I?i?noa?noai ina?oe Oe?a?ie

I?eea?iaonueeee oi?aa?neoao ?iai? Aaneey Noaoaieea

Caiooeye ?oneai ?ai?iae/

OAeE 669:621.315.592:54-165

Iniaeeaino? oa?iiaeaeo?e/ieo aeanoeainoae

ie?aie PbTe oa eiai aiaeia?a

Ciaoe?aeuei?noue 01.04.18 – o?ceea ? o?i?y iiaa?oi?

AAOI?AOA?AO

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?ceei-iaoaiaoe/ieo iaoe

?aaii-O?aie?anuee — 1999

Aeena?oaoe??th ? ?oeiien.

?iaioa aeeiiaia ia eaoaae?? o?ceee oaa?aeiai o?ea I?eea?iaonueeiai
oi?aa?neoaoo

?iai? Aaneey Noaoaieea I?i?noa?noaa ina?oe Oe?a?ie.

Iaoeiaee ea??aiee: caneoaeiiee ae?y/ iaoee ? oaoi?ee Oe?a?ie, aeieoi?
o?i?/ieo iaoe, i?ioani? O?a?e Aeieo?i Ieoaeeiae/,

I?eea?iaonueeee oi?aa?neoao ?iai? Aaneey Noaoaieea, aee?aeoi?
O?ceei-o?i?/iiai ?inoeoooo, caa?aeoaa/ eaoaae?e o?ceee oaa?aeiai o?ea,

i. ?aaii-O?aie?anuee.

Io?oe?ei? iiiiaioe: eao?aao Aea?aeaaii? i?ai?? Oe?a?ie a aaeoc? iaoee ?
oaoi?ee, aeieoi? o?ceei-iaoaiaoe/ieo iaoe, i?ioani? Aeieo?oe Ieeiea
Eaiio?eiae/,

?inoeooo o?ceee iai?ai?ia?aeiee?a IAI Oe?a?ie, caa?aeoaa/ a?aeae?eii
iiey?eoiiii? iioiaeaeo?ii?ee,

i. Ee?a.

aeieoi? oaoi?/ieo iaoe, i?ioani? Aoaoeia Aiaoie?e Aiaoie?eiae/,

?inoeooo oa?iiaeaeo?eee IAI Oe?a?ie, i?ia?aeiee iaoeiaee ni?a?ia?oiee,

i. *a?i?aoe?.

I?ia?aeia i?aai?caoe?y: ?inoeooo o?ceee IAI Oe?a?ie, eaai?aoi??y
?ici??ieo aeaeo?iiieo yaeu,

i. Ee?a.

Caoeno aeena?oaoe?? a?aeaoaeaoueny 9 aeiaoiy 1999 ?ieo i 10 aiae. ia
can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee E20.051.03 i?e I?eea?iaonueeiio
oi?aa?neoao? ?iai? Aaneey Noaoaieea ca aae?anith: 76000, i.
?aaii-O?aie?anuee, aoe. Oaa/aiea, 57, aoae. 115.

C aeena?oaoe??th iiaeia iciaeiieoeny a a?ae?ioaoe? I?eea?iaonueeiai
oi?aa?neoaoo (76000, i. ?aaii-O?aie?anuee, aoe. Oaa/aiea, 57).

Aaoi?aoa?ao ?ic?neaiee 9 aa?aniy 1999 ?ieo.

A/aiee nae?aoa?

niaoe?ae?ciaaii? a/aii? ?aaee A.I. Eeai?/ea.

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeuei?noue oaie. Aoaeoeai?noue aeei?enoaiiy oa?iiaeaeo?e/iiai
iaoa??aeo a ia?oo /a?ao aecia/a?oueny eiai iiaeeea?noth aeinyaiaiiy
aenieeo cia/aiue oa?iiaeaeo?e/ii? aeia?ioiino? (Z=2/, aea eiao?oe??io
oa?ii-a.?.n., ieoiia aeaeo?ii?ia?aei?noue, eiao?oe??io
oaieii?ia?aeiino?) [1, 2].

Niieoee AIVBVI ia?niaeoeai? iai?ai?ia?aeieeia? iaoa??aee aeey noai?aiiy
oa?iiaeaeo?e/ieo i?eno?i?a, ye? i?aoeththoue a ?ioa?aae? oaiia?aoo? a?ae
e?iiaoii? aei 800-900 E [3]. Na?aae oaeueeiaai?ae?a naeioeth aea?aeii
a?ae??ciy?oueny nai?ie aeanoeainoyie oaeo?eae naeioeth: aaaaoiaeieeiiee
oa?aeoa? aia?aaoe/iiai niaeo?o (N=4); iecuee? cia/aiiy a?aoeiai?
oaieii?ia?aeiino? (A=2,09·10-2 Ao·E-1·ni-1); ii??aiyii aenie? ?ooeeaino?
iin??a (103 ni2·A-1·n-1); iaea?eueoa cia/aiiy aaee/eie -1, ui aaaea aei
nooo?aiai c?inoaiiy iaeneiaeueiiai cia/aiiy oa?iiaeaeo?e/ii?
aeia?ioiino? (Zmax) [4, 5].

Ca?eueoaiiy a?aeiioaiiy ?ooeeaino? iin??a no?oio aei oaieii?ia?aeiino?
?a/iaeie iiaeia aeinyaoe aaaaeaiiyi ?ciaaeaioieo aoii?a cai?uaiiy ca
?aooiie c?inoaiiy ?icn?thaaiiy oiiii?a ? nooo?aiai ciaioaiiy
eiao?oe??ioa oaieii?ia?aeiino? (A). Ua iaeiei aaaeeeaei iiiaioii
i?aeaeuaiiy Z ? c?inoaiiy eiao?oe??ioa oa?ii-a.?.n. aeey iaeano?
neeueiiai ae?iaeaeaiiy ca ?aooiie naeaeoe?? iin??a ca aia?a??th
aa?’??aie ia a?aieoeyo e?enoae?o?a /e ia aeieao ca?ai, ui iniaeeai
aoaeoeaii aeey oiieiie?aeiaiai iaoa??aeo [6]. O ca’yceo ?c oeei, caaea/a
i?aeaeuaiiy oa?iiaeaeo?e/ii? aeia?ioiino? aeeth/a? ia o?eueee ?ic?iaeo
oaoiieia?/ieo iaoiae?a iie?auaiiy ia’?iieo ia?aiao??a ie?aie, aea ?
iaoiaee oe?eani?yiiaaiiai noai?aiiy aecia/aieo aeanoeainoae
i?aee?enoae?/ieo oa i?aeca?aiieo a?aieoeue. Na?aae ieo ne?ae a?aecia/eoe
ye /enoi oaoiieia?/i? (oaiia?aoo?i? oiiae ae?iuoaaiiy, oiaueia ie?aee,
??ae i?aeeeaaeee, oiui), oae ? ciai?oi? oaeoi?e: oa?i?/iee a?aeiae,
aieea eenith a i?ioean? aeo?eiee, ?aae?aoe?eiiai ii?ii?iaiiy oa ?ioa.

Ia aeeaey/enue ia o?eaae? oa aaaaoi/enaeuei? aeine?aeaeaiiy oaeo?eaeo
naeioeth, o e?oa?aoo?? a?aenooi? nenoaiaoeciaai? aeai? a?aeiinii anueiai
eiiieaeno oa?iiaeaeo?e/ieo oa?aeoa?enoee. Oea /anoeiai iia’ycaii c oei,
ui ??ci? aaoi?e aeine?aeaeoaaee o?eueee ie?ai? noi?iie ieoaiiy. Inoaii?
oneeaaeith? i?iaeaio iioei?caoe?? aeanoeainoae oiieiie?aeiaiai iaoa??aeo
oa ia?aiao??a oa?iiaeaeo?e/ieo i?eno?i?a. E??i oiai, aeey i?aeaeuaiiy ?o
?iai/eo oa?aeoa?enoee iaiao?aeia /?oea ?icoi?iiy o?ce/ieo i?ioean?a, ui
a?aeaoaathoueny a aaciaiio iaoa??ae? i?e eiai aenieoaoaoe?? o aecia/aieo
oiiaao. ?ica’ycaiiy oeeo caaaeaiue iiaea a?aee?eoe iia? iiaeeeaino?
i?aeoe/iiai aeei?enoaiiy oaeo?eaeo naeioeth oa eiai aiaeia?a.

Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie. ?iaioa aeeiiaia
a eaai?aoi??yo eaoaae?e o?ceee oaa?aeiai o?ea oa O?ceei-o?i?/iiai
?inoeoooo i?e I?eea?iaonueeiio oi?aa?neoao? ?iai? Aaneey Noaoaieea.

Aeena?oaoe?eia aeine?aeaeaiiy ? neeaaeiaith /anoeiith eiiieaenieo
iaoeiai-oaoi?/ieo i?ia?ai I?iiaoee Oe?a?ie “?ic?iaea i?ia?aneaieo
oaoiieia?e neeaaeieo iai?ai?ia?aeieeiaeo ie?aie ia iniia? niieoe AIVBVI
aeey i?eno?i?a aeaeo?ii?ee (i?iaeo 05.44.06//27-93)” oa oaiaoe/iiai
ieaio IAeAeE? I?iina?oe Oe?a?ie “Aieea ciai?oi?o oaeoi??a ia aeaeo?iii?
i?ioeane a oiieeo iai?ai?ia?aeieeiaeo ie?aeao oaeueeiaai?ae?a naeioeth ?
ieiaa” (aeiaeaoie ? 2 aei iaeaco ? 330 I?i?no?a ina?oe Oe?a?ie a?ae
13.12.1996 ?.).

?iaioa aeeiiaia i?e /anoeiaiio ni?eyii? I?aeia?iaeii? Ni?in?anueei?
I?ia?aie i?aeo?eiee ina?oe a aaeoc? oi/ieo iaoe (a?aio ? GSU052281), a
oaeiae Eaa?iaoo I?i?no??a Oe?a?ie (??oaiiy eieaa?? a?ae 26 aa?aciy 1997
?, i?ioieie ? 4/7-6 oa iinoaiiae I?aceae?? ? Eii?oaoo ii Aea?aeaaieo
i?ai?yo Oe?a?ie a aaeoc? iaoee ? oaoi?ee a?ae 5 o?aaiy 1997 ?. ? 2 i?i
i?enoaeaeaiiy noeiaiae?? Eaa?iaoo I?i?no??a Oe?a?ie aeey iieiaeeo
a/aieo).

Iaoa ? caaea/? aeine?aeaeaiiy iieyaathoue o anoaiiaeaii? caeiiii??iinoae
aieeao no?oeoo?e, oiia ae?iuoaaiiy ? ciai?oi?o oaeoi??a (oa?i?/iiai
a?aeiaeo, ?aae?aoe?eiiai ii?ii?iaiiy, eaaoaaiiy) ia oa?iiaeaeo?e/i?
oa?aeoa?enoeee ie?aie oaeo?eaeo naeioeth oa eiai aiaeia?a.

Aeey aeinyaiaiiy iinoaaeaii? iaoe ?ica’ycai? oae? caaea/?:

1. ?aae?ciaaia oaoiieia?y ae?iuoaaiiy oiieiie?aeiaiai iaoa??aeo
inaaeaeaiiyi c ia?iai? oace iaoiaeii aa?y/i? no?iee, a oaeiae
iiiie?enoae?a oaeo?eaeo naeioeth ? ?yaeo oaa?aeeo ?ic/ei?a ia eiai
iniia? iaoiaeii A??aeaeiaia.

2. Anoaiiaeaii aieea oaoiieia?/ieo oaeoi??a ae?iuoaaiiy (oaiia?aoo?
aeia?iaoaaiiy OA, no?iie eaia?e ON, inaaeaeaiiy OI, ia?oe?aeueiiai oeneo
ia?e oaeueeiaaio a cii? eiiaeainaoe??), a oaeiae oiaueie oa ?iaeo
i?aeeeaaeie ia oa?iiaeaeo?e/i? aeanoeaino? ie?aie oaeo?eaeo naeioeth ?
eiai aiaeia?a.

3. Aeine?aeaeaii oaiia?aoo?i? oa eiioeaio?aoe?ei? caeaaeiino?
oa?iiaeaeo?e/ieo aeanoeainoae ie?aie ? e?enoae?a oaeo?eaeo naeioeth.

4. Aea/aii caeiiii??iino? ci?ie oa?iiaeaeo?e/ieo ia?aiao??a ie?aie PbTe
i?ae aieeaii ciai?oi?o oaeoi??a: oaiia?aoo?iee a?aeiae, ?aae?aoe?eia
ii?ii?iaiiy o aaeooi? ? aoiinoa?? eenith.

5. Aeine?aeaeaii caeaaei?noue iniiaieo oa?iiaeaeo?e/ieo ia?aiao??a ?yaeo
oaa?aeeo ?ic/ei?a, oiieeo ie?aie ? e?enoae?a ia iniia? oaeueeiaai?ae?a
naeioeth ? ieiaa a?ae ?o o?i?/iiai neeaaeo. Iioei?ciaaii iniiai?
oa?iiaeaeo?e/i? oa?aeoa?enoeee iaoa??ae?a.

Ia’?eoii aeine?aeaeaiiy aoee ie?aee ? e?enoaee oaeo?eaeo naeioeth oa
eiai aiaeiae PbTe:In(I), PbTe-SnTe:In, Pb1-XSnXTe1-YSeY, PbSe.

IAOEIAA IIAECIA IAeA?AEAIEO ?ACOEUeOAO?A

1. Aia?oa anoaiiaeaii, ui aeey ae??aiiaeenia?niiai iaoa??aeo
(PbTe/II-1), aiane?aeie c?inoaiiy eiao?oe??ioa oa?ii-a.?.n. () ?
ciaioaiiy a?aoeiai? oaieii?ia?aeiino? (A), ia? i?noea cia/ia iie?auaiiy
(a?eueo ye o 6 ?ac?a o ii??aiyii? c PbTe/(111) BaF2) oa?iiaeaeo?e/ii?
aeia?ioiino? (Z).

2. I?aeoaa?aeaeaii, ui ca?eueoaiiy oiaueie oiieeo ie?aie a ?ioa?aae?
0,05-0,5 iei i?eaiaeeoue aei c?inoaiiy oa?iiaeaeo?e/ieo ia?aiao??a i?e
200 E o 2-2,5 ?ace. Iaeneioi i?eiaeo cia/aiue oa?iiaeaeo?e/ieo
ia?aiao??a (2, Z, ZT) oianoeo ie?aie (1,0-10 iei) i?e 200 E i?eiaaea? ia
?ioa?aae eiioeaio?aoe?e (1-3)·1017 ni-3.

3. Aeyaeaii aenie? cia/aiiy oa?ii-a.?.n. oa iie?auaiiy oa?iiaeaeo?e/ii?
aeia?ioiino? i?e ?cio?iiiiio a?aeiae? o aaeooi? ie?aie ?-PbTe.
Aenia?eiaioaeuei? ?acoeueoaoe iiyniaii aia?iiey?iith aeeooc??th
iiceoeaii ca?yaeaeaieo aaeain?e oaeo?o ? aeaeo?ii?a aaeea ie?aie oa
ooai?aiiyi aeaioa?iai? ?-n-no?oeoo?e.

4. Iieacaii, ui aaeni?aoe?y eenith iiaa?oiath ie?aie n-PbTe ? ooai?aiiy
iioaioe?aeueieo aa?’???a ia a?aieoe? ca?ai aaaeooue aei aiiiaeueii
aenieeo cia/aiue oa?ii-a.?.n. oa c?inoaiiy oa?iiaeaeo?e/ii? iiooaeiino?.

5. Anoaiiaeaii, ui i?ae aieeaii -ii?ii?iaiiy ie?aie n-PbTe, inaaeaeaieo
ia II-1 ia? i?noea ciaioaiiy ieoiii? aeaeo?ii?ia?aeiino? oa c?inoaiiy
eiao?oe??ioa oa?ii-a.?.n. Ci?ia aeanoeainoae iia’ycaia ?c ciaioaiiyi
oiee?anueei? eiioeaio?aoe?? ? ?ooeeaino? aeaeo?ii?a ca ?aooiie
i?iieeiaiiy eenith ia a?aieoeyo ca?ai, a oaeiae oa?iiaeeooc?? ?
?aae?aoe?eii-noeioeueiaaieo i?ioean?a.

6. Aeine?aeaeaii oaiia?aoo?i? caeaaeiino? oa?iiaeaeo?e/ieo aeanoeainoae
e?enoae?a PbTe n- ? ?-oeio. I?aeoaa?aeaeaii, ui yeui a iaeano? iecueeeo
oaiia?aoo? 10-100 E iniiai? oa?iiaeaeo?e/i? ia?aiao?e iathoue
oaiaeaioe?th aei c?inoaiiy, oi aeey oaiia?aoo? 100-500 E 2 ? Z ??cei
ciaioo?oueny, a ZT ia? oa?aeoa?iee iaeneioi. Aenia?eiaioaeuei?
?acoeueoaoe iiyniaii ca ?aooiie neeaaeii? aoaeiae aaeaioii? ciie ?
?icn?thaaiiy iin??a ia ?ii?ciaaieo oeaio?ao oa aeonoe/ieo eieeaaiiyo.

7. Aia?oa i?iaaaeaii aiae?c caeaaeiinoae oa?iiaeaeo?e/ieo oa?aeoa?enoee
PbTe:In, (Pb0,8Sn0,2)1-XInXTe a?ae neeaaeo. Aecia/aii ?ieue ?iae?th o
yaeuao ia?aiino oa eiai aieea ia oa?iiaeaeo?e/i? ia?aiao?e. Iieacaii, ui
aeiaeaoeiaa eaaoaaiiy eiaeii aei 0,1-0,3 ao. % i?eaiaeeoue aei c?inoaiiy
oa?iiaeaeo?e/ieo ia?aiao??a ca ?aooiie ca?eueoaiiy ieoiii?
aeaeo?ii?ia?aeiino?. Iaea?eueoa cia/aiiy oa?iiaeaeo?e/ii? iiooaeiino? oa
aeia?ioiino? a /ioe?e-eiiiiiaioiiio oaa?aeiio ?ic/ei? Pb1-XSnXTe1-YSeY
aeinyaathoue i?e neeaae? o=0,10; o=0,97.

