OA?E?ANUeEEE IAOe?IIAEUeIEE OI?AA?NEOAO ?i. A.I.EA?AC?IA

OAI*OE EAII?Ae AIOIIIAE*

OAeE 547.461.5:547.476.5:547.856.1

NEIOAC OA O?I?*I? IA?AOAI?AIIss

IIO?AeIEO AEOOA?AI?IIAEO EENEIO ?

AAOA?IOeEEE?*IEO NIIEOE IA ?O INIIA?

02.00.03 – i?aai?/ia o?i?y

Aaoi?aoa?ao

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

aeieoi?a o?i?/ieo iaoe

Oa?e?a – 1999

Aeena?oaoe??th ? ?oeiien.

?iaioa aeeiiaia a Iaoe?iiaeuei?e oa?iaoeaaoe/i?e aeaaeai?? Oe?a?ie
(i.Oa?e?a), I?i?noa?noai ioi?iie caei?ia’y Oe?a?ie.

Iaoeiaee eiinoeueoaio /eai–ei?aniiiaeaio IAI Oe?a?ie, aeieoi? o?i?/ieo
? oa?iaoeaaoe/ieo iaoe, i?ioani? *a?ieo Aaeaioei Iao?iae/, Iaoe?iiaeueia
oa?iaoeaaoe/ia aeaaeai?y Oe?a?ie (i.Oa?e?a), ?aeoi? aeaaeai??.

Io?oe?ei? iiiiaioe: /eai–ei?aniiiaeaio IAI Oe?a?ie, aeieoi? o?i?/ieo
iaoe, i?ioani? Iiiia Aiaoie?e Oaaei?iae/, ?inoeooo o?ceei-i?aai?/ii?
o?i?? oa aoaeao?i?? ?i. E.I.Eeoaeiaiea IAI Oe?a?ie (i.Aeiiaoeuee),
aee?aeoi? ?inoeoooo

aeieoi? o?i?/ieo iaoe, i?ioani? ?eue/aiei Aiae??e sseiae/, ?inoeooo
i?aai?/ii? o?i?? IAI Oe?a?ie (i. Ee?a), i?ia?aeiee iaoeiaee ni?a?ia?oiee

aeieoi? o?i?/ieo iaoe, i?ioani? Aeanaiei Na?a?e Ieoaeeiae/,
Oa?e?anueeee iaoe?iiaeueiee oi?aa?neoao ?i. A.I.Ea?ac?ia, i?ioani?
eaoaae?e i?aai?/ii? o?i??

I?ia?aeia onoaiiaa — O?ceei-o?i?/iee ?inoeooo ?i. I.A.Aiaaonueeiai IAI
Oe?a?ie, a?aeae?e o?i?? a?ieia?/ii aeoeaieo ?a/iaei (i.Iaeana)

Caoeno a?aeaoaeaoueny » 3 » a?oaeiy 1999 ?ieo i 1400 ia can?aeaii?
niaoe?ae?ciaaii? a/aii? ?aaee Ae 64.051.14 o Oa?e?anueeiio
iaoe?iiaeueiiio oi?aa?neoao? ?i. A.I.Ea?ac?ia (61077, i.Oa?e?a, ie.
Naiaiaee, 4, aoae. 7-80).

C aeena?oaoe??th iiaeia iciaeiieoeny o Oeaio?aeuei?e iaoeia?e
a?ae?ioaoe? Oa?e?anueeiai iaoe?iiaeueiiai oi?aa?neoaoo ?i. A.I.Ea?ac?ia
(61077, i.Oa?e?a, ie. Naiaiaee, 4).

Aaoi?aoa?ao ?ic?neaii » 2 » eenoiiaaea 1999 ?ieo.

A/aiee nae?aoa? niaoe?ae?ciaaii? a/aii? ?aaee Eia?iiaa E.I.

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeuei?noue oaie. ?ic?iaea iiaeo i?ea?iaeueieo iaoiae?a neioaco
a?ieia?/ii aeoeaieo ?a/iaei (AA?) oa noai?aiiy ia ?o iniia?
aenieiaoaeoeaieo ? iaeioiene/ieo e?ea?nueeeo cania?a ? iaei??th c
aeooaeueieo caaea/ ye i?aai?/iiai neioaco, oae ? oa?iaoeaaoe/ii? iaoee
oa i?aeoeee a oe?eiio.

*eneaii? aeine?aeaeaiiy, ye? i?iaiaeyoueny a Iaoe?iiaeuei?e
oa?iaoeaaoe/i?e aeaaeai?? Oe?a?ie, na?ae/aoue i?i ia?niaeoeai?noue
iiooeo AA? na?aae iio?aeieo aeeea?aiiiaeo eeneio. Aoaeo/e i?e?iaeieie
iaoaaie?oaie, aiie cia/ii ciaioothoue oiene/i?noue niieoe i?e aaaaeaii?
?o o?aaiaio?a aei no?oeoo?e AA?. E??i oiai, aeeea?aiiia? eeneioe ?
c?o/ieie iin?yie oa?iaeioi??a, ia??aeei caeaoieie e ?icoe?eoe ae?aiacii
a?ieia?/ii? ae??.

Iiooe AA? o ?yae? aeeea?aiiiaeo eeneio i?iaiaeeoueny, aieiaiei /eiii, o
3-o iai?yieao: neioac ??ciiiai?oieo iio?aeieo aeeea?aiiiaeo eeneio
e?i?eii? aoaeiae; neioac niieoe, a yeeo iaeia /e iaeaea? ea?aieneeuei?
a?oie aeeea?aiiiai? eeneioe aeeth/athoueny a no?oeoo?o aaoa?ioeeee?/ii?
nenoaie, ? neioac eiiaeainiaaieo aaoa?ioeeee?/ieo nenoai, a yeeo
aeeea?aiiiaa eeneioa ? neeaaeiaith /anoeiith aaoa?ioeeeeo.

Ia ia??iae ieaioaaiiy aeaii? ?iaioe aoee i?iaaaeai? a?oioiai?
aeine?aeaeaiiy na?aae iio?aeieo uaaeaai?, iaeiiiai?, yioa?ii? eeneio oa
iaiane/aieo aeeea?aiiiaeo eeneio – iaea?iiai?, ooia?iai?. ?i
i?eae?eyeanue oaaaa a ieai? neioaco, aea/aiiy o?i?/ieo aeanoeainoae,
?aaeoe?eii? caeaoiino?, oa?iaeieia?/ii? aeoeaiino?.

Ia’?eoaie aeey iiaeo aeine?aeaeaiue aoei aea?aii iio?aei? aeooa?iai?
eeneioe, a naia: aeooa?ai?eia? eeneioe, a?i?ea?ae?aceaee oa
a?ainoeueoiiia?ae?aceaee aeooa?iai? eeneioe.

Nenoaiaoe/i? aeine?aeaeaiiy c neioaco AA? a ?yae? iio?aeieo aeooa?iai?
eeneioe aei oeueiai /ano ia i?iaiaeeeeny. Ine?eueee eeth/iaeie niieoeaie
a neioac? iio?aeieo aeooa?iai? eeneioe ? ?i?aee, cia/io oaaao
ieaioaaeiny i?eae?eeoe aeine?aeaeaiith oiia ?aaeoe??
oeeeeiaeaa?ae?aoaoe?? aeooa?ai?iiaeo eeneio c ??cieie cai?nieeaie a?ey
aoiia acioo, anoaiiaeaiith iaae canoinoaaiiy iaea?eueo ?iciianthaeaeaieo
iaoiae?a neioaco oeeee?/ieo ?i?ae?a, ?ica’ycaiith ieoaiiy i?i ?ieue
aoeaoaoo iao??th a ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? aeooa?ai?eiaeo eeneio.

Aaaeeeaei c oai?aoe/ii? ? c i?aeoe/ii? oi/ee ci?o ? neioac ia iniia?
a?i?e- ? a?eenoeueoiiia?ae?aceae?a aeooa?iai? eeneioe iiaeo aoeeethth/eo
cania?a — aeooa??i?ae?a, aoii acioo yeeo niieo/aiee c ea?aienai?aei- aai
noeueoiiai?aeia?oiith; c’ynoaaiiy aieeao ea?aai?aeiiai oa
noeueoai?aeiiai o?aaiaio?a ia o?i?/i? aeanoeaino? oa ?aaeoe?eio
ni?iiiaei?noue ?i?ae?a.

A?aeiiino? i?i aeei?enoaiiy aio?ai?ei?ea?ae?aceae?a aeeea?aiiiaeo eeneio
oa ?o iio?aeieo o neioac? aaoa?ioeeee?/ieo niieoe a?aenooi?. Oae?
no?oeoo?e ca oiia ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? caeaoi? ooai?eoe ye
o?iacie?iiiiaee, oae ? ?i?aeiee oeeeee. Iaeiei ?c aeooaeueieo caaaeaiue
aeine?aeaeaiiy aoei anoaiiaeaiiy caeaaeiino? i?ae oiiaaie i?iaaaeaiiy
?aaeoe?? oa ooai?aiiyi cacia/aieo oeeee?a.

Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie. Aeena?oaoe?eia
?iaioa aeeiiaia ca?aeii c ?anioae?eainueeith i?iaeaiith «Oa?iaoe?y»
(iiia? aea?aeaaii? ?a?no?aoe?? 81030210) oa ieaiaie IAe? Oe?OA (iiia?
aea?aeaaii? ?a?no?aoe?? 01.91.0002385).

Iaoa ? caaea/? aeine?aeaeaiiy. Aeena?oaoe?eia ?iaioa i?enay/aia
?ic?iaoe? aoaeoeaieo iaoiae?a neioaco aeooa?ai?eiaeo eeneio, a?i?e-,
a?eenoeueoiiia?ae?aceae?a aeooa?iai?, yioa?ii?, ooaeaai? eeneio oa ?o
iio?aeieo, aea/aiith ?o o?i?/ieo aeanoeainoae, c’ynoaaiith aieeao
no?oeoo?ieo iniaeeainoae ia o?i?/i? ia?aoai?aiiy, noai?aiith ia iniia?
iio?aeieo aeeea?aiiiaeo eeneio aaoa?ioeeee?/ieo no?oeoo?, onoaiiaeaiith
ca’yceo i?ae oiiaaie i?iaaaeaiiy ?aaeoe?? aaoa?ioeeee?caoe?? oa ??
iai?yieii, aea/aiith a?ieia?/ii? aeoeaiino? neioaciaaieo niieoe.

Caaea/? aeine?aeaeaiiy:

1. ?ic?iaeoe i?aia?aoeai? iaoiaee neioaco N-cai?uaieo aeooa??i?ae?a;
aeey oeueiai aeine?aeeoe ?aaeoe?th oeeeeiaeaa?ae?aoaoe?? aeooa?ai?iiaeo
eeneio, ye? i?noyoue ??ciiiai?oi? cai?nieee a?ey aoiia acioo. Anoaiiaeoe
?ieue aoeaoaoo iao??th a ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? aeooa?ai?eiaeo
eeneio.

2. Aeine?aeeoe o?i?/i? aeanoeaino? N-cai?uaieo aeooa??i?ae?a — ?aaeoe?e
ye c? caa?aaeaiiyi, oae ? c ?ice?eooyi ?i?aeiiai oeeeeo. I?inoaaeeoe
aieea aaee/eie ?i?aeiiai oeeeeo, i?e?iaee ioeeaio?eueiiai ?aaaaioo,
cai?nieea i?e ?i?aeiiio aoii? acioo ia ?o ?aaeoe?eio ni?iiiaei?noue.

3. Ia iniia? iio?aeieo aio?ai?ei?ea?ae?aceaeo, ye? i?noyoue iaeei aai
aeaa o?aaiaioe aeeea?aiiiai? eeneioe, cae?enieoe neioac iiaeo
aaoa?ioeeee?/ieo no?oeoo? — iio?aeieo o?iacie?iiio-4. Anoaiiaeoe
caeiiii??i?noue o ia?aoai?aii? N’-aio?ai?ei?ea?ae?aceae?a aeeea?aiiiaeo
eeneio ye no?oeoo?, ye? ca oiia ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? caeaoi?
ooai?eoe ye ?i?aeiee, oae ? o?iacie?iiiiaee oeeeee, c’ynoaaoe aieea
no?oeoo?ieo iniaeeainoae oa oiia i?iaaaeaiiy ?aaeoe?? aaoa?ioeeee?caoe??
ia ?? iai?yiie.

Iaoeiaa iiaecia iaea?aeaieo ?acoeueoao?a. ?ic?iaeaii i?eioeeie neioaco
N-cai?uaieo aeooa??i?ae?a, a oiio /ene? iiaeo aoeeethth/eo ?aaaaio?a –
N-(a?i?eai?aei)- oa N-(a?eenoeueoiiai?aei)aeooa??i?ae?a. Anoaiiaeaii, ui
?aaeoe?y oeeeeiaeaa?ae?aoaoe?? aeooa?ai?iiaeo eeneio ia i?ioiaeeoue ca
a?eueoino? oiia, ye? aeei?enoiaothoue aeey neioaco iaea?eueo
?iciianthaeaeaieo /ioe?ueio ? i’yoe/eaiieo ?i?ae?a.

Aia?oa anoaiiaeaii ?ieue aoeaoaoo iao??th a ?aaeoe??
oeeeeiaeaa?ae?aoaoe?? aeooa?ai?eiaeo eeneio. Aoeaoao-?ii nooo?ai
i?aeaeuo? ioeeaio?euei? aeanoeaino? ai?aeiiai aoiia acioo, ia?aaiaey/e
eiai a ai?iiio oi?io.

Aeine?aeaeaii ?aaeoe?th N-a?eeaeooa??i?ae?a c iaioaoei?eaeii oa
o?eoei?ieneaeii oinoi?o. I?iaeoeoaie ?aaeoe?? c o?eoei?ieneaeii oinoi?o
? aeooa?ai?eia? eeneioe, a c iaioaoei?eaeii oinoi?o, a caeaaeiino? a?ae
oiia, ooai?ththoueny aeooa?ai?eia? eeneioe aai
N-a?ee-a,a-aeeoei?aeooa??i?aee.

Aeyaeaii iniaeeaino? eoaeiiai a?ae?ie?co ? aeeiaie?co noeoeei- ?
aeooa??i?ae?a, aoii acioo yeeo niieo/aiee c noeueoiiai?aeia?oiith.

Aecia/aii e?iaoe/i? oa oa?iiaeeiai?/i? ia?aiao?e ?aaeoe?? a?ae?aceiie?co
N-a?ee- ? N-(a?eenoeueoiiai?aei)aeooa??i?ae?a. Cai?iiiiiaaii iiaee
iaoai?ci aieeao noeueoiiai?aeia?oie ia a?ae?aceiie?c ?i?ae?a.
Cai?iiiiiaaii iaea?eueo eiia??i? e?iaoe/i? noaie ?aaeoe?? a?ae?aceiie?co
cacia/aieo ?i?ae?a. Anoaiiaeaii, ui ?aaeoe?eia ni?iiiaei?noue i’yoe- oa
oanoe/eaiieo ?i?aeieo oeeee?a aecia/a?oueny ia o?eueee aaee/eiith
oeeeeo, aea ? i?e?iaeith ioeeaio?eueiiai ?aaaaioo oa oa?aeoa?ii
cai?nieea i?e ?i?aeiiio aoii? acioo.

Aia?oa anoaiiaeaii caeiiii??iino? a ia?aoai?aii?
Nc-aio?ai?ei?ea?ae?aceae?a aeeea?aiiiaeo eeneio oa ?o iio?aeieo ye
no?oeoo?, ui ca oiia ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? caeaoi? ooai?thaaoe
ye ?i?aeiee, oae ? o?iacie?iiiiaee oeeee. ?ic?iaeai? iaoiaee neioaco
aeicaieythoue oe?eani?yiiaaii cae?enithaaoe neioac cacia/aieo oeeee?a.

I?iaaaeaii oa?iaeieia?/i? aeine?aeaeaiiy neioaciaaieo iio?aeieo
aeooa?iai? eeneioe ca 10 oanoaie, aecia/aii ?o aino?o oiene/i?noue,
anoaiiaeaii aeaye? caeiiii??iino? i?ae aoaeiaith niieoe oa ?o
a?ieia?/iith aeoeai?noth.

