I?I?NOA?NOAI INA?OE OE?A?IE

IAOe?IIAEUeIA A??IE*A AEAAeAI?ss OE?A?IE

EO?IAEUeIA

?ai? ?aaiiae/

OAeE 553.93:550.42.001.18

IOe?IEA OA I?IAIICOAAIIss AI?NOO OIENE*IEO

AEAIAIO?A A NENOAI? AOA?EEss — A??IE*A IANA —

I?IAeOEOE CAAAA*AIIss (IA I?EEEAAe?

*ENOssEIAI-NI?AEIssINUeEIAI AAIEIAI-

I?IIENEIAIAI ?AEIIO)

04.00.16 Aaieia?y oaa?aeeo ai?th/eo eiiaeei

Aaoi?aoa?ao

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa

aaieia?/ieo iaoe

Aei?i?iiao?ianuee-1999

Aeena?oaoe??th ? ?oeiien.

?iaioa aeeiiaia a Iaoe?iiaeuei?e a??ie/ee aeaaeai?? Oe?a?ie.

Iaoeiaee ea??aiee — aeieoi? aaieia?/ieo iaoe, i?ioani?, i?ioani?
eaoaae?e aaieia?? ?iaeiaeu ei?enieo eiiaeei Iaoe?iiaeueii? a??ie/i?
aeaaeai?? Oe?a?ie I?i?noa?noaa ina?oe Oe?a?ie (i. Aei?i?iiao?ianuee)
Aeia?iai?nueeee I.I.

Io?oe?ei? iiiiaioe:

-aeieoi? aaieia?/ieo iaoe, i?ioani?, caa?aeoaa/ eaoaae?e aaieia??
?iaeiaeu ei?enieo eiiaeei Aeiiaanueeiai a??ie/i-iaoaeo?a?eiiai ?inoeoooo
I?i?noa?noaa ina?oe Oe?a?ie (i. Ae/aanuee) Ai?iaee Aiaoie?e Oaaei?iae/.

-eaiaeeaeao aaieia?/ieo iaoe, a/aiee nae?aoa? I?eaei?i?ianueeiai
iaoeiaiai oeaio?o IAI Oe?a?ie (i. Aei?i?iiao?ianuee) Aa?ia Oaia?a
Aieiaeeie??aia

I?ia?aeia i?aai?caoe?y — ?inoeooo aaieia?/ieo iaoe IAI Oe?a?ie (i.
Ee?a), a?aeae?e aaieia?? aoa?eueieo ?iaeiaeu.

Caoeno a?aeaoaeaoueny “ 19 ” “ eenoiiaaea ” 1999 ?. i 14-00 aiaeei? ia
can?aeaii? niaoe?ae?ciaaii? ?aaee Ae 08.080.05 a Iaoe?iiaeuei?e a??ie/ee
aeaaeai?? Oe?a?ie (49027, i. Aei?i?iiao?ianuee, i?. E. Ia?ena 19).

C aeena?oaoe??th iiaeia iciaeiieoeny a a?ae?ioaoe? IAAO ca aae?anith:
49027,

i. Aei?i?iiao?ianuee, i?. E. Ia?ena, 19.

Aaoi?aoa?ao ?ic?neaiee “ 13 “ “ aeiaoiy ” 1999 ?.

A/aiee nae?aoa niaoe?ae?ciaaii? ?aaee,

eaiaeeaeao aaieia?/ieo iaoe
A.E.Eiciaee

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Iineeaiiy aeiia aei ioi?iie iaaeieeoiueiai na?aaeiaeua iaoiiaeth?
?icoe?aiiy ?ia?o ii aea/aiith oiene/ieo oa iioaioe?eii oiene/ieo
aeaiaio?a aoa?eey, ai?uoth/eo ii??ae, i?iaeoeo?a aoaeaaeaeiaooeo oa
ia?a?iaee aoa?eey, iaaacia/ieo caa?oaeiaiiyi iaaeieeoiueiai na?aaeiaeua
oa ii?ooaiiyi aeieia?/ii? ??aiiaaae.

