeaaeo ?
oaiia?aoo?e, ye? a?aeiia?aeathoue ca oi?io ae?aa?aie noaio oaa?aeiai
?ic/eio, ? aieiaiei oaeoi?ii, ui aecia/a? oa?iiaeeiai?/io iiaaae?ieo
aaaaoieiiiiiaioii? nenoaie.
I?e e?enoae?caoe?? oa??a i?ioyaii o?eaaeiai i?ii?aeeo /ano aai ae ?c
??aeei? oace iaeiai ia’?io ia ia?aiao?e oa??a nooo?ai a?aeaeaathoueny
aaiiao?e/i? ?ici??e ??aeei? oace. ?ic?iaeai? iaoaiaoe/i? iiaeae?
aeicaieythoue ioe?ieoe aieea oeueiai oaeoi?a ia ia?aiao?u iaoa?eaeo.
I?iaaaeaia a ?iaio? /enaeueia iiaeaethaaiiy oaeiai i?ioeano iieacaei, ui
aaiiao?e/ia iaiaaeaiiy iaoi/iiai ?ic/eio i?iyaey?oueny aeaiia oaeoi?aie.
Ii-ia?oa, oea nooo?aa ciaioaiiy oaeaeeino? e?enoae?caoe?? i?ney iiiaioa
t = 0,3 L2/D, ii-ae?oaa, a oeae aea iiiaio ii/eia?oueny nooo?aa
naa?aaaoe?eia ci?ia neeaaeo ? IEA oaa?aeiai ?ic/eio ?c-ca ii?ooaiiy
i?iii?oe?eiino? iioie?a ?a/iaeie aei o?iioo e?enoae?caoe??. Oiio i?e
io?eiaii? aeinoaoiuei oianoeo aenieiiaeii??aeieo oa??a oaa?aeeo ?ic/ei?a
iaae?yoeny ia ca?eueoaiiy oiaueie ie?aee ca ?aooiie ca?eueoaiiy /ano
?inoo iaaei?aaaeaii.
A i?ioean? cae?eniaiiy iiaeaethaaiiy i?ioean?a oaciooai?aiiy a
aaoa?ieiiiiiaioieo nenoaiao A3A5 aoee aeyaeai? iniaeea? ?ioa?aaee
neeaae?a ? oaiia?aoo?, aea niinoa??aaeanue aiiiaeueii aeniea /ooeea?noue
nenoaie aei aoaeue-yeeo aa??aoe?e ia?aiao??a, i?ioeano oaciooai?aiiy.
Oe? iaeano? aea/aeenue a ?iaio? iaea?eueo aeieeaaeii ye a oai?aoe/iiio,
oae ? a aenia?eiaioaeueiiio a?aeiioaii?. A iiaeaeuei?e nenoai?
GaoIn1-oPyAs1-y neacaia a?aeiineoueny aei ?ioa?aaeo neeaae?a c
y = 0,1–0,25, aea aeyaeyeanue aiiiaeueii aeniea /ooea?noue IEA aei ci?i
oaiia?aoo?e ?inoo (iae. 3).
Aiae?c iieacaa, ui oaea neooaoe?y iaoiiaeaia oa?iiaeeiai?/ieie
aeanoeainoyie nenoaie ? ia caeaaeeoue a?ae e?iaoeee oaciooai?aiiy.
Ae?enii, ciaeaeai? ooieoe?? ci?uaiiy aecia/athoue iayai?noue iaeanoae
iaci?ooaaiino? a oaa?ae?e oac? a aaaaoueio aaaaoieiiiiiaioieo oaa?aeeo
?ic/eiao nenoaie A3A5. Cieaeaiiy oa?iiaeeiai?/ii? no?eeino? oace ?
aeanoea?noth i?aeaeuaiiai /enea ci?ooaaieo eiiiiiaio?a, yea a?aeiia?aea?
ca ca?eueoaiiy e?eoe/ii? oaiia?aoo?e ?icoa?oaaiiy. A?aei?oeii, ui aeey
aeo?aeieo iio??eieo nenoai oaeiai aeaeo iaeanoae ?iciaaeo a a?eueoino?
nenoai A3A5 ia niinoa??aa?oueny. Oiio oaeo iiaaae?ieo iaiao?aeii
i?eciaoe ao?eaooii naia aaaaoieiiiiiaioieo oaa?aeeo oac.
Oa?iiaeeiai?/ii eaac?noaa?euei? noaie
aaaaoieiiiiiaioieo oaa?aeeo ?ic/ei?a
Aenie? cia/aiiy a?eueieo aia?a?e oaa?aeioaciiai ci?uaiiy, ye? ciaeaeai?
a iiia?aaeiueiio ?icae?e?, iathoue iiceoeai? cia/aiiy. Nenoai?, yea ia?
cia/io iiceoeaio aioaeuei?th ci?uaiiy, i?e aecia/aieo oiiaao
a?aeiia?aea? ianoaa?eueiee aai ae, a e?aeiueiio aeiaaeeo,
eaac?noaa?eueiee noai.
Canoinoaaiiy caaaeueiiai oa?iiaeeiai?/iiai e?eoa??th no?eeino? oac aei
aaaaoieiiiiiaioieo oaa?aeeo ?ic/ei?a ?c cai?uaiiyi eiiiiiaio?a aai a
iaei?e, aai a iaio i?ae?ao?oeao e?enoae?/ii? no?oeoo?e noaea?eoo
aeicaieeei a aeai?e ?iaio? io?eiaoe nenoaie ??aiyiue, ui iienothoue
iieiaeaiiy ni?iiaeaeae iaci?ooaaiino?.
A ?iaio? a ?aieao oai??? i?inoeo ?ic/ei?a cai?iiiiiaai? ae?ace, ui
iienothoue iieiaeaiiy iaae? iaoanoaa?eueii? iaeano? noaio oaa?aeeo
?ic/ei?a c iaiia oeiaie cai?uaiiy eiiiiiaio?a a i?ae?ao?oeao no?oeoo?e
noaea?eoo. Oe? ae?ace ? iane?aeeii ??aiino? oa?iiaeeiai?/ieo
iioaioe?ae?a a?ia?ieo inaaaeieiiiiiaio?a, ui ooai?ththoue /aoaa?iee
oaa?aeee ?ic/ei. C aeei?enoaiiyi io?eiaieo oi?ioe aeeiiai? ?ic?aooiee
iieiaeaiue ni?iiaeaeae iaci?ooaaiino?, iaae iaoanoaa?eueieo iaeanoae ?
eiiiae neeaae?a ?iciaaeo iaea?eueo aaaeeeaeo /ioe?eeiiiiiaioieo oaa?aeeo
?ic/ei?a (GaInPAs, GaInAsSb, InPAsSb) aeey oeiiaeo oiia ai?oaen?aeueii?
e?enoae?caoe??. Io?eiai? aeai? iieacothoue, ui i?e ?iciaae? ia?ane/aiiai
oaa?aeiai ?ic/eio eiiiaee neeaae?a ??aiiaaaeieo oac, ye i?aaeei,
iai?aaeai? a?ae eaaeiieaaeiai aei naiiai ooaiieaaeiai eiiiiiaioa
iaoa??aeo (iae. 4).