I?aeoe/ia cia/aiiy iaea?aeaieo ?acoeueoao?a. ?ic?iaeaii iia? oa
aaeineiiaeaii ?nioth/? neioaoe/i? iaoiaee, ui cia/ii ?icoe?ththoue
iiaeeeaino? a aaeoc? neioaco aeooa?ai?eiaeo eeneio, a?i?e-,
a?eenoeueoiiia?ae?aceae?a aeeea?aiiiaeo eeneio oa ?o iio?aeieo, o oiio
/ene? e aaoa?ioeeee?/ieo no?oeoo?.

Aeyaeaii iaeioiene/i? ?a/iaeie c ae?aaeaiith a?iiae?eai?/iith,
aioea?eoi?/iith, ae?o?aoe/iith, aioea?iiene/iith aeoeai?noth. Ca
?acoeueoaoaie ne?ei?iao a?ae?a?aii 3 ?a/iaeie, ye? ia?aaeaii aeey
iiaeeaeaiiai oa?iaeieia?/iiai aeine?aeaeaiiy, a ia ?a/iaeio, yea aeyaeea
cia/io aioea?eoi?/io aeoeai?noue, ?ic?iaeaii i?iaeo OON oa eaai?aoi?iee
oaoiieia?/iee ?aaeaiaio.

Iniaenoee aianie caeiaoaa/a. Aeena?oaoe?eia ?iaioa ? naiino?eiith
iaoeiaith i?aoeath, yea aeeth/a? aeine?aeaeaiiy aaoi?a ca ia??iae
1985-1997 ??. A on?o ?iaioao, aeeiiaieo c? ni?aaaoi?aie, aianie aaoi?a
iieyaa? a iniaeno?e o/ano? a ieaioaaii?, i?iaaaeaii? aenia?eiaioaeueieo
aeine?aeaeaiue, a ocaaaeueiaii? io?eiaieo ?acoeueoao?a, a iaaiai?aii?
aeaieo oa?iaeieia?/iiai ne?ei?iao.

Ai?iaaoe?y ?acoeueoao?a aeena?oaoe??. Iniiai? ?acoeueoaoe aeine?aeaeaiiy
aoee i?aaenoaaeai? ia IV Ananithciiio c’?cae? oa?iaoeaao?a (Eacaiue,
1986), Ananithci?e eiioa?aioe?? c i?iaeai i?io?eaeoeee, ae?aaiinoeee oa
e?eoaaiiy na?oeaai-noaeeiieo caoai?thaaiue (Iineaa, 1987),
?anioae?eainuee?e iaoeia?e eiioa?aioe?? «?aae?caoe?y iaoeiaeo
aeinyaiaiue a i?aeoe/i?e oa?iaoe??» (Oa?e?a, 1991), OVI Oe?a?inuee?e
eiioa?aioe?? c i?aai?/ii? o?i?? (Oa?iii?eue, 1992), I Eiia?an? na?oiai?
oaaea?aoe?? oe?a?inueeeo oa?iaoeaaoe/ieo oiaa?enoa (Euea?a, 1994), OVII
Oe?a?inuee?e eiioa?aioe?? c i?aai?/ii? o?i?? (Oa?e?a, 1995),
?anioae?eainuee?e eiioa?aioe?? «Aeinyaiaiiy no/anii? oa?iaoe??—a
iaaee/io i?aeoeeo» (Oa?e?a, 1996), Oe?a?inuee?e eiioa?aioe?? “O?i?y
acioai?nieo aaoa?ioeeee?a” (Oa?e?a, 1997), nan?? A?aeae?eaiiy o?i?? IAI
Oe?a?ie “Iaoeia? iniiae ?ic?iaee e?ea?nueeeo i?aia?ao?a” (Oa?e?a, 1998),
V Iaoe?iiaeueiiio c’?cae? oa?iaoeaao?a Oe?a?ie (Oa?e?a, 1999).

Ioae?eaoe??. Ca iaoa??aeaie aeena?oaoe?? iioae?eiaaii 30 noaooae o
iaoeiaeo aeo?iaeao, 3 noaoo? a ca??ieeao iaoeiaeo i?aoeue, 19 oac
aeiiia?aeae, io?eiaii 1 aaoi?nueea na?aeioeoai, 1 iaoaio.

No?oeoo?a aeena?oaoe??. Aeena?oaoe?eia ?iaioa aeeeaaeaia ia 312
noi??ieao ae?oea?nueeiai oaenoo, i?noeoue 60 oaaeeoeue ? 25 ?enoie?a.
Neeaaea?oueny c? anooio, i’yoe ?icae?e?a, caaaeueieo aeniiae?a ? nieneo
aeei?enoaieo aeaea?ae (331iaeiaioaaiiy)

iniiaiee ci?no ?iaioe

1. Aeine?aeaeaiiy ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? aeooa?ai?eiaeo eeneio.

Neioac aeooa?ai?eiaeo eeneio (??) cae?enithaaee aoeeethaaiiyi
a?aeiia?aeieo ai?i?a (?) aeooa?iaei aia?ae?eaeii o ??aee?e aai oaa?ae?e
oac?.

Aenia?eiaioaeueii anoaiiaeaii, ui oeeee?caoe?y eeneio (II) a ?i?aee
(III) ia a?aeaoaa?oueny ca a?eueoino? oiia, ye? aeei?enoiaothoue o
neioac? 4- oa 5-oe/eaiieo ?i?ae?a. Oae, ?i?aee (???) ia ooai?ththoueny
i?e iaa??aaii? eeneio (II) aei oaiia?aoo?e ieaaeaiiy, i?e ae??
o?ii?eoei?eaeii, o?eoei?eaeii oinoi?o, i?e ia?iaoe? iaioaieneaeii
oinoi?o, ioeoiaei aia?ae?eaeii.

Ii?aee (???) neioaciaaii iaa??aaiiyi eeneio (??) a na?aaeiaeu? ioeoiaiai
aia?ae?eaeo a i?enooiino? aoeaoaoo iao??th (oeae iaoiae oe?iei
canoiniao?oueny aeey neioaco ?ioeo oeeee?/ieo ?i?ae?a). Aeo?ae ?i?ae?a –
60-97%. Ie ni?iaoaaee anoaiiaeoe ?ieue aoeaoaoo iao??th a oe?e ?aaeoe??.

Cai?iiiiiaaia ?iai/a a?iioaca iieyaaea a oiio, ui aoeaoao-?ii a?ae?eaa?
i?ioii a?ae aoiia acioo ? ia?aaiaeeoue inoaii?e a ai?iiio oi?io. Oea
cia/ii ca?eueoo? ioeeaio?euei? aeanoeaino? ai?aeiiai aoiia acioo eeneioe
(II), caaaeyee /iio noa? iiaeeeaei ooai?aiiy ?i?aeiiai oeeeeo.

C iaoith ia?aa??ee oeueiai i?eiouaiiy aea/aii aieea aeaeo?iiiaeiii?ieo
oa aeaeo?iiiaeoeaioi?ieo cai?niee?a o aaicieueiiio yae?? eeneio (II) ia
oaeaee?noue ?aaeoe?? ?o oeeeeiaeaa?ae?aoaoe??. sseui ?aaeoe?th
i?enei?ththoue aeaeo?iiiaeoeaioi?i? cai?nieee, oi aiia a?aeaoaa?oueny
/a?ac ooai?aiiy ai?iiii? oi?ie (A), yeui aeaeo?iiiaeiii?i?, oi eeneioe
(II) anooiathoue a ?aaeoe?th a iaeo?aeuei?e oi?i?.

Eiioeaio?aoe?? ?a/iaei a ?aaeoe?ei?e noi?o? aei??thaaee iaoiaeii
OO-niaeo?ineii?? (?en. 1). Aeyaeaii, ui ?aaeoe?y a?aeaoaa?oueny
e?euee?nii, iaiai?ioiuei, i?aeii?yaeeiao?oueny e?iaoe/iiio ??aiyiith
ia?oiai ii?yaeeo. Eiinoaioe oaeaeeino? aecia/aii a?ao?/ii (oaae. 1).

Io?eiai? aeai? na?ae/aoue i?i i?enei?aiiy ?aaeoe?? oeeeeiaeaa?ae?aoaoe??
a i?enooiino? aeaeo?iiiaeoeaioi?ieo cai?niee?a, ui aeicaieeei iai
c?iaeoe aeniiaie: caieeaiiy aeooa?ai?eiaeo eeneio (II) a ?i?aee (III)

n*10–3ci–1 ?en. 1.
Ci?ia iioe/ii? aonoeie ?aaeoe?eiiai na?aaeiaeua o aeiaaeeo ?aaeoe??
oeeeeiaeaa?ae?aoaoe?? 4-aoieneea?aii?eaeooa?ai?eiai? eeneioe (I?ae).
a?aeaoaa?oueny /a?ac noaae?th ooai?aiiy ai?iia (A). Ca oiia aeine?aeo, a
na?aaeiaeu? ioeoiaiai aia?ae?eaeo, oeeeeiaeaa?ae?aoaoe?? ia?aaeo?
i?ioean ooai?aiiy ci?oaiiai aia?ae?eaeo ioeoiai? ? aeooa?ai?eiai? eeneio
(A). Ooai?aiiy inoaiiueiai aaaea aei «cae?eooy» OH-eeneioiiai oeaio?o ?,
e??i oiai, i?aeaeuothoueny aeaeo?io?euei? aeanoeaino? aoiia aoaeaoeth
ea?aieneeueii? a?oie, i?ioa oaea i?aeaeuaiiy iaaeinoaoi?, uia aieeiooe
ia ?acoeueoao ?aaeoe??. Aeei?ecoaiiy iaa?oue o?eooi?ioeoiaiai
aia?ae?eaeo cai?noue ioeoiaiai ia i?eaiaeeoue aei ?i?aeo.

Ia iniia? aeuaaeeeaaeaiiai cai?iiiiiaaii oaeo noaio ooai?aiiy
aeooa??i?aeiiai oeeeeo:

A aeai?e ?aaeoe?? ia? i?noea i?aeaeuaiiy aeaeo?io?eueieo aeanoeainoae
ea?aieneeueii? a?oie aiane?aeie ooai?aiiy ci?oaiiai aia?ae?eaeo, a
aoeaoao iao??th i?aeneeth? ioeeaio?euei? aeanoeaino? aoiia acioo.

Aeoiaey/e ?c iaaaaeaii? noaie ooai?aiiy ?i?ae?a (III), iiaeia c?iaeoe
i?eiouaiiy: yeui aeei?enoiaoaaoe ?ic/eiiee, yeee “iiaeaaeya” ae NH-
eeneioiee oeaio? eeneio (II), oi oea a i?ecaiaeeei aei coieiee ?aaeoe??.
I ae?enii, i?e i?iaaaeaii? ?aaeoe?? a na?aaeiaeu? ioeoiaa
eeneioa-ioeoiaee aia?ae?eae (1:1) o i?enooiino? aoeaoaoo iao??th
aeae?eaii aeo?aei? eeneioe (??).

2. Aeine?aeaeaiiy ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? N’-aoeee-,
N’-aoeee-N’-a?eea?ae?aceae?a aeooa?iai?, yioa?ii? eeneio.

Neioac N’-a?i?e-, N’-a?eenoeueoiiia?ae?aceae?a aeooa?iai? eeneioe (V)
cae?enithaaee ?aaeoe??th a?aeiia?aeieo a?ae?aceae?a (IV) c aeooa?iaei
aia?ae?eaeii a ?ic/eiieeo aai a oaa?ae?e oac?.

sse ? o aeiaaeeo eeneio (??), ooai?aiiy ?i?ae?a (VI) ?c eeneio(V) ia
a?aeaoaa?oueny ca a?eueoino? oiia, ye? aeei?enoiaothoue aeey
oeeee?caoe?? ai?aeiaeo eeneio. Iaa??aaiiy eeneio (V) a ioeoiaiio
aia?ae?eae? a i?enooiino? aoeaoaoo iao??th i?eaiaeeoue aei
N-(N’-aoeaoeea?i?eai?aei)- oa
N-(N’-aoeaoeea?eenoeueoiiai?aei)aeooa??i?ae?a (VII) (ni. A), oiaoi ca
aeaieo oiia, ii?yae c oeeeeiaeaa?ae?aoaoe??th a?aeaoaa?oueny oaeiae
aoeaoeethaaiiy ea?aai?aeii? aai noeueoiiai?aeii? a?oie. Io?eiaoe ?i?aee
(VI) eoaeiei a?ae?ie?cii N’-aoeaoee?i?ae?a (VII) ia aaeaeiny (?icae. 5).

N-(A?i?eai?aei)- ? N-(a?eenoeueoiiai?aei)aeooa??i?aee (VI) aeae?eaii i?e
iaa??aaii? eeneio (V) c aea?iieaeoey?iith e?euee?noth ioeoiaiai
aia?ae?eaeo a i?enooiino? aoeaoaoo iao??th. Iaea?aeai? ?acoeueoaoe
na?ae/aoue, ui a ?aaeoe?th aoeaoeethaaiiy anooiathoue ia nai? eeneioe
(V), a i?iaeoeoe ?o oeeee?caoe?? — ?i?aee (VI), oiaoi nii/aoeo
i?ioiaeeoue ?aaeoe?y oeeeeiaeaa?ae?aoaoe??, a iio?i — aoeaoeethaaiiy.

C iaoith iiooeo ?aaaaio?a, ye? iiaeia aoei a aeei?enoaoe aeey
aoeaoeethaaiiy ?i?ae?a (VI), a oaeiae c iaoith anoaiiaeaiiy ?ie?
aoeaoaoo iao??th a oe?e ?aaeoe?? i?iaaaeaii ?yae aeine?ae?a. ?i?aee (VI)
iaa??aaee c ioeoiaith eeneioith, aoeeaoeaoaoii, ioeoiaei aia?ae?eaeii c
oa aac aoeaoaoo iao??th. N’-Aoeaoee?i?aee (VII) io?eiaii o?eueee a aeaio
inoaii?o aeiaaeeao (ni. A). Oie oaeo, ui eeneioe (V) c ioeoiaei
aia?ae?eaeii aac aoeaoaoo iao??th ia ooai?ththoue ?i?aee (VI), a
inoaii?, ca oeeo naieo oiia, ia?aoai?ththoueny ia N’-aoeaoee?i?aee
(VII), aeicaiey? i?eionoeoe, ui aoeaoao iao??th ? eaoae?caoi?ii ?aaeoe??
oeeeeiaeaa?ae?aoaoe?? ? ia aieeaa? ia i?ioean aoeaoeethaaiiy.

Neioaciaai? N’-aoeaoee?i?aee (VII) «oi?iaeueii» iiaeia ?icaeyaeaoe ye
iio?aei? a?aeiia?aeieo N’,N’-aeecai?uaieo a?ae?aceae?a. C iaoith
c’ynoaaiiy aieeao aeaio cai?niee?a a?ey b-aoiia acioo a?ae?aceaeiiai
o?aaiaioa ia i?ioean oeeeeiaeaa?ae?aoaoe?? aei aeine?ae?a caeo/aii
N’-aoeee-N’-a?eea?ae?aceaee yioa?ii? (?O, n=2) oa aeooa?iai? (?O, n=3)
eeneio.

Aeo?aei? eeneioe (?O, n=2; ?O, n=3) neioaciaaii 2 niiniaaie:
aoeeethaaiiyi yioa?iei aai aeooa?iaei aia?ae?eaeaie a?ae?aceae?a (VIII)
(ni. A) ? ca niiniaii A, yeee iieyaa? a iine?aeiaiiio aoeeethaaii?
a?eea?ae?acei?a (O) nii/aoeo oeeee?/ieie aia?ae?eaeaie (io?eiothoue
niieoee (O?)), a iio?i oei?aia?ae?eaeaie a?aeiia?aeieo eeneio.