Iniiaieie aeaiaioaie, ye? i?e ianiaiio niaethaaii? aoa?eey
caa?oaeiththoue iaaeieeoi? na?aaeiaeua, ?: S, Be, As, F, aeey eio?eo
a?aeii? aenie? ai?noe oiene/ieo niieo/aiue a iia?o??, aiae?, ye?
ia?aaeuothoue a?aie/ii aeiionoei? eiioeaio?aoe?? (AAeE). E??i oiai,
?nio? iaaaciaea i?noeaaiai caa?oaeiaiiy iaaeieeoiueiai na?aaeiaeua ca
?aooiie Pb, Ni, Mn, Cr, V, Co, niieo/aiiy eio?eo a?aeiinyoueny aei
iioaioe?eii oiene/ieo.

Ia oa?eoi??? *enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai ?aeiio i?e
aeine?aeaeaii? ai?noo oiene/ieo aeaiaio?a a aoa?ee? a?aecia/ai?
ia?aaeuaiiy ii?i AAeE: As a 1,6; Be a 1,4; Mn a 70; Pb a 14; V a 2; Cr a
2 ?ace. A a??ie/ee ian? a?aecia/ai? ia?aaeuaiiy ii?i AAeE: Cr -ii 11; Mn
oa V ii 6; Ni oa Pb — ii 4; Hg — ii 1 oaoo?. A i?iaeoeoao oa a?aeoiaeao
aoaeacaaaa/aiiy ia?aaeuaiiy a?aecia/aeinue ia an?o caaaa/oaaeueieo
oaa?eeao ?aeiio: Hg — eean AEI — ia 1, eean AI — ia 2; Mn — eean AEI —
ia 3, eean AN — ia 1, a?aeoiaee — ia 2; Cr — eean AI — ia 1, eean AO —
ia 4, a?aeoiaee — ia 4; V — eean AO — ia 1, a?aeoiaee — ia 4 oaa?eeao.
I?e aeine?aeaeaii? a?aeoiae?a aoaeaaeaeiaooeo a?aecia/ai? oae?
ia?aaeuaiiy AAeE As a 1,7; Pb a 30; Ni a 2,3; V a 1,5 ?ace.

Oe? oaeoe iaoiiaeththoue iayai?noue a a?oioiaiio iie?ea? oa i?aecaiieo
aiaeao ?aeiio ??cieo ca ianooaaaie oa ?ioaineaiino? cii caa?oaeiaiiy,
ye? iathoue eiiieaeniee oa?aeoa?. Aiae?c ?iciiae?eo oeeo cii iieaco?, ui
iniiaia ?ieue a caa?oaeiaii? iaaeieeoiueiai na?aaeiaeua iaeaaeeoue
aeaeiaoaiei oa caaaa/oaaeueiei i?aei?e?inoaai.

Aeooaeuei?noue oaie aeena?oaoe?eii? ?iaioe iaoiiaeaia iio?aaith ??oaiiy
ieoaiue ioi?iie iaaeieeoiueiai na?aaeiaeua ca ?aooiie ai?iaaaeaeaiiy a
ae?iaieoeoai iaoeiai iaa?oioiaaieo iaoiae?a i?iaiicoaaiiy oa
iiaeaethaaiiy ai?noo oiene/ieo aeaiaio?a a aoa?ee?, a??ie/ee ian?, oa
i?iaeoeoao caaaa/aiiy, ye? aeicaieyoue aecia/eoe oa nai?/anii cieceoe
ai?no oeeo aeaiaio?a o oiaa?i?e i?iaeoeoe?? oa a?aeoiaeao iaio ii?i
AAeE.

Aeena?oaoe?eia ?iaioa aeeiioaaeanue a Iaoe?iiaeuei?e a??ie/?e aeaaeai??
Oe?a?ie o a?aeiia?aeiino? aei oaie IA – 2,5 “Aaieiai-aeiiii?/ia ioe?iea
oaoiiaaiieo ?iaeiaeu, i?aaenoaaeaieo a?aeoiaeaie aoaeacaaaa/aiiy”.

Iaoa aeine?aeaeaiue — ?ic?iaea iaoiaeee i?iaiicoaaiiy oa iiaeaethaaiiy
ai?noo oiene/ieo aeaiaio?a a nenoai? aoa?eey – a??ie/a iana — i?iaeoeoe
caaaa/aiiy.

Aeey aeinyaiaiiy iinoaaeaii? iaoe iaiao?aeii aoei ae??oeoe ?yae
caaaeaiue:

-ioe?ieoe oa aecia/eoe caeiiii??iino? ?iciiae?eo oiene/ieo aeaiaio?a a
aoa?ee?, ai?uoth/eo ii?iaeao, a??ie/ee ian? oa i?iaeoeoao caaaa/aiiy;

— anoaiiaeoe aaio?i?/i? anioe?aoe?? oiene/ieo aeaiaio?a o aoa?ee?;

— i?iaanoe oei?caoe?th ai?uoth/eo ii??ae, ye caaaa/oth/eo, oae ?
?icoaiaeoth/eo a??ie/o iano oiene/ieie aeaiaioaie;

— ?ic?iaeoe iaoiaee i?iaiicoaaiiy oa iiaeaethaaiiy ai?noo oiene/ieo
aeaiaio?a a a??ie/ee ian? oa i?iaeoeoao caaaa/aiiy.

Iaoeia? iieiaeaiiy, ui caoeuathoueny aaoi?ii:

1. O?ni? ei?aeyoe?ei? ca’ycee i?ae oiene/ieie aeaiaioaie aeicaieythoue
aeei?enoiaoaaoe ?o aeey i?iaiicoaaiiy ai?noo oeeo aeaiaio?a o aoa?ee?
?aeiio.

2. ?aaoeueiaaia iinooieaiiy ai?uthth/eo ii??ae a a??ie/o iano ?
ea?iaaiei ia?aiao?ii ?? oiene/iino?.

3. Aaiaoe/i? ca’ycee oiene/ieo aeaiaio?a c i?aai?/iith oa i?ia?aeueiith
/anoeiith aoa?eey aeicaieythoue i?iaiicoaaoe ai?no oeeo aeaiaio?a a
i?iaeoeoao caaaa/aiiy.

Iaoeiaa iiaecia io?eiaieo ?acoeueoao?a iieyaa? a oiio, ui aeey
*enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai ?aeiio aia?oa:

— anoaiiaeai? aaio?i?/i? anioe?aoe?? oiene/ieo aeaiaio?a o aoa?ee?;

— ?ic?iaeai? iaoiaeeee i?iaiicoaaiiy ai?noo oiene/ieo aeaiaio?a a
a??ie/ee ian? oa i?iaeoeoao caaaa/aiiy;

— cai?iiiiiaai? iaoiaeeee iiaeaethaaiiy ai?noo oiene/ieo aeaiaio?a o
aoa?ee?, ai?uthth/eo ii?iaeao, ye? ? o aeaeiaooeo, a??ie/i? ian? oa
i?iaeoeo?a caaaa/aiiy.

I?aeoe/ia cia/aiiy ?iaioe iieyaa? a ?ic?iaoe? oa ai?iaaaeaeaii? o
ae?iaieoeoai iaoiae?a i?iaiicoaaiiy oa iiaeaethaaiiy ai?noo oiene/ieo
aeaiaio?a a a??ie/ee ian? oa i?iaeoeoao caaaa/aiiy, ui aeicaieythoue
caa/anii ia?aaeaa/aoe aeeiiaiiy oaoiieia?/ieo caoiae?a ii cieaeaiith
ai?noo oeeo aeaiaio?a ieae/a ii?i AAeE.