?c ?ic?aooie?a ne?ae, ui ni?iiaeaeuei? ? a?iiaeaeuei? ?cioa?ie i?e
oeiiaeo oiiaao i?iaaaeaiiy i?ioeano ?OA ?icoaoiaai? aaciina?aaeiuei
iiaeeco iaea?eueo aaaeeeaeo niieoe oaa?aeeo ?ic/ei?a nenoai A3A5 (iae.
4), a a ?yae? nenoai iaa?oue ? ?o ai?uothoue. A ?iaio? aeieacaii, ui
naia iano?eeee aai aeecueeee aei iueiai noai oaa?aei? oace ?
oa?iiaeeiai?/iith i?e/eiith iiyae e?iaoe/ieo aiiiae?e (iae. 3) o
i?io?eaii? i?ioeano oaciooai?aiiy. A?aei?/a?oueny, ui aoaeo
ni?iiaeaeueiiai ?iciaaeo oaa?aeeo ?ic/ei?a a ?aaeueieo aenia?eiaioao
ianeo?oueny a?eueo neeueieie o?ce/ieie yaeuaie. Aieiaia c ieo – oea
noaa?e?coth/ee aieea ianeaii? i?aeeiaeee, yea ? ?i?oe?aoi?ii ciai?oi?o
iie?a i?oaeieo iai?oa a nenoai?.
?icaeyae ciai?oi?o aeaoi?ioth/eo iai?oa a caaaeueiiio aia?aaoe/iiio
aaeain? oaa?aei? oace i?aeoe/ii ci?ia? iaiaaeaiiy ia iiaeeea?noue
io?eiaiiy oac ?c neeaaeii, ui iiiaaea? a iaeanoue ianoaa?eueiino?.
?ioeie neiaaie, aaaaeaiiy a ??aiyiiy o?i?/ii? ni?iiaeae? i?oaeii?
aia?a?? aeaoi?iaoe?? oiiei? ie?aee iieaco?, ui aaeee? iaeano?
iaci?ooaaiino? cae?eaathoueny. Oiio noaa?aeaeo?oueny, ui naia i?oaeia
aia?a?y ? ?i?oe?aoi?ii ai?oaen?aeueiiai i?ioeano a oeeo ianoaa?eueieo
oiiaao. Na?aae aeieac?a aeecueeino? noaio nenoai A3A5 aei aaniethoiiai
ianoaa?eueiiai a?aei?/athoueny aenia?eiaioaeueii niinoa?aaeoaai? no?eaee
neeaae?a a ai?oaen?aeueieo oa?ao i?e ia?aoiae? iaae no?eeino? o aeiaaeeo
inaaeaeaiiy oianoeo ie?aie, iiaeoeyoe?y (ia??iaee/i? i?e?ieieeaaiiy)
neeaaeo ia?iaiaeeeoey?ii o?iioo e?enoae?caoe?? ?, aieiaia, – oea aeniea
/ooeea?noue ia?aiao??a oaciooai?aiiy aei oiia i?iaaaeaiiy i?ioeano (iae.
3).
I?ioeane ?aeaenaoe?? ia??aiiaaaeieo noai?a i?e aaoa?iai?oaen??
Iaea?eueo aaaiiei aeieacii aaeaeaaoiino? ?ic?iaeaieo o?ce/ieo oyaeaiue
?aaeueiei i?ioeanai iaiao?aeii aeciaoe aenieioi/iee iien i?ioeano
iane/aiiy aaaaoieiiiiiaioii? ??aeei? oace ?c ?ic/eithaaii? i?aeeiaeee,
yeee o?nii iia’ycaiee c iiyaith a nenoai? i?oaeieo iai?oa ? yaeuaie
ianiia?aiino eiiiiiaio?a a eiioaeooth/eo na?aaeiaeuao.
Iniiaith oa?iiaeeiai?/ieo ?ic?iaie iineoaeea aenia?eiaioaeueii aeyaeaiee
oaeo ?nioaaiiy ia iiaa?oi? i?aeeiaeee a i?ioean? eiioaeoo c ??aeeith
oacith oiieiai ia?ao?aeiiai oa?o. I?enooi?noue oaeiai oa?o a oe?eiio
eiiieaen? ai?oaen?aeueieo nenoai a aeaiee /an aeieacaia aaaaoueia
aaoi?aie, a oiio /ene? ? ?acoeueoaoaie iiaeaii? ?iaioe.
Ca?aeii c ?ic?iaeaieie oyaeaiiyie i?eioneaeinue, ui iayai?noue
aeaoi?iaoe?eii? neeaaeiai? caeeoeiai? aia?a?? ci?uaiiy o iai?oaeaiiio
ia?ao?aeiiio oa?? ia ii/aoeia?e noaae?? aca?iiae?? noeioeth? ?ic/eiaiiy
i?aeeiaeee c ia?aaaaeaiiyi ??aeei? oace a ia?ane/aiee noai. Ia oe?e
noaae?? i?ioean ?ic/eiaiiy iienoaaany iaoaiaoe/iith ?ioa?i?aoaoe??th
iiaeae? iiaiiai ia?ai?ooaaiiy ?icieaao, eiee eiioeaio?aoe?? eiiiiiaio?a
ia iaae? ?icae?eo oac i?aeei?ythoueny ??aiyiiyi ??aiiaaae
i?oaeii-aeaoi?iiaaiee oa? – ia?ane/aia ??aeea oaca. Oaeee i?aeo?ae aei
aiae?co i?ioean?a ianiia?aiino aei?aaaeaiee oei, ui i?e iane/aii?
?icieaao c i?aeeiaeee-aeaea?aea ?ic/eithaaia oaa?aea oaca ciaoiaeeoueny
a ieaei?e /anoei? ?icieaao, ui noeioeth? iiyao eiiaaeoeaiiai
ianiia?aiino a ia’?i? ??aeei? oace. Aeae? i?eioneaeinue, ui
ia?aioieiaeaeaiiy ??aeei? oace iaaaeeea ? iaaeinoaoi? aeey ooai?aiiy
ca?iaee?a oaa?aei? oace a ia’?i? ?icieaao, ? a oie ae /an nenoaia
aeinyaea naiai e?ioeaaiai, eaac???aiiaaaeiiai noaio, ui aecia/a?oueny
eiie?aoiith o?ao?aoeaiith e?aieith ia iiaa?oi? eaac???aiiaaaeiiai
e?ea?aeona nenoaie.
Ianooiiee aoai iiaeaethaaiiy a?oiooaaany ia i?eiouaii?, ui a i??o
c?inoaiiy oiaueie ia?ao?aeiiai oa?o ca ?aooiie ianiiai?io eiiiiiaioaie
/a?ac i?aeoacio iaaeo ia?aiao?e inoaiiueiai aeinyaee nai?o e?eoe/ieo
cia/aiue. Inoaii? iaoiiaeth? ?aeaenaoe?th a nenoai? i?oaeieo iai?oa, ui
i?ecaiaeeoue aei ciaioaiiy a?eueii? aia?a?? oaa?aei? oace. ?acoeueoaoii
oaeiai i?ioeano iiaeiii aooe inaaeaeaiiy ia i?aeeiaeoe? caeeoeiai?
?ic/eiaii? a ??aee?e oac? ?a/iaeie aai, ui oa ae naia, ooai?aiiy ia
i?aeeiaeoe? caoeniiai oa?o. E?ioeaaeie i?iaeoeoaie oaei? aca?iiae??
iiaeii? aooe oace ?c neeaaeii, ui a?aeiia?aea? ??aiiaaaei?e ae?aa?ai?
noaio. Iiaeaethaaiiy oaeiai inaaeaeaiiy cae?enithaaeinue o
a?aeiia?aeiino? c iiaeaeeth aeeooc?eii-iaiaaeaii? e?enoae?caoe?? a
i?eiouaii? i?i oa, ui eiioeaio?aoe?? eiiiiiaio?a ia iaae? ?icae?eo oac
i?aeei?ythoueny oiiaai o?i?/ieo oaciaeo ??aiiaaa.
?ic?aooiee ii ioe?ioe? ia?aiao??a aca?iiae?? i?aeeiaeie GaP ? GaAs c
??aeeeie ?icieaaaie Ga-In-P, Ga-P-As, Al-Ga-P-As ca aeacaieie oyaeaiiyie
iieacaee oe?eeii caaeia?eueio a?aeiia?aei?noue ?ic?aooie?a ?c
niaoe?aeueii i?iaaaeaieie aenia?eiaioaie.
Iaiao?aeii iniaeeai a?aei?oeoe, ui ?acoeueoao aca?iiae??
i?aeeiaeee-aeaea?aea c iane/aiith ??aeeith oacith, ye i?aaeei, ca
eiioeaio?aoe??th eiiiiiaio?a nooo?ai a?ae??ciy?oueny a?ae aeo?aeii?.
Oeae oai?aoe/iee aeniiaie i?aeoaa?aeaeo?oueny niaoe?aeueii i?iaaaeaieie
aenia?eiaioaie, aea iieacaii nooo?aa ci?uaiiy o?ao?aoeaii? oi/ee a?ae
ii/aoeiaiai iieiaeaiiy a ?acoeueoao? ?aeaenaoe?eiiai i?ioeano. Oiio
?aii?oaaiiy oeueiai yaeua i?e ea?oaaii? neeaaeii oac iiaea neoaoaaoe
aeaea?aeii nooo?aeo iiieeie i?e i?iaaaeaii? i?ioeano aaoa?iai?oaen??.
Io?eiai? ?acoeueoaoe c iiaeaethaaiiy i?ioean?a ?aeaenaoe?? iieiaeaiiy
i?aeoacii? iaae? a aaaaoieiiiiiaioieo nenoaiao iieacothoue ye
i?eioeeiiao iiaeeea?noue iiaeaethaaiiy iane/aiiy ??aeei? oace a nenoaiao
c iayai?noth iaoai?/ieo iai?oaeaiue, oae ? aeiaiaeeoue canoiniaoaai?noue
?ic?iaeaieo oyaeaiue i?i ci?uaiiy oaciaeo ??aiiaaa ca ?aooiie iayaiino?
i?oaeieo iai?oa a nenoai? aei iieno ?aeaenaoe?eieo yaeu i?e
aaoa?iai?oaen??.
?aeaenaoe?ei? i?ioeane, iaoiiaeai? iayai?noth a ai?oaen?aeueieo nenoaiao
iaoai?/ieo iai?oa, aeei?enoiaoaaeenue a ?iaio? i?e ?ic?iaoe?
niaoe?aeueieo ?aaeei?a ?cioa?i?/iiai io?eiaiiy ie?aie oaa?aeeo ?ic/ei?a.
Ae?enii, ea?oth/e aaee/eiith aia?a?? i?oaeieo aeaoi?iaoe?e,
cae?enith?oueny ci?ia aaee/eie eiioaeoiiai ia?aioieiaeaeaiiy ??aeei?
oace, ui i?ecaiaeeoue aei inaaeaeaiiy ia i?aeeiaeoe? ai?oaen?aeueiiai
oa?o. Oaeee niin?a ai?oaen?? iiaeia ?aae?coaaoe, aeei?enoiaoth/e
i?aeaeuaia /enei oa?iiaeeiai?/ieo nooiai?a naiaiaee a aaaaoieiiiiiaioieo
nenoaiao aeey ea?oaaiiy aaee/eiith i?oaeii? aia?a??. Canoinoaaiiy
anueiai eiiieaeno oai?aoe/ieo ia?aaeoiia aeaii? ?iaioe aeicaieeei
oai?aoe/ii aea?aoe oiiae ?ic/eiaiiy ia?ciia??iaee/ii? i?aeeiaeee GaP
(111) a ?icieaa? In–P, ye? i?e iaci?ii?e oaiia?aoo?? i?ioeano
caaacia/oaaee e?enoae?caoe?th oa?o oaa?aeiai ?ic/eio GaInP ia
?ciia??iaee/i?e eiio i?aeeiaeoe? GaAs (A.N. ? 1232078). ?ioeie neiaaie,
?ic?iaeai? iiaeaeuei? oyaeaiiy ia o?eueee aeicaieyee iienaoe ?
?ioa?i?aooaaoe aenia?eiaioaeuei? ?acoeueoaoe, aea e aeicaieeee
ia?aaeaa/eoe ? e?euee?nii ni?iaiicoaaoe iia? ?aaeeie e?enoae?caoe??
aaaaoieiiiiiaioieo oa??a.
INIIAI? AENIIAEE
I?aaenoaaeai? a aeai?e ?iaio? ?acoeueoaoe oai?aoe/ieo ?
aenia?eiaioaeueieo aeine?aeaeaiue i?ioeano oaciooai?aiiy a
aaaaoieiiiiiaioieo iai?aipia?aeieeiaeo nenoaiao aeicaieythoue c?iaeoe
ianooii? ocaaaeueiaiiy ? aeniiaee:
1. Aia?oa cae?eniaii oa?iiaeeiai?/ia ? iaoaiaoe/ia iiaeaethaaiiy
i?ioean?a oaciooai?aiiy a aaaaoieiiiiiaioieo iai?ai?ia?aeieeiaeo
nenoaiao i?e io?eiaii? iaoa??ae?a aeaeo?iiii? oaoi?ee
aaaaoiooieoe?iiaeueiiai i?ecia/aiiy.