I?aeoe/ia oe?ii?noue iaea?aeaieo ?acoeueoao?a aecia/a?oueny
aeei?enoaiiyi aeine?aeaeoaaieo iaoa??ae?a o oa?iiaeaeo?e/ieo
ia?aoai?thaa/ao aia?a?? oa iaea?aeaiiyi nenoaiaoeciaaieo aeaieo i?i ?o
iioeiaeuei? cia/aiiy a caeaaeiino? a?ae oaoiieia?? ae?iuoaaiiy, aieeao
ciai?oi?o oaeoi??a (oaiia?aoo?a, ii?ii?iaiiy, aeii?oee), ye? iaiao?aeii
a?aoiaoaaoe i?e aeaioiaeaii? a?aeiia?aeieo i?eno?i?a c ea?iaaieie oa
noaa?eueieie oa?aeoa?enoeeaie. I?aeoe/i? ?acoeueoaoe ?iaioe caoeuai?
/ioe?ia iaoaioaie Oe?a?ie, a iaoeia? ?acoeueoaoe ioae?eaoe?e
aeei?enoiaothoueny a iaa/aeueiiio i?ioean? I?eea?iaonueeiai oi?aa?neoaoo
?iai? Aaneey Noaoaieea i?e /eoaii? niaoeeo?no iaa?no?ai oa ani??aioai
“Oa?iiaeaeo?e/i? iaoa??aee ? i?eno?i?”.

Aeinoia??i?noue oa iaa?oioiaai?noue io?eiaieo ?acoeueoao?a caaacia/ai?:

— aeei?enoaiiyi eiiieaeno aca?iiaeiiiaithth/eo aenia?eiaioaeueieo
iaoiaeee;

— ocaiaeaeai?noth ?ic?iaeaieo iiaeaeueieo oyaeaiue c iaea?aeaieie
aenia?eiaioaeueieie ?acoeueoaoaie;

— ocaiaeaeai?noth ?acoeueoao?a i?ae niaith, a oaeiae c e?oa?aoo?ieie
aeaieie;

— a?aeoai?aiiyi ie?aieo ?acoeueoao?a o aeine?aeaeaiiyo, i?iaaaeaieo a
?ioeo iaoeiaeo caeeaaeao.

Iniaenoee aianie caeiaoaa/a iieyaa? o i?iaaaeaii? aenia?eiaioaeueieo
aeine?aeaeaiue, iienaieo a aeena?oaoe??, a oaeiae o/ano? a iaaiai?aii?
?acoeueoao?a, io?eiaieo aaoi?ii ? eiai eieaaaie, ?o ?ioa?i?eoaoe??,
iaienaii? oa ioi?ieaii? noaoae. Iniiai? iaoeia? ?acoeueoaoe
i?ea?iaeuei?, ?yae c ieo caoeuai? iaoaioaie ? aeiiia?aeaeeny aaoi?ii ia
iaoeiaeo eiioa?aioe?yo ? nai?ia?ao. O i?aoeyo, aeeiiaieo ?acii c ?ioeie
ni?aaaoi?aie, aeena?oaio iniaenoi aecia/aa caaaeaiiy ? ?o aeeiioaaa [1,
2, 4, 6, 11, 12]; aiooaaa ia’?eoe aeey aeine?aeaeaiue ? aaciina?aaeiuei
aeeiioaaa aei??thaaiiy [9, 10]; iniaenoi ?iaea ?ic?aooiee [3, 5]. Aaoi?
i?eeiaa o/anoue o i?aeaioiaoe? oa i?iaaaeaii? ?yaeo i?aeia?iaeieo
eiioa?aioe?e c o?ceee ? oaoiieia?? oiieeo ie?aie.

Ai?iaaoe?y ?acoeueoao?a aeena?oaoe??. Iniiai? ?acoeueoaoe ?iaioe
aeiiia?aeaeenue ? iaaiai?thaaeenue ia:

IV I?aeia?iaeia eiioa?aioe?y c o?ceee ? oaoiieia?? oiieeo ie?aie.
–?aaii-O?aie?anuee. –1993.

V I?aeia?iaeia eiioa?aioe?y c o?ceee ? oaoiieia?? oiieeo ie?aie.
–?aaii-O?aie?anuee. –1995.

Iao/ii-oaoie/aneay eiioa?aioeey “Oaoieea e oeceea yeaeo?iiiuo nenoai e
ono?ienoa”. –Noiu. –1995.

International workshop on advanced technologies of multicomponent solid
films and structures and their application in photonics. – Uzhgorod.
–1996.

3/4 VI I?aeia?iaeia eiioa?aioe?y c o?ceee ? oaoiieia?? oiieeo ie?aie.
–?aaii-O?aie?anuee. –1997.

3/4 International Conference “Advanced Materials”. –Kiev. –1999.

3/4 7th International Conference “Physics and Technology of Thin Films”.
–Ivano-Frankivsk. –1999.

Ioae?eaoe??. Ca oaiith aeena?oaoe?? iioae?eiaaia 31 ?iaioa: c ieo 6
noaoae a ?aoa?iaaieo aeo?iaeao (1 iaeiiiniaiaa), 4 iaoaioe, 11 noaoae o
ca??ieeao ? a?nieeao (c ieo 1 iaeiiiniaiaa), a oaeiae 10 aeiiia?aeae ia
eiioa?aioe?yo; 12 uieii iacaaieo ?ia?o iaaiaeyoueny a nieneo ioae?eaoe?e
o e?ioe? aaoi?aoa?aoo.

No?oeoo?a oa ianya aeena?oaoe??. Aeena?oaoe?eia ?iaioa neeaaea?oueny c?
anooio, /ioe?ueio ?icae?e?a, aeniiae?a oa nieneo aeei?enoaii?
e?oa?aoo?e. Ianya aeena?oaoe?? neeaaea? 157 noi??iie iaoeiiieniiai
oaenoo, aiia i?noeoue 57 ?enoie?a ? 20 oaaeeoeue. Nienie aeei?enoaieo
aeaea?ae ia?aoiao? 124 iaeiaioaaiiy.

O anooi? iaa?oioiaaia aeooaeuei?noue ?iaioe, noi?ioeueiaaia iaoa ?
caaea/? aeine?aeaeaiue, iaaaaeaia iaoeiaa iiaecia aeena?oaoe?? oa ??
i?aeoe/ia oe?ii?noue. I?aaenoaaeai? a?aeiiino? i?i ai?iaaoe?th ?iaioe oa
ioae?eaoe??.

O ia?oiio ?icae?e? iienaii iniiae oai??? oa?iiaeaeo?e/ieo yaeu.
C?iaeaia ioe?iea aoaeoeaiino? oaa?aeeo o?e ye oa?iiaeaeo?e/iiai
iaoa??aeo. Ia?oee ?icae?e caaa?oo?oueny aeniiaeaie c aiae?oe/iiai
iaeyaeo, iaoith oa caaaeaiiyie aeine?aeaeaiiy.

O ae?oaiio ?icae?e? iienaia oaoiieia?y ae?iuoaaiiy oiieeo ie?aie
oaeo?eae?a naeioeth oa oaa?aeeo ?ic/ei?a ia ?o iniia? c ia?iai? oace
iaoiaeii aa?y/i? no?iee. Aeaia oa?aeoa?enoeea iniiaieo iaoiaeee
aeine?aeaeaiiy oa?iiaeaeo?e/ieo aeanoeainoae iaoa??aeo. Iniaeeao oaaao
caa?iaii ia iaoiaeeeo aei??thaaiiy oaieii?ia?aeiino? oiieeo ie?aie.

O?ao?e ?icae?e i?enay/aiee aeine?aeaeaiith aieeao oaoiieia?/ieo
oaeoi??a ae?iuoaaiiy o iaoiae? aa?y/i? no?iee ia oa?iiaeaeo?e/i?
aeanoeaino? ie?aie PbTe. Aea/aii oa?iiaeaeo?e/i? aeanoeaino? i?e
?cio?iiiiio a?aeiae? o aaeooi?, aoiinoa?? eenith, a oaeiae i?e
?aae?aoe?eiiio ii?ii?iaii?.

Aeine?aeaeaiith caeaaeiinoae iniiaieo oa?iiaeaeo?e/ieo ia?aiao??a
e?enoae?a PbTe n- ? ?-oeio i?ia?aeiino?, a oaeiae eiai aiaeia?a
a?aeaaaeaiee /aoaa?oee ?icae?e ?iaioe.

INIIAIEE CI?NO AeENA?OAOe??