?acoeueoaoe aeena?oaoe?eii? ?iaioe ai?iaaaeaeai? ia oaooao: “Ci?y” (aeo
ai?iaaaeaeaiiy a?ae 19.06.1998 ?.), “Ni?aeiyinueea” (aeo ai?iaaaeaeaiiy
a?ae 11.08.1999 ?.) ae?iaie/iai ia’?aeiaiiy “Ni?aeiaaio?aoeeo” c iaoith
iie?ioaiiy yeino? iaeueiiai, ui aeaeiaoaa?oueny; a Oi?acuee?e
aaieiai?ica?aeoaaeuei?e aeniaaeeoe?? i?e aeaoaeuei?e ?ica?aeoe?
Ni?aeiyinueei? ieiu? (aeo ai?iaaaeaeaiiy a?ae 16.05.1999 ?.).

Iniaenoee aianie aaoi?a a i?aoeyo, ye? iioae?eiaai? c? ni?aaaoi?aie,
iieyaa? a ianooiiiio: [1, 2, 4, 6, 8, 9, 10, 11, 12, 13] — ca??
oaeoe/iiai iaoa??aeo, i?iaaaeaiiy /enaeueieo ?ic?aooie?a, oi?ioaaiiy
aeniiaeo, [5, 7] — ?ic?iaea iaoaiaoe/ii? iiaeae?, i?iaaaeaiiy
aenia?eiaioaeueieo ?ia?o, oi?ioaaiiy aeniiaeo.

Ai?iaaoe?y ?acoeueoao?a ?iaioe. Iniiai? ?acoeueoaoe ?iaioe
aeiiia?aeaeenue ia Ia??oiieuenuee?e aeieia?/i?e eiioa?aioe?? “Ia?a?iaea
a?aeoiae?a oa i/enoea no?/ieo aiae” o 1997 ?. (i. Ia??oiieue),
i?aeia?iaei?e iaoeiai-i?aeoe/i?e eiioa?aioe?? “?aa?ii – no?aoaa?y
aeaeeaaiiy ? ?icaeoeo Aeiiaano” o 1996 ?. (i. Aeiiaoeuee), Ae?oa?e
Ia??oiieuenuee?e aeieia?/i?e eiioa?aioe?? “Aeieia?y i?iieneiaiai i?noa”
o 1997 ?. (i. Ia??oiieue), Anaoe?a?inuee?e iaoeiai-iaoiaee/i?e
eiioa?aioe?? c i?aeia?iaeiith o/anoth “Aeieia?y oa ?iaeaia??y. Noai,
iane?aeee, oeyoe noai?aiiy aeieia?/ii /enoeo oaoiieia?e” o 1998 ?. (i.
Aei?i?iaeca?aeeinuee), i?aeia?iaei?e iaoeiai-i?aeoe/i?e eiioa?aioe??
“OOI noi??//y: i?iaeaie oa ia?niaeoeae inai?iiy ?iaeiaeu ei?enieo
eiiaeei” o 1998 ?. (i. Aei?i?iiao?ianuee), ?icoe?aiiio can?aeaii?
eaoaae?e aaieia?? oaa?aeeo iaeeaieo ei?enieo eiiaeei IAAO o 1998 ?. (i.
Aei?i?iiao?ianuee), i?aeia?iaei?e iaoeiai-i?aeoe/i?e eiioa?aioe??
“Aeooaeuei? i?iaeaie aaieia?? oa ?aoe?iiaeueiiai i?e?iaeiei?enooaaiiy” o
1999 ?. (i. Aei?i?iiao?ianuee), i?aeia?iaei?e eiioa?aioe?? “Aaciaea
aeeoo?ae?yeueiino? ia ii?ic? OOI noi??//y” o 1999 ?. (i. Aeoooa),
i?aeia?iaei?e iaoeiai-i?aeoe/i?e eiioa?aioe?? “Iaoai aoa?eueieo ?iaeiaeu
Oe?a?ie” o 1999 ?. (i. Aei?i?iiao?ianuee).

Ioae?eaoe??. ?acoeueoaoe aeena?oaoe?? iioae?eiaai? a 13 iaoeiaeo
noaooyo.

Aeena?oaoe?y ? ?oeiienii, yeee neeaaea?oueny c? anooio, /ioe?ueio
?icae?e?a, aeniiae?a oa nieneo aeei?enoaieo aeaea?ae. Ianya aeena?oaoe??
127 noi??iie, o oiio /ene? 105 noi??iie iniiaiiai oaenoo, 13
?ethno?aoe?e, 2 oaaeeoe? oa nienie aeei?enoaieo aeaea?ae c 102
iaeiaioaaiiyie.

Aaoi? aaey/iee aeieoi?o aaieia?/ieo iaoe, i?ioani?o Aeia?iai?nueeiio
I.I. ca iaoeiaa ea??aieoeoai oa iino?eio oaaao aei ?iaioe. Iaoeia?
eiinoeueoaoe?? oa i?aeoe/io aeiiiiiao iaaeaaaee aeieoi?e aaieia?/ieo
iaoe Iaai?iee TH.I., Iaai?iee A.I., I?eoiae/aiei A.O., eaiaeeaeao
aaieia?/ieo iaoe Nao?iiia ?.E. Aeeaieo aaey/i?noue aaoi? aeneiaeth?
eaiaeeaeaoo aaieia?/ieo iaoe ?oeiao A.A. ca aeiiiiiao a cai?? oa
ia?iaoe? oaeoe/iiai iaoa??aeo, iaoeia? eiinoeueoaoe?? oa iino?eio oaaao
ia an?o aoaiao aeeiiaiiy ?iaioe.

INIIAIEE CI?NO ?IAIOE

?ICAe?E 1

AIAE?OE*IEE IAEssAe OA CAAAeAIIss AeINE?AeAEAIUe

Ieoaiiyi aaio?i?? i?ioean?a ooai?aiiy aoaeaiinieo iieeaae?a,
?iciianthaeaeaiith oiene/ieo aeaiaio?a a aoa?ee? oa ai?uoth/eo ii?iaeao
i?enay/ai? ?iaioe Ia?aeueiaia I.?., E?c?eueooaeia E.ss., Ai?iaiai A.O.,
Iaiaoiai? I.O., TH?ianueeiai A.C., Eea? A.?., Aa?ie O.A., ?oeiaa A.A.

?ic?iaoe? iaoiae?a i?iaiicoaaiiy aaee/ei caa?oaeiaiiy aoa?eey
ai?uoth/eie ii?iaeaie i?enay/ai? ?iaioe Oe?ieiaa A.C., Naa?aeaanueeiai
A.E., Ni??iiaa A.A., Aeia?iai?nueeiai I.I., Iaai?iiai TH.I., Nao?iiiaa
?.E., ?oeiaa A.A.

Ieoaiiyi i?iaiicoaaiiy ai?noo i?ia?aeueieo eiiiiiaio?a i?e caaaa/aii?
aoa?eey i?enay/ai? ?iaioe ?acoiiaa E.A., A?othoeia I.A., A?aiianueeiai
TH.A., Ieo?ioaiiaa N.?., Caieyeiaa A.I.

Aiae?c ?ia?o, i?enay/aieo ieoaiiyi ?iciianthaeaeaiiy oiene/ieo aeaiaio?a
na?ae/eoue, ui a Aeiiaan? ?niothoue ??ci? ??ai? aea/aiino? ?iciiae?eo
oeeo aeaiaio?a a aoa?ee? oa ai?uoth/eo ii?iaeao a ??cieo ?aeiiao
aanaeio. Iaio aeine?aeaeaiei ? *enoyeiai-Ni?aeiyinueeee
aaieiai-i?iieneiaee ?aeii.

Iaeyae ?ia?o oaeiae iieacaa, ui a?eueo?noue aaoi??a aeae?ey? eiiieaen
aeaiaio?a ye?nieie iaoiaeaie c aeei?enoaiiyi e?i?eiiai eiao?oe??ioa
ei?aeyoe??, ui ?iaeoue io?eiaio ?ioi?iaoe?th iaiaae?eiith oa caeaaeiith
a?ae iaeeieoeue aei??o ai?noo aeaiaio?a.

Eeaneo?eaoe?y oa aiae?c ?ia?o, i?enay/aieo i?iaiicoaaiith aaee/ei
caa?oaeiaiiy ai?uothth/eie ii?iaeaie aoa?eey iieacaa, ui a i?aeoeoe?
i?iaiicieo iaoiae?a iiaeia aeae?eeoe: aaieiai-ae?aaiinoe/iee,
aaieiai-noaoenoe/iee, aaieiai-aaio?ce/iee ? iaoiae aiaeia?e. ?c
ia?a?aoiaaieo iaoiae?a, ia aeoieo aaoi?a, iaea?eueo i?eionoeiei aeey
a??ie/i-aaieia?/ieo oa a??ie/i-oaoi?/ieo oiia *enoyeiai-Ni?aeiyinueeiai
aaieiai-i?iieneiaiai ?aeiio ? ai?iaiaaiee ia oaooao aaieiai-noaoenoe/iee
iaoiae.

Iaeyae iaoeiaeo ?ia?o c ieoaiue caaaa/aiiy aoa?eey aeicaieea anoaiiaeoe,
ui a oeae /an oaaaa caa?iooa aei ieoaiue i?iaiicoaaiiy cieueiino? o
i?iaeoeoao ia?a?iaee aoa?eey, oa i?aeoe/ii a?aenooi? ?iaioe, uiaei
i?iaiicoaaiiy ai?noo oiene/ieo aeaiaio?a (AOA) a i?iaeoeoao caaaa/aiiy
aoa?eey.

Aiae?oe/iee iaeyae iaoeiaeo ?ia?o c ieoaiue i?iaiicoaaiiy ai?noo
oiene/ieo aeaiaio?a o aoa?ee?, a??ie/ee ian?, i?iaeoeoao caaaa/aiiy
aeicaieea anoaiiaeoe ?nioaaiiy aaaeeeai? iaoeiai? oa i?aeoe/ii?
i?iaeaie, noi?ioethaaoe iaoo oa caaaeaiiy, ye? iaaaaeai? a caaaeuei?e
oa?aeoa?enoeoe? aeena?oaoe??.

?ICAe?E 2

IAOIAeEEA AEEIIAIIss ?IA?O, IA’AEOE OA IANssAE AeINE?AeAEAIUe

Aeey aeinyaiaiiy iinoaaeaii? iaoe aoee aeine?aeaeai? ia AOA a aoa?ee? oa
ai?uoth/eo ii?iaeao 876 aiae?c?a, io?eiai? i?e ia?aoei?
aaieiai?ica?aeoaaeueieo naa?aeeiaei, 121 aiae?c ia AOA a a??ie/ee ian?,
69 aiae?c?a ia AOA a i?iaeoeoao caaaa/aiiy aoa?eey. Aoee i?iaiae?ciaai?
287 ea?ioaaeieo ae?aa?ai oa ii?iaeueieo no?aoea?ao?/ieo ?ic??c?a,
aeaoaeueii aea/ai? 53 c?acea oa 24 aeoae?eaoa c?ace?a ea?ia
?ica?aeoaaeueieo naa?aeeiaei. Aaoi?ii aoee a?ae?a?ai? ia oaooao
*enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai ?aeiio aeey
aeine?aeaeaiiy AOA: a aoa?ee? 48 i?ia, 31 i?iaa ia AOA a a??ie/?e ian?,
39 i?ia ia AOA a i?iaeoeoao caaaa/aiiy, 25 i?ia ia aoa?eueieo neeaaeao.
I?iae aoee a?ae?a?ai? oaeiae ia aoa?eueieo neeaaeao oaoo oa
caaaa/oaaeueieo oaa?eeao a?aeiia?aeii aei AINO 9815-75, AINO 10442-71 oa
AINO 16094-78. Aecia/aiiy iia??oiino? a?aeai?o oa ia?iaee i?ia
i?iaiaeeeiny o a?aeiia?aeiino? c NO NYA 4384-83. An? i?iae
aiae?coaaeenue o eaai?aoi??yo Ai?e?anueei? oa A?oai?anueei? A?A.

Ae?oaee aoai iieyaaa o i?iaaaeaii? eaai?aoi?ieo aeine?aeaeaiue aoa?eey
aoaeaiao?ia?ao?/ieie oa i?ia?aeia?/ieie iaoiaeaie.

Noaoenoe/ia ia?iaea ?acoeueoao?a niaeo?aeueieo aiae?c?a aeeiioaaeanue c
aeei?enoaiiyi i?ia?ai Statistica 5.773, Mathematica 3.1, Statgrafics
1.0, Mathcad 7 Pro, Excel 97, SPSS 7.0 oa aeeth/aea:

a) ?ic?aooiie iniiaieo noaoenoe/ieo oa?aeoa?enoee aii??e/ieo
?iciiae?eaiue oiene/ieo aeaiaio?a (na?aaei?o oa iiaeaeueieo cia/aiue,
aeenia?n??, eiao?oe??io?a aa??aoe??, aneiao???, aenoeano oa ?io?);

a) ?ic?aooiie oa aiae?c eiao?oe??io?a e?i?eii? oa aaia-ei?aeyoe??,
ei?aeyoe?? Ni??iaia oa Eaiaeaeea c iaoith aeyaeaiiy ia?aaaiaoe/ieo
anioe?aoe?e oiene/ieo aeaiaio?a;

a) ?aiaeoaaiiy aaee/ei ei?aeyoe?eieo ca’yce?a oa ?ic?aooiie ??aiyiiy
?aa?an?? iioeiaeueii ai?ieneioth/eo caeaaeiinoae i?ae aeaiaioaie, ye?
aoiaeyoue a anioe?aoe?th;

a) aeeiiaiiy aeene?ei?iaioiiai oa eeanoa?iiai aiae?c?a c iaoith
anoaiiaeaiiy ?yae?a nii??aeiaiino? oiene/ieo aeaiaio?a c i?aai?/iith
?a/iaeiith aoa?eey a on?o ?iai/eo ieanoao *enoyeiai-Ni?aeiyinueeiai
?aeiio. Oea aeicaieeei aeyaeoe aaio?i?/i? anioe?aoe?? aac aeei?enoaiiy
a?iioaoe/ieo i?eiouaiue a?aeiinii aeaeo ooieoe?? ?iciiae?eaiiy ?o
aaia?aeueieo noeoiiinoae oa iaeeieoeue aei??o. Ia’?aeiaiiy aeaiaio?a
i?iaiaeeeinue i?e iayaiino? aeaio eiao?oe??io?a ei?aeyoe?? ia iaio 0,5
oa aeia??/i? eiia??iino? 95%.

I?e ioe?ioe? ca’yceo oiene/ieo aeaiaio?a c i?aai?/iith oa i?ia?aeueiith
/anoeiaie aoa?eey aoee aeei?enoai? eiao?oe??ioe: nii??aeiaiino? c
i?aai?/iith /anoeiith, i?eaaaeaiith eiioeaio?aoe??th oa i?eaaaeaiei
aeoyaaiiyi, ia iniia? yeeo aoea i?iaaaeaia oei?caoe?y ai?uoth/eo ii??ae,
ye caaaa/oth/eo oa ?icoaiaeoth/eo a??ie/o iano oiene/ieie aeaiaioaie.

I?e ?ic?iaoe? ei?ioeino?ieiaiai i?iaiicoaaiiy, iaoiaeeee iiaeaethaaiiy
AOA a a??ie/ee ian? oa i?iaeoeoao caaaa/aiiy aoa?eey aoa aeei?enoaiee
iaoiae noaoenoe/iiai ieaioaaiiy –“/i?iee” yuee c ai??i?iei oyaeaiiyi i?i
ia’?eoe aeine?aeaeaiue. Aaeaeaaoi?noue iiaeae? ia?aa??yeanue ca
e?eoa??yie O?oa?a, Nouethaeaioa.

I?e na?aaeiueino?ieiaiio i?iaiicoaaii? oiene/iino? a??ie/i? iane aeey
aecia/aiiy i?e?iuaiiy iiooaeiino? oi?, ui aeeia?oueny, aoa aeei?enoaiee
aaieiai-noaoenoe/iee iaoiae i?iaiicoaaiiy A.A.I. “Aeiiaanaaieia?y”,
ai?iaiaaiee ia oaooao *enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai
?aeiio.

Ia’?eoaie aeine?aeaeaiiy aoee iieeaaee aoaeaiinii? oi?iaoe??
*enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai ?aeiio. C iaoith
iie?ioaiiy a??ia?aeiino? oa oi/iino? oa?aeoa?enoee oa caeiiii??iinoae,
ui aeine?aeaeoaaeenue, aoei i?iaaaeaii ?aeiioaaiiy ieiu?, aieiaiei
e?eoa???i yeiai noaee a??ie/i-aaieia?/i? oa aoaeaiao?ia?ao?/i?
iniaeeaino? oaooiieano?a. A ?acoeueoao? aoee aeae?eai? oae? ieiu?:
i?ai?/ia — ieanoe na?oe N23 o/o “Aieeinueea” oa oaooa “E?nia”. No?aeia —
oaooe “Ci?y”, “I?ai?/ia”, “I?onueea”, “Ni?aeiyinueea”. I?aaeaiia – oaooe
“Oaea?iee”, “Aeiiaoeueea”, ?i. E?nae?aa. Cao?aeia – oaooe “I?ia?an” oa
?i. Eoooa?ia. Na?oa N25 — ieanoe na?oe N25 o/o “Aieeinueea”, oaooe:
3-a?n, “*a?aiia C??ea”, “Ia’?aeiaia”, o/o “Oi?acueea”. Aoaeaai?uoth/?
ii?iaee ?aeiio aoee iiae?eai? ia 3 e?oieiai-aaio?i?/i? a?oie: ia?oa –
ii?iaee na?oe N23 i?ai?/ii-no?aeii? /anoeie ?aeiio, ae?oaa – ii?iaee
na?oe N23 i?aaeaiii-cao?aeii? /anoeie ?aeiio oa o?aoy – na?oa N25.

Aeei?enoaiiy aeaiiai ianyao oaeoe/iiai iaoa??aeo, eiiieaeniiai iaoiaeo
aeine?aeaeaiue aeicaieeei io?eiaoe aeinoia??i? ?acoeueoaoe oe??? ?iaioe.

?ICAe?E 3

CAEIIII??IINO? ?ICIIAe?EO OIENE*IEO AEAIAIO?A A AOA?EE? OA AI?UOTH*EO
II?IAeAO *ENOssEIAI-NI?AEIssINUeEIAI AAIEIAI-I?IIENEIAIAI ?AEIIO

Aiae?c ?acoeueoao?a aeene?ei?iaioiiai oa eeanoa?iiai aiae?c?a,
?ic?aoiaaieo eiao?oe??io?a nii??aeiaiino? c i?aai?/iith /anoeiith,
i?eaaaeaii? eiioeaio?aoe?? oa i?eaaaeaiiai aeoyaaiiy aeicaieea
anoaiiaeoe ?yaee nii??aeiaiino? oiene/ieo aeaiaio?a c i?aai?/iith
/anoeiith aoa?eey ii ieanoao:

ia i?ai?/i?e ieiu? — h11i — Aa > Ni, V, Cr, Co > Hq, As, F, Mn, Pb; h10a
— Be, Mn > As, Ni, V, Cr, Co > Hq, F, Pb; h8 — Be, Mn > V, Ni, Cr, Co >
Hq, F, Pb; h7 — Be, Mn > Ni, Cr,Co > Hq, As, F, Pb, V;

ia no?aei?e ieiu?: h7 — Be, Mn > Ni, V, Cr, Co > F, Pb; h61 — Be, Mn >
Ni, V, Cr, Co > Hq, As, F, Pb; h31 — Be, Mn > Ni, V, Cr, Co > Hq, As, F,
Pb; h21 — Be, Mn > Hq, As, Ni, Cr > F, Pb, Co;

ia i?aaeaii?e ieiu?: h61 — As, