10
OA?E?ANUeEEE AeA?AEAAIEE OI?AA?NEOAO
EAO?E* AAIIAAe?E NA?A?EIAE*
OAeE 535.37
IIOE*I? NIAEO?E OA AENEOIIIA AeEIAI?EA J-AA?AAAO?A C AIA?AAOE*IEI OA
OIIIEIA?*IEI AACEAAeAessI
01.04.05- iioeea, eaca?ia o?ceea
AAOI?AOA?AO
aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy
eaiaeeaeaoa o?ceei-iaoaiaoe/ieo iaoe
Oa?e?a- 1999
Aeena?oaoe?y ? ?oeiienii.
?iaioa aeeiiaia a IOE “?inoeooo iiiie?enoae?a” IAI Oe?a?ie
Iaoeiaee ea??aiee: aeieoi? o?ceei-iaoaiaoe/ieo iaoe,
noa?oee iaoeiaee ni?a?ia?oiee
Iaethe?i TH??e A?eoi?iae/ (i?ia?aei?e iaoeiaee ni?a?ia?oiee IOE
“?inoeooo iiiie?enoae?a” IAI Oe?a?ie)
Iooe?ei? iiiiaioe: aeieoi? o?ceei-iaoaiaoe/ieo iaoe, i?ioani?
Ieeineaanueeee Aieiaeeie? Einoyioeiiae/
(caa?aeoaa/ eaoaae?e Oa?e?anueeiai aea?aeaaiiai oi?aa?neoaoo)
aeieoi? o?ceei-iaoaiaoe/ieo iaoe,
noa?oee iaoeiaee ni?a?ia?oiee
Inoaiaiei I?ia ?aai?aia
(noa?oee iaoeiaee ni?a?ia?oiee ?inoeoooo o?ceee IAI Oe?a?ie, i.
Ee?a)
I?ia?aeia i?aai?caoe?y: Ee?anueeee iaoe?iiaeueiee oi?aa?neoao
?i. O. A. Oaa/aiea (eaoaae?a caaaeueii? o?ceee)
Caoeno a?aeaoaeaoueny “ 12 ” eenoiiaaea 1999 ?. 14 aiae.
ia can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee Ae.64.051.03 o Oa?e?anueeiio
aea?aeaa-
iiio oi?aa?neoao? (310077, i. Oa?e?a, iaeae. Naiaiaee, 4, aoae. ?i.
E.Ae. N?iaeueieeiaa)
C aeena?oaoe??th iiaeia iciaeiieoeny o Oeaio?aeuei?e iaoeia?e
a?ae?ioaoe? Oa?e?anueeiai aea?aeaaiiai oi?aa?neoaoo
Aaoi?aoa?ao ?ic?neaiee “ 1 ” aeiaoiy 1999 ?.
A/aiee nae?aoa? niaoe?ae?ciaaii? a/aii? ?aaee
A.I.Iieaea
CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE
Aeooaeuei?noue oaie. Inoaii?i /anii iaaecae/aeii c?inea caoe?eaaeai?noue
o aeine?aeaeaiiyo iioe/ieo aeanoeainoae aoiiieo ? iieaeoey?ieo
eeanoa??a, ?ici??e yeeo neeaaeathoue aeanyoee iaiiiao??a. Oea, a ia?oo
/a?ao, coiiaeaii oei, ui iaii/anoeiee aeicaieythoue i?inoaaeeoe
ooiaeaiaioaeuei? caeiiii??iino? oi?ioaaiiy iioe/ieo aeanoeainoae i?e
ia?aoiae? a?ae iiiaeeiieeo aoii?a oa iieaeoe aei iae?ineii?/ieo
ia’?eo?a: e?enoae?a, iie?ia??a, neea ? o.?.. E??i oiai, aeei?enoaiiy
eaaioiai?ici??iiai aoaeoo iaaea? iiaeeea?noue ea?oaaoe iioe/ieie
aeanoeainoyie iaii/anoeiie ? noai?thaaoe ia ?oi?e iniia? iia?
ia?niaeoeai? iaoa??aee aeey eaca?ii? oaoi?ee, iioiaeaeo?ii?ee,
iioiaieieiiieo eiioi?eaoe?eieo nenoai, iioe/ieo eiii’thoa??a, oiui.
J-aa?aaaoe iaeaaeaoue aei iaii/anoeiie, ui naiiaii?yaeeiaothoueny o
ae?aeaeo?e/ieo iao?eoeyo, ooai?thth/e iieaeoey?i? eaioethaeee, ye?
neeaaeathoueny ?c nioai iieaeoe. A inoaii? aeanyoue ?ie?a aaeaeiny
cia/ii i?inoiooenue o ?icoi?ii? i?e?ineii?/ii? i?e?iaee aeneoiiieo
caoaeaeaiiue J-aa?aaao?a. Anoaiiaeaii, ui aeiaaeeia aeaeieae?caoe??
aeneoiiiiai noaio a J-aa?aaaoao ? iniiaiei ianooaaii eaaiooaaiiy, ui
aecia/a? ia?aiao?e ?oiuei? iioe/ii? nioae iiaeeiaiiy, ?aae?aoe?eiee /an
caoooaiiy aeneoiiieo caoaeaeaiue ? iae?i?ei? iioe/i? aeanoeaino?.
Aaaaea?oueny, ui aeiaaeeia aeaeieae?caoe?? aeneoiia, yeo i?eeiyoi
aeneiaethaaoe aeey J-aa?aaao?a ca aeiiiiiaith /enea eiaa?aioii ca’ycaieo
iieaeoe, caeaaeeoue a?ae ?ioaa?aeo ia?aiino oa aia?aaoe/iiai
(ae?aaiiaeueiiai) aaceaaeaey o iieaeoey?iiio eaioethaeeo. Iaeii/anii
caeeoa?oueny iaaeine?aeaeaiei aieea ia aeneoiiio aeeiai?eo J-aa?aaao?a
oiiieia?/iiai (iaae?aaiiaeueiiai) aaceaaeaey. Oai?aoe/i? ?iaioe,
aeeiiai? o oeueiio iai?yieo, ia?aaeaa/athoue aeaye? iniaeeaino? a
aeneoiiiiio niaeo?? J-aa?aaao?a c oiiieia?/iei aaceaaeaeyi. Na?aae oeeo
iniaeeainoae iaiao?aeii a?aecia/eoe ?noioio iiaeeo?eaoe?th oi?ie
aeneoiiii? nioae iiaeeiaiiy ? iayai?noue i?ea u?eueiino? noai?a o
oeaio?? aeneoiiii? ciie.
I?iaeaia aieeao aia?aaoe/iiai ? oiiieia?/iiai aaceaaeaey ia aeeiai?eo
aeaeo?iiieo caoaeaeaiue a iaii/anoeieao aeoiaeeoue aeaeaei ca iaae?
aeine?aeaeoaaii? oaie ? noaiiaeoue caaaeueiio?ce/iee ?ioa?an.
Iaaecae/aeii aeooaeueiith caeeoa?oueny i?iaeaia noai?aiiy iaii/anoeiie c
iiaeeeaei ea?oaaiiyi aia?aaoe/iei ? oiiieia?/iei aaceaaeaeyi, a oaeiae
?iciiae?e aiane?a aia?aaoe/iiai ? oiiieia?/iiai aaceaaeaey, a
iniaeeaino? aeeiai?ee aeaeo?iiieo caoaeaeaiue iaii/anoeiie.
Iaea?eueo aaaaoee aenia?eiaioaeueiee iaoa??ae ii aeeiai?oe? aeneoiiieo
caoaeaeaiue io?eiaii aeey J-aa?aaao?a PIC (1,1’-ethyl-2,2’-cyanine
iodide). O aeai?e ?iaio? aeey iaea?aeaiiy J-aa?aaao?a aeei?enoaii
iieaeoee 1-methyl,-1’-octadethyl-2,2’-cyanine iodide (aeae? iieiaiiaai?
S120), ui iathoue ?aeaioe/io o?iiioi?io /anoeio c iieaeoeaie PIC. Iaeiae
iayai?noue oa?oiiaoaaiiy N18I37 o iieaeoeao S120 iaaea? ?i aio?o?euei?
aeanoeaino?, yeeo iaia? o iieaeoe PIC. Aio?o?euei? aeanoeaino? iieaeoe
S120 aeicaieeee ea?oaaoe no?oeoo?ith J-aa?aaao?a S120, ui ?ai?oa aoei
iaiiaeeeaei aeey J-aa?aaao?a PIC.
A?aoiaoth/e u?eueiee aca?iica’ycie i?ae iioe/ieie aeanoeainoyie
J-aa?aaao?a oa ?oiueith no?oeoo?ith, a oaeiae iiaeie iiaeeeainoyie
ea?oaaoe no?oeoo?ith J-aa?aaao?a, aaaaea?oueny aeooaeueiei iiaeaeueoee
?icaeoie aeine?aeaeaiue, ni?yiiaaieo ia caaaa/aiiy ciaiue i?i
i?e?ineii?/io i?e?iaeo aeneoiiiiai caoaeaeaiiy J-aa?aaao?a.
Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie. ?iaioo aeeiiaii
o ?aieao athaeaeaoieo iaoeiai-aeine?aeieo ?ia?o Iaoe?iiaeueii? Aeaaeai??
Iaoe Oe?a?ie (? aea?ae ?a?no?aoe?? 0196u009875 ? 0197U006933), oa
a?aio?a INTAS (94-044 ? 96-0626).
Iaoa ? caaea/? aeine?aeaeaiiy. Iniiaiith iaoith ?iaioe aoei
aenia?eiaioaeueia aeine?aeaeaiiy iioe/ieo niaeo??a oa aeeiai?ee
aeneoiiieo caoaeaeaiue J-aa?aaao?a S120 c aia?aaoe/iei ? oiiieia?/iei
aaceaaeaeyi.
Eiie?aoi? caaea/? aeine?aeaeaiiy:
-aeine?aeaeaiiy iioe/ieo niaeo??a i?e ooai?aii? ? oa?i?/iiio ?oeioaaiiy
J-aa?aaao?a S120 o a?ia?ieo ?ic/eiao aeeiaoeeoi?iai?ae-aiaea (AeIOA-A)
??ciiiai?oiiai neeaaeo;
-aeine?aeaeaiiy oi?ie iecueeioaiia?aoo?ii? aeneoiiii? nioae iiaeeiaiiy
J-aa?aaao?a S120 oa ?? caeaaeiino? a?ae neeaaeo iao?eoe?, yea neeo?oueny
i?e ioieiaeaeaii? a?ia?iiai ?ic/eio AeIOA-A (N-iao?eoey);
-aea/aiiy eaiae?a iaaeoaeaeeeo i?ioean?a ?aeaenaoe?? aeneoii?a o
J-aa?aaaoao S120 ?c neeueiei oiiieia?/iei oa aia?aaoe/iei aaceaaeaeyi;
-ocaaaeueiaiiy io?eiaieo aenia?eiaioaeueieo ?acoeueoao?a, oa ?ic?iaea
iiaeo iiaeaeae oa i?aeoiae?a, uiaei ?icoi?iiy i?e?ineiie/ii? i?e?iaee
aeneoiiieo caoaeaeaiue o iaii/anoeieao.
Caniae oa iaoiaeeee aeine?aeaeaiiy. Aenia?eiaioaeuei? ?acoeueoaoe, ui
iiaeai? o aeena?oaoe?ei?e ?iaio?, io?eiai? caniaaie cae/aeii? ? eaca?ii?
aea??eiai? iioe/ii? niaeo?ineii?? c aeei?enoaiiyi oaiia?aoo? a ?ioa?aae?
4,2450 E. Aenia?eiaioe c naeaeoeaii? niaeo?ineii?? aoee aeeiiai?
caaaeyee canoinoaaiith aeaio ca’ycaieo iiiio?iiaoi??a IAe?-23. Aeey
iaea?aeaiiy ?ioi?iaoe?? i?i ia?aiao?e, eio?? oa?aeoa?ecothoue
?aeaenaoe?ei? i?ioeane o caoaeaeaiiio noai? J-aa?aaao?a,
aeei?enoiaoaaany aaoiiaoeciaaiee i?einaeoiaeiee eaca?iee
niaeo?ioeoi?eiao?, ui neeaaea?oueny c Nd:YAG eaca?a c aeoeaiith
neio?ii?caoe??th iiacaeiaaei?o iiae, eaca?a ia i?aai?/ieo aa?aieeao ?
nenoaie /an-ei??aeueiaaiiai ?aooieo ie?aieo oioii?a.
Aeey i?iaaaeaiiy aeine?aeaeaiue aoea a?aei?aoeueiaaia iaoiaeeea, yea
aeicaiey? io?eioaaoe J-aa?aaaoe iieaeoe S120 o N-iao?eoeyo c caaeaiith
ia?aaaaith oeio aaceaaeaey (aia?aaoe/iiai aai oiiieia?/iiai).
Iaoeiaa iiaecia iaea?aeaieo ?acoeueoao?a. Anoaiiaeaii yaeua
eiiia?aoeaiiai noai?aiiy oa oa?i?/iiai ?oeioaaiiy J-aa?aaao?a S120 o
a?ia?ieo ?ic/eiao AeIOA-A ??ciiiai?oiiai neeaaeo. Aenia?eiaioaeueii
anoaiiaeaii oa aeine?aeaeaii caeiiii??iino? o?ainoi?iaoe?? oi?ie
iecueei/anoioiiai e?ath nioae iiaeeiaiiy J-aa?aaao?a S120 o N-iao?eoeyo
??ciiiai?oiiai neeaaeo, ciaeaeaii caeaaei?noue o?ainoi?iaoe?? oi?ie
nioae a?ae nooiaiy oiiieia?/iiai aaceaaeaey J-aa?aaao?a. Cai?iiiiiaaii
i?e?ineii?/io iiaeaeue no?oeoo?e J-aa?aaao?a S120 oa ?o nieueaaoii?
iaieiiee, yea aeicaiey? iiynieoe ooai?aiiy oiiieia?/iiai oa
aia?aaoe/iiai aaceaaeaey o iieaeoey?iiio eaioethaeeo aa?aaaoa.
Iaea?aeaii ia?aiao?e, ye? /enaeueii oa?aeoa?ecothoue noaoe/ia aaceaaeaey
J-aa?aaao?a. Anoaiiaeaii ??aiicia/iee ca’ycie i?ae aaee/eiith
oiiieia?/iiai aaceaaeaey oa ?iia??i?noth aaoieieae?caoe?? aeneoii?a o
J-aa?aaaoao S120. Iaaeaii aeaoaeueiee aiae?c iioiaeaeaiiy ii?iaiai?
aaoieieae?caoe?? aeneoii?a o J-aa?aaaoao, oa aaaaeaii e?eoe/io aeiaaeeio
eaioethaa, uiaei aaoieieae?caoe?? aeneoii?a o J-aa?aaaoao S120.
Eiie?aoi? iaoeia? ?acoeueoaoe oa iieiaeaiiy, ui aeiinyoueny ia caoeno.
1. ?ic?iaea oa noai?aiiy i?ea?iaeueiiai niaeo?ioeoi?eiao?a c iecueeei
??aiai ?icn?yiiai na?oea ia aac? aeaio ca’ycaieo iiiio?iiaoi??a IAe?-23,
yeee aeicaiey? aanoe aeine?aeaeaiiy iioe/ieo niaeo??a iiaeeiaiiy oa
ethi?ianoeaioe?? o oe?ieiio ?ioa?aae? oaiia?aoo? (4,2-450 E), aeeth/ii c
i?einaeoiaeiei ?iciiae?eii o /an?.
2. Anoaiiaeaii caaaeueio (?ciaanoe/io) oi/eo ia?aoeio o n?iaenoa?
niaeo??a iiaeeiaiiy J-aa?aaao?a i?e ??cieo oaiia?aoo?ao oa ??ciiio
neeaae? ?ic/eio, ui aeicaieeei anoaiiaeoe aoaeo eiiia?aoeaiiai ooai?aiiy
oa oa?i?/iiai ?oeioaaiiy J-aa?aaao?a S120 o a?ia?ieo ?ic/eiao AeIOA-A.
3. Aenia?eiaioaeueia aeyaeaiiy ci?ie oi?ie iecueeioaiia?aoo?ii? nioae
iiaeeiaiiy J-aa?aaao?a S120 o N-iao?eoeyo ??ciiiai?oiiai neeaaeo, ia
iniia? yeeo anoaiiaeaii neeueia oiiieia?/ia aaceaaeaey o iieaeoey?ieo
eaioethaeeao J-aa?aaao?a.
4. Iiaeaeue o?ce/ii? nenoaie, yea neeaaea?oueny c J-aa?aaaoa oa eiai
nieueaaoii? iaieiiee, eio?a aeicaieeea ia i?e?ineii?/iiio ??ai? iiynieoe
iayai?noue o J-aa?aaao?a S120 aia?aaoe/iiai oa oiiieia?/iiai aaceaaeaey,
a oaeiae aecia/eoe caniae ea?oaaiiy noaoe/iei aaceaaeaeyi.
5. ?acoeueoaoe aeine?aeaeaiiy aan?iiy aeneoiiii? nioae na?o?iiy
J-aa?aaao?a S120 ianoeaie aeneoiiieo caoaeaeaiue oa ?o niaeo??a
na?o?iiy, ui iathoue ?iciiae?eaiiy o /an?, ia iniia? eio?eo
i?aeoaa?aeaeaii iiaeeea?noue ?nioaaiiy a?eueieo oa aaoieieae?ciaaieo
aeneoii?a o nenoaiao c iaeiiaei??iei aeneoiiiei o?ainii?oii.
I?aeoe/ia cia/aiiy iaea?aeaieo ?acoeueoao?a. Aecia/a?oueny ieceith iiaeo
?acoeueoao?a, eio?? noinothoueny iniaeeainoae ooai?aiiy oa oa?i?/iiai
?oeioaaiiy iieaeoey?ieo no?oeoo? ia iniia? aio?o?eueieo iieaeoe, a
oaeiae o ?ice?eoo? iiaeo aniaeo?a aeeiai?ee aeneoiiieo caoaeaeaiue o
eaac?-1D oa 1D nenoaiao. Io?eiai? ?acoeueoaoe aeicaieythoue
oe?eani?yiiaaii aoaeoaaoe iieaeoey?i? iaiino?oeoo?e, o yeeo ia?aaaaea?
oiiieia?/ia aai aia?aaoe/ia aaceaaeaey. Oea aaciina?aaeiuei a?aee?eaa?
iiaeeea?noue iiaeeaeaiiy caaaeueiio?ce/ieo oyaeaiue i?i i?e?ineii?/io
i?e?iaeo aeneoiiieo caoaeaeaiue oa aeneoiiiiai o?ainii?oo o eaac?-1D oa
1D iieaeoey?ieo nenoaiao.
Io?eiai? aenia?eiaioaeuei? ?acoeueoaoe aeicaieeee aenoiooe i?eioeeiiai
iia? ?aea? oa iieiaeaiiy uiaei aeneoiiii? aeeiai?ee eaac?-1D oa 1D
nenoai ? oiio caioi/othoue aei i?iaeiaaeaiiy aeine?aeaeaiue. ?aea? oa
i?aeoiaee, ye? ?icaeioo? a ?iaio?, iiaeooue aooe aeei?enoai? o oiae?
aeine?aeaeaiiue i?iaeai, iia’ycaieo c oioineioacii oa ooieoe?iioaaiiyi
aeeaeo ee?oei. Aenia?eiaioaeuei? ?acoeueoaoe ciaoiaeyoue aaciina?aaei?
canoinoaaiiy i?e ?ic?iaoe? iiaeo aeniei/ooeeaeo oioiiaoa??ae?a oa
aioeuen?e, a oaeiae iioe/ieo eiioi?eaoe?eieo nenoai, ye? iio?aaothoue
iioe/ieo iaoa??ae?a c aenieei iae?i?eiei eoa?/iei ni?eeiyooyi.
Iniaenoee aianie caeiaoaa/a. Aeena?oaio aaciina?aaeiuei a?aa o/anoue o
noai?aii? ooieoe?iiaeueieo aeaiaio?a oa aoce?a eiiieaena
aenia?eiaioaeueii? aia?aoo?e, ieaioaaii? oa i?iaaaeaii? onueiai oeeeeo
aenia?eiaioaeueieo aeine?aeaeaiue, caeiaany ia?iaeith oa aiae?cii
io?eiaieo ?acoeueoao?a, ?ic?iaeith oa aiae?cii oai?aoe/ieo iiaeaeae.
Aaoi? aaciina?aaeiuei a?aa o/anoue o iaienaii? noaoae c oaie
aeena?oaoe??.
Ai?iaaoe?y ?acoeueoao?a aeena?oaoe??. Iniiai? ?acoeueoaoe
aeena?oaoe?eii? ?iaioe aeiiia?aeaeenue oa iaaiai?thaaeenue ia
eiioa?aioe?yo: 5th International Conference on Methods and Applications
of Fluorescence Spectroscopy, Berlin, Germany, 1997; The Jablonski
Centennial Conference, Torun, Poland, 1998; ?? I?aeia?iaeia
oeiea-eiioa?aioe?y “Aeaeo?iii? i?ioeane a i?aai?/ieo iaoa??aeao”, Ee?a,
Oe?a?ia, 1998.
Ioae?eaoe??. Iaoa??aee aeena?oaoe?eii? ?iaioe a?aeia?aaeai? o 7 ?oaooao.
C ieo 4 iaae?oeiaai? noaoo? o iaoeiaeo oaoiaeo aeo?iaeao oa 3 oace
aeiiia?aeae.
No?oeoo?a ? ianya aeena?oaoe??. Aeena?oaoe?y neeaaea?oueny c ia?aaeiiae,
5 ?icae?e?a, aeniiae?a oa nieneo aeei?enoaieo e?oa?aoo?ieo aeaea?ae c
154 iaeiaioaaiue. Aiia aeeeaaeaia ia 150 noi??ieao, i?noeoue 37 ?enoie?a
oa 5 oaaeeoeue.
INIIAIEE CI?NO ?IAIOE
O ia?aaeiia? iaa?oioiaaii aeooaeuei?noue oaie oa noi?ioeueiaaii iaoo
aeena?oaoe?eii? ?iaioe, iiaeaii ei?ioeo oa?aeoa?enoeeo noa?e
aeine?aeaeaiue, iiaeaii eiie?aoi? iaoeia? ?acoeueoaoe oa iieiaeaiiy, ye?
aeiinyoueny ia caoeno, iaoeiaa iiaecia oa i?aeoe/ia oe?ii?noue
aeena?oaoe?eii? ?iaioe. I?eaaaeaii iien no?oeoo?e ?iaioe oa aeai? uiaei
?? ai?iaaoe??.
Ia?oee ?icae?e “E?oa?aoo?iee iaeyae” i?enay/aii aiae?oe/iiio iaeyaeo oa
oi?ioethaaith iniiaieo iieiaeaiue oa aeinyaiaiue ca inoaii? aeanyoe??//y
o aaeoc? aeine?aeaeaiiy aeeiai?ee aeneoiiieo caoaeaeaiue o ??cieo
iieaeoey?ieo nenoaiao. I?iaiae?ciaaii ?aea?, oyaeaiiy oa o?ce/i?
iiaeae?, ye? aeei?enoiaothoueny aeey iiyniaiiy iioe/ieo aeanoeainoae
J-aa?aaao?a.
O ae?oaiio ?icae?e? “Aenia?eiaioaeueia oaoi?ea oa iaoiaeeee
aeine?aeaeaiiy” iiaeaii iien aaoiiaoeciaaiiiai niaeo?ioeoi?eiao?a ia
aac? aeaio ca’ycaiieo iiiio?iiaoi??a IAe?-23 c iecueeei ??aiai
?icn?yiiai na?oea, aeey aei??thaaiue iioe/ieo niaeo??a o ae?aiacii?
0,30,8 iei, iaaeaii no?oeoo?io noaio aenia?eiaioaeueiiai eiiieaeno oa
iienaii eiai iniiai? ooieoe?iiaeuei? aocee. Aeaoaeueii iienaii
noaiaiinaeoiaeiee eaca?iee niaeo?ioeoi?eiao?, eio?ee neeaaea?oueny c
i?einaeoiaeiiai Nd:YAG-eaca?a c aeoeaiith neio?ii?caoe??th iiacaeiaaei?o
iiae; eaca?a ia i?aai?/ieo aa?aieeao; nenoaie naeaeoe?? eaca?ieo
?iioeuen?a; nenoaie ?a?no?aoe?? na?o?iiy, yea i?aoeth? ia i?aenoaa?
ei?aeueiaaiiiai o /an? ?aooieo oioii?a.
Aeey iaeiie/aiiy aenia?eiaioaeueieo aeaieo o nenoaiao ?a?no?aoe??, a
oaeiae aeey iiaeaeueoiai iaoaiaoe/iiai ia?aoiaoaaiiy aeaieo
aeei?enoiaoaaany ia?niiaeueiee eiii’thoa? c iaiao?aeiei i?ia?aiiei
caaacia/aiiyi.
Iiaeaii iien iaeaaeiaiiy, eio?a caaacia/o? aeine?aeaeaiiy o oe?ieiio
?ioa?aae? oaiia?aoo?: e??iaaii? nenoaie, ye? aeicaieyee i?iaiaeeoe
aei??thaaiiy a?ae 1,5 aei 150 E; ??aeeiiee oa?iinoao, ui i?aoeth? o
?ioa?aae? oaiia?aoo? 300450 E.
Iiyniaii oaoiieia?th i?eaiooaaiiy J-aa?aaao?a S120 o a?ia?ieo ?ic/eiao
aeeiaoeeoi?iai?ae oa aiaea.
O?ao?e ?icae?e “Ooai?aiiy, no?oeoo?a oa iioe/i? aeanoeaino? J-aa?aaao?a
S120 o ?ic/eiao AeIOA-A” i?noeoue ?acoeueoaoe aeine?aeaeaiue
iniaeeainoae ooai?aiiy oa oa?i?/iiai ?oeioaaiiy J-aa?aaao?a S120 o
a?ia?ieo ?ic/eiao AeIOA-A ??ciiiai?oiiai neeaaeo i?e ??cieo
oaiia?aoo?ao. Anoaiiaeaii aca?iica’ycie i?ae iioe/ieie oa?aeoa?enoeeaie
J-aa?aaao?a S120 oa ?o no?oeoo?ith.
Ia a?aei?io a?ae iieaeoe ??N, eio?? aa?aaothoueny o aiaeieo ?ic/eiao i?e
aeoaea aenieeo eiioeaio?aoe?yo (10-2 iieue/e), iieaeoee S120 iathoue
aeiyoeiai aaaeeeao aeanoea?noue – aio?o?euei?noue, yea iia’ycaia c
i?enooi?noth aoaeaaiaeiaaiai ?aaeeeaeo N18I37 oa ca?yaeo ia o?iiioi?i?e
/anoei? iieaeoee (?en.1, anoaaea). Caaaeyee aio?o?eueiino? iieaeoe S120
?o aa?aaaoe?y aoea iiaeeeaa i?e aeiaeaaaii? aiaee aei ii/aoeiaiai
?ic/eio S120 (10-5 iieue/e) a AeIOA. I?aeaeuaiiy ai?noo aiaee o
a?ia?iiio ?ic/ei? AeIOA-A a?ae 50% aei 70 % ni?e/eith? iaeaea iiaia
cieeiaiiy nioae iiiiia??a o niaeo?? iiaeeiaiiy oa ia?iuoaaiiy
?ioaineaiino? aeiaaioaeeueiai? aocueei? nioae iiaeeiaiiy J-aa?aaao?a
S120. N?iaenoai niaeo??a iiaeeiaiiy iiiiia??a S120 oa J-aa?aaao?a S120 o
?ic/eiao AeIO-A ??ciiai neeaaeo iaei ?ciaanoe/io oi/eo, yea iicia/a?
iiaio oa?iiaeeiai?/io ??aiiaaao i?ae ainaiaeai iaanioe?eiaaieo iieaeoe
S120 oa ?o J-aa?aaaoaie.
I?aeaeuaiiy oaiia?aoo?e aeine?aeaeoaaieo ?ic/ei?a o iaaeao 1070 0 N
ni?e/eith? iiaia cieeiaiiy J-aa?aaao?a. ?o nioaa iiaeeiaiiy ca
?ioaineai?noth cieaeoaaeanue, a nioaa iiaeeiaiiy iiiiia??a S120 c?inoaea
(?en.1). O oeueiio aeiaaeeo noeoii?noue niaeo??a oaeiae iaea ni?eueio
?ciaanoe/io oi/eo (?en.1). Nioaa iiaeeiaiiy J-aa?aaao?a, iaa?ouei?e
aeinyaiaii? oaiia?aoo?e, aeecueei? aei iaae? iiaiiai c?oeioaaiiy
J-aa?aaao?a (?en.1), iaea aeiaaioaeeueiaee cnoa 27 ni-1. Ia iaae?
iiaiiai c?oeioaaiiy J-aa?aaao?a ?ioaa?aeueia ieiua nioae iiiiia??a
ca?eueoeeanue oaea?/?, a ?ioaa?ae i?ae J-nioaith ciaioeany a /ioe?e ?ace
(?en.1).
?en.1 Oaiia?aoo?ia o?ainoi?iaoe?y nioa iiaeeiaiiy iiiiia??a iieaeoe S120
? J-aa?aaao?a S120: 1 – 17 0C; 2 – 30 0C; 3 – 50 0C.
Iayai?noue ?ciaanoe/ieo oi/ie o n?iaenoa? niaeo??a iiaeeiaiiy iiiiia??a
S120 oa ?o J-aa?aaao?a, i?e ??cieo oaiia?aoo?ao oa neeaae? ?ic/eio
AeIOA-A, aeiaaioaeeueiaee cnoa nioae iiaeeiaiiy J-aa?aaao?a (?en.1), a
oaeiae cao?eniaaia ci?ia ?ioaa?ae?a a?aeiia?aeieo nioa iiaeeiaiiy
icia/a?, ui J-aa?aaaoe S120 oi?iothoueny oa ?oeiothoueny ye ?aeeia oe?ea
aac ae?iaeaiiy ia o?aaiaioe /e iiiioiiii? aeenioe?aoe?? ia ie?ai?
iieaeoee.
O /aoaa?oiio ?icae?e? ”Iecueeioaiia?aoo?ia niaeo?ineii?y J-aa?aaao?a
S120.” iaaaaeaii aiae?c oi?ie iecueeioaiia?aoo?ii? nioae iiaeeiaiiy
J-aa?aaao?a S120 oa ?o ethi?ianoeaioe?? i?e naeaeoeaiiio caoaeaeaii? o
N-iao?eoeyo AeIOA-A ??ciiiai?oiiai neeaaeo oa oaa?aeeo ie?aeao ia
ae?aeaeo?e/ieo i?aeeeaaeeao, io?eiaieo ca oaoiieia??th
Eaiaith?a-Aeiaeaeao. Anoaiiaeaii caeaaei?noue ci?ie oi?ie
iecueei/anoioiiai e?ath aeneoiiiiai iiaeeiaiiy J-aa?aaao?a a?ae
e?eueeino? aiaee o N-iao?eoeyo.
Aeneoiiia nioaa iiaeeiaiiy J-aa?aaao?a S120 o N-iao?eoe? c iaeneiaeueiei
(70%) ai?noii aiaee iaea aneiao?e/io oi?io ? iaee?auei /eiii iieno?oueny
neeaaeiei eiioo?ii Aaonna-Ei?aioea c ??ciith i?aoe?eiith ia i?aaenio?
a?aeiia?aeieo iieiaeiie eiioo?a Ei?aioea oa eiioo?a Aaonna (?en.2a).
Aiaeia?/io oi?io aeneoiiii? nioae iiaeeiaiiy i?e iecuee?e oaiia?aoo??
iaee J-aa?aaaoe ??N. Aea cieaeaiiy a?aenioeiaiai ci?noo aiaee o
N-iao?eoe? o iacia/ieo iaaeao a?ae 70% aei 50%, ni?e/eith? nooo?ao ci?io
oi?ie iecueei/anoioiiai e?ath nioae iiaeeiaiiy J-aa?aaao?a S120. I?e
ai?no? aiaee 50% iecueei/anoioiee e?ae nioae iiaeeiaiiy J-aa?aaao?a S120
iaee?auei /eiii iieno?oueny iieiaeieith eiioo?a Ei?aioea (?en.2a). I?e
i?ii?aeiiio ai?no? aiaee i? eiioo? Ei?aioea, i? eiioo? Aaonna ia
aeathoue caaeia?eueii? ai?ieneiaoe?? iecueei/anoioiiai e?ath nioae
iiaeeiaiiy J-aa?aaao?a S120.
?en.2 Nioaa iiaeeiaiiy J-aa?aaao?a S120 i?e ??ciiio ai?no? aiaee o
N-iao?eoe? (O-1,5 E): a) 70%; a) 50%.
Nioaa iiaeeiaiiy J-aa?aaao?a S120 o EA ie?aeao oaeiae aoea
aneiao?e/iith. Aea ?? iecueei/anoioiee e?ae iaa i?ii?aeio oi?io i?ae
eiioo?ii Ei?aioea oa eiioo?ii Aaonna aiaeia?/ii oiio, ui niinoa??aaeinue
aeey N-iao?eoeue c i?ii?aeiei ai?noii aiaee.
Aneiao?e/ia oi?ia aeneoiiii? nioae iiaeeiaiiy, yea ?ai?oa niinoa??aaeany
aeey J-aa?aaao?a ??N oa TDBN
(5,5′,6,6′-tetrachloro-1,1′-diethyl-3,3′-di(4-sulfobutyl)-benzimidazoloc
arbocyanine), iiynith?oueny ?nioaaiiyi aia?aaoe/iiai aaceaaeaey o
J-aa?aaao?a, yea coiiaeth? aaonniao oi?io iecueei/anoioiiai e?ath
aeneoiiii? nioae iiaeeiaiiy oa ei?aioeaao oi?io ?? aeniei/anoioiiai
e?ath. Oea ia? i?noea ? aeey J-aa?aaao?a S120 i?e aaeeeiio (70%) ai?no?
aiaee o N-iao?eoe? (?en.2a). Ci?ia oi?ie iecueei/anoioiiai e?ath nioae
iiaeeiaiiy J-aa?aaao?a S120 o N-iao?eoe? c iaeei ai?noii aiaee (50%),
iia’ycaia c aeieeiaiiyi oiiieia?/iiai aaceaaeaey o iieaeoey?i?e
no?oeoo?? J-aa?aaao?a S120. Ei?aioeaaa oi?ia iecei/anoioiiai e?ath
aeneoiiii? nioae iiaeeiaiiy J-aa?aaao?a c oiiieiae/iei aaceaaeaeyi aoea
ia?aaeaa/aia iauiaeaaii o oai?aoe/i?e ?iaio? J. Knoester (1993).
Aiae?c no?oeoo?e J-aa?aaaoa S120 oa eiai nieueaaoii? iaieiiee o
C-iao?eoe? AeIOA-A aeicaieea cai?iiiioaaoe i?e?ineii?/io iiaeaeue
oi?ioaaiiy J-aa?aaao?a S120. Iniiaia ?aeay oe??? iiaeae? eaaeeoue o
i?eioeei? naeaeoeaii? nieueaaoaoe?? iieaeoeaie aiaee oa AeIOA iieaeoe
S120 aiane?aeie ?o aio?o?eueieo aeanoeainoae. Iieaeoee aiaee
nieueaaoothoue ia?aaaaeii ca?yaeaeaio o?iiioi?io /anoeio iieaeoe S120 o
iieaeoey?ieo eaioethaeeao J-aa?aaaoa oa iiai?noth a?aenooi? a?ey
aoaeaaiaeiaaeo ?aaeeeae?a N18I37. Aiane?aeie ??cii??aeiino? nieueaaoii?
iaieiiee J-aa?aaao?a S120 aeieeathoue cia/i? oeoeooaoe??
i?aeiieaeoey?ieo iie?a, eio?? i?ecaiaeyoue aei aia?aaoe/iiai aaceaaeaey,
nooo?ai a?eueoiio, i?ae aeey J-aa?aaao?a ??N /e ODBC. Inoaii? iathoue
iaeii??aeio nieueaaoio iaieiieo c ??aiii??iei ?iciiae?eii iieaeoe aiaee.
Oiio iiaia oe?eia ia i?aaenio? nioae iiaeeiaiiy J-aa?aaao?a S120 (380
ni-1) nooo?ai a?eueoa, i?ae aeey J-aa?aaao?a ??N (34 ni-1) oa
J-aa?aaao?a ODBC (160 ni-1).
Aeei?enoaiiy cai?iiiiiaaii? iiaeae? aoaeiae J-aa?aaao?a S120 aeicaiey?
iine?aeiaii iiynieoe aeieeiaiiy oiiieia?/iiai aaceaaeaey o no?oeoo??
J-aa?aaao?a S120 oa ci?io oi?ie aeiaaioaeeueiaiai e?ath aeneoiiii? nioae
iiaeeiaiiy, ui niinoa??aaeanue o aenia??iaio? (?en.2). C oe??? iiaeae?
c?icoi?ei, ui e?euee?noue aiaee o a?ia?i?e iao?eoe? AeIOA-A iiaea
nooo?ai aieeaaoe ia nooi?iue oii?yaeeoaaiiy aoaeaaiaeiaaeo ?aaeeeae?a. A
naia, i?e ca?eueoaii? ai?noo aiaee ciaioo?oueny i?ino??, aeinooiiee aeey
aoaeaaiaeiaaeo ?aaeeeae?a, aiane?aeie /iai o iieaeoey?ieo eaioethaeeao
J-aa?aaao?a aiie noathoue a?eueo oii?yaeeiaai?. O naith /a?ao
aoaeaaiaeiaaa eaiea N18I37 ae?? ye “aaae?eue”, aeaa?oath/e o?iiioi?io
/anoeio iieaeoee S120 c noiiee oii?yaeeiaaieo iieaeoe, oei naiei
ci?ithth/e oiiieia?/ia aaceaaeaey o no?oeoo?? J-aa?aaaoa. Ioaea, i?e
iaeiio (50%) ai?no? aiaee o a?ia?i?e iao?eoe? AeIOA-A aoaeaaiaeiaa?
?aaeeeaee N18I37 iaea?eueo ?icoii?yaeeiaai?, oa ia? i?noea cia/i?
oiiieia?/ia aaceaaeaey, eio?a ? i?e/eiith ci?ie oi?ie iecueei/anoioiiai
e?ath nioae iiaeeiaiiy J-aa?aaao?a (?en.2).
O i’yoiio ?icae?e? “Aeeiai?ea aeneoiiieo caoaeaeaiue J-aa?aaao?a c
oiiieia?/iei ? aia?aaoe/iei aaceaaeaeyi” iaaaaeaii ?acoeueoaoe
aenia?eiaioaeueiiai aeine?aeaeaiiy iecueeioaiia?aoo?ii? ethi?ianoeaioe??
J-aa?aaao?a S120 o N-iao?eoeyo AeIOA-A c iaeei ai?noii aiaee, a oaeiae
e?iaoeea na?o?iiy oa niaeo?e aei?ii?ithaaiiy, ?iciiae?eaii? o /an?,
J-aa?aaao?a S120 c ianoeaie aeneoiiieo caoaeaeaiue.
Anoaiiaeaiee ?ai?oa oaeo ia?aiino aia?a?? aeneoiiiiai caoaeaeaiiy
J-aa?aaao?a S120 ia aeneoiii? ianoee, ye? iaaienii iniaeeaei /eiii o
iaaieo e?eueeinoyo ca’ycoaaeenue c J-aa?aaaoaie, aoei aeei?enoaii aeey
iiaeaeueoiai ooi/iaiiy i?e?iaee oe?iei? iecueeioaiia?aoo?ii? nioae
ethi?ianoeaioe?? J-aa?aaao?a, o no?oeoo?? yeeo iaioaaei ia?aaaaeii
oiiieia?/ia aaceaaeaey. Niaeo?e na?o?iiy J-aa?aaao?a S120 c aeneoiiieie
ianoeaie (?en.3), eio?? ?iciiae?eai? o /an?, aeyaeee, ui nioaa na?o?iiy
J-aa?aaao?a S120 ia? neeaaeio no?oeoo?o. Aiia ae?enii neeaaea?oueny c
aeaio nioa. A?aeiinii aocueea, ei?ioeioaeeueiaa nioaa na?o?iiy a?eueieo
aeneoii?a (?en.3a- 2), yea aaneoueny aeneoiiieie ianoeaie (?en.3a-1) oa
ia? niaeo?aeueii-ethi?ianoeaioi? oa?aeoa?enoeee, eio?? noiae? c oaeeie
aeey nioae iecueeioaiia?aoo?ii? ethi?ianoeaioe?? J-aa?aaao?a ??N. Oe?iea
nioaa aei?ii?ithaaiiy, iaeneioi yei? cnoaa?oueny o iecueei/anoioiee e?ae
a caeaaeiino? a?ae cnoao /aniaiai a?eia (?en.3), iaoiiaeaia
ethi?ianoeaioe??th aaoieieae?ciaaieo aeneoii?a. Aei oiai ae ci?ia
iaeneioio, ?ioaineaiino? ? oe?eie oe??? nioae (?en.3) aeaco? ia
iacae?i/ai?noue i?ioeano aaoiei-eae?caoe?? aeneoii?a o J-aa?aaaoao S120
c ieeiii /ano ii??aiyii c /anii ?o aei?ii?ithaaiiy.
?en. 3. ?iciiae?eai? o /an? niaeo?e na?o?iiy J-aa?aaao?a S120 c
aeneoiiieie ianeaie i?e O=1,5E: a) 1-noaoe?iia?iee niaeo?; 2 – /aniaa
a?eii 0-0,1 in. a) 3 -/aniaa a?eii 0,4-1,4 in; 4 – /aniaa a?eii
1,5-3,5 in.
Ia a?aei?io a?ae nioae na?o?iiy aaoieieae?ciaaieo aeneoii?a, iaeneioi
nioae na?o?iiy aeneoiiieo ianoie oa ?? oe?eia o niaeo?ao, ui iathoue
?iciiae?euei?noue o /an? (?en.3), ia ci?iththoueny. Ci?ia ?ioaineaiino?
na?o?iiy o nioc? aeneoiiieo ianoie iia’ycaia ?c ci?iith /aniaiai a?eia
?a?no?aoe?? niaeo??a ii a?aeiioaiith aei /ano ia?aiino aeneoiiiiai
caoaeaeaiiy aei ianoie oa /ano ?o aei?ii?ithaaiiy.
O ?icae?e? i?iaiae?ciaaii iioiaeaeaiiy ii?iao aaoieieae?caoe?? aeneoii?a
o J-aa?aaaoao, oa aaaaeaii iiiyooy e?eoe/ii? aeiaaeeie aeaeieae?caoe??
aeneoiia, uiaei oiia eiai ia?aoiaeo aei aaoieieae?ciaaiiai noaio.
Aeniiaie. Iiaeaii iniiai? ?acoeueoaoe oa aeniiaee.
Iniiai? ?acoeueoaoe oa aeniiaee.
1. Ia i?aenoaa? aeine?aeaeaiiy nioa iiaeeiaiiy J-aa?aaao?a S120 oa
iaanioe?eiaaieo iieaeoe S120 o ?ic/eiao AeIOA-A ??ciiiai?oiiai neeaaeo ?
i?e ??cieo oaiia?aoo?ao anoaiiaeaii caaaeueio (?ciaanoe/io) oi/eo
ia?aoeio o n?iaenoa? niaeo??a iiaeeiaiiy, ui aeicaiey? c?iaeoe aeniiaee
i?i oa?iiaeeiai?/io ??aiiaaao i?ae ainaiaeai iiiiia??a ? J-aa?aaao?a c
aecia/aiei nooiaiai anioe?aoe?? (n-ia?e c aecia/aiei n). I?e oa?i?/iiio
?oeioaaii? J-aa?aaaoe S120 aeenioe?ththoue ia a?aeiia?aeia /enei
iiiiia??a, aac ooai?aiiy i?ii?aeieo n-ia??a c iaioei /eneii n.
2. Ci?ia oi?ie aeiaaioaeeueiaiai e?ath iecueeioaiia?aoo?ii? nioae
iiaeeiaiiy J-aa?aaao?a S120 i?e ci?i? ai?noo aiaee o N-iao?eoe? AeIOA-A
iia’ycaia ?c ci?iith oiiieia?/iiai aaceaaeaey o no?oeoo?? J-aa?aaaoa,
yeee caeaaeeoue a?ae oii?yaeeoaaiiy ?aaeeeae?a N18I37 i?ae aieeaii
iieaeoe aiaee o nieueaaoi?e iaieiioe?.
3. Nieueaaoia iaieiiea J-aa?aaao?a S120 o N-iao?eoe? AeIOA-A nooo?ai
iaiaeii??aeia aiane?aeie aea??eiai? nieueaaoaoe?? iieaeoeaie aiaee
aio?o?eueieo iieaeoe S120. Iaiaeii??aeia nieueaaoia iaieiiea J-aa?aaao?a
S120 aeeeeea? cia/ia aia?aaoe/ia oa oiiieia?/ia aaceaaeaey, eio?a
ia?aaa?oo? aiaeia?/ia aeey a?aeiieo J-aa?aaao?a ??N oa ODBC.
4. Oe?iea iecueeioaiia?aoo?ia nioaa na?o?iiy J-aa?aaao?a S120 ia?
neeaaeio no?oeoo?o ? neeaaea?oueny c aeaio nioa c a?aei?iieie
niaeo?aeueii-ethi?ianoeaioieie aeanoeainoyie. Aocueea ei?ioeioaeeueiaa
nioaa aaneoueny aeneoiiieie ianoeaie ? iaeaaeeoue aei na?o?iiy a?eueieo
aeneoii?a, ye? caa??aathoue ?ooeea?noue. Oe?iea aeiaaioaeeueiaa nioaa,
ui i?eeyaa? aei ia? iaeaaeeoue na?o?iith aaoieieae?ciaaieo aeneoii?a,
ye? ia aanyoueny aeneoiiieie ianoeaie.
5.I?aeaeuaiiy oiiieia?/iiai aaceaaeaey o no?oeoo?? J-aa?aaao?a S120
ni?e/eith? c?inoaiiy aoaeoeaiino? aaoieieae?caoe?? aeneoiiieo
caoaeaeaiue. Cieaeaiiy aa?’??o aaoieieae?caoe?? o oeueiio aeiaaeeo
coiiaeaii aeaiia i?e/eiaie: caaaeueiei c?inoaiiyi ii/aoeiai?
aeaoi?iaoe?? J-aa?aaao?a S120 oa a?eueo neeueiith eieae?caoe??th
aeneoiiiiai caoaeaeaiiy ia ae?eyioe? iieaeoey?iiai eaioethaeea, ui
cia/ii iineeth? aeneoii-oiiiiio aca?iiae?th.
Caaaeuei? ?acoeueoaoe ?iaioe a?aeia?aaeai? o ioae?eaoe?yo
1. Ethieianoeaioeey naiaiaeiuo e aaoieieaeeciaaiiuo yeneoiiia a
J-aa?aaaoao oeii-2-iiiiiaoei oeeaieia. / TH.A. Iaetheei, A.N. Eao?e/,
I.?. Aeiaoiae, E. Eaiieooe Iioeea e Niaeo?ineiiey. – 1998. – O.85,aui.4.
– N.577-580.
2. Ieceioaiia?aoo?iay niaeo?ineiiey aanii?yaeea a 1D nenoaiao
(J-aa?aaaoao). / TH.A. Iaetheei, I.A. Oiaia/aiei, A.N. Eao?e/, E.
Eaiieooe OIO. – 1998. – O.24, ?12. – N.1171-1180.
3. Mechanism of excitonic trapping in quasi-1D molecular chains
(J-aggregates). / Yu.V. Malyukin, O.G. Tovmachenko, G.S. Katrich, S.L.
Efimova, K. Kemnitz Molecular Crystals and Liquid Crystals. – 1998. –
V.324. – P.267-274.
4. Self-organization features of 1-methyl-1’-octadecyl-2,2’-cyanine
iodide molecular chains (J-aggregates) in dimethylformamide-water binary
solvents./ Yu V. Malyukin, O. G. Tovmachenko, G. S. Katrich, A. A.
Ischenko, K. Kemnitz Functional Materials – 1999- V.6, ?1 – P. 116-120.
5. Mechanism of excitonic trapping in quasi-1D molecular chains
(J-aggregates). / Yu.V. Malyukin, O.G. Tovmachenko, G.S. Katrich, S.L.
Efimova, K. Kemnitz Proc. “Electronic Processes in Organic Materials”.
– Kyiv (Ukraine). – 1998. – V. 22B. – P. 39.
6. Effect of anomalous intensification of the exciton band in a system
“J-aggregate-exciton trap” / Yu.V. Malyukin, O.G. Tovmachenko, G.S.
Katrich, K. Kemnitz Proc. The Jablonski Centennial Conference. – Torun
(Poland). – 1998. – P.105, page 191.
7. Investigation of J-aggregate disordering degree and its influence on
J-aggregate spectral characteristics. / Yu.V. Malyukin, O.G.
Tovmachenko, G.S. Katrich, K.Kemnitz Proc. The Jablonski Centennial
Conference. – Torun (Poland). – 1998. – P.153, page 259
A.N. Eao?e/ “Iioe/i? niaeo?e oa aeneoiiia aeeiai?ea J-aa?aaao?a c
aia?aaoe/iei oa oiiieia?/iei aaceaaeaeyi”.
Aeena?oaoe?y o oi?i? ?oeiieno ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa
o?ceei-iaoaiaoe/ieo iaoe ca niaoe?aeuei?noth 01.04.05 – iioeea, eaca?ia
o?ceea. – Oa?e?anueeee aea?aeaaiee oi?aa?neoao, Oa?e?a, 1999.
O aeena?oaoe?ei?e ?iaio? aeine?aeaeaii iioe/i? niaeo?e ? iniaeeaino?
ooai?aiiy oa ?oeioaaiiy J-aa?aaao?a aio?o?eueieo iieaeoe. Anoaiiaeaii
aca?iica’ycie oi?ie aeneoiiii? nioae iiaeeiaiiy c aia?aaoe/iei oa
oiiieia?/iei aaceaaeaeyi o iieaeoey?iiio eaioethaeeo J-aa?aaao?a.
C’yniaaii neeaaeio no?oeoo?o iecueeioaiia?aoo?ii? nioae ethi?ianoeaioe??
J-aa?aaao?a, eio?a oi?io?oueny na?o?iiyi a?eueieo oa aaoieieae?ciaaieo
aeneoii?a. Aeyaeaii cieaeaiiy aa?’??o aaoieieae?caoe?? aeneoii?a o
J-aa?aaaoao c a?eueo neeueiei oiiieia?/iei aaceaaeaeyi. Iaaeaii
i?e?ineiie/io iiaeaeue J-aa?aaao?a, ui aeicaiey? iine?aeiaii iiynithaaoe
niinoa?aaeai? iniaeeaino? iioe/ieo niaeo??a oa aeeiai?ee aeneoii?a o
J-aa?aaaoao S120 c aaeeeei aia?aaoe/iei oa oiiieia?/iei aaceaaeaeyi.
Eeth/ia? neiaa: Iioe/i? niaeo?e, aeneoiie, J-aa?aaaoe, aia?aaoe/ia
aaceaaeaey, oiiieiae/ia aaceeaaeaey.
G.S.Katrich. ”Optical spectra and exiton dynamics of J-aggregates with
energy and topological disorder “.
The dissertation in the manuscript form on the search of the scientific
degree of candidate of physical and mathematical sciences, speciality
01.04.05 – optics, leser physics. Kharkiv State University, Kharkov,
Ukraine, 1999.
In the dissertation the optical spectra and features of J-aggregates
amfiphilic molecules formation and destruction are investigated. The
interrelation of the exiton absorption band form with the energy and
topological disorder in the J-aggregates molecular chain is established.
The complex structure of the J-aggregate low-temperature luminescence is
shown. It is formed by both free and self-trapped exiton luminescence.
The exiton self-trapping barrier decreasing in J-aggregates with
stronger topological disorder is found out. The microscopic model of the
J-aggregates organization is given which allowed to explain consistently
observed features of the exiton optical dynamics in J-aggregate with
strong energy and topological disorder.
Keywords: optical spectra, exiton, J-aggregates, energy disorder,
topological disorder.
A.N.Eao?e/ “Iioe/aneea niaeo?u e yeneoiiiay aeeiaieea J-aa?aaaoia n
yia?aaoe/aneei e oiiieiae/aneei aanii?yaeeii”.
Aeenna?oaoeey a oi?ia ?oeiiene ia nieneaiea o/?iie noaiaie eaiaeeaeaoa
oeceei-iaoaiaoe/aneeo iaoe ii niaoeeaeueiinoe 01.04.05 – iioeea,
eaca?iay oeceea. Oa?ueeianeee ainoaea?noaaiiue oieaa?neoao, Oa?ueeia,
Oe?aeia, 1999.
A aeenna?oaoeeiiiie ?aaioa, ia iniiaaiee aeaoaeueiiai aiaeeca iioe/aneeo
niaeo?ia iiaeiuaiey J-aa?aaaoia S120 e iaannioeee?iaaiiuo iieaeoe S120 a
?anoai?ao AeIOA-A, onoaiiaeaiu iniaaiiinoe ia?aciaaiey e ?ac?ooaiey
J-aa?aaaoia aioeoeeueiuo iieaeoe. Ca?aaeno?e?iaaiiay iauay
(eciaanoe/aneay) oi/ea ia?ana/aiey a naiaenoaa niaeo?ia iiaeiuaiey, i?e
ia?aciaaiee J-aa?aaaoia S120 e a i?ioeanna eo oaiia?aoo?iiai ?ac?ooaiey,
iicaieeea naeaeaoue auaiae i oa?iiaeeiaie/aneii ?aaiiaanee iaaeaeo
ainaiaeai iiiiia?ia e J-aa?aaaoia n ii?aaeaeaiiie noaiaiueth
annioeeaoeee (ii?aaeaeaiiia /enei-n annioeee?iaaiiuo iieaeoe). A oiaea
aiaeeca niaeo?ia iiaeiuaiey J-aa?aaaoia S120 e iaannioeee?iaaiiuo
iieaeoe S120 a ?anoai?ao AeIOA-A a eioa?aaea oaiia?aoo? 10-70 0N
ca?aaeno?e?iaaii ia?a?ani?aaeaeaiea eioaineaiinoe iiaeiuaiey a iieina
iiiiia?ia e a J-iieina. I?e iaa?aaa ia?acoea aei 60 0N iaaethaeaeinue
iieiia en/aciiaaiea iieinu iiaeiuaiey J-aa?aaaoia. Oa?ie/aneia
?ac?ooaiea J-aa?aaaoia oa?aeoa?eciaaeinue eeiaeiui ?inoii eioaa?aeueiie
ieiuaaee iiae iieinie iiaeiuaiey iaannioeee?iaaiiuo iieaeoe S120 e
eaaae?aoe/iie caaeneiinoueth eciaiaiey eioaa?aeueiie ieiuaaee iiae
iieinie J-aa?aaaoia, a oaeaea caoeene?iaaii aeeeiiiaieiiaia niauaiea
iaeneioia iiaeiuaiey J-aa?aaaoia ii ia?a ?inoa oaiia?aoo?u ia?acoea.
Iieo/aiiua ?acoeueoaou iicaieytho ooaa?aeaeaoue, /oi oi?ie?iaaiea e
oaiia?aoo?iia ?ac?ooaiea J-aa?aaaoia S120 i?ioaeaao aac ia?aciaaiey
i?iiaaeooi/iuo n–ia?ia n iaeui /eneii-n.
Onoaiiaeaii eciaiaiea oi?iu aeeeiiiaieiiaiai e?ay ieceioaiia?aoo?iie
iieinu iiaeiuaiey J-aa?aaaoia S120 i?e eciaiaiee i?ioeaioiiai
niaea?aeaiey aiaeu a noaeeothuaeny iao?eoea. Oae i?e aieueoii
niaea?aeaiee aiaeu (70%) ieceioaiia?aoo?iue niaeo? iiaeiuaiey
J-aa?aaaoia S120, oae aea eae e niaeo? iiaeiuaiey J-aa?aaaoia PIC,
iienuaaeny ninoaaiui eiioo?ii Aaonna-Ei?aioea. I?e oiaiueoaiee
niaea?aeaiey aiaeu a noaeeothuaeny iao?eoea aei 50% iaaethaeaeanue
o?ainoi?iaoeey niaeo?a iiaeiuaiey J-aa?aaaoia e yenia?eiaioaeueiay
e?eaay iaeeo/oei ia?acii iienuaaeanue anneiao?e/iui eiioo?ii
Ei?aioea-Ei?aioea. O?ainoi?iaoeey ieceioaiia?aoo?iuo niaeo?ia iiaeiuaiey
naycaia n eciaiaieai yia?aaoe/aneiai e oiiieiae/aneiai aanii?yaeea a
iieaeoey?iie oeaii/ea J-aa?aaaoia. I?aaeeiaeaia iiaeaeue iaiaeii?iaeiie
nieueaaoaoeee J-aa?aaaoia S120 a ?anoai?a AeIOA-A. Aeaiiay iiaeaeue
iicaieyao iauynieoue iiyaeaiea a no?oeoo?a J-aa?aaaoa cia/eoaeueiiai
oiiieiae/aneiai e yia?aaoe/aneiai aanii?yaeea, eioi?ue i?aainoiaeeo
aiaeiae/iua oa?aeoa?enoeee aeey J-aa?aaaoia PIC e TDBC.
Iiaeoaa?aeaeaii, /oi oe?ieay ieceioaiia?aoo?iay iieina naa/aiey
J-aa?aaaoia S120 eiaao neiaeioth no?oeoo?o e ninoieo ec aeaoo iiein n
?aciuie niaeo?aeueii-ethieianoeaioiuie naienoaaie. Oceay,
ei?ioeiaieiiaay iieina oooeony yeneoiiiuie eiaooeaie e i?eiaaeeaaeeo
naiaiaeiui yeneoiiai, nio?aiythuei iiaeaeaeiinoue. I?eiueathuay e iae
oe?ieay aeeeiiiaieiiaay iieina i?eiaaeeaaeeo naa/aieth
aaoieieaeeciaaiiuo yeneoiiia, yeneoiiiuie eiaooeaie ia oooeony.
Ia iniiaaiee iieo/aiiuo yenia?eiaioaeueiuo ?acoeueoaoia onoaiiaeaii, /oi
iiauoaiea oiiieiae/aneiai aanii?yaeea a J-aa?aaaoao S120 i?eaiaeeo e
aic?anoaieth yooaeoeaiinoe aaoieieaeecaoeee yeneoiiiuo aicaoaeaeaiee.
Iiieaeaiea aa?uea?a aaoieieaeecaoeee, a yoii neo/aa, iaoneiaeaii aeaoiy
i?e/eiaie: iauei aic?anoaieai ia/aeueiie aeaoi?iaoeee iieaeoey?iuo
oeaii/ae e aieaa neeueiie eieaeecaoeeae yeneoiiiiai aicaoaeaeaiey ia
o?aaiaioa iieaeoey?iie oeaii/ee, eioi?ia i?eaiaeeo e oneeaieth eiinoaiou
yeaeo?iiii-eieaaaoaeueiiai acaeiiaeaenoaey.
Eeth/aaua neiaa: iioe/aneea niaeo?u, yeneoiiu, J-aa?aaaou,
yia?aaoe/aneee aanii?yaeie, oiiieiae/aneee aanii?yaeie.
Нашли опечатку? Выделите и нажмите CTRL+Enter