?. Oa?iiaeaeo?e/i? aeanoeaino? iiiie?enoae?/ieo ? iie?e?enoae?/ieo
ie?aie oaeo?eaeo naeioeth. Aeine?aeaeaii caeaaei?noue oa?iiaeaeo?e/ieo
ia?aiao??a oiieeo ie?aie n-PbTe, inaaeaeaieo ia neiee (111)
iiiie?enoae?a BaF2 ? aii?oio iie?ai?aeio no??/eo II-1 o iaoiae? aa?y/i?
no?iee a?ae oaoiieia?/ieo oaeoi??a: oaiia?aoo?e aeia?iaoaaiiy (OA),
no?iie eaia?e (ON) oa inaaeaeaiiy (OI). Ia?aiao?aie iioei?caoe?? aea?aii
eiao?oe??io oa?ii-a.?.n. (), ieoiia aeaeo?ii?ia?aei?noue (),
oa?iiaeaeo?e/ia aeia?ioi?noue (Z=2/, aea eiao?oe??io
oaieii?ia?aeiino?). Iieacaii, ui oe? caeaaeiino? iathoue aeaeyae
iie?iii?a ae?oaiai ii?yaeeo. Oae, cie?aia, aeey ie?aie:

PbTe/(111)BaF2

Z, K-1=-3,409·10-3+0,117·10-4·OI-0,059·10-4·OA+0,077·10-4·ON-1,524x

x10-9·OI·OA-1,168·10-8·OI·ON+1,085·10-8·OA·ON-1,964·10-10·OI2- (1)

-1,977·10-9·OA2-0,565·10-8·ON2.

PbTe/II-1

Z, E-1=-0,515+0,872·10-5·OI+5,393·10-4·OA+7,647·10-4·ON+0,063x

x10-5·OI·OA+0,033·10-5·OI·ON-0,026·10-5·OA·ON- (2)

-0,084·10-5·OI2-0,041·10-5·OA2-0,043·10-5·ON2.

?en. 1. Caeaaei?noue oa?iiaeaeo?e/ii? aeia?ioiino? Z ie?aie
n-PbTe/(111)BaF2 (a) ? n-PbTe/II-1 (a) a?ae oaiia?aoo? inaaeaeaiiy OI oa
no?iie eaia?e ON o iaoiae? aa?y/i? no?iee (oaiia?aoo?a aeia?iaoaaiiy
OA, E: 818 (a), 759 (a)).

Oaaeeoey 1.

Iioeiaeuei? cia/aiiy oa?iiaeaeo?e/ieo ia?aiao??a oa oaoiieia?/ieo
oaeoi??a iiiie?enoae?/ieo oa iie?e?enoae?/ieo ie?aie n-PbTe, ae?iuaieo c
ia?iai? oace iaoiaeii aa?y/i? no?iee

Ia?aiao?e

iioei?caoe??Iioeiaeuei? cia/aiiyAenia?eiai-oaeuei?

cia/aiiyOaeoi?eIa?aiao?eOI, EOA, EON,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(111)BaF2,
ieA·E-1473818953145152, Ii-1·ni-14738189734174102,
Ao·E-2·ni-14738189731,9·10-51,7·10-5Z,
E-14738189730,7·10-30,6·10-3PbTe/II-1, ieA·E-1453759843314321,
Ii-1·ni-14537598334374152, Ao·E-2·ni-14537598234,4·10-54,3·10-5Z,
E-14537598233,6·10-33,7·10-3

A?ao?/ia i?aaenoaaeaiiy aiae?oe/ieo caeaaeiinoae (1), (2) cia?aaeaii ia
?en. 1. A oaaeeoe? iaaaaeaii ciaeaeai? oaoiieia?/i? oaeoi?e, i?e yeeo
ie?aee PbTe iathoue iaeneiaeuei? oa?iiaeaeo?e/i? ia?aiao?e.

I?e/eiith cia/ii a?eueoeo cia/aiue eiao?oe??ioa oa?ii-a.?.n. () oa
oa?iiaeaeo?e/ii? aeia?ioiino? (Z), iie?e?enoae?/ieo ie?aie PbTe ia II-1,
ii??aiyii c iiiie?enoae?/ieie ia BaF2 (?en. 1, oaae. 1), ? nooi?iue
no?oeoo?ii? caaa?oaiino? eiiaeainaoo. Ae??aiiaeenia?niee iaoa??ae, o
aeiaaeeo inaaeaeaiiy ia aii?oio i?aeeeaaeeo II-1, oa?aeoa?eco?oueny
neeueii ?icaeiooith i?aeca?aiiith no?oeoo?ith ? ooai?aiiyi
iioaioe?aeueieo aa?’???a. Oea i?eaiaeeoue aei c?inoaiiy eiao?oe??ioa
oa?ii-a.?.n. () oa ciaioaiiy a?aoeiai? oaieii?ia?aeiino? (a) /a?ac
cia/ia ?icn?thaaiiy oiiii?a ia no?oeoo?ieo aeaoaeoao.

??. Oa?iiaeaeo?e/i? aeanoeaino? oiieeo ? oianoeo ie?aie oaeo?eaeo
naeioeth. Aea/aii iniaeeaino? oa?iiaeaeo?e/ieo ia?aiao??a oiieeo
(oiaueia 0,05-0,5 iei) ? oianoeo (oiaueia 1,0-10 iei) ie?aie n-PbTe.
Iieacaii, ui aeey oiieeo ie?aie a iaeano? iecueeeo oaiia?aoo? 80-200 E
eiioeaio?aoe?y iin??a ciaioo?oueny c ?inoii oaiia?aoo?e. I?e
iiaeaeueoiio i?aeaeuaii? oaiia?aoo?e eiioeaio?aoe?y, ye ? a oianoeo

?en. 2. Caeaaei?noue i?eiaeo cia/aiue oa?iiaeaeo?e/ieo ia?aiao??a oiieeo
ie?aie PbTe a?ae oiaueie.

ie?aeao, c?inoa?. Oaiia?aoo?i? caeaaeiino? ?ioeo oa?iiaeaeo?e/ieo
ia?aiao??a oiieeo ? oianoeo ie?aie iiae?ai? i?ae niaith: ?ooeea?noue
iin??a no?oio o anueiio ?ioa?aae? ia? /?oei ae?aaeaio oaiaeaioe?th aei
niaaeaiiy; ieoiia aeaeo?ii?ia?aei?noue ciaioo?oueny; ?io?
oa?iiaeaeo?e/i? ia?aiao?e 2, Z, ZT c oaiia?aoo?ith iathoue yaii
ae?aaeaiee iaeneioi (200 E). I?e oeueiio ca?eueoaiiy oiaueie oiieeo
ie?aie i?eaiaeeoue aei c?inoaiiy oa?iiaeaeo?e/ieo ia?aiao??a i?e 200 E o
2-2,5 ?ace (?en. 2). Aeey oianoeo ie?aie anoaiiaeaii eiioeaio?aoe?eio
caeaaei?noue i?eiaeo cia/aiue oa?iiaeaeo?e/ieo ia?aiao??a. Aiie iathoue
iaeneioi aeey eiioeaio?aoe?? aeaeo?ii?a (1-3)·1017 ni-3 (?en. 3).

?en. 3. Caeaaei?noue i?eiaeo cia/aiue oa?iiaeaeo?e/ieo ia?aiao??a
oianoeo ie?aie PbTe a?ae eiioeaio?aoe?? iin??a.

Caoaaaeeii, ui iaeneiaeuei? cia/aiiy oa?iiaeaeo?e/ieo ia?aiao??a oiieeo
ie?aie (?en. 2) i?eaeecii o aeaa ?ace a?eueo? ca oe? ae cia/aiiy aeey
oianoeo (?en. 3). Inoaii? iia’ycaii ?c ??ciei iaoai?ciii ?icn?thaaiiy
iin??a. ?ic?aooiie iieacaa, ui aeey oiieeo ie?aie ia?aaaaea?
?icn?thaaiiy aeaeo?ii?a ia iiaa?oiyo ie?aee, oiio aeiaaeeia a?eueiiai
i?ia?ao iin??a aecia/a?oueny ?? oiaueiith ? ia caeaaeeoue a?ae aia?a??
iin??a. O ca’yceo ?c oeei ieoiia aeaeo?ii?ia?aei?noue oiieeo ie?aie ia
ii?yaeie a?eueoa, i?ae aeey oianoeo, ui ? iaoiiaeth? iii?oia c?inoaiiy
?o oa?iiaeaeo?e/ii? aeia?ioiino?.

???. Aieea a?aeiaeo o aaeooi? ia oa?iiaeaeo?e/i? aeanoeaino? ie?aie
oaeo?eaeo naeioeth. Oa?i?/iee ?cio?iiiee a?aeiae ie?aie ?-PbTe o aaeooi?
ia ii/aoeiaiio aoai? aaaea aei nooo?aeo ci?i oa?iiaeaeo?e/ieo ia?aiao??a
(oaae. 2). Oae, cie?aia, iathoue i?noea ciaioaiiy eiioeaio?aoe?? ae??ie
oa ieoiii? aeaeo?ii?ia?aeiino?, c?inoaiiy eiao?oe??ioa oa?ii-a.?.n. oa
?ooeeaino?, a oaeiae 2, Z oa ZT (oaae. 2). I?e oeueiio ne?ae a?aei?oeoe
aea? iniaeeaino?: aaeee? cia/aiiy eiao?oe??ioa oa?ii-a.?.n. ie?aie
p-PbTe, a?aeiaeaieo i?e 500 E; ci?ia ciaeo i?ia?aeiino? c ?- ia n-oei
i?e oaiia?aoo?? a?aeiaeo 600 E (oaae.2).