2. Iieacaii, ui a aaaaoieiiiiiaioieo iai?aipia?aeieeiaeo nenoaiao A3A5
caaeia?eueia a?aeiia?aei?noue oaip?? aeniapeiaioo ca oaciaeie
p?aiiaaaaie picieaa–epenoae a oepieiio oaiiapaoopii-eiioeaiopaoe?eiiio
ia’?i? oaciaiai ipinoi?o aeinyaa?oueny o?eueee ?c canoinoaaiiyi e?i?eii
caeaaeieo a?ae oaiiapaoope i?eaaaeaieo caeeoeiaeo aiapa?e ci?uaiiy a
iaio eiioaeooth/eo oacao. Oeyoii iine?aeiaiiai picaeyaeo oapaeoapa
oaciauo ??aiiaaa a?ae a?iapieo nenoai aei aaaaoieiiiiiaioieo aecia/aii
iaa?p naiiocaiaeaeaieo oapiiaeeiai?/ieo ooieoe?e, canoinoaaiiy yeeo aea?
iaee?auo a?aeiia?aei?noue aeniapeiaioaeueiei aeaiei.
3. Iieacaii, ui a aaaaoieiiiiiaioieo iai?aipia?aeieeiaeo nenoaiao, ui
epenoae?cothoueny a nopoeoop? oi?iae?, iienaoe oacia? p?aiiaaae
epenoae–picieaa–aac iiaeia o?eueee ?c canoinoaaiiyi oaip?? anioe?eiaaieo
pic/ei?a ? oyaeaiue i?i ?nioaaiiy eeniaaeo eiiieaen?a neeaaeiiai neeaaeo
a aaaaoieiiiiiaioi?e ??aee?e oac?. O a?aeiia?aeiino? c oaip??th
anioe?eiaaieo pic/ei?a aeeiiaii aiae?c ae?aa?aie noaio a iaeano?
oi?iaeaooai?aiiy nenoaie oeeie–iapaaiaoeue–cae?ci–eenaiue.
4. A ?aieao oai??? i?inoeo ?ic/ei?a ? oyaeaiue i?i ieineo i?oaeio
aeaoi?iaoe?th oiieiai oa?o cai?iiiiiaai? ??aiyiiy eaac?p?aiiaaaeii?
ae?aa?aie noaio aeaoipiiaaia ie?aea–aeaniee picieaa aeey
aaaaoieiiiiiaioieo nenoai A3A5. O a?aeiia?aeiino? c iiaeaeeth ipoaeiiai
ni?yaeaiiy ai?oaen?aeueiiai oa?o ? i?aeeiaeee aeeiiaii aiae?c ia?aiao??a
eaac?noaa?eueii? ??aiiaaae a caeaaeiino? a?ae oiia aca?iiae?? i?aeeiaeie
? picieaao aeey /ioepe- ? opeeiiiiiaioieo oaa?aeeo ?ic/ei?a A3A5.
5. O a?aeiia?aeiino? c oaip??th aeeooc?eii iaiaaeaiiai pinoo aeeiiaii
e?iaoe/iee aiae?c i?ioean?a ianiia?aiino i?e oaciooai?aii? a
aaaaoieiiiiiaioieo iai?ai?ia?aeieeiaeo nenoaiao. Aeey ?cioa?i?/ieo oiia
e?enoae?caoe?? ciaeaeai? aiae?oe/i? ?ica’ycee aeeoapaioe?eieo ??aiyiue
ianiia?aiino, ye? nipaaaaeeea? ia ii/aoeia?e noaae?? ai?oaen?aeueii?
aca?iiae?? (t ? 0,2L2/D). Iieacaii, ui aeey aeacaiiai /aniaiai ?ioapaaeo
neeaae inaaeaeoaaii? oace caeeoa?oueny noaeei, a ?iaap?aioiith ci?iiith,
yea caaacia/o? epenoae?caoe?th oa?o iaeiiai ? oiai ae neeaaeo ?c
picieaao c p?ciei ii/aoeiaei ai?noii eiiiiiaio?a, ? iapaiaop ?.
6. Iieacaii, ui aeey a?eueoino? oaa?aeeo ?ic/ei?a niieoe A3A5 oeiia?
oaiia?aoo?ii-eiioeaio?aoe?ei? oiiae oaciooai?aiiy ?c aeaniiai picieaao
?icoaoiaai? iiaeeco aai iaa?oue a na?aaeei? iiaa?oiiue iaoanoaa?eueiiai
/e iaa?oue aaniethoii ianoaa?eueiiai noaio oaa?aei? oace. A paieao
oaip?? ipinoeo pic/ei?a cai?iiiiiaai? aepace ? aeeiiai? pic?aooiee
iieiaeaiiy ni?iiaeaeueieo ? a?iiaeaeueieo iiaapoiiue a /aoaapieo
oaa?aeeo ?ic/eiao nenoai A3A5.
7. Ia iniia? ?ic?iaeaieo oai?aoe/ieo oyaeaiue cai?iiiiiaaii iaeao
?iaeaia?ieo ia/enethaaeueieo i?ia?ai, ye? aeicaieythoue iia?aoeaii
iiaeaethaaoe eiie?aoi? ?aaeeie oaciooai?aiiy a aaaaoieiiiiiaioieo
iai?ai?ia?aeieeiaeo nenoaiao. Canoinoaaiiy ia/enethaaeueieo ipiapai
aeicaieeei aoaeoeaii ea?oaaoe ipioeanii io?eiaiiy ai?oaen?aeueieo
aaoapinopoeoop ia iniia? aaaaoieiiiiiaioieo nenoai A3A5 a paieao
aeine?aeiiai ae?iaieoeoaa ipeeaae?a ?iopaepanii? iioiaeaeopii?ee ?
ipioeanii aepiuoaaiiy a nap?eiiio ae?iaieoeoa? ia’?iieo iiiiepenoae?a
iaai?oieo oi?iaeae. Oai?aoe/ii ia?aaeaa/aii ? ?aae?ciaaii iiaee iaoiae
?cioa?i?/ii? ai?oaen?? oaa?aeeo ?ic/ei?a nenoaie A3A5.
INIIAI? IOAE?EAOe?? II OAI? AeENA?OAOe??
Eociaoeia A.A., Iineaei I.I., Ni?ieei A.N. Ia?aaiiaaniua yaeaiey i?e
aeeaeeinoiie aaoa?iyieoaenee iieoi?iaiaeieeiauo oaa?aeuo ?anoai?ia. –
I.: Iaoaeeo?aey, 1991. – 174 n.
Ai?aeaiie A.O., Iaeeaaie A.I., Iineaei I.I., Ni?ieei A.N., Oneeia A.N.
Enneaaeiaaiea oaciauo ?aaiiaanee a nenoaia Ga–In–P–As. – AEOO, 1982. –
O. 56. – ? 10. – N. 2416–2421.
Gorelenok A.T., Kuznetsov V.V., Moskvin P.P., Sorokin V.S.
Perculiarities of LPE in GaInPAs/InP lattice-matched heterostructure. –
J. Cryst.Growth, 1987. – V. 80. – P. 298–306.
Iineaei I.I. Eaacenoaaeeueiua ninoiyiey a oaoiieiaee iiiaieiiiiiaioiuo
no?oeoo? aeey iee?iyeaeo?iieee // Iaoa??aee III Iiaeia?iaeii?
iaoeiai-i?aeoe/ii? eiioa?aioe?? "No/anii oaoiieiai? a aa?ieinii/iiio
eiiieaeni". – AEeoiie?, 9–11 aa?aniy, 1997 ?. – N. 108–110.
Iineaei I.I. Oa?iiaeeiaie/aneia iiaeaee?iaaiea noaaeee ieii/aoaeueiiai
niaeaiey ea?aie/aneeo aa?ee-no?iioeeaauo iaaieoiuo no?oeoo?// Iaoa??aee
III Iiaeia?iaeii? iaoeiai-i?aeoe/ii? eiioa?aioe?? "No/anii oaoiieiai? a
aa?ieinii/iiio eiiieaeni". – AEeoiie?, 9–11 aa?aniy, 1997 ?. – N. 41–43.
Iineaei I.I. Caeiiiia?iinoe eciaiaiey naienoa oaa?aeuo ?anoai?ia
GaxIn1-xPyAs1-y // Ecaanoey EYOE. – 1982. – Aui. 302. – N. 64–68.
Iineaii I.I. Oa?iiaeeiaiiea eaacinoaaieueii? ?iaiiaaae iiae iai?oaeaiith
aaaaoieiiiiiaioiith aiioaeniaeueiith ieiaeith oa aeaniei ?icieaaii a
nenoaiao A3A5 // Ainiee Ee?anueeiai oi-oo. Oic.-iao. iaoee. – 1998. – ?
2. – C. .
Iineaii I.I. Oaciaa ?iaiiaaaa iiae ne?eaeaiith iiaa?oiath e?enoaeioia oa
?o aeaniei ?icieaaii a nenoaii aa?ie–no?iioeie–caeici–eenaiue // Ainiee
Ee?anueeiai oi-oo. Oic.-iao. iaoee. – 1998. – Aei. 1. – N. 394–402.
Iineaii I.I. Oa?iiaeeiaiiea iiaeca?ieiii? aca?iiaei? iiae /an
inoaoi/iiai niieaiiy e?enoaeioia aa?ie-no?iioei?aeo aaenaoa?eoia. 1.
Oa?iiaeeiaii/ii iniaeeainoi niieaiiy i oaciaa ?iaiiaaaa iiae ne?eaeaiith
iiaa?oiath e?enoaeioia oa ?o aeaniei ?icieaaii a nenoaii
aa?ie–no?iioeie–caeici–eenaiue // Ainiee AEIOI. – 1997. – ? 6/Oaoi?/i?
iaoee. – N. 29–34.
Iineaii I.I. Oa?iiaeeiaiiea iiaeca?ieiii? aca?iiaei? iiae /an
inoaoi/iiai niieaiiy e?enoaeioia aa?ie-no?iioei?aiai aaenaoa?eoia. 2.
Iiaeca?iiee ianiiaiii i?e niieaiii a i?enooiinoi ?iaeei? oace oa
iiaeaethaaiiy i?ioeano inoaoi/iiai niieaiiy ii?ioeo aa?ie-no?iioei?aiai
oa?eoo // Ainiee AEIOI. – 1997. – ? 7/Oaoi?/i? iaoee. – N. 23–26.
Iineaei I.I., Eociaoeia A.A., Naaiei E.A. Oaciaua ?aaiiaaney a iaeanoe
oieiaeaia?aciaaiey nenoaiu aeaeaci–eenei?iae. – AEOO, 1988. – O. 62. – ?
12. – N. 3196–3200.
Euiei N.A., Iineaei I.I., Ioaie/iia A.A., Naaiei E.A. ?aaiiaaney
e?enoaee–?anieaa-aac a iaeanoe ia?aciaaiey oieiaee nenoaiu
oeeie–ia?aaiaoe–aeaeaci–eenei?iae. 1. Aiaeec oaciauo ?aaiiaanee a
enoiaeiuo aeia?iuo nenoaiao. – AEOO, 1991. – O. 65. – ? 5. – N.
1179–1183.
Euiei N.A., Iineaei I.I., Ioaie/iia A.A., Naaiei E.A. ?aaiiaaney
e?enoaee–?anieaa–aac a iaeanoe ia?aciaaiey oieiaee nenoaiu
oeeie–ia?aaiaoe–aeaeaci–eenei?iae. III. Oa?iiaeeiaieea oaciauo
?aaiiaanee e aeeaa?aiia ninoiyiey a iaeanoe ia?aciaaiey oieiaee nenoaiu
oeeie–ia?aaiaoe–aeaeaci–eenei?iae. – AEOO, 1992. – O. 66. – ? 9. – N.
2310–2315.
Euiei N.A., Iineaei I.I., Ioaie/iia A.A., Naaiei E.A. ?aaiiaaney
e?enoaee–?anieaa–aac a iaeanoe ia?aciaaiey oieiaee nenoaiu
oeeie–ia?aaiaoe–aeaeaci–eenei?iae. II. Oaciaua ?aaiiaaney a
oa??eoiia?acothueo o?aoeiiiiiaioiuo oaa?aeuo ?anoai?ao nenoaiu
oeeie–ia?aaiaoe–aeaeaci–eenei?iae. – AEOO, 1991. – O. 65. – ? 5. – N.
1184–1189.
Iineaei I.I., Ni?ieei A.N. I?ioeannu ianniia?aiina i?e iieo/aiee
yieoaeneaeueiuo neiaa GaxIn1-xPyAs1-y iaoiaeii nooiai/aoiai
ioeaaeaeaiey. *. I. ?ino ec iieoaaneiia/iie aeeaeeie oacu. – AEOO, 1984.
– O. 58. – ? 2. – N. 422–427.
Kuznetsov V.V., Moskvin P.P, Sorokin V.S. Growth kinetic in LPE of the
Ga–In–P–As system. – J.Cryst. Growth, 1984. – V. 66. –P. 562–574.
Kuznetsov V.V, Moskvin P.P, Sorokin V.S. Coherent phase diagram and
interface relaxation processes during LPE of A3B5 solid solutions. –
J.Cryst. Growth, 1988. – V. 88. – P. 241–262.
Eociaoeia A.A., Iineaei I.I., Ni?ieei A.N. Oa?iiaeeiaie/aneay
onoie/eainoue oaa?aeuo ?anoai?ia GaxIn1-xPyAs1-y // Ecaanoey AI NNN?.
Na?. Iai?aai. iaoa?., 1985. – O. 21. – ? 12. – N. 2006–2010.
Eociaoeia A.A., Iineaei I.I., Naaeianee A., Ni?ieei A.N. Eeiaoeea
i?ioeanna ?anoai?aiey a?naieaea eiaeey a ?anieaaao nenoaiu
eiaeee–iuoueye // Ecaanoey AI NNN?. Na?. Iai?aaie/. iaoa?., 1983. – O.
19. – ? 4. – N. 541–545.
Eociaoeia A.A., Iineaei I.I., Ni?ieei A.N. Aeeoooceiiiua i?ioeannu i?e
aeeaeeioaciie yieoaenee a nenoaia Ga–In–P // Ecaanoey AI NNN?. Na?.
Iai?aaie/aneea iaoa?., 1985. – O. 21. – ? 6. – N. 892–896.
Iineaei I.I., Ni?ieei A.N. Iniaaiiinoe ii?aaeaeaiey eiyooeoeeaioia
aeeooocee eiiiiiaioia a ?anieaaao nenoai A3A5 // Ecaanoey aocia. Oeceea.
– 1987. – Aui.4. – N.19–25.
Iineaei I.I., Ni?ieei A.N. Aeeyiea oa?aeoa?a oaciauo ?aaiiaanee ia
eeiaoeeo e?enoaeeecaoeee oaa?aeuo ?anoai?ia
GaxIn1-xPyAs1-y. – AEOO, 1987. – O. 56. – ? 2. – N. 398–403.
Iineaei I.I., Ni?ieei A.N. I?ioeannu ianniia?aiina i?e iieo/aiee
yieoaeneaeueiuo neiaa GaxIn1-xPyAs1-y iaoiaeii nooiai/aoiai
ioeaaeaeaiey. *. II. ?ino ec ia?aie/aiiiai iauaia aeeaeeie oacu. – AEOO,
1983. – Aui. 12. – N. 2953–2956.
Eociaoeia A.A., Iineaei I.I., Ni?ieei A.N. Acaeiinaycue iiaeaeae
ianniia?aiina i?e aeeaeeioaciie yieoaenee oaa?aeuo ?anoai?ia // Ecaanoey
AI NNN?. Na?. Iai?aaie/aneea iaoa?., 1988. – O. 24. – N. 1912–1914.
Ai?aeaiie A.O., Iineaei I.I., Ni?ieei A.N., Oneeia A.N. Iniaaiiinoe
iieo/aiey aaoa?ino?oeoo? InGaAsP/InP n o/aoii eeiaoe/aneeo yooaeoia //
Oacenu 3-ae Ananithciie eiioa?aioeee ii oece/aneei i?ioeannai a
iieoi?iaiaeieeiauo aaoa?ino?oeoo?ao. – Iaeanna, 1982. – N. 46.
Euiei N.A., Iineaei I.I., Ioaie/iia A.A., Naaiei E.A. Iaoaiaoe/aneay
iiaeaeue e?enoaeeecaoeee oaa?aeuo ?anoai?ia ia?aaiaoe-oeeieiauo
oa??eoia. – AEOO, 1994. – O. 68. – ? 5. – N. 813–816.
Euiei N.A., Iineaei I.I, Ioaie/iia A.A., Iiiia A.A. Oaiaaa A.N.
Oa?iiaeeiaie/aneia i?iaiice?iaaiea oeceei-oeie/aneeo oneiaee au?aueaaiey
iieoi?iaiaeieeia ni no?oeoo?ie oieiaee // Oacenu eiioa?aioeee
“Oeceei-oeie/aneea iniiau iieo/aiey e enneaaeiaaiey iieoi?iaiaeieeia a
oaa?aeii e aeeaeeii ninoiyiee”. – Eoeya, 1989.
Euiei N.A., Iineaei I.I., Ioaie/iia A.A., Iiiia A.A., Oaiaaa A.N.
Oa?iiaeeiaieea au?aueaaiey iauaiiuo iiiie?enoaeeia iaaieoiuo
iieoi?iaiaeieeia // Oacenu aeieeaaeia eiioa?aioeee “Oeceei-oeie/aneea
iniiau iieo/aiey e enneaaeiaaiey iieoi?iaiaeieeia a oaa?aeii e aeeaeeii
ninoiyiee”. – Eoeya,1989. – N. 103.
Eociaoeia A.A., Iineaei I.I., Ni?ieei A.N. Eiaa?aioiay aeeaa?aiia
ninoiyiey /aou?aoeiiiiiaioiuo nenoai A3A5. – AEOO, 1986. – O. 60. –
? 6. – N. 1376–1381.
Ai?aeaiie A.O., Aeceaania A.A., Iineaei I.I., Ni?ieei A.N., Oa?ania E.N.
Caaeneiinoue oe?eiu cai?auaiiie ciiu io ninoaaa oaa?aeuo ?anoai?ia
GaInPAs. – OOI, 1981. – O. 15. – ? 12. – N. 2410–2414.
Iineaei I.I., Ni?ieei A.N. Eeiaoeea i?ioeannia i?e aeeaeeioaciie
yieoaenee oaa?aeuo ?anoai?ia GaxIn1-xPyAs1-y. – AEOO, 1983. – O. 57. –
? 7. – N. 1684–1689.
Gorelenok A.T., Moskvin P.P., Sorokin V.S., et al. Phase equilibria in
InGaAsP system. – J. Cryst. Growth, 1982. – V. 60. – ? 2. – P. 355–362.
Iineaei I.I., Ni?ieei A.N. I?ioeannu ianniia?aiina i?e iieo/aiee
yieoaeneaeueiuo neiaa GaxIn1-xPyAs1-y iaoiaeii nooiai/aoiai
ioeaaeaeaiey. *. II. ?ino ec ia?aie/aiiiai iauaia aeeaeeie oacu. – AEOO,
1983. – O. 57. – ? 12. – N. 2953–2956.
Eociaoeia A.A., Iineaei I.I., Ieueoiaee ss., Ni?ieei A.N.
?aeaenaoeeiiiay ecioa?ie/aneay yieoaeney oaa?aeuo ?anoai?ia A3A5 //
Ecaanoey AI NNN?. Na?. Iai?aaie/aneea iaoa?eaeu, 1986. – O. 22. – ? 11.
– N. 1773–1778.
A.n. 1232078 NNN?, IEE I 01L 21/208. Niinia ecaioiaeaiey yieoaeneaeueiuo
no?oeoo? GaoIn1-oP/GaAs / A.A. Eociaoeia (NNN?), I.I. Iineaei (NNN?),
A.N. Ni?ieei (NNN?), ss. Ieueoiaee, (II?). 6 n. io 19.07.84.
Kuznetsov V.V., Moskvin P.P, Sorokin V.S. Mass transfer during growth of
Ga-In-P-As solid solution in the equilibrium cooling growth technique. –
Crystal Res. Technol., 1985. – V. 20. – ? 5. – P. 439–446.
Euiei N.A., Iineaei I.I., Ioaie/iia A.A., Naaiei E.A. Oi?aaeaiea
i?ioeannii e?enoaeeecaoeee oaa?aeuo ?anoai?ia ia?aaiaoe-oeeieiauo
oa??eoia. – AEOO, 1994. – O. 68. – ? 5. – N. 817–819.
Iineaei I.I., Ia/eiieeia N.TH., Ni?ieei A.N. Oaciaua ?aaiiaaney a
nenoaia aaeeee–aethieiee–eiaeee–oinoi?. – AEOO, 1982. – O. 56. – ? 8. –
N. 2067–2069.
Iineaei I.I., Ia/eiieeia N.TH., Ni?ieei A.N. ?an/ao eiioeaio?aoeee
nianoaaiiuo aeaoaeoia e ioeeiiaiey io noaoeiiao?ee a oaa?aeuo ?anoai?ao
GaoIn1-oPyAs1-y. – E?enoaeeia?aoey, 1983. – O. 28. – Aui. 3. – N.
530–537.
Iineaei I.I., Ia/eiieeia N.TH. ?an/ao eiioeaio?aoeee nianoaaiiuo
aeaoaeoia a oaa?aeuo ?anoai?ao oinoeae-a?naieae aaeeey // Ecaanoey EYOE.
Iao/iua o?oaeu, 1981. – Aui. 281. – N. 98–105.
Iinea?i I.I. Oa?iiaeeiai?ea ? e?iaoeea oaciooai?aiiy a
aaaaoieiiiiiaioieo iai?ai?ia?aeieeiaeo nenoaiao. – ?oeiien.
Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy aeieoi?a o?ceei-iaoaiaoe/ieo
iaoe ca niaoe?aeuei?noth 01.04.07 – o?ceea oaa?aeiai o?ea. – Ee?anueeee
oi?aa?neoao ?iai? Oa?ana Oaa/aiea, i. Ee?a, 1999 ?.
I?iaaaeai? oai?aoe/i? oa aenia?eiaioaeuei? aeine?aeaeaiiy i?ioean?a
oaciooai?aiiy a aaaaoieiiiiiaioieo nenoaiao A3A5. Iniiae oai?aoe/ieo
?ic?iaie neeaee oyaeaiiy oa?iiaeeiai?ee ?ic/ei?a a iaaeeaeaii?
?aaoey?ieo, eaac??aaoey?ieo oa anioe?eiaaieo iiaeaeae. ?ic?iaeai?
oa?iiaeeiai?/i? oyaeaiiy aeicaieeee aeinyaiooe caaeia?eueiiai iieno
oaciaeo ??aiiaaa oa i?iaiicoaaoe e?i?? ?iciaaeo oaa?aeiai noaio
aaaaoieiiiiiaioii? oace. Cai?iiiiiaai? iaoaiaoe/i? iiaeae?, ye?
iienothoue e?iaoeeo e?enoae?caoe?? oaa?aeeo ?ic/ei?a c ??aeei? oace.
Aeeiiaii aiae?c aieeao iaoai?/ieo iai?oaeaiue i?e oaciooai?aii? ia
ci?uaiiy oaciaeo ??aiiaaa oa ia e?iaoeeo ?inoo aaaaoieiiiiiaioii?
ie?aee. Aenia?eiaioaeueii i?aeoaa?aeaeai? oai?aoe/i? aeniiaee i?i aieea
ia?aiao??a ?inoiaiai oeeeeo ia aeanoeaino? e?enoae?/ieo oac. Ae?iaeai?
?aeiiaiaeaoe?? uiaei iioei?caoe?? i?ioeano ea?oaaiiy oaciooai?aiiyi a
aaaaoieiiiiiaioieo nenoaiao.
Eeth/ia? neiaa: oaa?ae? ?ic/eie niieoe A3A5, e?enoae?caoe?y c ??aeei?
oace, aaoa?iai?oaen?y, oacia? ??aiiaaae oa e?iaoeea e?enoae?caoe??.
Iineaei I.I. Oa?iiaeeiaieea e eeiaoeea oaciia?aciaaiey a
iiiaieiiiiiaioiuo iieoi?iaiaeieeiauo nenoaiao. – ?oeiienue.
Aeenna?oaoeey ia nieneaiea o/aiie noaiaie aeieoi?a oeceei-iaoaiaoe/aneeo
iaoe ii niaoeeaeueiinoe 01.04.07 – oeceea oaa?aeiai oaea. – Eeaaneee
ainoaea?noaaiiue oieaa?neoao eiaie Oa?ana Oaa/aiei, a. Eeaa, 1999 a.
I?iaaaeaii oai?aoe/aneia e yenia?eiaioaeueiia enneaaeiaaiea i?ioeannia,
i?ioaeathueo i?e oaciia?aciaaiee /aou?aoeiiiiiaioiuo iieoi?iaiaeieeiauo
oaa?aeuo ?anoai?ia nenoaiu A3A5 e oaa?aeuo ?anoai?ia iaaieoiuo
iieoi?iaiaeieeia ni no?oeoo?ie oieiaee ec aeeaeeie oacu.
Iniiaie oai?aoe/aneeo ?ac?aaioie neoaeeee i?aaenoaaeaiey ?aaiiaaniie
oa?iiaeeiaieee iiiaieiiiiiaioiuo ?anoai?ia. Iieacaii, /oi
oaeiaeaoai?eoaeueiia iienaiea iieiaeaiee iiaa?oiinoae aeeaa?aiiu
ninoiyiey /aou?aoeiiiiiaioiuo nenoai A3A5 a oe?ieii eioa?aaea oaiia?aoo?
ii anaio iieth aeeaa?aiiu ninoaaia aiciiaeii oieueei n i?eiaiaieai a
oai?ee ?aaoey?iuo ?anoai?ia eeiaeii caaenyueo io oaiia?aoo?u
i?eaaaeaiiuo naiaiaeiuo yia?aee niaoaiey a aeeaeeie e oaa?aeie oacao.
e aeaiiui ii eeeaeaeono nenoaiu Fe3O4–(Fe–O)l.
A ?aaioa iieacaii, /oi eioa?i?eoaoeey yenia?eiaioaeueiuo aeaiiuo ii AEOY
iiiaieiiiiiaioiuo oaa?aeuo ?anoai?ia e aeaiiuo ii ?inoo iauaiiuo
iiiie?enoaeeia oieiaeae eae oa?iiaeeiaie/anee ?aaiiaaniuo i?eaiaeeo e
nouanoaaiiui ioeaeai a /eneaiiuo cia/aieyo eneiiuo oa?iiaeeiaie/anee
?aaiiaaniuo ia?aiao?ia nenoai. Iniiaiuie oece/aneeie yaeaieyie
ioaaonoaaiiuie ca oaeia iiaaaeaiea nenoai a ?aaioa n/eoaeenue iaee/ea
i?e oaciia?aciaaiee iieae oi?oaeo iaoaie/aneeo iai?yaeaiee,
iaoneiaeaiiuo ianiioaaonoaeai ia?eiaeia e?enoaeee/aneeo ?aoaoie iaaeaeo
ieaieie e iiaeeiaeeie, e eeiaoe/aneea yooaeou, naycaiiua n eiia/iie
nei?inoueth aeeoooceiiiiai iiaeaiaea aauanoaa e o?iioo e?enoaeeecaoeee.
A ?aaioa a ?aieao oai?ee ?aaoey?iuo ?anoai?ia e eeiaeiie aiecio?iiiie
oai?ee oi?oainoe i?aaeeiaeaiu o?aaiaiey eaace?aaiiaaniiai ninoiyiey
oi?oai aeaoi?ie?iaaiiue oiieee neie ia ianneaiie iiaeeiaeea -
iiiaieiiiiiaioiay aeeaeeay oaca. ?aoaiey i?aaeeiaeaiiuo o?aaiaiee
iicaieeee i?iaiaeece?iaaoue oa?aeoa? niauaiey oaciauo ?aaiiaanee i?e
inaaeaeaiee oi?oai aeaoi?ie?iaaiiie ieaiee a nenoaia Ga-In-P-As ia
enoiaeiua aeia?iua iiaeeiaeee. Iieo/aia eiee/anoaaiiay eioi?iaoeey i
aaee/eia eiioaeoiiai ia?aioeaaeaeaiey eieoeee?iaaiiiai oi?oaeie
iai?yaeaieyie a neiyo, a oaeaea ia eciaiaiee ninoaaa inaaeaeaaiuo neiaa
ec-ca iaee/ey a ?inoiauo nenoaiao iaoaie/aneeo aeaoi?iaoeee.
Aeey iienaiey i?ioeania ianniia?aiina a iiiaieiiiiiaioiuo nenoaiao
eniieueciaaeenue i?aaenoaaeaiey i aeeoooceiiii-ia?aie/aiiie
e?enoaeeecaoeee e iiaeaeue iieiiai ia?aiaoeaaiey ?anieaaa. Oi?ioee?iaea
e?aaaie caaea/e aeey aeeooa?aioeeaeueiuo o?aaiaiee ianniia?aiina
caaa?oaeanue eniieueciaaieai a ea/anoaa a?aie/iuo oneiaee aeey
eiioeaio?aoeee eiiiiiaioia ia a?aieoea ?acaeaea ?anieaa-e?enoaee
o?aaiaiee ?aaiiaaniie aeeaa?aiiu ninoiyiey eee aea o?aiaiee
eaace?aaiiaaney oi?oai iai?yaeaiiue neie - iiiaieiiiiiaioiay aeeaeeay
oaca. A ?aaioa iaeaeaiu aiaeeoe/aneea ?aoaiey o?aaiaiee aeeooocee a
i?eaeeaeaiee iieoaaneiia/iuo n?aae, iicaieythuea naanoe nenoaio
aeeooa?aioeeaeueiuo o?aaiaiee ianniia?aiina e aeaaa?ae/aneei, /oi
iicaieeei yooaeoeaii iaoiaeeoue ?aoaiea e?aaaie caaea/e. Iieo/aiiua a
?aaioa aeeooa?aioeeaeueiua o?aaiaiey ianiiiaiaia eiiiiiaioia iaaeaeo
aaciaie n?aaeie, ?anieaaii e ?anoouei e?enoaeeii i?e e?enoaeeecaoeee
iauaiiuo iiiie?enoaeeia ia?aaiaoe-oeeieiauo oa??eoia ?aoaeenue
/eneaiiuie iaoiaeaie.
?ac?aaioaiiua oa?iiaeeiaie/aneea i?aaenoaaeaiey i ia?aaiiaaniuo
yaeaieyo, niioonoaothuea i?ioeannai e?enoaeeecaoeee, iicaieeee o/anoue
eo a oai?aoe/aneii aiaeeca e ii?aaeaeeoue /eneaiiua cia/aiey
oa?iiaeeiaie/aneeo ooieoeee iiaeaeueiuo nenoai Ga-In-P-As e Zn-Mn-Fe-O.
N iiiiuueth ?ac?aaioaiiuo oa?iiaeeiaie/aneeo iiaeaeae oaciia?aciaaiey e
iaeaeaiiuo oa?iiaeeiaie/aneeo ooieoeee i?iaiaeece?iaaii aeeyiea ninoaaa
enoiaeiie aeeaeeie oacu, oaiia?aoo?u e nei?inoe ?inoa, noaiaie
ia?aioeaaeaeaiey e o. ae. ia ia?aiao?u e?enoaeeecoaiuo iiiaieiiiiiaioiuo
oaa?aeuo ?anoai?ia A3A5 e oaa?aeiai ?anoai?a ZnoMn1-oFeyO1-y.
Aeinoeaiooi niioaaonoaea ?an/aoia yenia?eiaioai ii iienaieth i?ioeannia
oaciia?aciaaiey a ?anniao?eaaaiuo iiiaieiiiiiaioiuo iieoi?iaiaeieeiauo
nenoaiao.
Eeth/aaua neiaa: iiiaieiiiiiaioiua iieoi?iaiaeieeiaua oaa?aeua ?anoai?u
nenoaiu A3A5, AEOY, oaciaua ?aaiiaaney e eeiaoeea e?enoaeeecaoeee.
Moskvin P.P. Thermodynamic & kinetic milticomponent semiconductors
phases formation. – Manuscript.
The dissertation advanced for degree of Doctor of Science (Physics &
Matermatics) in speciality of 01.04.07 – Solid State Physics. – Taras
Schevchenko Kyiv University, Kyiv, 1999.
There are 54 scientific papers included monograth of the authorship
represented. Disertation includes the results of theoretical &
experimental investigation of thermodynamics of formation process for
multicomponent semiconductors from liquid solutions A3B5 systems. The
phase equilibria is analysed according the simple solution in
quasiregular & associated solutions treatments. The termodynamic
equations describing the metastable equilibrium between elastically
strained solid solution & liquid pases in quaternary systems are
obtained. A theoretical analysis of growth kinetics is carried out in
terms of the diffusion-limited growth model. The influence of growth
regimes on parameters of the layers for electronics devices is studied.
Key words: A3B5 solid solution, growth from liquid phase, LPE, phases
equilibria, growth kinetics.
PAGE 43
Нашли опечатку? Выделите и нажмите CTRL+Enter