Eeneioe (IX) iaa??aaee aei oaiia?aoo?e ieaaeaiiy, ae?yee ia ieo
o?ii?eoei?eaeii, eei’yoeee a ioeoiaiio aia?ae?eae? a i?enooiino?
aoeaoaoo iao??th oa aac iueiai. Aeine?aee iieacaee, ui iio?aei?
aeooa?iai? eeneioe (?O, n=3) caieeathoueny a ?i?aee (O??, n=3) o?eueee
i?e iaa??aaii? ?o c ioeoiaei aia?ae?eaeii o i?enooiino? aoeaoaoo
iao??th. Iio?aei? ae yioa?ii? eeneioe (?O, n=2) anooiathoue a ?aaeoe?th
oeeeeiaeaa?ae?aoaoe??, e??i cacia/aieo oiia, ua e i?e iaa??aaii? ?o aei
oaiia?aoo?e ieaaeaiiy, ia?iaoe? o?ii?eoei?eaeii. Iaoiaeii
aeeoa?aioe?aeueiiai oa?i?/iiai aiae?co i?aeoaa?aeaeaii oaeo oeeee?caoe??
eeneioe (?O, n=2) a ?i?aee (O??, n=2) a ieaa?.

I?ioa aeyaeeiny, ui eeneioe (IX, n=2) ia oeeee?cothoueny i?e iaa??aaii?
a ioeoiaiio aia?ae?eae? aac aoeaoaoo iao??th. Io?eiaiee ?acoeueoao ia
a?aeiia?aea? aeaiei e?oa?aoo?e, ca?aeii c yeeie iio?aei? yioa?ii?
eeneioe ?, cie?aia, N’-aoeeea?ae?aceaee yioa?ii? eeneioe ca oeeo oiia
ooai?ththoue ?i?aeiee oeeee. Oe?eeii eiia??ii, ui iaiiaeeea?noue
ooai?aiiy ?i?ae?a (XII, n=2) i?e iaa??aaii? eeneio (IX, n=2) a ioeoiaiio
aia?ae?eae? aeeeeeaia i?inoi?iaeie oo?oaeiaiiyie, ye? iia’ycai? c
iiyaith ua iaeiiai cai?nieea a?ey b-aoiia acioo.

3. E?iaoeea eaoae?oe/iiai aoeeethaaiiy a?ainoeueoiiia?ae?aceae?a
aeooa?iaei aia?ae?eaeii o i?enooiino? ea?aiiiaeo eeneio

Aea/aii e?iaoeeo eaoae?oe/iiai aoeeethaaiiy a?ae?aceae?a (IV) aeooa?iaei
aia?ae?eaeii a na?aaeiaeu? ae?ienaio oa aaicieo. Iieacaii, ui
oaeaee?noue ?aaeoe?? nooo?ai c?inoa? i?e aeiaeaaaii? a ?aaeoe?eio
nenoaio ea?aiiiaeo eeneio, eaoae?oe/ia aeoeai?noue yeeo ca?eueoo?oueny
c? c?inoaiiyi neee eeneioe oa cia/ii aeua a na?aaeiaeu? aaicieo, i?ae o
ae?ienai?.

Aieea oaiia?aoo?e ia eiinoaioe oaeaeeino? kN2 i?aeii?yaeeiao?oueny
??aiyiith A??ai?ona, ui aeaei ciiao ?ic?aooaaoe oa?iiaeeiai?/i?
ia?aiao?e aeoeaaoe?? ?aaeoe?? (oaae. 2). I?aeaeuaiiy aeiii?ieo
aeanoeainoae cai?nieea a aaicieueiiio yae?? a?ae?aceae?a (IV) aaaea aei
cieaeaiiy aia?a?? (Aa) oa aioaeuei?? (DH?) aeoeaaoe?? ?aaeoe?? oa
ca?eueoaiiy eiinoaio oaeaeeino? ?aaeoe?? kN2.

?aaeoe?y iineoue ?cie?iaoe/iee oa?aeoa?. Aaee/eia ?cie?iaoe/ii?
oaiia?aoo?e neeaaea? 663 E.

Ia iniia? aeyaeaieo caeiiii??iinoae cai?iiiiiaaii a??ia?aeio noaio
aoeeethaaiiy a?ae?aceae?a (IV) aeooa?iaei aia?ae?eaeii o i?enooiino?
ea?aiiiaeo eeneio.

?aaeoe?y i?ioiaeeoue /a?ac ia?ao?aeiee oeeee?/iee eiiieaen (A), a yeiio
ea?aiiiaa eeneioa caaaeyee aeaeo?iiiaeiii?iiio oa aeaeo?iiiaeoeaioi?iiio
oeaio?ai ni?ey? ia?aoai?aiith eiai a eeneioo (V).

4. Aeine?aeaeaiiy ?aaeoe?? N-a?eeaeooa??i?ae?a c iaioaoei?eaeii ?
o?eoei?ieneaeii oinoi?o

Aeine?aeaeaii ia iienaio a e?oa?aoo?? ?aaeoe?th aca?iiae??
N-a?eeaeooa??i?ae?a c iaioaoei?eaeii ? o?eoei?ieneaeii oinoi?o. Aeey
oeueiai ?i?aee (III) ni?eaee c ?nl5 ? iaa??aaee c ?INl3. A ?acoeueoao?
iaio ?aaeoe?e aoee aeae?eai? eeneioe (II).

I/aaeaeii, ?aaeoe?y i?ioiaeeoue /a?ac noaae?th ooai?aiiy i?iaeoeo?a
i?e?aeiaiiy ?ONl3 aai ?nl5 aei ?i?aeo, ye? ?iciaaeathoueny aei eeneioe
(II) i?ae /an aeiaeaaaiiy aei ?aaeoe?eii? noi?o? aiaee c e?eaith.

Iiaiai ?acoeueoaoo aaeaeiny aeinyaoe i?e iaa??aaii? ?i?ae?a (III) c ?nl5
ca a?eueo i’yeeo oiia (t<80 0C). A oeueiio aeiaaeeo iniiaiei i?iaeoeoii ?aaeoe?? aoee N-a?ee-a,a-aeeoei?aeooa??i?aee (XIII). I?e iaa??aaii? ?i?ae?a (III) c ?Inl3 ca oeeo aea oiia ciiao aoee aeae?eai? eeneioe (II). ?i?aee (XIII) aaeaeiny iaea?aeaoe oaeiae i?e iaa??aaii? ?i?ae?a (III) c iaioaoei?eaeii oinoi?o a na?aaeiaeu? ?Inl3 (e?au? ?acoeueoaoe — i?e oaiia?aoo?? ?aaeoe?eiiai na?aaeiaeua ia aeua 70 °N) aai a na?aaeiaeu? oei?ioi?io. Aca?iiae?y ?i?ae?a (VI, X=SO2) c ?nl5, iacaeaaeii a?ae oiia ?aaeoe??, i?ecaiaeeoue aei ?ice?eooy ?i?aeiiai oeeeeo c ooai?aiiyi eeneio (V, X=SO2). 5. Iniaeeaino? eoaeiiai a?ae?ie?co e aeeiaie?co N-(a?eenoeueoiiai?aei)- oa N-(N'-aoeaoeea?eenoeueoiiai?aei)noeoeei- ? aeooa??i?ae?a A i?ioean? aeeiiaiiy aenia?eiaioo anoaiiaeaii, ui ia ?acoeueoao eoaeiiai a?ae?ie?co N'-aoeaoeenoeoeei- (VII, n=2) ? N'-aoeaoeeaeooa??i?ae?a (VII, n=3) cia/ii aieeaa? ?ici?? ?i?aeiiai oeeeeo. Oae, o aeiaaeeo i’yoe/eaiiiai (noeoeei?i?aeiiai) oeeeeo (VII, n=2), ye ? i/?eoaaeiny, a i?enooiino? aea?iiey?ii? e?eueeino? ?ic/eio a?ae?ieneaeo iao??th nii/aoeo ?aea a?aeuaieaiiy aoeaoeeueiiai caeeoeo e ooai?ththoueny iao???a? nie? (XIV), c yeeo i?e i?aeeeneaii? aeae?eythoue ?i?aee (VI, n=2), a i?e iaaeeeoeo eoao ?ice?eaa?oueny noeoeei?i?aeiee oeeee c ooai?aiiyi eeneio (XV). Io?eiaoe iao???a? nie? (XVI) ?c N'-aoeaoeeaeooa??i?ae?a (VII, n=3) ca oeeo aea oiia ia aaeaeiny. I?e aeei?enoaii? aea?iiey?ii? e?eueeino? eoao c ?aaeoe?eiiai na?aaeiaeua aoee aeae?eai? aeo?aei? N'-aoeaoeeaeooa??i?aee (VII, n=3) ? eeneioe (V) o ni?aa?aeiioaii? aeecueeiio 1:1. Oiaoi, a i?ioean? a?ae?ie?co nii/aoeo a?aeaoaa?oueny ?ice?eooy ?i?aeiiai oeeeeo c ooai?aiiyi i?ii?aeiiai i?iaeoeoo (A), ? o?eueee iio?i ?aea a?aeuaieaiiy a?ae iueiai aoeaoeeueii? a?oie. Aeyaeaia a?aei?ii?noue niiioeaea ian aeine?aeeoe eoaeiee a?ae?ie?c noeoeei- (VI, n=2) ? aeooa??i?ae?a (VI, n=3), ye? ia iathoue aoeaoeeueiiai caeeoeo. Noeoeei?i?aee (VI, n=2) i?e aeiaeaaaii? aea?iiey?ii? e?eueeino? aiaeiiai ?ic/eio NaII ooai?ththoue iao???a? nie? (XIV), a iaaeeeoie eoao i?eaiaeeoue aei eeneio (XV). Io?eiaoe iao???a? nie? aeooa??i?ae?a (XVI) ciiao ia aaeaeiny; i?ney i?aeeeneaiiy aoee aeae?eai? eeneioe (V) c aeoiaeii aei 95%. Oaeo ??cieoeth a i?io?eaii? a?ae?ie?co iiaeeeai iiynieoe ia eeoa a?eueoith ?aaeoe?eiith caeaoi?noth aeooa??i?aeiiai oeeeeo, aea ? ??cieie eeneioieie aeanoeainoyie noeoeei- (VI, n=2) oa aeooa??i?ae?a (VI, n=3). Ii??aiyiiy cia/aiue ?Ea iieacaei, ui aeooa??i?aee (VI, n=3) ? neaaoeie NI-eeneioaie, i?ae noeoeei?i?aee (VI, n=2). Ia a?aei?io a?ae iao???aeo nieae noeoeei?i?ae?a (XIV), iao???a? nie? aeooa??i?ae?a (XVI) a?ae?ie?cothoueny. Oea i?ecaiaeeoue aei oiai, ui o aeiaaeeo aeooa??i?ae?a (VI, n=3) ca oiia aenia?eiaioo a?aeaoaathoueny ia?aeaeueii aea? ?aaeoe?? — nieaooai?aiiy oa a?ae?ie?c c ?ice?eooyi ?i?aeiiai oeeeeo. Ine?eueee inoaiiy ?aaeoe?y iacai?ioiy, oi e?ioeaaei i?iaeoeoii ?aaeoe?? ? eeneioe (V). Iao???a? nie? aeooa??i?ae?a (XVI) c aeoiaeii aei 94% aaeaeiny io?eiaoe i?e aeei?enoaii? cai?noue aiaeiiai ?ic/eio NaII aiaeii-ae?ienaiiaiai ?ic/eio. A inoaiiueiio nie? (XVI) ia?ic/eii?. I?iaaaeai? aeine?aeaeaiiy aeeiaie?co noeoeei- (VI, n=2) oa aeooa??i?ae?a (VI, n=3) iieacaee ?ica?aei?noue o ?o o?i?/ieo aeanoeainoyo ? a aeai?e ?aaeoe??. Anoaiiaeaii, ui iaa??aaiiy aeooa??i?ae?a (VI, n=3) o iaoaiie? a i?enooiino? iaoeeaoo iao??th i?eaiaeeoue aei iaoeeiaeo ao???a N'-a?eenoeueoiiia?ae?aceae?a aeooa?iai? eeneioe (XVII), a o aeiaaeeo noeoeei?i?ae?a (VI, n=2) ?aaeoe?y coieiy?oueny ia noaae?? ooai?aiiy nie? (XIV). Ao??e (XVII) aoei io?eiaii oaeiae ?c N'-aoeaoeeaeooa??i?ae?a (VII, n=3). N'-aoeaoeenoeoeei?i?aee (VII, n=2) ca oeeo oiia aeathoue nie? (XIV). 6. ?aaeoe?? oeeee?/ieo iio?aeieo aeooa?iai? eeneioe c I- oa N-ioeeaio?eueieie ?aaaaioaie Iaoeeia? ao??e (XVII) neioaciaaii aeae?eueeiia niiniaaie. I?e iaa??aaii? eeneio (II, V) c iaoeeiaei nie?oii o i?enooiino? eiioeaio?iaaii? n??/aii? eeneioe (ni. A). Aeo?ae ao???a (XVII) aei 92%. I?e aoeeethaaii? niieoe (I, IV) oei?aia?ae?eaeii iiiiiaoeeiaiai ao??o aeooa?iai? eeneioe (ni. A); ?aaeoe?th i?iaiaeeee a na?aaeiaeu? e?eaeaii? ioeoiai? eeneioe a i?enooiino? aacaiaeiiai aoeaoaoo iao??th aai o?eaoeeai?io. Aeo?ae ao???a (XVII) noaiiaeoue 66-92%. I?e aca?iiae?? ?i?ae?a (III,VI) c iaoeeiaei nie?oii o i?enooiino? iaoeeaoo iao??th (ni. A). Aeei?enoaiiy aeeiaieyo?a, ye eaoae?caoi?o, aeey ?ice?eooy ?i?aeiiai oeeeeo c iaoith neioaco ao???a ?ai?oa ia i?iaiaeeeiny. Ai?aee (XVIII) oa a?ae?aceaee (XIX) aeiaooi a ?acoeueoao? ?aaeoe?? ai?iie?co /e a?ae?aceiie?co ?i?ae?a (III, VI). ?aaeoe?th i?iaiaeeee a na?aaeiaeu? aoaiieo, ae?ienaio aai 25% aiaeiiai ?ic/eio AeIOA, aeo?ae i?iaeoeo?a aei 95%. Aoeeea?ae?aceaee (XX) ? a?eenoeueoiiia?ae?aceaee (XXI) neioaciaaii aoeeethaaiiyi a?ae?aceae?a (XIX) aia?ae?eaeaie /e oei?aia?ae?eaeaie ea?aiiiaeo aai noeueoiiiaeo eeneio. Aeo?ae i?iaeoeo?a noaiiaeoue 51-97%. I?e aca?iiae?? a?ae?aceae?a (XIX) c ae?oaoe/ieie, a?iiaoe/ieie oa aaoa?ioeeee?/ieie aeueaeaa?aeaie /e eaoiiaie io?eiaii aee?e(a?ee-,aaoa?ee-)?aeaia?ae?aceaee (XXII). ?aaeoe?y a?aeaoaa?oueny i?e iaa??aaii? (aei 30 oa) a na?aaeiaeu? aoaiieo aai 25%-iiai aiaeiiai /e nie?oiaiai ?ic/eio AeIOA a caeaaeiino? a?ae ?ic/eiiino? aeo?aeieo i?iaeoeo?a; aeo?ae aei 98%. I?e eei'yo?ii? aoeeea?ae?aceae?a (XX) o na?aaeiaeu? o?eoei?ieneaeo oinoi?o io?eiaii iio?aei? ienaae?acieo (XXIII). 7. E?iaoeea a?ae?aceiie?co N-a?eeaeooa??i?ae?a o aeeiaoeeoi?iai?ae? Aeey ioe?iee ?aaeoe?eii? caeaoiino? i'yoe oa oanoe/eaiieo ?i?ae?a o ?aaeoe?yo c ioeeaio?eueieie ?aaaaioaie aeine?aeaeaii e?iaoeeo a?ae?aceiie?co N-a?eeaeooa??i?ae?a (III) o AeIOA. Anoaiiaeaii, ui a?ae?aceiie?c ?i?ae?a (?I?) o AeIOA ia oneeaaeith?oueny iia?/ieie i?ioeanaie, a?aeaoaa?oueny e?euee?nii ? iacai?ioiuei, a?aeiia?aea? e?iaoe/iiio ??aiyiith ae?oaiai ii?yaeeo. Aei??yi? i?e ??cieo oaiia?aoo?ao eiinoaioe oaeaeeino? i?aeii?yaeeiaothoueny ??aiyiith A??ai?ona, ui aeicaieeei ?ic?aooaaoe ia?aiao?e aeoeaaoe?? ?aaeoe?? (oaae. 3). E?euee?nia ioe?iea aieeao aeaeo?iiii? i?e?iaee cai?niee?a ia e?iaoe/i? oa oa?iiaeeiai?/i? oa?aeoa?enoeee ?aaeoe?? i?iaiaeeeany ca aeiiiiiaith ??aiyiiy Aaiiaoa. Iieacaii, ui aaaaeaiiy aeoeaioi?ieo cai?niee?a a no?oeoo?o ?i?ae?a aaaea aei ca?eueoaiiy oaeaeeino? o?i?/ii? aca?iiae?? e cieaeo? aia?a?th aeoeaaoe??. ?cie?iaoe/ia oaiia?aoo?a ?aaeoe?? neeaaea? 867,2 E. Ni?anoaaeaiiy e?iaoe/ieo ? oa?iiaeeiai?/ieo oa?aeoa?enoee ?aaeoe?? a?ae?aceiie?co N-a?eeaeooa??i?ae?a (III) c iaea?aeaieie ?ai?oa ?acoeueoaoaie a?ae?aceiie?co N-a?eenoeoeei?i?ae?a iieacaei, ui ia a?aei?io a?ae eoaeiiai a?ae?ie?co (aea ca?aeii c aeaieie e?oa?aoo?e, a?eueoo ?aaeoe?eio caeaoi?noue aeyaeee aeooa??i?aee) a?eueo ?aaeoe?eiini?iiiaeieie i?e a?ae?aceiie?c? ? noeoeei?i?aee. I?i oea na?ae/eoue ca?eueoaiiy aia?a?? aeoeaaoe?? (Aa), aioaeuei?? aeoeaaoe?? (?I?) o aeiaaeeo N-a?eeaeooa??i?ae?a (III). Aeey ?ioa?i?aoaoe?? aeyaeaieo ?ica?aeiinoae iaoiaeii iieaeoey?ii? iaoai?ee i?iaaaeaii eiioi?iaoe?eiee aiae?c iieaeoe N-oai?enoeoeei?i?aeo oa N-oai?eaeooa??i?aeo, a oaeiae iaoiaeii MNDO ?ic?aoiaai? ca?yaee ia aoiiao ?o ?aaeoe?eieo oeaio??a. Ca?aeii c ?ic?aooieaie ca iaoiaeii IIO (?en. 2), a iaenoaa?euei?o?e eiioi?iaoe?? iieaeoee N-oai?enoeoeei?i?aeo oai?eueiee oa ?i?aeiee oeeeee aeaaaeai? c iaei??? ieiueie oa ?icoaoiaai? a?aeiinii iaeei aei iaeiiai i?ae eooii 38°, a a iieaeoe? N-oai?eaeooa??i?aeo oeae eoo noaiiaeoue 54°. Cia/aiiy oi?n?eieo eoo?a a noeoeei?i?aeiiio oeeee? neeaaea? aeecueei 3°, ui a?aeiia?aea? i?aeoe/ii ieineiio oeeeeo. Aeooa??i?aeiee oeeee ia? oi?io eiiaa?oa, a yeiio aoii acioo, aoiie aoaeaoeth ea?aii?eueieo ? a-iaoeeaiiaeo a?oi eaaeaoue a iaei?e ieiuei?, a b-iaoeeaiiaa a?oia aeaaaeaia c ieiueie. *anoeia? iiceoeai? ca?yaee ia aoiiao aoaeaoeth ea?aii?e?a noeoeei?i?aeiiai oeeeeo iaio?, i?ae aiaeia?/i? ca?yaee aeey aeooa??i?aeiiai oeeeeo. Ioaea, a ?aaeoe?yo c ioeeaio?eueieie ?aaaaioaie a?eueo ?aaeoe?eiini?iiiaeieie iathoue aooe aeooa??i?aee (ui aenia?eiaioaeueii i?aeoaa?aeaeaii e?iaoe/ieie aeaieie eoaeiiai a?ae?ie?co). O aeiaaeeo ae a?ae?aceiie?co e?iaoe/iicia/eieie, iae?iia??i?oa, ? aeinooii?noue ea?aii?e?a ?i?aeiiai oeeeeo. Oea i?aeoaa?aeaeothoue ieae/? cia/aiiy ?S? aeey N-a?eeaeooa??i?ae?a (III), ye? oa?aeoa?ecothoue oii?yaeeiaai?noue ia?ao?aeiiai noaio. A iieaeoe? aeooa??i?aeo b-iaoeeaiiaa a?oia noai?th? aeiaeaoeia? noa?e/i? ia?aoeiaee aeey iieaeoee a?ae?aceio. Inoaiiy, e??i oiai, ia? a?eueoee ia'?i, i?ae a?ae?ieneae-?ii, ? cacia? a?eueoeo «i?inoi?iaeo oneeaaeiaiue» i?e aoaoe? aoiia aoaeaoeth ea?aii?eueii? a?oie aeooa??i?aeo. Aeoiaey/e c aeyaeaieo e?iaoe/ieo caeiiii??iinoae ? aiae?co ?acoeueoao?a ?ic?aooie?a, aeneiaeaii i?eiouaiiy, ui iaoai?ci ?aaeoe?? aeeth/a? ioeeaio?eueio aoaeo iieaeoee a?ae?aceio ii ea?aii?euei?e a?oi? ?i?aeo (III) c ooai?aiiyi eiiieaeno A, a yeiio ca ?aooiie aioo??oiueiiieaeoey?iiai eeneioiiai eaoae?co (a-aoaeo a?ae?aceio) a?aeaoaa?oueny oaeaeeee ?iciiae?e ca?yae?a. A ?acoeueoao? ooai?th?oueny a?iiey?iee eaa?eueiee ?ioa?iaae?ao A, yeee eaaei o?ainoi?io?oueny o a?aeiia?aeiee a?ae?aceae (XIX). Ii??aiyii iecuee? aia?a?? oa aioaeuei?? aeoeaaoe??, ye? aeyaeythoue iaeo /ooeea?noue aei ci?ie i?e?iaee cai?nieea a iieaeoe? noano?aoo, aeacothoue ia oa, ui i?ioeane ?ic?eao oa ooai?aiiy ca'yce?a o ia?ao?aeiiio noai? a?aeaoaathoueny neio?iiii. 8. E?iaoeea a?ae?aceiie?co N-(a?eenoeueoiiai?aei)aeooa??i?ae?a o aeeiaoeeoi?iai?ae? C iaoith aeine?aeaeaiiy aieeao a?ainoeueoiiai?aeiiai o?aaiaioa ia ?aaeoe?eio ni?iiiaei?noue ?i?ae?a aea/aii e?iaoeeo a?ae?aceiie?co N-(a?eenoeueoiiai?aei)aeooa??i?ae?a (VI) o AeIOA. ?aaeoe?y a?aeaoaa?oueny iacai?ioiuei, i?aeoe/ii c e?euee?niei aeoiaeii. Eiio?ieueieie aeine?aeaie aoei anoaiiaeaii, ui a?ae?aceiie?c ?i?ae?a (VI) ia iieno?oueny e?iaoe/ieie ??aiyiiyie oe?ei/eneiaeo ii?yaee?a. Ia?oe?aeuei? ii?yaeee ii ?aaaaioao ci?iththoueny i?e aa??thaaii? ?o eiioeaio?aoe??, oaiia?aoo?e aai aeaeo?iiii? i?e?iaee cai?nieea a aaicieueiiio yae?? ?i?ae?a. sse aeaeii c aeaieo oaae. 4, c i?aeaeuaiiyi eiioeaio?aoe?? a?ae?aceio c?inoathoue eiinoaioe oaeaeeino? ae?oaiai ii?yaeeo (kH.). Oea aeaco? ia eaoae?oe/io aeoeai?noue ioeeaio?eueiiai ?aaaaioo. A?ae?aceiie?c N-a?eeaeooa??i?ae?a (III), iao???aeo nieae N-(a?eenoeueoiiai?aei)aeooa??i?ae?a (XVI) a AeIOA ia cacia? eaoae?oe/ieo aoaeo?a ? a?aeaoaa?oueny ca?aeii e?iaoe/iiai ??aiyiiy ae?oaiai ii?yaeeo. Oea aeicaiey? c?iaeoe aeniiaie — o aeyaeaii? eaoae?oe/iiai aieeao a?ae?aceio a ?aaeoe?? a?ae?aceiie?co ?i?ae?a (VI) aa?a o/anoue aoii aiaeith noeueoiiai?aeiiai o?aaiaioa iieaeoee ?i?ae?a. I?iaaaeai? iaoiaeaie IIO ? INDO ?ic?aooiee ca?yae?a ia aoiiao ?aaeoe?eieo oeaio??a ?i?ae?a (VI) iieacaee, ui a ?o iieaeoeao ea?aii?euei? a?oie ?i?aeiiai e?eueoey "ia??aiioe?ii?", ??cieoey a ca?yaeao ia aoiiao aoaeaoeth neeaaea? +0,029, iiynith?oueny oea ?nioaaiiyi aioo??oiueiiieaeoey?iiai aiaeiaaiai ca'yceo (AIAC). AIAC ni?ey? i?e?aeiaiith iieaeoee a?ae?aceio c ooai?aiiyi i?ii?aeiiai i?iaeoeoo (A). Aiaeiaaee ca'ycie a ?ioa?iaae?ao? (A), i/aaeaeii, ia?aoeiaeaea? ooai?aiith ?ioiai AIAC, /a?ac yeee cae?enith?oueny aioo??oiueiiieaeoey?iee iniiaiee eaoae?c (noai A). sse iane?aeie cieaeaiiy aoaeoeaiino? aioo??oiueiiieaeoey?iiai eaoae?co ? noai?ththoueny oiiae aeey ?aae?caoe?? i?aeiieaeoey?iiai eaoae?oe/iiai ni?eyiiy c aieo ?ioi? iieaeoee a?ae?aceio (noai A). A?aeiii, ui a oaeiai ?iaeo i?ioeanao, aea niiioaiii a?aeaoaa?oueny eaoae?c ae?oaith iieaeoeith ioeeaio?ea, ye i?aaeei, niinoa??aa?oueny e?i?eia caeaaei?noue aaee/eie kH. a?ae eiioeaio?aoe?? eaoae?caoi?a. Ui ae noino?oueny ?aaeoe??, yea aeine?aeaeo?oueny, oi aeacaia caeaaei?noue ia ? e?i?eiith. Iiae?aiee oa?aeoa? ci?ie cia/aiiy kH. na?ae/eoue i?i oneeaaeiaiiy e?iaoeee a?ae?aceiie?co ?i?ae?a (VI) ??aiiaaaeiei i?ioeanii, yeee ?aae?co?oueny i?ae ?aaaaioaie. A?aoiaoth/e eeneioii-iniiaiee oa?aeoa? aeo?aeieo niieoe, iiaeia i?eionoeoe iayai?noue i?ioie?oe/ii? ??aiiaaae i?ae ieie, ui i?aeoaa?aeaeaii aaniethoieie cia/aiiyie a?aeiia?aeieo eiinoaio (E?), ye? aoee ciaeaeai? ca aenia?eiaioaeueieie cia/aiiyie ?Ea ?aaaaio?a o AeIOA (oaae. 5). Oaaeeoey 5. — Cia/aiiy ?Ea ?i?ae?a (VI) ? eiinoaioe i?ioie?oe/ii? ??aiiaaae (E? , e/iieue) i?ae ?i?aeaie oa a?ae?aceiii o AeIOA i?e 295E Niieoea (VI a) R = 4-OCH3 (VI a) R = 4-CH3 (VI a) R = H (VI a) R = 4-Br (VI ae) R = 4-NO2 pEa 14,7 14,6 14,2 13,6 12,5 E? 0,0013 0,0016 0,004 0,016 0,20 ?ia?aoth/ee aieea i?ioie?oe/ii? ??aiiaaae e?iaoe/ii aeyaey?oueny aeey oeo ?i?ae?a, ye? iathoue aeoeaioi?i? cai?nieee. Ciaioaiiy oaeaeeino? ?aaeoe?? niinoa??aaee ? i?e aianaii? a ?aaeoe?eio nenoaio i?iaeoeo?a ia?aoai?aiiy, ye? oaeiae aeyaeythoue eeneioi? aeanoeaino?. A?aoiaoth/e ana caaaeaia, cai?iiiii oaeo a??ia?aeio noaio ?aaeoe??: 9. Ia?aoai?aiiy N'-aio?ai?ei?ea?ae?aceae?a aeeea?aiiiaeo eeneio ca oiia ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? Aeo?aei? eeneioe (XXVa,a) neioaciaaii i?e aca?iiae?? a?aeiia?aeieo oeeee?/ieo aia?ae?eae?a c a?ae?aceaeii aio?ai?eiai? eeneioe (XXIV) a na?aaeiaeu? e?eaeaii? ioeoiai? eeneioe. Aeae?eeoe N'-aio?ai?ei?ea?ae?aceae aeooa?iai? eeneioe (XXVa) a oeeo oiiaao ia aaeaeiny, aeei?enoaiiy ??cieo ?ic/eiiee?a (ae?ienai, aoaiie, AeIOA, aaicie oa ?i.), i?iaaaeaiiy ?aaeoe?? a ?icieaa? ia ci?ieei ?? ?acoeueoaoo. A aeine?aeao ooai?thaaeanue a'ycea neeiiiae?aia iana, ?ic/eiia o aiae?, yea ia e?enoae?coaaeany. I?e iaa??aaii? niieoe (XXVa,a) a ioeoiaiio aia?ae?eae? io?eiaii a?aeiia?aeii 3-noeoeei?i?aei-, 3-ooae?i?aei-2-iaoeeo?iacie?iiie-4 (XXVIa,a). Niieoeo (XXVIa) neioaciaaii aac aeae?eaiiy eeneioe (XXVa). Ia oeyoo ia?aoai?aiiy eeneio (XXV) a aaoa?ioeeeee (XXVI) a?aeaoaa?oueny o?e i?ioeane: aoeaoeethaaiiy, ooai?aiiy o?iacie?iiiiaiai oa ?i?aeiiai oeeee?a. C iaoith anoaiiaeaiiy iine?aeiaiino? oeeo i?ioean?a i?iaiaeeee ?aaeoe?th, ci?ithth/e ni?aa?aeiioaiiy ?aaaaio?a. Iaeiae aeei?enoaiiy iaa?oue aea?iieueieo e?eueeinoae eeneioe oa ioeoiaiai aia?ae?eaeo ia aieeioei ia ?acoeueoao ?aaeoe??, ui ia aeicaieeei iai anoaiiaeoe iine?aeiai?noue aeaio inoaii?o i?ioean?a. I?e ni?aa?aeiioaii? ?aaaaio?a (1:1) ?aaeoe?y a?aeaoaa?oueny i?aeoe/ii a ?icieaa?, a ca oeeo oiia i?ioiaeeoue ooai?aiiy ye noeoeei?i?aeiiai ? ooae?i?aeiiai, oae ? o?iacie?iiiiaiai oeeee?a. Ieae/a, ia noai? i?aaenoaaeai? eiia??i? oeyoe ia?aoai?aiiy eeneio (XXV) a iio?aei? o?iacie?iiio (XXVI). Ine?eueee iai?yi ?aaeoe?? ia caeaaeeoue a?ae e?eueeino? acyoiai a ?aaeoe?th ioeoiaiai aia?ae?eaeo, oi iiaeia i?eionoeoe, ui nii/aoeo eaea aoeaoeethaaiiy (oeyo A). Iiaeaeueoee ia?aa?a ?aaeoe?? (A aai A) caeaaeeoue a?ae oiai, yeee i?ioean – ooai?aiiy o?iacie?iiiiaiai /e ?i?aeiiai oeeeeo ? a?eueo aea?aeiei. sse iaie anoaiiaeaii (?icae. 10, 11), i?e i?iaaaeaii? ?aaeoe?? a ioeoiaiio aia?ae?eae? a i?enooiino? aoeaoaoo iao??th a?eueo ni?eyoeeaei ? i?ioean ooai?aiiy ?i?aeiiai oeeeeo, oiio, iaea?eueo a??ia?aeii, iniiaiei iai?yieii ia?aoai?aiiy eeneio (XXV) a niieoee (XXVI) ? oeyo (A, A, AE). Aaoa?ioeeeee (XXVI) caeiaooi oaeiae i?e aca?iiae?? o?iacie?iiio (XXVII) c a?aeiia?aeieie oeeee?/ieie aia?ae?eaeaie. ?aaeoe?th i?iaiaeeee aac aeae?eaiiy eeneio (XXVIII). Iaie cai?iiiiiaaii iaeiinoaae?eiee iaoiae neioaco niieoee (XXVII) oa?iie?cii noi?o? aio?ai?ei?ea?ae?aceaeo (XXIV) c ioeoiaei aia?ae?eaeii (ni?aa?aeiioaiiy ?aaaaio?a 1:1) a na?aaeiaeu? aoeeaiae?eieth. Aeo?ae i?iaeoeoo (XXVII) — 45%. 3-Aee?e(a?ee)?aeaiai?ii-2-iaoeeo?iacie?iiie-4 (XXIX) aoei neioaciaaii i?e iaa??aaii? niieoee (XXVII) c aeueaeaa?aeaie /e eaoiiaie a 25% nie?oiaiio ?ic/ei? AeIOA. Aeo?ae i?iaeoeo?a ?aaeoe?? — 45-80%. Aoeeethaaiiyi aaoa?ioeeeeo (XXVII) oei?aia?ae?eaeaie /e aia?ae?eaeaie a?aeiia?aeieo eeneio io?eiaii 3-aoeeeai?ii-2-iaoeeo?iacie?iiie-4 (XXX). ?aaeoe?th cae?enithaaee a e?eaeai?e ioeoia?e eeneio?, aeo?ae i?iaeoeo?a noaiiaea 52-88%. A?aeiii, ui o?iacie?iiiiaee oa ?i?aeiee oeeeee i?aeaeathoueny eoaeiiio a?ae?ie?co. Aenia?eiaioaeueii anoaiiaeaii: i?e ae?? eoao ia aaoa?ioeeee (XXVIa) ?ice?eaa?oueny o?eueee ?i?aeiee oeeee c ooai?aiiyi eeneioe (XXVIIIa). Niieoee (XXXI) aoei caeiaooi i?e eei'yo?ii? eeneio (XXV) a ioeoia?e eeneio? aai a na?aaeiaeu? aoeeaiae?eieth. Ca inoaii?o oiia aeo?ae i?iaeoeoo aeuee ? noaiiaeoue 86-90%. Iiaeeea? oeyoe ia?aoai?aiiy eeneio (XXV) a iio?aei? o?iacie?iiio (XXXI) iaaaaeaii ieae/a: ?c aeaio iai?yie?a oeyo (A, A, A) caea?oueny iaio ?aaeueiei /a?ac oo?oaeiaiiy c ooai?aiiyi aeanyoe/eaiiiai yae?a niieoee (A). Ia oeyoo (A, Ae, A) eeneioe (XXV) caciathoue ia?aai?aeoaaiiy c ooai?aiiyi niieoee (A), yea iine?aeiaii ia?aoai?th?oueny a eeneioo (Ae), a aeae? a e?ioeaaee i?iaeoeo (XXXI). I?i iiaeeea?noue ?aaeoe?? ia?aai?aeoaaiiy na?ae/eoue ?ic?iaeaiee iaie neioac niieoee (XXVII), a iniia? yeiai eaaeeoue oa?iie?c noi?o? aio?ai?ei?ea?ae?aceaeo (XXIV) ? ioeoiaiai aia?ae?eaeo a ni?aa?aeiioaii? (1:1). 10. Ia?aoai?aiiy ae?aoeeeueieo iio?aeieo aio?ai?ei?ea?ae?aceaeo ca oiia ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? Eeneioe (XXXII) neioaciaaii oeyoii aoeeethaaiiy a?ae?aceaeo (XXIV) aeaiia iieyie a?aeiia?aeiiai oeeee?/iiai aia?ae?eaeo. ?aaeoe?th i?iaiaeeee a na?aaeiaeu? ae?ienaio aai ioeoiai? eeneioe, aeo?ae i?iaeoeo?a 76-94%. Eeneioe (XXXII) caaaeyee no?oeoo?iei iniaeeainoyi caeaoi? ooai?thaaoe ye ?i?aeiee, oae ? o?iacie?iiiiaee oeeeee, oiio ?o iaa??aaee aei oaiia?aoo?e ieaaeaiiy, eei'yoeee a ioeoia?e eeneio?, aoeeaiae?eie? aai a ioeoiaiio aia?ae?eae? a i?enooiino? aoeaoaoo iao??th, oiaoi i?aeaeaaaee oiiaai, ca yeeo iiaeeeaa ooai?aiiy cacia/aieo oeeee?a. A ioeoiaiio aia?ae?eae? a i?enooiino? aoeaoaoo iao??th eeneioe (XXXII) ia?aoai?ththoueny a ae??i?aee (XXXIII). Oaeee ?acoeueoao ?aaeoe?? na?ae/eoue, ui ca aeaieo oiia i?ioean ooai?aiiy ?i?aeiiai oeeeeo ? a?eueo ni?eyoeeaei, i?ae i?ioean ooai?aiiy o?iacie?iiiiai? no?oeoo?e. A?oiooth/enue ia aeine?aeaeaiiyo, i?iaaaeaieo iaie ?ai?oa (?icae. 2), ne?ae aoei a i/?eoaaoe, ui a iaaeeeoeo ioeoiaiai aia?ae?eaeo cai?noue ae??i?ae?a (XXXIII) ooai?thaaoeiooueny ?o aoeaoeeuei? iio?aei? ii ea?aai?aei?e a?oi? (XXXIV). Aeae?eaiiy a ?acoeueoao? ?aaeoe?? i?iaeoeo?a (XXXIII), iaea??ia?aei?oa, iia'ycaia c i?inoi?iaith iaaeinooii?noth ea?aai?aeiiai o?aaiaioa aeey aoeaoeethaaiiy, ine?eueee i?iaaaeaiiy ?aaeoe?? ca a?eueo aei?noe?oeo oiia i?eaiaeeoue aei N'-aoeaoeeae??i?ae?a (XXXIV). Iaa??aaiiy eeneioe (XXXIIa) a aoeeaiae?eie? aai aei oaiia?aoo?e ieaaeaiiy noi?iaiaeaeo?oueny a?aeuaieaiiyi iaeiiai c caeeoe?a aeeea?aiiiai? eeneioe ? ooai?aiiyi ooaeaceii[1,2-b]o?iacie?ii-2,12-ae?iio (XXXIa). Aaoa?ioeeee (XXXIa) neioaciaaii oaeiae oa?iie?cii ae??i?aeo (XXXIIIa). Iai?yi ?aaeoe?? a ioeoia?e eeneio? aecia/a?oueny i?e?iaeith aeeea?aiiiai? eeneioe. O aeiaaeeo eeneioe (XXXIIa), yea ia? aeaa caeeoee ooaeaai? eeneioe, c ?aaeoe?eii? noi?o? aeae?eaii ae??i?ae (XXXIIIa), a eeneioa (XXXIIa), yea ia? caeeoee yioa?ii? eeneioe, aeaea iiaee i?iaeoeo — 2-(2'-ea?aien?aoee)-3-noeoeei?i?aeio?iacie?iii-4 (XXXV). Iaaii, iai?yi ?aaeoe?? a ioeoia?e eeneio? aecia/a?oueny nooiaiai naiaiaee ea?aieneeueieo a?oi a iieaeoe? aeeea?aiiiai? eeneioe. A iieaeoe? ooaeaai? eeneioe ea?aieneeuei? a?oie aei?noei o?eniaai? a iaei?e ieiuei? ? oiio i?ioean ooai?aiiy ?i?aeiiai oeeeeo ? a?eueo aea?aeiei. A iieaeoe? yioa?ii? eeneioe ea?aieneeuei? a?oie iathoue a?eueoo eiioi?iaoe?eio naiaiaeo, a a?oie -NININI- ? -NINI-, ye? niieo/ai? c aaicieueiei e?eueoeai, cae??ieai? a?eueo aei?noei, oiio aiie ia?oeie anooiathoue o ?aaeoe?th, ooai?thth/e o?iacie?iiiiao no?oeoo?o (XXXV). I?e ni?ia? ia?ae?enoae?coaaoe niieoeo (XXXV) ?c 96° aoeeiaiai nie?oo niinoa??aaee ia?aoai?aiiy ?? a aaoa?ioeeee (XXXIa), /iai ia aoei i?e aaaaoi?acia?e e?enoae?caoe?? niieoee (XXXV) ?c ae?ienaio. Oea iiaeeeai iiynieoe iayai?noth aiaee a ?ic/eiieeo. Eaae?noue, c yeith a?aeaoaa?oueny ia?aoai?aiiy niieoee (XXXV) a aaoa?ioeeee (XXXI), iaaooue, aciic? aeaui i?iynieoe ci noaie ooai?aiiy iio?aeieo o?iacie?iiio-4 (XXXI) ?c eeneioe (OOO??). A?oiooth/enue ia iaoeo aeine?aeaeaiiyo, ca?aeii c yeeie aaoa?ioeeee (XXXI) ooai?th?oueny ye ?c eeneioe (XXXII), oae ? c ae??i?aeo (XXXIII), cai?iiiiiaaii aeaa oeyoe (A ? Ae) ooai?aiiy niieoee (XXXI). Ie ia io?eiaee aeaieo, ye? aoee a ni?iiiaei? a?aeoeeeoe iaeio ?c oeeo noai. Iiaeeeai eeoa i?eionoeoe, ui ooai?aiiy aaoa?ioeeeeo (XXXI) a?aeaoaa?oueny /a?ac noaae?th ooai?aiiy niieoee (A), a ye?e eaaei a?aeuaieth?oueny iaeei ?c caeeoe?a aeeea?aiiiai? eeneioe. 11. Aeine?aeaeaiiy ?aaeoe?? N'-?cii?ii?e?aeaia?ae?aceaeo aio?ai?eiai? eeneioe c oeeee?/ieie aia?ae?eaeaie C iaoith ia?aa??ee ciaeaeaii? caeiiii??iino? – i?ioean ooai?aiiy ?i?aeiiai oeeeeo a ioeoiaiio aia?ae?eae? ca iayaiino? aoeaoaoo iao??th ? a?eueo ni?eyoeeaei (?icae. 10), a oaeiae c iaoith aea/aiiy aieeao no?oeoo?ieo ci?i o a?ae?aceaeiiio o?aaiaio? ia iai?yi oeeeeiaeaa?ae?aoaoe?? iaie aeey aeine?aeaeaiue aoei acyoi N'-?cii?ii?e?aeaia?ae?aceae aio?ai?eiai? eeneioe (XXXVI). I?iaaaeai? aeine?aeaeaiiy i?aaenoaaeai? ia noai?: Aoeeethaaiiyi a?ae?aceaeo (XXXVI) oeeee?/ieie aia?ae?eaeaie caeiaooi eeneioe (XXXVII). ?aaeoe?th i?iaiaeeee a na?aaeiaeu? e?eaeaii? ioeoiai? eeneioe aai ae?ienaio. Aeo?ae i?iaeoeoo noaiiaeoue 74%. Iaa??aaiiy eeneio (XXXVII) a na?aaeiaeu? ioeoiaiai aia?ae?eaeo a i?enooiino? aoeaoaoo iao??th ia i?eaiaeeoue aei ooai?aiiy o?iacie?iiiiai? no?oeoo?e (XXXIX), a aea? ?i?aee (XXXVIII). Oaeee ?acoeueoao i?aeoaa?aeaeo? c?iaeaiee ?ai?oa aeniiaie i?i oa, ui i?ioean oeeeeiaeaa?ae?aoaoe?? c ooai?aiiyi ?i?aeiiai oeeeeo ca oeeo oiia ?aaeoe?? ? a?eueo ni?eyoeeaei. I?e iaa??aaii? a?ae?aceaeo (XXXVI) c ooaeaaei aia?ae?eaeii a na?aaeiaeu? aoeeaiae?eieth iaea?aeaii aeaa i?iaeoeoe: a?aeiia?aeiee ?i?ae (XXXVIII) oa eiiaeainiaaiee aaoa?ioeeee (XXXIa), ye? aaeaeiny aeineoue eaaei ?icae?eeoe caaaeyee ?o ??ci?e ?ic/eiiino? a ae?ienai?. Aeo?ae ?i?aeo (XXXVIII)—55%, niieoee (XXXIa) —10%. Oaeei /eiii, aeeiiai? iaie aeine?aeaeaiiy ii anoaiiaeaiith caeiiii??iinoae a ia?aoai?aii? iio?aeieo N-aio?ai?ei?ea?ae?aceaeo, ye? i?noyoue iaeei /e aeaa caeeoee aeeea?aiiiaeo eeneio, ye no?oeoo?, ui ca ni?eueieo oiia ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? caeaoi? ooai?thaaoe ye ?i?aeiee oeeee, oae ? iio?aei? o?iacie?iiiiaiai ?yaeo, aeicaieeee c'ynoaaoe: i?iaaaeaiiy ?aaeoe?? a ioeoiaiio aia?ae?eae? a i?enooiino? aoeaoaoo iao??th aaaea aei ooai?aiiy a?aeiia?aeieo ?i?ae?a; a oiiaao oa?iie?co i?ioean oi?ioaaiiy o?iacie?iiiiai? no?oeoo?e ? a?eueo ni?eyoeeaei; iai?yi ?aaeoe?? a na?aaeiaeu? ioeoiai? eeneioe aecia/a?oueny i?e?iaeith aeeea?aiiiai? eeneioe. A ooai?aii? ?i?aeiiai oeeeeo caae?yi? ea?aieneeueia a?oia (aeaeo?io?eueiee oeaio?) ? ai?aeia a?oia (ioeeaio?eueiee oeaio?), a a ooai?aii? o?iacie?iiiiai? no?oeoo?e aa?ooue o/anoue aea? ai?aei? a?oie. Ine?eueee ea?aieneeueia a?oia aeyaey? aeu? aeaeo?io?euei? aeanoeaino?, oi ooai?aiiy ?i?aeiiai oeeeeo a priori aeaea?oueny a?eueo aea?aeiei i?ioeanii, ui ? niinoa??aa?oueny i?e i?iaaaeaii? ?aaeoe?? a ioeoiaiio aia?ae?eae?. E??i oiai, ca oiia ?aaeoe?? ca?eueoothoueny aeaeo?io?euei? aeanoeaino? ea?aieneeueii? a?oie aiane?aeie ooai?aiiy ci?oaiiai aia?ae?eaeo, a oaeiae i?aeaeuothoueny ioeeaio?euei? aeanoeaino? ai?aeiiai aoiia acioo caaaeyee i?ioeano NI®N– (?icae. 1). C i?aeaeuaiiyi oaiia?aoo?iiai ?aaeeio, a oiiaao oa?iie?co, iai?yi ?aaeoe?? aecia/a?oueny ?icoaooaaiiyi ?aaeoe?eieo oeaio??a iaeei a?aeiinii iaeiiai. A?eueo aei?noei cae??ieai? ?aaeoe?ei? oeaio?e anooiathoue a ?aaeoe?th ia?oeie. Eiieo?aioiee oa?aeoa? iathoue i?ioeane oi?ioaaiiy ?i?aeiiai /e o?iacie?iiiiaiai oeeeeo i?e i?iaaaeaii? ?aaeoe?? a ioeoia?e eeneio?, iai?yi ?aaeoe?? o oeueiio aeiaaeeo aecia/a?oueny i?e?iaeith aeeea?aiiiai? eeneioe (?icae. 10). 12.Eoaeiee a?ae?ie?c oa aeeiaie?c N-(2'-noeoeei?i?aeiaaicai?aei)noeoeei?i?aeo oa N-(2'-aeooa??i?aeiaaicai?aei)aeooa??i?aeo Ae??i?aee (XXXIII) i?noyoue o nai?e no?oeoo?? aeaa ?i?aei? oeeeee, aoii acioo yeeo ca'ycaiee c ??cieie cai?nieeaie ? ye?, ca?aeii c aeeeaaeaiei aeua (?icae. 5,7), iiaeii? ??cieoeny ca o?i?/ieie aeanoeainoyie. Oe?eaai aoei i?inoaaeeoe aieea cai?nieea oa aaee/eie oeeeeo ia o?i?/i? ia?aoai?aiiy noeoeei- oa aeooa??i?ae?a a ?aaeoe?yo eoaeiiai a?ae?ie?co oa aeeiaie?co. Iaoiaeii INDI iaie ?ic?aoiaaii ca?yaee ia ?aaeoe?eieo oeaio?ao iieaeoe ae??i?ae?a (XXXIII), ?acoeueoaoe iaaaaeai? a oaae. 6. sse aeaeii c oaae. 6, ca?yaee ia aoiiao aoaeaoeth ea?aii?eueieo a?oi aeaio ?i?aeieo oeeee?a aeyaeeeny ??cieie. sseui aeey ?i?aeiiai oeeeeo, ca'ycaiiai c NI-a?oiith, oea iiaeeeai iiynieoe iayai?noth a ?o iieaeoe? aioo??oiueiiieaeoey?iiai aiaeiaaiai ca'yceo (?icae. 8), oi ??cieoey a ca?yaeao a ?i?aeiiio yae??, niieo/aiiio c aaicieueiei e?eueoeai, a?eueo ca ana, iia'ycaia c iayai?noth ia'?iiiai cai?nieea a i?oi-iieiaeaii?. I?iaaaeai? iaie aeine?aeaeaiiy eoaeiiai a?ae?ie?co oa aeeiaie?co ae??i?ae?a (XXXIII) i?aeoaa?aeeee aeyaeai? ?ai?oa a?aei?iiino? a ?o o?i?/ieo aeanoeainoyo. Oae, o aeiaaeeo i'yoe/eaiiiai oeeeeo — N-(2'-noeoeei?i?aeiaaicai?aei)noeoeei?i?aeo (XXXIIIa) a i?enooiino? iiaea?eii? e?eueeino? eoao ?ice?eaa?oueny o?eueee ?i?aeiee oeeee, yeee c'?aeiaiee c oai?eueiei ?aaeeeaeii. I?iaeoeoii ?aaeoe?? ? N-[2'-(3''-ea?aienei?ii?ii?eai?ii)aaicai?aei]noeoeei?i?ae (XL). Aiaeia?/ii a?aeaoaa?oueny ?aaeoe?y ae??i?aeo (XXXIIIa) c iaoaiieii a i?enooiino? iaoeeaoo iao??th, a ?acoeueoao? yei? ooai?th?oueny N-[2'-(3''-iaoieneea?aii?ei?ii?ii?eai?ii)aaicai?aei]noeoeei?i?ae (XLI). A i?ioean? a?ae?ie?co oa aeeiaie?co N-(2'-aeooa??i?aeiaaicai?aei)aeooa??i?aeo (XXXIIIa) (oanoe/eaiiee oeeee) ?ice?eaathoueny iaeaeaa ?i?aei? oeeeee c ooai?aiiyi, a?aeiia?aeii, eeneioe (XXXIIa) oa iaoeeiaiai ao??o N-[2'-(4''-iaoieneea?aii?eaooe?eeai?ii)aaici?e]a?ae?aceaeo aeooa?iai? eeneioe (XLII). A?ieia?/ia aeoeai?noue A ?acoeueoao? i?iaaaeaieo oa?iaeieia?/ieo aeine?aeaeaiue neioaciaaieo ?a/iaei ca 10 oanoaie ciaeaeaii niieoee, ye? aeyaeythoue ae?aaeaio a?iiae?eai?/io, aioei?e?iaio, aioea?eoi?/io, i?ioecaiaeueio, ae?o?aoe/io, aioea?iiene/io, aaiinoaoe/io ae?th. Anoaiiaeaii, ui a?eueo?noue iio?aeieo aeooa?ai?iiaeo eeneio a?aeiineoueny aei eeano iaeioiene/ieo oa i?aeoe/ii iaoiene/ieo ?a/iaei. Aiae?c ?acoeueoao?a a?ieia?/ieo aeine?aeaeaiue iieacaa, ui iio?aei? aeooa?iai? eeneioe a ?yae? oa?iaeieia?/ieo oano?a (a?iiae?eai?/ia, i?ioecaiaeueia, i?ioenoaeiiia ae?y) ca /eneii niieoe, ye? aeyaeee a?ieia?/io ae?th, iinooiathoueny iio?aeiei ?ioeo aeeea?aiiiaeo eeneio. ?acii c oei, iio?aei? aeooa?iai? eeneioe aeyaeee aioea?eoi?/io ae?th, yea ia oa?aeoa?ia aeey iio?aeieo ?ioeo aeeea?aiiiaeo eeneio ae?oaoe/iiai ?yaeo, aiie aeyaeee cia/io aaiinoaoe/io, aioea?iiene/io aeoeai?noue; aoaeo/e ai?iiiith neeaaeiaith nieae ai?iiae?eaeei?th, aiie cia/ii i?aeneeththoue aioei?e?iaio ae?th ?, ui aaaeeeai, nooo?ai cieaeothoue oiene/i?noue. Ca ?acoeueoaoaie i?iaaaeaieo a?ieia?/ieo aeine?aeaeaiue a?ae?a?aii o?e niieoee, ye? ia?aaeaii aeey iiaeeaeaiiai oa?iaeieia?/iiai aei?iaoaaiiy. Ia b-(2'-ea?aieneaaici?e)a?ae?aceae 4-iaoeeaeooa?ai?eiai? eeneioe, ui aeyaea cia/io aioea?eoi?/io aeoeai?noue, ?ic?iaeaii i?iaeo OON oa eaai?aoi?iee oaoiieia?/iee ?aaeaiaio. Aeniiaee 1. ?ic?iaeaii aoaeoeai? iaoiaee neioaco N-cai?uaieo aeooa??i?ae?a, aeya-eaii ?yae iniaeeainoae ?o o?i?/ii? iiaaae?iee, c'yniaaii aieea aaee/eie ?i?aeiiai oeeeeo, oa?aeoa?o cai?nieea i?e aoii? acioo oa i?e?iaee ioeeaio?eueiiai ?aaaaioo ia ?o ?aaeoe?eio ni?iiiaei?noue. Anoaiiaeaii caeaaei?noue i?ae oiiaaie i?iaaaeaiiy ?aaeoe?? oeeeeiaeaa?ae?aoaoe??, no?oeoo?ieie iniaeeainoyie oa iai?yieii ?aaeoe?? aaoa?ioeeee?caoe?? N'-aio?ai?ei?ea?ae?aceae?a aeeea?aiiiaeo eeneio oa ?o iio?aeieo – niieoe caeaoieo ca ni?eueieo oiia ooai?thaaoe ? ?i?aeiee ? o?iacie?iiiiaee oeeee. Ca ?acoeueoaoaie a?ieia?/ieo aeine?aeaeaiue a?ae?a?aii 3 ?a/iaeie, ui ia?aaeaii aeey iiaeeaeaiiai oa?iaeieia?/iiai aea/aiiy ? ye? iiaeooue ciaeoe canoinoaaiiy a iaaee/i?e i?aeoeoe?. Ia b-(2'-ea?aieneaaici?e)a?ae?aceae 4-iaoeeaeooa?ai?eiai? eeneioe, ui aeyaea cia/iee aioea?eoi?/iee aoaeo, ?ic?iaeaii i?iaeo oei/aniai? oa?iaeiiaeii? noaoo? oa eaai?aoi?iee oaoiieia?/iee ?aaeaiaio. 2. A ?acoeueoao? a?oioiaiiai aeine?aeaeaiiy ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? aeooa?ai?iiaeo eeneio, ye? i?noyoue ??ci? cai?nieee i?e ai?aeiiio aoii? acioo, ?ic?iaeaii i?aia?aoeai? iaoiaee neioaco N-cai?uaieo aeooa??i?ae?a, iaeieo ?c eeth/iaeo niieoe o neioac? iio?aeieo aeooa?iai? eeneioe. · Neioac N-cai?uaieo aeooa??i?ae?a cae?eniaii i?e iaa??aaii? a?aeiia?aeieo aeooa?ai?iiaeo eeneio a na?aaeiaeu? ioeoiaiai aia?ae?eaeo a i?enooiino? aoeaoaoo iao??th. Anoaiiaeaii, ui ?aaeoe?y oeeeeiaeaa?ae?aoaoe?? iiiiai?ae?a aeooa?iai? eeneioe ia i?ioiaeeoue ca a?eueoino? oiia, ca yeeo ooai?ththoueny iaea?eueo ?iciianthaeaeai? 4-?e ? 5-oe/eaii? ?i?aee; · Iia? aoeeethth/? ?aaaaioe – N-(a?i?eai?aei)- oa N-(a?eenoeueoiiai?aei)aeooa??i?aee io?eiaii i?e aca?iiae?? N'-a?i?e-, N'-a?eenoeueoiiia?ae?aceae?a aeooa?iai? eeneioe c aea?iieueiith e?euee?noth ioeoiaiai aia?ae?eaeo a i?enooiino? aoeaoaoo iao??th. A iaaeeeoeo ioeoiaiai aia?ae?eaeo ii?yae c ?aaeoe??th oeeeeiaeaa?ae?aoaoe?? a?aeaoaa?oueny ? aoeaoeethaaiiy ii ea?aienai?aei- /e noeueoiiai?aeia?oi?; · Iayai?noue aeaio cai?niee?a i?e ?-aoii? acioo a?ae?aceaeiiai o?aaiaioa noai?th? aeiaeaoeia? i?inoi?ia? ia?aoeiaee aeey ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? N',N'-aeecai?uaieo iiiia?ae?aceae?a yioa?ii? oa aeooa?iai? eeneio. 3. A ?acoeueoao? i?iaaaeaieo e?iaoe/ieo aeine?aeaeaiue ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? aeooa?ai?eiaeo eeneio a ioeoiaiio aia?ae?eae? a i?enooiino? aoeaoaoo iao??th c'yniaaii ?ieue inoaiiueiai a oe?e ?aaeoe??: aoeaoao-?ii nooo?ai i?aeaeuo? ioeeaio?euei? aeanoeaino? ai?aeiiai aoiia acioo aeooa?ai?eiai? eeneioe, ia?aaiaey/e eiai a ai?iiio oi?io. 4. Ia iniia? aea/aiiy e?iaoeee eaoae?oe/iiai aoeeethaaiiy a?eenoeueoiiia?ae?aceae?a aeooa?iaei aia?ae?eaeii o ??cieo ?ic/eiieeao o i?enooiino? ea?aiiiaeo eeneio cai?iiiiiaaii noaio ?aaeoe??, yea aeeth/a? ooai?aiiy ia?ao?aeiiai oeeee?/iiai eiiieaeno, aea iieaeoea ea?aiiiai? eeneioe caaaeyee a?ooieoe?iiaeueiiio oa?aeoa?o ni?ey? i?ioeano aoeeethaaiiy. 5. A ?aaeoe?? N-a?eeaeooa??i?ae?a c o?eoei?ieneaeii oinoi?o aeae?eaii aeooa?ai?eia? eeneioe; i?e ae?? iaioaoei?eaeo oinoi?o, a caeaaeiino? a?ae oiia, ooai?ththoueny aeooa?ai?eia? eeneioe /e N-a?ee-a,a-aeeoei?aeooa??i?aee. N-(A?eenoeueoiiai?aei)aeooa??i?aee ca oeeo oiia ooai?ththoue eeoa N'-a?eenoeueoiiia?ae?aceaee aeooa?iai? eeneioe. 6. Anoaiiaeaii, ui ?aaeoe?eia caeaoi?noue i'yoe- oa oanoe/eaiieo ?i?aeieo oeeee?a a ?aaeoe?? c acioi- ? eeniaai?nieie ioeeaio?eueieie ?aaaaioaie aecia/a?oueny ia o?eueee aaee/eiith oeeeeo, aea ? oa?aeoa?ii cai?nieea i?e ?i?aeiiio aoii? acioo ? i?e?iaeith ioeeaio?eueiiai ?aaaaioo: · Aeyaeaii ?yae iniaeeainoae a ?aaeoe?yo eoaeiiai a?ae?ie?co oa aeeiaie?co iieaeoe N-(a?eenoeueoiiai?aei)- oa N-(N'-aoeaoeea?eenoeueoiiai?aei)noeoeei- ? aeooa??i?ae?a, iia'ycaieo c iayai?noth noeueoiiai?aeii? a?oie oa c aaee/eiith ?i?aeiiai oeeeeo. Anoaiiaeaii, ui a ?aaeoe?? eoaeiiai a?ae?ie?co N-(N'-aoeaoeea?eenoeueoiiai?aei)noeoeei- ? aeooa??i?ae?a ia? i?noea ??cia iine?aeiai?noue i?ioean?a a?aeuaieaiiy aoeaoeeueiiai caeeoeo oa ?ice?eooy ?i?aeiiai oeeeeo. Aeeiaie?c N-(a?eenoeueoiiai?aei)noeoeei- oa aeooa??i?ae?a a i?enooiino? iaoeeaoo iao??th noi?iaiaeaeo?oueny ?ice?eooyi ?i?aeiiai oeeeeo o aeiaaeeo oanoe/eaiiiai oeeeeo ? i?eaiaeeoue aei a?aeiia?aeieo ao???a, a o aeiaaeeo i'yoe/eaiiiai oeeeeo ?aaeoe?y coieiy?oueny ia noaae?? ooai?aiiy iao???ai? nie? ii SI2NI-a?oi?; · Anoaiiaeaii, ui a ?aaeoe?th eoaeiiai a?ae?ie?co oa aeeiaie?co N-(2'-noeoeei?i?aeiaaicai?aei)noeoeei?i?ae, yeee i?noeoue aeaa i'yoe/eaii? ?i?aei? oeeeee, ca'ycaieo c ??cieie cai?nieeaie, anooia? o?eueee iaeiei oeeeeii, yeee niieo/aiee c aaicieueiei yae?ii, oiae? ye o iieaeoe? N-(2'-aeooa??i?aeiaaicai?aei)aeooa??i?aeo ?ice?eaathoueny iaeaeaa oeeeee, ooai?thth/e, a?aeiia?aeii, aeeeeneioo /e ae?ao??; · Ia iniia? e?iaoe/ieo oa oa?iiaeeiai?/ieo ia?aiao??a ?aaeoe?? a?ae?aceiie?co N-a?eeaeooa??i?ae?a cai?iiiiiaaii a??ia?aeio noaio oe??? ?aaeoe??, yea ia?aaeaa/a? ooai?aiiy i?ii?aeiiai ia?ao?aeiiai noaio. Anoaiiaeaii, ui a ?aaeoe?yo a?ae?aceiie?co aieea ?ici??o oeeeeo ia ?aaeoe?eio ni?iiiaei?noue N-a?eenoeoeei- ? N-a?eeaeooa??i?ae?a ia? i?ioeeaaeiee oa?aeoa?, i?ae o ?aaeoe?? eoaeiiai a?ae?ie?co. Iaioa ?aaeoe?eia caeaoi?noue N-a?eeaeooa??i?ae?a o ?aaeoe?? a?ae?aceiie?co aecia/a?oueny i?e?iaeith ioeeaio?eueiiai ?aaaaioo oa aeinooii?noth ea?aii?e?a ?i?aeiiai oeeeeo; · A ?acoeueoao? aeine?aeaeaiiy e?iaoeee a?ae?aceiie?co N-(a?eenoeueoii-ai?aei)aeooa??i?ae?a o aeeiaoeeoi?iai?ae? cai?iiiiiaaii iiaee iaoai?ci aieeao noeueoiiai?aeia?oie ia a?ae?aceiie?c ?i?ae?a. Cai?iiiiiaaii eiia??io e?iaoe/io noaio ?aaeoe??, yea aeeth/a? ? iia?/i? i?ioie?oe/i? i?ioeane, ui aeieeathoue aiane?aeie eeneioii-iniiaiiai oa?aeoa?o ?aaaaio?a ? i?iaeoeo?a ?o ia?aoai?aiiy. 7. Aia?oa i?iaaaeaii aeine?aeaeaiiy ii anoaiiaeaiith caeiiii??iinoae a ia?aoai?aii? N'-aio?ai?ei?ea?ae?aceae?a aeeea?aiiiaeo eeneio oa ?o iio?aeieo ye no?oeoo?, ui a oiiaao ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? caeaoi? ooai?thaaoe ? ?i?aeiee oeeee, ? iio?aei? o?iacie?iiiiaiai ?yaeo. Anoaiiaeaii: · i?iaaaeaiiy ?aaeoe?? a ioeoiaiio aia?ae?eae? a i?enooiino? aoeaoaoo iao??th aaaea aei ooai?aiiy a?aeiia?aeieo ?i?ae?a; · a oiiaao oa?iie?co i?ioean ooai?aiiy o?iacie?iiiiai? no?oeoo?e ? a?eueo ni?eyoeeaei; · iai?yi ?aaeoe?? a na?aaeiaeu? ioeoiai? eeneioe aecia/a?oueny i?e?iaeith aeeea?aiiiai? eeneioe. 8.A ?acoeueoao? i?iaaaeaiiai oa?iaeieia?/iiai ne?ei?iao neioaciaaieo niieoe ca 10 oanoaie aeyaeaii ?a/iaeie c ae?aaeaiith a?iiae?eai?/iith, ae?o?aoe/iith, aioea?iiene/iith, aioea?eoi?/iith ae??th. Aea/aiiy aino?i? oiene/iino? neioaciaaieo niieoe iieacaei, ui a?eueo?noue ?c ieo ? iaeioiene/ieie aai i?aeoe/ii iaoiene/ieie ?a/iaeiaie. Nienie iioae?eiaaieo i?aoeue ca oaiith aeena?oaoe?? 1. Eeiaoeea aeae?aceiieeca N-a?eeaeooa?eieaeia a aeeiaoeeoi?iaieaea. N?aaieoaeueiay ioeaiea ?aaeoeeiiiie niiniaiinoe noeoeei- e aeooa?eieaeia / A.I.*a?iuo, A.A.Ao?ye, E.A.Oai/oe, E.I.Oai/oe, A.E.Iaeo?eia // AEI?O. – 1993. – O. 29, aui. 10. – N. 1971-1975. 2. Eco/aiea ?aaeoeee oeeeeiaeaaeae?aoaoeee N'-a?iee-N'-a?eenoeueoiiiaeae?aceaeia aeooa?iaie eeneiou/ E.A.Oai/oe, A.I.*a?iuo, E.N.A?eoeaiei, A.Ae.Ai?y/ee, E.E.Eaaiiaa // AEI?O. – 1994. – O.30, aui.4. – N. 588-590. 3. Eeiaoeea aeae?aceiieeca N-(a?eenoeueoiiaieaei)aeooa?eieaeia a aeeiaoeeoi?iaieaea. E aii?ino i iaoaiecia aeeyiey noeueoiiaieaeiiai o?aaiaioa ia ?aaeoeeiiioth niiniaiinoue eieaeia/ A.I.*a?iuo, A.A.Ao?ye, E.A.Oai/oe, A.Ae.Ai?y/ee, A.E.Iaeo?eia// AEI?O. – 1994. – O.30, aui. 6. – N. 859-864. 4. Iniaaiiinoe uaei/iiai aeae?ieeca e aeeiaieeca N-(a?eenoeueoiiaieaei)- e N-(N'-aoeaoeea?eenoeueoiiaieaei)noeoeei- e aeooa?eieaeia/ E.A.Oai/oe, A.I.*a?iuo, E.N.A?eoeaiei, A.Ae.Ai?y/ee, E.E.Eaaiiaa// AEI?O. – 1996. – O.32, aui. 3. – N. 409-412. 5. Oai/oe E.A., Iaothiei I.A., Ia?ouiia A.A. Eiiaeainaoeey a?ainoeueoiiaieaeia n yoeeiaui yoe?ii N-iaceoeeienaieiiaie eeneiou// AEI?O. – 1996. – O. 32, aui. 10. – N. 1560-1562. 6. Oai/oe E.A., *a?iuo A.I., Eaaiiaa E.E. Eco/aiea oeeeeiaeaaeae?aoaoeee N'-aoeee-N'-a?eeaeae?aceaeia yioa?iie e aeooa?iaie eeneio// AEI?O. – 1997. – O. 33, aui. 4. – N. 494-496. 7. Oai/oe E.A., *a?iuo A.I., Ia?ouiia A.A. Neioac eieaeia o?ain-aeiieoiaie eeneiou // AEI?O. – 1997. – O. 33, aui.8. – N. 1257. 8. Oai/oe E.A. Aoeeee?iaaiea a?ainoeueoiiaieaeia e a?ainoeueoiiiaeae?aceaeia aeeyoe?aie uaaaeaaie eeneiou a i?enoonoaee iaoeeaoa iao?ey // AEI?O. – 1997. – O. 33, aui.9. – N. 1431-1432. 9. Oai/oe E.A., *a?iuo A.I., Oai/oe E.I. ?ieue aoeaoaoa iao?ey a ?aaeoeee oeeeeiaeaaeae?aoaoeee aeooa?aieeiauo eeneio// AEI?O. – 1998. – O. 34, aui.2. – N. 258-260. 10. Oai/oe E.A. I?aa?auaiea N'-aio?aieeieeaeae?aceaeia aeeea?aiiiauo eeneio: neioac i?iecaiaeiuo oeiacieei-4-iia// AEI?O. – 1998. – O. 34, aui. 4. – N. 568-571. 11. I?aa?auaiea aeeaoeeeueiuo i?iecaiaeiuo aio?aieeiaeae?aceaea a oneiaeyo ?aaeoeee oeeeeiaeaaeae?aoaoeee/ E.A.Oai/oe, A.I.*a?iuo, E.E.Eaaiiaa, A.E.Nieoeianeee, I.A.AEe?ia, A.A.Oo?ia// AEI?O. – 1999. – O. 35, aui. 2. – N. 305-308. 12. E.A.Oai/oe. Uaei/iie aeae?ieec e aeeiaieec N'-(2'-noeoeeieieaeiaaicaieaei)noeoeeieieaea e N'-(2'-aeooa?eieaeiaaicaieaei)aeooa?eieaea// AEI?O. – 1999. – O.35, aui.9. – N. 1349-1351. 13. E.A.Oai/oe. Eco/aiea ?aaeoeee N'-ecii?iieeeaeaiaeae?aceaea aio?aieeiaie eeneiou n ooaeaaui aiaeae?eaeii // AEI?O. – 1999. – O.35, aui.9. – N. 1428-1429. 14. Oai/oe E.A. Eoaeiee a?ae?ie?c aee?eiaeo ao???a a?ainoeueoii?eienai?iiaeo eeneio // Oe?.oei.aeo?i. – 1996. – O. 62, ?7. – N. 56-58. 15. Oai/oe E.A. Aea/aiiy ?aaeoe?? N-a?eeaeooa??i?ae?a c iaioaoei?eaeii ? o?eoei?ieneaeii oinoi?o// A?niee oa?iaoe??. –1994. –? 3-4. –N. 107-109. 16. Ia?niaeoeae iiooeo a?ieia?/ii aeoeaieo ?a/iaei a ?yaeo iio?aeieo aeeea?aiiiaeo eeneio/ A.O.*a?ieo, ?.A.Coiaiaoeue, E.I.Oai/oe, C.?.Eiaaeaiei, E.A.Oai/oe. // A?niee oa?iaoe??. – 1994. – ? 3-4. – N.110-114. 17. Neioac oa aioei?e?iaia aeoeai?noue R-aeooa?ai?eao?a 2-aoiene-6,9-ae?ai?iiae?eaeei?th/ N.A.?na?a, I.I.Ua?aae, E.A.Oai/oe, E.O.Neea?aa, E.I.Oai/oe // A?niee oa?iaoe??. – 1994. – ? 3-4. – N.115-117. 18. Neioac oa a?ieia?/ia aeoeai?noue iio?aeieo a?ae?aceae?a a?eenoeueoiiia?ae?aceae?a aeooa?iai? eeneioe/ A.I.*a?ieo, A.Ae.Ai?y/ee, E.A.Oai/oe, ?.E.?aaiiaa, O.I.Eaiaai, ?.E.Aeeeee // A?niee oa?iaoe??. – 1995. – ? 3-4. – N. 24-28. 19. Eiino?othaaiiy oa neioac a?ieia?/ii aeoeaieo ?a/iaei c oa?iaeioi?aie aeeea?aieneeueii? i?e?iaee/ A.I.*a?ieo, N.I.Eiaaeaiei, ?.N.A?eoeaiei, E.A.Oai/oe// A?niee oa?iaoe??. – 1996. – ? 1-2. – N. 54-60. 20. Neioac ooieoe?iiaeueieo iio?aeieo N'-a?i?ea?ae?aceae?a aeooa?iai? eeneioe oa ?o a?ieia?/ia aeoeai?noue/ O.I.Eaiaai, E.A.Oai/oe, ?.E.?aaiiaa, A.I.Eociaoeiaa, A.I.*a?ieo// A?niee oa?iaoe??. – 1996. – ? 3-4. –N. 48-50. 21. E?iaoeea eaoae?oe/iiai aoeeethaaiiy a?eenoeueoiiia?ae?aceae?a aeooa?iaei aia?ae?eaeii o na?aaeiaeu? ae?ienaio oa aaicieo a i?enooiino? ea?aiiiaeo eeneio/ A.I.*a?ieo, I.A.Ao?ye, A.Ae.Ai?y/ee, O.I.Eaiaai, ?.E.?aaiiaa, A.?.Iaeo??ia, E.A.Oai/oe// A?niee oa?iaoe??. – 1997. – ? 1(15). – N. 21-25. 22. Oai/oe E.A. Neioac oa a?ieia?/ia aeoeai?noue 3-aee?e(a?ee)?aeaiai?ii- oa 3-aoeeeai?ii-2-iaoeeo?iacie?iii?a-4// A?niee oa?iaoe??. – 1998. – ? 1(17). – N. 119-120. 23. Neioac ai?ae?a, a?ae?aceae?a N-(2-iaoeeo?iacie?iii-4-?e-3)noeoeeiai?iiai? eeneioe oa ?o a?ieia?/ia aeoeai?noue/ A.I.*a?ieo, I.I.Ia?oiiaiei, O.I.Eaiaai, E.I.Oai/oe, A.Ae.Ai?y/ee, E.A.Oai/oe// A?niee oa?iaoe??. – 1998. – ? 2(18). – N. 16-17. 24. Aeine?aeaeaiiy aeaeo?iiii? aoaeiae N-cai?uaieo aeooa??i?ae?a oa ?o a?ieia?/i? aeanoeaino?/ A.I.*a?ieo, O.I.Eaiaai, E.A.Oai/oe, ?.E.Noa?/eeiaa, E.I.Oai/oe, A.I.Eoci?oeiaa// A?niee oa?iaoe??. – 1999. – ? 2(20). – N. 28-30. 25. Iiene aeieiae/anee aeoeaiuo niaaeeiaiee n?aaee i?iecaiaeiuo aeooa?aieeiaie eeneiou/ E.A.Oai/oe, A.I.*oaa, E.I.Oai/oe, A.O.*a?iuo, E.A.Coiaiaoe// Oa?iaoeey. – 1992. – ? 6. – N. 26-30. 26. Neioac oa a?ieia?/ia aeoeai?noue aee?e(a?ee-, aaoa?ee-)?aeaia?ae?aceae?a a?eecai?uaieo aeooa?ai?eiaeo eeneio/ A.I.*a?ieo, E.A.Oai/oe, E.I.Oai/oe, A.?.Aa?aciyeiaa, N.ss.Iaoa??iei // Oa?iaoe.aeo?i. – 1991. – ?2. – N. 59-61. 27. Neioac, ?aaeoe?eia caeaoi?noue oa a?ieia?/ia aeoeai?noue iio?aeieo aeeea?aiiiaeo eeneio c aee?eueieie, a?eeueieie ? aaoa?ioeeee?/ieie cai?nieeaie/ A.I.*a?ieo, ?.N.A?eoeaiei, A.?.A?eaeania, N.I.Eiaaeaiei, E.A.Oai/oe// Oa?iaoe. aeo?i. – 1991. – ? 4. – N. 48-63. 28. Neioac e i?ioeaiainiaeeoaeueiay aeoeaiinoue a?eecaiauaiiuo aeooa?aieeiaie eeneiou e a? i?iecaiaeiuo/ E.A.Oai/oe, A.O.*a?iuo, E.I.Oai/oe, E.A.Coiaiaoe// Oa?iaoe. aeo?i. – 1991. – ? 4 (*.II, ?on.). – N. 32-35. 29. Oa?iia?aa?iao?e/i? aeine?aeaeaiiy N-cai?uaieo aeooa?ai?iiaeo eeneio oa ?o iio?aeieo/ E.A.Oai/oe, A.I.*a?ieo, E.I.Oai/oe, A.Ae.Ai?y/ee, ?.E.?aaiiaa, O.I.Eaiaai, I.A.Othe?i// Oa?iaoe. aeo?i. – 1997. – ? 5. – N. 48-52. 30. Neioac oa a?ieia?/ia aeoeai?noue aoeee- oa noeueoaoeeea?ae?aceae?a aeooa?iai? eeneioe, ?o ?i?ae?a oa nieae/ A.I.*a?ieo, E.A.Oai/oe, ?.N.A?eoeaiei, ?.E.?aaiiaa, A.Ae.Ai?y/ee, I.A.Othe?i, N.I.Eiaaeaiei // Oa?iaoe.aeo?i. – 1998. – ? 3. – N. 46-50. 31. Oai/oe E.A. Oeeee?/i? ?i?aee: neioac, o?i?/i? aeanoeaino? oa a?ieia?/ia aeoeai?noue/ Iaoeia? iniiae ?ic?iaee e?ea?nueeeo i?aia?ao?a: Iaoa??aee Iaoeiai? nan?? A?aeae?eaiiy o?i?? IAI Oe?a?ie. i.Oa?e?a, 9-11 /a?aiy 1998?. – Oa?e?a: Iniiaa. – 1998. – N. 115-126. 32. 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Iao. 22189 A Oe?a?ia, IEE A61E31/165, N08F22/38. i-Ea?aaoieneoai?eaeii?o?i?ae, yeee aeyaey? aeoeai?noue a?aeiinii a??ono aaceeoey?iiai noiiaoeoo oa a??ono i?inoiai aa?iano/ A.A.Ia?oeiia, A.A.Niaeyinueea, I.I.Ia?oiiaiei, E.I.Iai/aiei, ?.TH.Eo/ia, A.I.*a?ieo, E.A.Oai/oe (Oe?a?ia). – ? 96124562; Cayae. 05.12.96; Iioae. 30.06.98, Athe.?3. Oai/oe E.A. Neioac oa o?i?/i? ia?aoai?aiiy iio?aeieo aeooa?ai?iiaeo eeneio ? aaoa?ioeeee?/ieo niieoe ia ?o iniia?.- ?oeiien. Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy aeieoi?a o?i?/ieo iaoe ca niaoe?aeuei?noth 02.00.03 – i?aai?/ia o?i?y. – Oa?e?anueeee aea?aeaaiee oi?aa?neoao, Oa?e?a, 1999. Aeenna?oaoe?eia ?iaioa i?enay/aia ?ic?iaoe? aoaeoeaieo iaoiae?a neioaco aeooa?ai?eiaeo eeneio, a?eenoeueoiiia?ae?aceae?a aeooa?iai? eeneioe, a?i?ea?ae?aceae?a aeooa?iai?, yioa?ii?, ooaeaai? eeneio oa ?o iio?aeieo, aea/aiith ?o o?i?/ieo aeanoeainoae, c'ynoaaiith aieeao no?oeoo?ieo iniaeeainoae ia o?i?/i? ia?aoai?aiiy, noai?aiith ia iniia? iio?aeieo aeeea?aiiiaeo eeneio aaoa?ioeeee?/ieo niieoe, anoaiiaeaiith ca'yceo i?ae oiiaaie i?iaaaeaiiy ?aaeoe?? aaoa?ioeeee?caoe?? oa ?? iai?yieii, aea/aiith a?ieia?/ii? aeoeaiino? neioaciaaieo niieoe. A?oioiaii aeine?aeaeaii ?aaeoe?th oeeeeiaeaa?ae?aoaoe?? aeooa?ai?iiaeo eeneio, anoaiiaeaii ?ieue aoeaoaoo iao??th a oe?e ?aaeoe??. ?ic?iaeaii i?aia?aoeai? iaoiaee neioaco N-cai?uaieo aeooa??i?ae?a, iaeieo ?c eeth/iaeo niieoe a neioac? iio?aeieo aeooa?iai? eeneioe. Aea/aii o?i?/i? aeanoeaino? N-cai?uaieo aeooa??i?ae?a: ?aaeoe?? c PCl5, POCl3, eoaeiee a?ae?ie?c, aeeiaie?c, a?ae?aceiie?c, ai?iie?c. Aeyaeaii iniaeeaino? a i?io?eaii? ?aaeoe?e eoaeiiai a?ae?ie?co oa aeeiaie?co ?i?ae?a, aoii acioo yeeo ca'ycaiee c noeueoiiai?aeia?oiith. Aecia/ai? e?iaoe/i? oa oa?iiae?iai?/i? ia?aiao?e ?aaeoe?? a?ae?aceiie?co N-a?ee- ? N-(a?eenoeueoiiai?aei)aeooa??i?ae?a. Anoaiiaeaii, ui ?aaeoe?eia ni?iiiaei?noue i'yoe- oa oanoe/eaiieo ?i?ae?a aecia/a?oueny ia o?euee? aaee/eiith oeeeeo, aea ? oa?aeoa?ii cai?nieea i?e ?i?aeiiio aoii? acioo ? i?e?iaeith ioeeaio?eueiiai ?aaaaioo. Anoaiiaeaii caeiiii??iino? a ia?aoai?aii? N'-aio?ai?ei?ea?ae?aceae?a aeeea?aiiiaeo eeneio – no?oeoo?, ye? a oiiaao ?aaeoe?? oeeeeiaeaa?ae?aoaoe?? caeaoi? ooai?eoe ye ?i?aeiee, oae ? o?iacie?iiiiaee oeeee. Eeth/ia? neiaa: neioac, o?i?/i? aeanoeaino?, aeooa?iaa eeneioa, aeooa??i?ae, o?iacie?iii-4, ?aaeoe?y oeeeeiaeaa?ae?aoaoe??, eoaeiee a?ae?ie?c, aeeiaie?c, a?ae?aceiie?c, aaoa?ioeeee?caoe?y. Oai/oe E.A. Neioac e oeie/aneea i?aa?auaiey i?iecaiaeiuo aeooa?aieiiauo eeneio e aaoa?ioeeeee/aneeo niaaeeiaiee ia eo iniiaa.- ?oeiienue. Aeenna?oaoeey ia nieneaiea o/aiie noaiaie aeieoi?a oeie/aneeo iaoe ii niaoeeaeueiinoe 02.00.03 – i?aaie/aneay oeiey .- Oa?ueeianeee ainoaea?noaaiiue oieaa?neoao, Oa?ueeia, 1999. Aeenna?oaoeeiiiay ?aaioa iinayuaia ?ac?aaioea yooaeoeaiuo iaoiaeia neioaca aeooa?aieiiauo eeneio, a?eenoeueoiiiaeae?aceaeia aeooa?iaie eeneiou, a?ieeaeae?aceaeia aeooa?iaie, yioa?iie, ooaeaaie eeneio e eo i?iecaiaeiuo, eco/aieth eo oeie/aneeo naienoa, auyaeaieth aeeyiey nooeoo?iuo iniaaiiinoae ia oeie/aneea i?aa?auaiey, nicaeaieth ia iniiaa i?iecaiaeiuo aeeea?aiiiauo eeneio aaoa?ioeeeee/aneeo niaaeeiaiee, onoaiiaeaieth nayce iaaeaeo oneiaeyie i?iaaaeaiey ?aaeoeee aaoa?ioeeeeecaoeee e a? iai?aaeaieai, eco/aieth aeieiae/aneie aeoeaiinoe neioace?iaaiiuo niaaeeiaiee. ?ac?aaioaiu i?aia?aoeaiua iaoiaeu neioaca N-caiau?iiuo aeooa?eieaeia, iaeieo ec eeth/aauo niaaeeiaiee a neioaca i?iecaiaeiuo aeooa?iaie eeneiou. Aeey yoiai ananoi?iiia eco/aia ?aaeoeey oeeeeiaeaaeae?aoaoeee aeooa?aieiiauo eeneio, aoii acioa eioi?uo niaaeeiai n ?acee/iuie caianoeoaeyie. Yenia?eiaioaeueii onoaiiaeaii, /oi aeooa?aieeiaua eeneiou, N'-a?iee-, N'-a?eenoeueoiiiaeae?aceaeu aeooa?iaie eeneiou ia ia?acotho eieaeiue oeeee i?e iaa?aaaiee eo aei oaiia?aoo?u ieaaeaiey, i?e ia?aaioea eo oeiieeoei?eaeii, o?eoei?eaeii e iaioaieneaeii oinoi?a, oenoniui aiaeae?eaeii, o.a. ?aaeoeey ia i?ioiaeeo a aieueoeinoaa oneiaee, a eioi?uo ia?acothony iaeaieaa ?ani?ino?aiaiiua 4-o e 5-oe/eaiiua eieaeu. N-Caiau?iiua aeooa?eieaeu neioace?iaaiu i?e iaa?aaaiee iiiiaieaeia aeooa?iaie eeneiou a oenoniii aiaeae?eaea a i?enoonoaee aoeaoaoa iao?ey. Onoaiiaeaia ?ieue iineaaeiaai: aoeaoao-eii cia/eoaeueii oaaee/eaaao ioeeaioeeueiua naienoaa aieaeiiai aoiia acioa aeooa?aieeiaie eeneiou, ia?aaiaey aai a aieiiioth oi?io. ?aaeoeey oeeeeiaeaaeae?aoaoeee N'-a?iee-, N'-a?eenoeueoiiiaeae?aceaeia aeooa?iaie eeneiou a oenoniii aiaeae?eaea ineiaeiyaony i?ioeannii aoeaoeee?iaaiey ii ea?aienaieaei- eee noeueoiiaieaeia?oiia. Iiaua aoeeee?othuea n?aaenoaa - N-(a?ieeaieaei)- e N-(a?eenoeueoiiaieaei)aeooa?eieaeu iieo/aiu i?e eniieueciaaiee yeaeiieueiuo eiee/anoa ?aaaaioia. Eco/aiu oeie/aneea naienoaa iieo/aiiuo niaaeeiaiee. Enneaaeiaaia ?aaeoeey N-a?eeaeooa?eieaeia n iaioaoei?eaeii e o?eoei?ieneaeii oinoi?a. I?e aeaenoaee o?eoei?ieneaea oinoi?a ec ?aaeoeeiiiie n?aaeu auaeaeaiu aeooa?aieeiaua eeneiou; a ?aaeoeee n iaioaoei?eaeii oinoi?a, a caaeneiinoe io oneiaee, ia?acothony aeooa?aieeiaua eeneiou eee N-a?ee-?,a-aeeoei?aeooa?eieaeu. Iaia?oaeai ?yae iniaaiiinoae a i?ioaeaiee ?aaeoeee uaei/iiai aeae?ieeca e aeeiaieeca N-(a?eenoeueoiiaieaei)- e N-(N'-aoeaoeea?eenoeueoiiaieaei)noeoeei- e aeooa?eieaeia. Onoaiiaeaii,/oi a ?aaeoeee uaei/iiai aeae?ieeca N-(N'-aoeaoeea?eenoeueoiiaieaei)noeoeei- e aeooa?eieaeia eiaao ianoi ?acee/iay iineaaeiaaoaeueiinoue i?ioeannia iouaieaiey aoeaoeeueiiai inoaoea e ?ane?uoey eieaeiiai oeeeea. Iaa?aaaiea N-(a?eenoeueoiiaieaei)aeooa?eieaeia a iaoaiiea a i?enoonoaee iaoeeaoa iao?ey i?eaiaeeo e ?ane?uoeth eieaeiiai oeeeea e ia?aciaaieth iaoeeiauo yoe?ia N'-a?eenoeueoiiiaeae?aceaeia aeooa?iaie eeneiou, a neo/aa N'-(a?eenoeueoiiaieaei)noeoeeieieaeia ?aaeoeey inoaiaaeeaaaony ia noaaeee ia?aciaaiey iao?eaaie niee ii SO2NH-a?oiia. Eco/aia eeiaoeea aeae?aceiieeca N-a?ee- e N-(a?eenoeueoiiaieaei)aeooa?eieaeia a aeeiaoeeoi?iaieaea. I?aaeeiaeai iiaue iaoaieci aeeyiey noeueoiiaieaeiie a?oiiu ia aeae?aceiieec eieaeia, eioi?ue aeeth/aao ia?aciaaiea aioo?eiieaeoey?iie aiaei?iaeiie nayce. I?aaenoaaeaiu aa?iyoiua noaiu ?aaeoeee. Onoaiiaeaii, /oi ?aaeoeeiiiay niiniaiinoue iyoe- e oanoe/eaiiuo eieaeia ii?aaeaeyaony ia oieueei aaee/eiie oeeeea, ii e oa?aeoa?ii caianoeoaey i?e eieaeiii aoiia acioa e i?e?iaeie ioeeaioeeueiiai ?aaaaioa. Auyaeaiu caeiiiia?iinoe a i?aa?auaiee N'-aio?aieeieeaeae?aceaeia aeeea?aiiiauo eeneio e eo i?iecaiaeiuo eae no?oeoo?, eioi?ua a oneiaeyo ?aaeoeee oeeeeiaeaaeae?aoaoeee niiniaiu ia?aciauaaoue e eieaeiue oeeee, e i?iecaiaeiua oeiacieeiiiiaiai ?yaea. A oenoniii aiaeae?eaea a i?enoonoaee aoeaoaoa iao?ey aieaa aeaaii?eyoiui i?ioeannii yaeyaony ia?aciaaiea eieaeiiai oeeeea, a oneiaeyo oa?iieeca – i?ioeann ia?aciaaiey oeiacieeiiiiaie no?oeoo?u, iai?aaeaiea ?aaeoeee a n?aaea oenoniie eeneiou ii?aaeaeyaony i?e?iaeie aeeea?aiiiaie eeneiou. I?iaaaeai oa?iaeieiae/aneee ne?eieia neioace?iaaiiuo niaaeeiaiee ii 10 oanoai. Iaia?oaeaiu aauanoaa n au?aaeaiiie aeiiaeeeaie/aneie, aeeo?aoe/aneie, aioeaeiiene/aneie, aioea?eoie/aneie aeoeaiinoueth. Eeth/aaua neiaa: neioac, oeie/aneea naienoaa, aeooa?iaay eeneioa, aeooa?eieae, oeiacieeiii-4, ?aaeoeey oeeeeiaeaaeae?aoaoeee, uaei/iie aeae?ieec, aeeiaieec, aeae?aceiieec, aaoa?ioeeeeecaoeey. L.A. Shemchuk. Synthesis and chemical changes of glutaramine acids derivatives and heterocyclic structures on their basis. –– Manuscript. Thesis for Doctor of Chemistry Sciences Degree in speciality 02.00.03. –– Organic Chemistry/. –– Kharkov State University, Kharkov, 1999. In the work some effective methods of synthesis of glutaramine acids, aroylsulphonohydrazides of glutaric acids, aroylhydrazides of glutaric, succinic, phthalic acids and their derivatives are developed, their chemical properties are studied, the influence of their structural peculiarities on chemical changes is examined, heterocyclic structures on the basis of dicarboxycal acids derivatives are made, the link between the conditions of heterocyclization reaction and its direction is established, biological properties of the compounds synthetizid are studied. The reaction of cyclodehydratation of glutaramide acids is thoroughly examined, the role of sodium accetate in this reaction is determined. Preparative methods of synthesis of glutarimides which are some of key compounds in the synthesis of glutaric acids derivatives are developed. Chemical properties of N-substituted glutarimides (reactions with PCl5, POCl3, alkaline hydrolysis, alcoholysis, hydrazinolysis, aminolysis) are studied. Some peculiarities of the reactions of alkaline hydrolysis and alcoholysis of imides where a nitrogen atom is connected with a sulphonamidogroup are revealed. Kinentic and termodinamical coordinates of hydrazinolisis of N-aryl- and N-(arylsulphonamido)glutarimides are determined. It is discovered that the reactivity of five- and six-membered imides is determined not only by the cycle size, but the substitute nature in the imide atom of nitrogen and the nature of the nucleofilic reagent. Regularies in the changes of N-antraniloylhydrazides of dicarboxycal acids which can form both imide and chinazolinone cycles. Key words: synthesis, chemical properties, glutaric acid, glutarimide, chinazolinone-4, reaction of cyclodehydratation, alcaline hydrolisis, alcoholysis, hydrazinolisis, heterocyclization. Aeena?oaoe??th ? ?oeiien. ?iaioa aeeiiaia a Iaoe?iiaeuei?e oa?iaoeaaoe/i?e aeaaeai?? Oe?a?ie (i.Oa?e?a), I?i?noa?noai ioi?iie caei?ia'y Oe?a?ie. Iaoeiaee eiinoeueoaio /eai–ei?aniiiaeaio IAI Oe?a?ie, aeieoi? o?i?/ieo ? oa?iaoeaaoe/ieo iaoe, i?ioani?, *a?ieo Aaeaioei Iao?iae/, Iaoe?iiaeueia oa?iaoeaaoe/ia aeaaeai?y Oe?a?ie (i.Oa?e?a), ?aeoi? aeaaeai??. Io?oe?ei? iiiiaioe: /eai–ei?aniiiaeaio IAI Oe?a?ie, aeieoi? o?i?/ieo iaoe, i?ioani?, Iiiia Aiaoie?e Oaaei?iae/, ?inoeooo o?ceei-i?aai?/ii? o?i?? oa aoaeao?i?? ?i. E.I.Eeoaeiaiea IAI Oe?a?ie (i.Aeiiaoeuee), aee?aeoi? ?inoeoooo aeieoi? o?i?/ieo iaoe, i?ioani? ?eue/aiei Aiae??e sseiae/, ?inoeooo i?aai?/ii? o?i?? IAI Oe?a?ie (i. Ee?a), i?ia?aeiee iaoeiaee ni?a?ia?oiee aeieoi? o?i?/ieo iaoe, i?ioani? Aeanaiei Na?a?e Ieoaeeiae/, Oa?e?anueeee aea?aeaaiee oi?aa?neoao, i?ioani? eaoaae?e i?aai?/ii? o?i?? I?ia?aeia onoaiiaa O?ceei-o?i?/iee ?inoeooo ?i. I.A.Aiaaonueeiai IAI Oe?a?ie, a?aeae?e… (i.Iaeana) Caoeno a?aeaoaeaoueny "____"______________1999?. i ____ aiaeei? ia can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee Ae 64.051.14 o Oa?e?anueeiio aea?aeaaiiio oi?aa?neoao? (61077, i.Oa?e?a,, ie. Naiaiaee, 4, aoae. 7-80). C aeena?oaoe??th iiaeia iciaeiieoeny o Oeaio?aeuei?e iaoeia?e a?ae?ioaoe? Oa?e?anueeiai aea?aeaaiiai oi?aa?neoaoo (61077, i.Oa?e?a, ie. Naiaiaee, 4). Aaoi?aoa?ao ?ic?neaii "____"____________1999 ?ieo. A/aiee nae?aoa? niaoe?ae?ciaaii? a/aii? ?aaee Eia?iiaa E.I.

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