Ciaioaiiy eiioeaio?aoe?? ae??ie ia ii/aoeiaeo aoaiao a?aeiaeo ie?aie o
aaeooi? iia’ycaia ?c ca?aeiaiiyi i?eiiaa?oiaaiai oa?o oaeueeiaaiii,
aaeain?? yeiai o e?enoae?/i?e a?aooe? PbTe ? aeaeo?e/ii aeoeaieie ?
aaia?othoue a?euei? aeaeo?iie. Oea ? aaaea aei ciaioaiiy eiioeaio?aoe??
ae??ie (oaae. 2): ooai?aiiy ia iiaa?oi? ?iaa?nii? iaeano? n-oeio. C
i?aeaeuaiiyi oaiia?aoo?e /e /ano a?aeiaeo iathoue i?noea i?ioeane
aia?iiey?ii? aeeooc?? aaeain?e oaeo?o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 ? aeaeo?ii?a (a-) aaeea ie?aie ?
ooai?aiiy aeaioa?iai? ?-n-no?oeoo?e. A?aeiae ie?aie i?e 600 E ia i?ioyc?
aiaeeie i?eaiaeeoue aei ia?aoai?aiiy ie?aee ?-oeio a aeaeo?iiio (oaae.
2). Cia/ia c?inoaiiy eiao?oe??ioa oa?ii-a.?.n. ia ii/aoeiaeo aoaiao
a?aeiaeo iaoiiaeaia ia?aaaaeaiiyi i?ioean?a aaeni?aoe?? eenith, yeee
caaaeaee ? o nenoai?, ? oi?ioaaiiyi iioaioe?aeueieo aa?’???a.

Oaaeeoey 2

Oa?iiaeaeo?e/i? ia?aiao?e ie?aie ?-PbTe i?e 200 E: na?aeiae?iuaieo oa
a?aeiaeaieo o aaeooi? ia i?ioyc? 1 aiae.

Ia?aiao?e

ie?aieNa?aei-ae?iuai? (p)A?aeiaeai?

I?e 500 E (p)A?aeiaeai?

I?e 600 E (n)n(p), 1018 ni-31,61,040,17, ni2·A-1·n-1117252975,
Ii-1·ni-1304225, ieA·E-1215770-1352, 10-5 Ao·E-2·ni-10,140,250,04Z, 10-4
K-10,370,670,12ZT, 10-20,751,340,25

IV. Aieea eenith ia oa?iiaeaeo?e/i? aeanoeaino? ie?aie oaeo?eaeo
naeioeth. Aaaeeeaei oaeoi?ii, ui aieeaa? ia eiiieaen oa?iiaeaeo?e/ieo
aeanoeainoae ie?aie, ? aaeni?aoe?y aoiinoa?iiai eenith ?o iiaa?oiath.
Anoaiiaeaii, ui a ie?aieo aeiaaeeao eenaiue cia/ii iie?auo? oa?ii-a.?.n.
ie?aie oaeo?eaeo naeioeth. Aeey iiyniaiiy oeueiai yaeua i?iiiio?oueny
iiaeaeue ?icn?thaaiiy iin??a ia iioaioe?aeueieo aa?’??ao. Aiane?aeie
naeaeoeaiiai ?icn?thaaiiy ia aa?’??ao, aeaeo?iie c aia?a??th iaioith ca
aia?a?th Oa?i? ia i?eeiathoue o/ano? a yaeuao ia?aiino.
Aenieiaia?aaoe/i? iin?? caa??aathoue aeiaaeeio a?eueiiai i?ia?ao oaeo
ae, ye o aacaeaoaeoiiio e?enoae?, oiaoi i?ioiaeyoue /a?ac aa?’??e. I?e
oeueiio ieoiia aeaeo?ii?ia?aei?noue () aeaui ciaioo?oueny, a eiao?oe??io
oa?ii-a.?.n. () iiaeiai c?inoaoe. Ine?eueee oa?iiaeaeo?e/ia
aeia?ioi?noue i?iii?oe?eia eaaae?aoo oa?ii-a.?.n. (Z=2/, aea —
eiao?oe??io oaieii?ia?aeiino?), oi ne?ae /aeaoe cia/iiai iie?auaiiy
oa?iiaeaeo?e/ieo oa?aeoa?enoee iaoa??aeo. Iioei?ci oaeiai i?aeoiaeo
i?aeneeth?oueny ua ? oei, ui aa?’??i? no?oeoo?e ?ioaineaii
ooai?ththoueny a aeenia?nieo ie?aeao, ui aaaea aei ciaioaiiy ua e
eiao?oe??ioa oaieii?ia?aeiino?.

Ae?enii, i?e aeo?eioe? ie?aie n-PbTe a aoiinoa?? eenith ?c ca?eueoaiiyi
eiai oeneo ieoiia aeaeo?ii?ia?aei?noue nii/aoeo ciaioo?oueny, a
oa?ii-a.?.n. c?inoa? (?en. 4). Iio?i oa?ii-a.?.n. ci?ith? na?e ciae,
aeinyaa? iaeneioio ? i?e ci?i? oeneo I2 niaaea? iaeaea aei aoiinoa?iiai
(?en. 4). Caoaaaeeii, ui eiao?oe??io oa?ii-a.?.n. aeo?eiaieo o eenith
ie?aie n-PbTe aiiiaeueii aaeeeee ? aeinyaa? iiiaae 103 ieA·E-1 (?en. 4).
Oa?iiaeaeo?e/ia iiooaei?noue 2, iath/e iaeneioie i?e 0,1 Ia ? 1,1 Ia,
caaaeii ciaioo?oueny (?en. 4).

?en. 4. Caeaaei?noue oa?iiaeaeo?e/ieo ia?aiao??a ie?aie PbTe a?ae oeneo
eenith.

O i?ioean? a?aeiaeo “ieeneaieo” ie?aie o aaeooi? ia? i?noea c?inoaiiy
eiioeaio?aoe?? aeaeo?ii?a ? ?o ?ooeeaino?. Ieoiia aeaeo?ii?ia?aei?noue,
ye ? oa?iiaeaeo?e/ia iiooaei?noue, i?e oeueiio c?inoathoue. Eiao?oe??io
oa?ii-a.?.n. i?ney ii/aoeiaiai aeayeiai c?inoaiiy ia?aaaaeii
ciaioo?oueny.

Aenia?eiaioaeuei? ?acoeueoaoe iiaeia iiynieoe, aa?o/e aei oaaae oa, ui
eenaiue ae?? ye aeii?oea, ca’ycoth/e ia iiaa?oi? a?euei? oa aaeaioi?
aeaeo?iie c ia’?io c?acea. I?e oeueiio an? aia?aaoe/i? ??ai?
iai?ai?ia?aeieea aee?eaeythoueny oaeei /eiii, ui ??aaiue Oa?i?
iaaeeaea?oueny aei aaeaioii? ciie ? a?ey a?eueii? iiaa?oi? ooai?th?oueny
iaeanoue i?inoi?iaiai ca?yaeo, ca?aeiaia aeaeo?iiaie. E??i oiai,
aiane?aeie neeueii ?icaeiooi? o ie?aeao iica?/ii? no?oeoo?e a iaeano?
a?aieoeue ca?ai ooai?ththoueny iioaioe?aeuei? aa?’??e, ye? oaeiae
ci?iththoue aia?aaoeeo iiaa?oi?, naeaeoeaii aieeaath/e ia iin?? ca?yaeo.
A?aecia/ai? iiaeae? aeathoue iiaeeea?noue e?euee?nii ioe?ieoe ci?ie
oa?iiaeaeo?e/ieo ia?aiao??a iai?ai?ia?aeieeiaiai iaoa??aeo i?e
aaeni?aoe?? eiai iiaa?oiath eenith ? aeia?a iiyniththoue
aenia?eiaioaeuei? ?acoeueoaoe (?en. 4).

Caoaaaeeii, ui aaeee? cia/aiiy eiao?oe??ioa oa?ii-a.?.n. a ie?aeao
n-PbTe, iaea?aeai? i?e ?o aeo?eioe? a eeni?, i?eaiaeyoue ? aei
ca?eueoaiiy ?o oa?iiaeaeo?e/ii? iiooaeiino?: ~ 20·10-5 Ao·E-2·ni-1 a
ii??aiyii? c (0,5-1,5)·10-5 Ao·E-2·ni-1 aeey iaieeneaieo ie?aie.

V. ?aae?aoe?eia ii?ii?iaiiy ie?aie PbTe oa ?o oa?iiaeaeo?e/i? ia?aiao?e.
Aeoeai? aeaiaioe ia iniia? oiieeo ie?aie PbTe ooieoe?iiothoue o ciiao
aeoeaii? ?aae?aoe??. O ca’yceo ?c oeei iaaiee ?ioa?an iathoue
aeine?aeaeaiiy aieeao ?ii?coth/iai aei?ii?ithaaiiy ia aeanoeaino? ?o
aeoeaieo a?oie.

Iaie aea/aii aieea aaiia-aei?ii?ithaaiiy ia oa?iiaeaeo?e/i? ia?aiao?e
ie?aie PbTe, inaaeaeaieo ia iie?ai?aeio no??/eo II-1.

Ie?aee i?aeaeaaaeeny ii?ii?iaiith o aaeooi? ? ia iia?o?? aaiia-eaaioaie
?c aia?a??th 1,25 IaA a?ae aeaea?aea Ni60, ?ioaineai?noue yeeo a eaiae?
noaiiaeea 103 ?·n-1. Aeice ii?ii?iaiiy aeiaiaeeeeny aei 2·108 ?.

?acoeueoaoe aeine?aeaeaiue aeiciaeo caeaaeiinoae oa?iiaeaeo?e/ieo
ia?aiao??a oiieeo ie?aie PbTe iaaaaeai? a oaaeeoe? 3. Ne?ae caa?iooe
oaaao ia nooo?ao a?aei?ii?noue o ci?i? ieoiii? aeaeo?ii?ia?aeiino? ?
eiao?oe??ioa oa?ii-a.?.n. ie?aie i?e ii?ii?iaii? o aaeooi? ? a
aoiinoa?? eenith. Oae, yeui ii?ii?iaiiy ie?aie aaiia-eaaioaie o aaeooi?
i?eaiaeeoue aei c?inoaiiy ? ciaioaiiy , oi ?aae?aoe?eia ia?iaea ie?aie
ia iia?o?? aaaea aei i?ioeeaaeieo ci?i ciaioaiiy ? c?inoaiiy . sseui
i?e oeueiio oa?iiaeaeo?e/ia iiooaei?noue ? aeia?ioi?noue o ia?oiio
aeiaaeeo aeaui ciaioo?oueny, oi ii?ii?iaiiy ? a?aeiae ia iia?o??
i?eaiaeyoue aei ?o c?inoaiiy (oaae. 3).

Aeiciao caeaaei?noue aeaeo?e/ieo ia?aiao??a ie?aie, ii?ii?iaieo o
aaeooi?, iiaeia iiynieoe aaia?aoe?eii-?aeiia?iaoe?eiei iaoai?ciii
ooai?aiiy aeaoaeo?a o aeaeyae? ia? O?aieaey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,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. O aeiaaeeo
ianeiiiainiaaieo c?ace?a n-oeio, ui ia?ii ia aeine?ae?, ci?ia
eiioeaio?aoe?? aeaeo?ii?a iia’ycaia ?c ooai?aiiyi iiceoeaii ca?yaeaeaieo
aaeain?e oaeo?o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 oa i?aeaoceiaeo aoii?a naeioeth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, ye? ?
aeiii?aie. Inoaii? ? aaaea aei c?inoaiiy ieoiii? aeaeo?ii?ia?aeiino?, ui
? niinoa??aa?oueny a aenia?eiaio? (oaae. 3).

I?e ii?ii?iaii? ie?aie aaiia-eaaioaie ia iia?o?? ii?yae ?c ooai?aiiyi
?aae?aoe?eieo aeaoaeo?a ia? i?noea ??no iioaioe?aeueieo aa?’???a ia
a?aieoeyo ca?ai ca ?aooiie ?aae?aoe?eii noeioeueiaaii? ? oa?i?/ii?
aeeooc?? eenith. A?aeiii, ui aaeni?aiaaiee ia iiaa?oi? ie?aie eenaiue
aeeooiaeo? a ?o ia’?i ii a?aieoeyo ca?ai iaa?oue i?e cae/aei?e aeo?eioe?
ia iia?o??. Oae ye o i?ioean? aaiia-ii?ii?iaiiy ie?aee iaa??aathoueny
aei 340-350 E, oi ?ioaineai?noue aeeooc?? c?inoa?. I?enei?aiith aeeooc??
aaea i?iieeeiai o i?eiiaa?oiaaee oa? a?aieoeue ca?ai eenith ni?eythoue
?aae?aoe?eii noeioeueiaai? i?ioeane. Eieae?caoe?y eenith ia a?aieoeyo
ca?ai iaoiiaeth? ye aeoeaioi?io ae?th, ui aaaea aei ciaioaiiy
eiioeaio?aoe?? iniiaieo iin??a, oae ? ooai?aiiy aia?aaoe/ieo
iioaioe?aeueieo aa?’???a, ye? ciaioothoue ?ooeea?noue iin??a ca?yaeo.
?ioith i?e/eiith ciaioaiiy eiioeaio?aoe?? aeaeo?ii?a iiaea aooe
?aae?aoe?eii-noeioeueiaaia aeeooc?y iaaeeeoeiaiai naeioeth c ia’?io
e?enoae?a ia iiaa?oith ie?aie aai a?aieoe? ca?ai. An? oe? aoaeoe ?
i?eaiaeyoue aei ciaioaiiy ieoiii? aeaeo?ii?ia?aeiino? ie?aie i?e
-ii?ii?iaii? ia iia?o?? (oaae. 3).

Oaaeeoey 3

Oa?iiaeaeo?e/i? aeanoeaino? ie?aie n-PbTe i?e ii?ii?iaii? -eaaioaie oa
a?aeiae? ia iia?o??.

Oa?iiaeaeo?e/i? ia?aiao?en, 1017

ni-3, 103

ni2·A-1·n-1,

Ii-1·ni-1,

ieA·E-12, 10-5

Ao·E-2·ni-1Z, 10-3 E-1Aeae ia?iaeeIi/aoeiaee8,22,42954054,841,15I?ney
ii?ii?iaiiy o aaeooi? (5·107 ?)

10,3

3,5

328

360

4,25

1,01I?ney ii?ii?iaiiy ia iia?o?? (5·107 ?)

5,1

0,9

240

532

6,79

1,62I?ney oa?i?/iiai a?aeiaeo ia iia?o?? (350 E, 14 aiae.)

6,8

1,2

274

490

6,58

1,57

I?aeoaa?aeaeaiiyi ?aaeueiino? oeeo i?ioean?a ? aiaeia?/ia ci?ia
aeaeo?e/ieo ia?aiao??a ie?aie i?e ?o oa?iia?aeiae? ia iia?o?? (oaae. 3).

INIIAI? ?ACOEUeOAOE AeENA?OAOe?EII? ?IAIOE

1. Aeine?aeaeaii caeaaei?noue oa?iiaeaeo?e/ieo ia?aiao??a oiieeo ie?aie
PbTe, inaaeaeaieo ia neiee (111) e?enoae?a BaF2 ? aii?oio iie?ai?aeio
no??/eo II-1 o iaoiae? aa?y/i? no?iee a?ae oaoiieia?/ieo oaeoi??a.
Anoaiiaeaii, ui aeey ae??aiiaeenia?niiai iaoa??aeo (PbTe/II-1),
aiane?aeie c?inoaiiy eiao?oe??ioa oa?ii-a.?.n. () ? ciaioaiiy a?aoeiai?
oaieii?ia?aeiino? (A), ia? i?noea cia/ia iie?auaiiy (a?eueo ye o 6 ?ac?a
o ii??aiyii? c PbTe/(111) BaF2) oa?iiaeaeo?e/ii? aeia?ioiino? (Z).

2. Ia iniia? aea/aiiy oaiia?aoo?ieo caeaaeiinoae oa?iiaeaeo?e/ieo
aeanoeainoae ie?aie n-PbTe anoaiiaeaii, ui iaeneiaeuei? cia/aiiy
oa?iiaeaeo?e/ii? iiooaeiino? (2) oa aeia?ioiino? (Z, ZT) i?eiaaeathoue
ia 200 E. Ca?eueoaiiy oiaueie oiieeo ie?aie a ?ioa?aae? 0,05-0,5 iei
i?eaiaeeoue aei c?inoaiiy oa?iiaeaeo?e/ieo ia?aiao??a i?e 200 E o 2-2,5
?ac?a. Iaeneioi i?eiaeo cia/aiue oa?iiaeaeo?e/ieo ia?aiao??a (2, Z, ZT)
oianoeo ie?aie (1,0-10 iei) i?e 200 E i?eiaaea? ia ?ioa?aae
eiioeaio?aoe?e (1-3)·1017 ni-3.

3. Aenie? cia/aiiy oa?ii-a.?.n. oa iie?auaiiy oa?iiaeaeo?e/ii?
aeia?ioiino? i?e ?cio?iiiiio a?aeiae? o aaeooi? ie?aie ?-PbTe iiyniaii
aia?iiey?iith aeeooc??th iiceoeaii ca?yaeaeaieo aaeain?e oaeo?o ?
aeaeo?ii?a aaeea ie?aie oa ooai?aiiyi aeaioa?iai? ?-n-no?oeoo?e.

4. I?iaaaeaii aenia?eiaioaeueia aeine?aeaeaiiy aieeao eenith ia
oa?iiaeaeo?e/i? aeanoeaino? oiieeo ie?aie PbTe n-oeio. Iieacaii, ui
aaeni?aoe?y iiaa?oiath ie?aie eenith ? ooai?aiiy iioaioe?aeueieo
aa?’???a ia a?aieoe? ca?ai aaaeooue aei aiiiaeueii aenieeo cia/aiue
oa?ii-a.?.n. oa c?inoaiiy oa?iiaeaeo?e/ii? iiooaeiino?.

5. Aaiia-ii?ii?iaiiy ie?aie n-PbTe, inaaeaeaieo ia II-1, aaaea aei
ciaioaiiy ieoiii? aeaeo?ii?ia?aeiino?, c?inoaiiy eiao?oe??ioa
oa?ii-a.?.n. ? c?inoaiiy oa?iiaeaeo?e/ieo ia?aiao??a. Oaea ci?ia
aeanoeainoae iia’ycaia ?c ciaioaiiyi oiee?anueei? eiioeaio?aoe?? ?
?ooeeaino? aeaeo?ii?a ca ?aooiie i?iieeiaiiy eenith ia a?aieoeyo ca?ai.
?ioaineai?noue i?iieeiaiiy eenith ia a?aieoeyo ca?ai aecia/a?oueny ye
iaa??aaiiyi c?ace?a aei 330-360 E i?e ii?ii?iaii?, ui ni?ey?
oa?iiaeeooc??, oae ? i?enei?aiiyi aeeooc?? aaea i?iieeeiai a
i?eiiaa?oiaaee oa? eenith ca aeiiiiiaith ?aae?aoe?eii-noeioeueiaaieo
i?ioean?a.

6. Aenia?eiaioaeuei? ?acoeueoaoe aeine?aeaeaiiy oaiia?aoo?ieo
caeaaeiinoae oa?iiaeaeo?e/ieo aeanoeainoae e?enoae?a PbTe n-? ?-oeio
i?ia?aeiino? iiyniaii c a?aooaaiiyi neeaaeii? aoaeiae aaeaioii? ciie ?
?icn?thaaiiy iin??a ia ?ii?ciaaieo oeaio?ao oa aeonoe/ieo eieeaaiiyo.
Aecia/aii ?ioa?aaee oaiia?aoo?, aeey yeeo iaoa??ae ia? iioeiaeuei?
cia/aiiy oa?iiaeaeo?e/ii? aeia?ioiino?. Cie?aia anoaiiaeaii, ui yeui a
iaeano? iecueeeo oaiia?aoo? 10-100 E iniiai? oa?iiaeaeo?e/i? ia?aiao?e
(2, Z, ZT) caaaeii c?inoathoue o anueiio aeine?aeaeoaaiiio ?ioa?aae?, oi
aeey oaiia?aoo? 100-500 E 2 ? Z ??cei ciaioothoueny, a aac?ici??ia
oa?iiaeaeo?e/ia aeia?ioi?noue ZT ia? oa?aeoa?iee iaeneioi. Aeey
e?enoae?a PbTe ?-oeio a?i ciaoiaeeoueny a iaeano? 200-300 E ? neeaaea?
(ZT)max=0,18, a aeey n-PbTe (ZT)max=0,25 i?e oaiia?aoo?ao 200-400 E.

7. I?aeoaa?aeaeaii, ui aeey oaa?aeiai ?ic/eio (Pb0,8Sn0,2)1-X?nXTe
(0,02o0,15) eiao?oe??io oa?ii-a.?.n. i?e oaiia?aoo?ao aeueo ca 250 E
a?ae’?iiee. I?e oaiia?aoo?ao ieae/eo a?ae 250 E e?enoaee neeaae?a
0,02o0,05 oa?aeoa?ecothoueny iaaaoeaiei cia/aiiyi oa?ii-a.?.n., a i?e
o0,05 iiceoeaiei. Iaeneiaeueiiai cia/aiiy oa?iiaeaeo?e/ia iiooaei?noue
aeinyaa? aeey neeaaeo o=0,02. Iieacaii, ui nooo?ao ?ieue o yaeuao
ia?aiino a?ae?a?athoue aeaeo?iie aeii?oeiai? ciie ?iae?th, aia?aaoe/ii
a?aeae?eaii? a?ae ciie i?ia?aeiino?. Iiaeaeueoa c?inoaiiy eiioeaio?aoe??
?iae?th i?eaiaeeoue aei ??ceiai niaaeaiiy oa?iiaeaeo?e/ieo
oa?aeoa?enoee.

8. Anoaiiaeaii, ui aeiaeaoeiaa eaaoaaiiy eiaeii aei 0,1-0,3 ao. %
e?enoae?a PbTe:In c iaeei ai?noii In (0,001-0,002 ao. %) i?eaiaeeoue aei
c?inoaiiy ?o oa?iiaeaeo?e/ieo ia?aiao??a, ui iia’ycaii ?c c?inoaiiyi
oiee?anueei? eiioeaio?aoe?? iin??a ? ieoiii? aeaeo?ii?ia?aeiino?.
Iiaeaeueoa ca?eueoaiiy ai?noo In ? I ia aaaeaia, ine?eueee neeueii
niaaea? oa?ii-a.?.n. ? iia?eueii c?inoa? aeaeo?ii?ia?aei?noue, ui a
naith /a?ao aaaea aei iecueeeo cia/aiue 2, Z ? ZT.

9. Ia iniia? aeine?aeaeaiiy aeanoeainoae /ioe?eeiiiiiaioiiai oaa?aeiai
?ic/eio Pb1-XSnXTe1-YSeY iieacaii, ui e?enoaee neeaaeo o=0,10, y=0,97
iathoue iaea?eueoa cia/aiiy oa?iiaeaeo?e/ii? iiooaeiino? 2 oa
oa?iiaeaeo?e/ii? aeia?ioiino? Z a iaeano? oaiia?aoo? 77-300 E.

NIENIE AEEI?ENOAIEO AeAEA?AE

1. Eiooa A.O. Iieoi?iaiaeieeiaua oa?iiyeaiaiou. –I.-E.: AI NNN?. –1960.
–346 n.

2. Aiaoe/oe E.E. Oa?iiyeaiaiou e oa?iiyeaeo?e/aneea ono?ienoaa:
Ni?aai/iee. Eeaa: Iaoe. aeoiea. –1979. –768 n.

3. Aa?eeinia I.O., Oaeeiiaa E.A. Iieoi?iaiaeieeiaua iaoa?eaeu ia iniiaa
niaaeeiaiee AIVBVI. –I.: Iaoea. –1975. –194 n.

4. ?aae/ TH.I., Aoeiiaa A.A., Nie?iia I.A. Iaoiaeu enneaaeiaaiey
iieoi?iaiaeieeia a i?eiaiaiee e oaeueeiaaieaeai naeioea PbTe, PbSe, PbS.
–I.: Iaoea. –1968. –384 n.

5. Aoeao E.I., Caei?aeiiaoe A.N. I?aaeaeueiay oa?iiaeaeo?e/aneay
aeia?ioiinoue iieoi?iaiaeieeiauo e?enoaeee/aneeo iaoa?eaeia// Oeceea e
oaoieea iieoi?iaiaeieeia. –1995. –O. 29. –Aui. 10. –N. 1743-1749.

6. Eeaei?aiei I.N. Ie?ii/iua oa?iiyeaiaiou: Oeceea e i?eiaiaiea. –I.:
Iaoea. –1985. –232 n.

NIENIE IIOAE?EIAAIEO I?AOeUe

1. D.M.Freik, A.V. Lisak, V.M. Chobanyuk, R.I.Zapukhlyak. The influence
of isochronous annealing of p-PbTe thin films in vacuum on their
thermoelectric properties// Journal of Thermoelectricity. –1999. –? 2.
–?. 69-75.

2. Ae.I. O?a?e, ?.?. Caiooeye, I.A. Eaeeithe, E.E. Iaaeeeianueea. Aieea
oiaueie ie?aie PbTe ia ?o oa?iiaeaeo?e/i? ia?aiao?e// Iioiaeaeo?ii?ea ?
iai?ai?ia?aeieeiaa oaoi?ea. –1999. -? 34. –N. 133-137.

3. Ae.I. O?aee, A.A. I?ieiiea, ?.E. Caiooeye, A.Ae. Iaoaee, A.I.
Iaeueiee. Nianoaaiiua aoiiiua aeaoaeou a oiieeo neiyo PbTe au?auaiiiuo
ec ia?iaie oacu// Iai?aaie/aneea iaoa?eaeu. –1998. –O. 34. -? 1. –N.
31-33.

4. Ae.I. O?a?e, A.A. Oaiaothe, ?.?. Caiooeye, I.A. Eii’yiei.
Iioei?caoe?y oa?iiaeaeo?e/ieo aeanoeainoae oiieeo ie?aie PbSe ia
iie?ai?ae?// Iioiaeaeo?ii?ea ? iai?ai?ia?aeieeiaa oaoi?ea. –1997. -? 32.
–N. 99-102.

5. E.E. Iaaeeeianueea, A.A. Eenae, ?.?. Caiooeye, A.Ae. Iaoa?e, ?.ss.
Ieoaeeueiiea. Iaoaiaoe/ia iiaeaethaaiiy aieeao oaoiieia?/ieo oaeoi??a
ae?iuoaaiiy ? neeaaeo ia aeaeo?e/i? aeanoeaino? oiieeo ie?aie oaa?aeeo
?ic/ei?a AIVBVI// A?niee I?eea?iaonueeiai oi?aa?neoaoo. Iaoaiaoeea.
O?ceea. O?i?y. –1999. –Aei. 1. –N. 113-125.

6. ?.?. Caiooeye. Aieea ?aae?aoe?eiiai ii?ii?iaiiy ia oa?iiaeaeo?e/i?
aeanoeaino? oiieeo ie?aie PbTe// A?niee I?eea?iaonueeiai oi?aa?neoaoo.
Iaoaiaoeea. O?ceea. O?i?y. –1999. –Aei. ??. –N. 70-74.

7. ?.?. Caiooeye. O?ce/i? iniiae oa?iiaeaeo?e/ieo yaeu o e?enoaeao
PbTe// O?ceea ? o?i?y oaa?aeeo o?e. A?niee ?aaii-O?aie?anueeiai
e?aeiaiai a?aeae?eaiiy Oe?a?inueeiai o?ce/iiai oiaa?enoaa oa
I?eea?iaonueeiai oi?aa?neoaoo. –1999. -? 7. –N. 25-53.

8. E.E. Iaaeeeianueea, A.A. I?ieii?a, ?.E. Ia?eaothe, ?.?. Caiooeye,
I.?. Iaaea/ei. Aieea eenith ia oa?iiaeaeo?e/i? aeanoeaino? oiieeo ie?aie
oaeo?eaeo naeioeth// O?ceea ? o?i?y oaa?aeeo o?e. A?niee
?aaii-O?aie?anueeiai e?aeiaiai a?aeae?eaiiy Oe?a?inueeiai o?ce/iiai
oiaa?enoaa oa I?eea?iaonueeiai oi?aa?neoaoo. –1999. -? 7. –N. 94-101.

9. O?a?e Ae.I., Aa?oaaa N.N., Caiooeye ?.?. Niin?a io?eiaiiy oaa?aeiai
?ic/eio PbTe-SnTe. Cayaea ? 98105777 ia aeaea/o iaoaioa Oe?a?ie a?ae
30.10.1998.

10. O?a?e Ae.I., Aa?oaaa N.N., Caiooeye ?.?. Niin?a io?eiaiiy
/ioe?eeiiiiiaioiiai oaa?aeiai ?ic/eio ia iniia? niieoe AIVBVI. Cayaea ?
98105775 ia aeaea/o iaoaioa Oe?a?ie a?ae 30.10.1998.

11. Caiooeye ?.?. Oa?iiaeaeo?e/i? aeanoeaino? oiieeo ie?aie oaeo?eaeo
naeioeth ia iie?ai?ae?. –A ei.: O?ceea ? oaoiieia?y oiieeo ie?aie. *. 1.
Oace aeii. VI I?aeia?iaeii? eiioa?aioe??. ?aaii-O?aie?anuee. –1997.
–N.49.

12. Caiooeye ?.?. Iniaeeaino? oa?iiaeaeo?e/ieo aeanoeainoae oiieeo
ie?aie oaeo?eaeo naeioeth. –A ei.: O?ceea ? oaoiieia?y oiieeo ie?aie.
Oace aeii. VI? I?aeia?iaeii? eiioa?aioe??. ?aaii-O?aie?anuee. –1999. –N.
142.

Caiooeye ?.?. Iniaeeaino? oa?iiaeaeo?e/ieo aeanoeainoae ie?aie PbTe oa
eiai aiaeia?a. –?oeiien.

Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa
o?ceei-iaoaiaoe/ieo iaoe ca niaoe?aeuei?noth 01.04.18 – o?ceea ? o?i?y
iiaa?oi?. I?eea?iaonueeee oi?aa?neoao ?iai? Aaneey Noaoaieea.
?aaii-O?aie?anuee, 1999.

Aea/aii caeiiii??iino? aieeao no?oeoo?e, aeaeo?e/ieo ia?aiao??a, oiia
ae?iuoaaiiy ? ciai?oi?o oaeoi??a (oa?i?/iee a?aeiae, ?aae?aoe?eia
ii?ii?iaiiy, eaaoaaiiy) ia oa?iiaeaeo?e/i? oa?aeoa?enoeee ie?aie
oaeo?eaeo naeioeth oa eiai aiaeia?a. Anoaiiaeaii, ui
ae??aiiaeenia?ni?noue, ca?eueoaiiy oiaueie a iaaeao 0,05-0,5 iei,
?cioa?i?/iee a?aeiae o aaeooi? i?eaiaeyoue aei c?inoaiiy
oa?iiaeaeo?e/ii? aeia?ioiino? oiieiie?aeiaiai iaoa??aeo. Oa?iia?aeiae
ie?aie n-PbTe o aoiinoa?? eenith oa ?o ?aae?aoe?eia ii?ii?iaiiy ca
?aooiie ooai?aiiy iioaioe?aeueieo aa?’???a ia a?aieoeyo ca?ai i?e
oa?iiaeeooc?? ? ?aae?aoe?eii-noeioeueaaieo i?ioeanao iaoiiaeththoue
aiiiaeueii aenie? cia/aiiy oa?ii-a.?.n.

#6.1. Eeth/ia? neiaa: oiie? ie?aee, eiao?oe??i oa?ii-a.?.n.,
oa?iiaeaeo?e/ia aeia?ioi?noue, ?aae?aoe?eia ii?ii?iaiiy, oa?i?/iee
a?aeiae, oa?iiaeeooc?y eenith, oaeo?eae naeioeth.

#14.2. Caiooeye ?.?. Iniaaiiinoe oa?iiyeaeo?e/aneeo naienoa ieaiie PbTe
e aai aiaeiaia. –?oeiienue.

Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa
oeceei-iaoaiaoe/aneeo iaoe ca niaoeeaeueiinoueth 01.04.18 – oeceea e
oeiey iiaa?oiinoe. I?eea?iaoneee oieaa?neoao eiaie Aaneeey Noaoaieea.
Eaaii-O?aieiane, 1999.

A aeenna?oaoeee e caueoa i?aaenoaaeaiu ?acoeueoaou enneaaeiaaiee,
eceiaeaiiua a 12 iao/iuo ioaeeeaoeeyo. ?aaioa iinayuaia eco/aieth
oa?iiyeaeo?e/aneeo ia?aiao?ia ieaiie oaeeo?eaea naeioea n- e ?-oeia
i?iaiaeeiinoe e eo aiaeiaia: PbTe:In(I), PbTe-SnTe:In, Pb1-XSnXTe1-YSeY,
PbSe.

Eco/aii caeiiiia?iinoe aeeyiey no?oeoo?u, yeaeo?e/aneeo ia?aiao?ia,
oneiaee au?aueaaiey e aiaoieo oaeoi?ia (oa?ie/aneee ioaeea,
?aaeeaoeeiiiia iaeo/aiea, eaae?iaaiea) ia oa?iiyeaeo?e/aneea
oa?aeoa?enoeee ieaiie oaeo?eaea naeioea e aai aiaeiaia. Onoaiiaeaiiei,
/oi iaeeiaeenia?niinoue, oaaee/aiea oieueiu a i?aaeaeao 0,05-0,5 iei,
ecioa?ie/aneee ioaeea a aaeooia i?eaiaeyo e aic?anoaieth
oa?iiyeaeo?e/aneie aeia?ioiinoe oiieiieaii/iiai iaoa?eaea. Oa?iiioaeea
ieaiie n-PbTe a aoiinoa?a eenei?iaea e eo ?aaeeaoeeiiiia iaeo/aiea ca
n/ao ia?aciaaiey iioaioeeaeueiuo aa?uea?ia ia a?aieoeao ca?ai i?e
oa?iiaeeoocee e ?aaeeaoeeiiii-noeioee?iaaiiuo i?ioeannao
i?aaeii?aaeaeytho aiiiaeueii aunieea cia/aiey oa?ii-y. ae.n.
Iiaeoaa?aeaeaii, /oi aeey oaa?aeiai ?anoai?a (Pb0,8Sn0,2)1-X?nXTe
(0,02o0,15) eiyooeoeeaio oa?ii-y.ae.n. i?e oaiia?aoo?ao aunoeo ca 250 E
io?eoeaoaeueiue. Onoaiiaeaii, /oi aeiiieieoaeueiia eaae?iaaiea eiaeii
aei 0,1-0,3 ao. % e?enoaeeia PbTe:In n iaeui niaea?aeaieai In
(0,001-0,002 ao. %) i?eaiaeeo e oaaee/aieth eo oa?iiyeaeo?e/aneeo
ia?aiao?ia.

#6.2. Eeth/aaua neiaa: oiieea ieaiee, eiyooeoeeaio oa?ii-y. ae.n.,
oa?iiyeaeo?e/aneay aeia?ioiinoue, ?aaeeaoeeiiiia iaeo/aiea, oa?ie/aneee
ioaeea, oa?iiaeeoocey eenei?iaea, oaeo?eae naeioea.

#14.3. Zapuchlyak R.I. Features of thermoelectric properties of PbTe
films and of their analogs. The manuscript.

A thesis on competition of a scientific degree of the candidate of
physical and mathematical sciences of a speciality 01.04.18 – surface
physics and chemistry. Pricarpathian university named after Wasyl
Stefanyk. Ivano-Frankivsk, 1999.

There were investigated regularities of influence of a structure,
electrical parameters, conditions of cultivation and external factors
(thermal annealing, radiation exposure, doping) on thermoelectric
properties of PbTe films and of their analogs. There was established,
that fine-dyspersity, increasing of a thickness in the boundaries
0,05-0,5 microns, isothermal annealing at vacuum leads to an increasing
of thermoelectric Q-factor of a thin-film material.

Thermoannealing of n-PbTe films at atmosphere of oxygen and their
radiation exposure at the expense of formation of potential barriers on
the boundaries of grains with thermodiffusion and radiation-stimulated
processes predetermine the anomalous high values of the Thermo-e.d.f.

#6.3. Keywords: thin films, thermo-e.d.f. factor, thermoelectric
Q-factor, radiation exposure, thermal annealing, thermodiffusion of
oxygen, tellurid of lead.

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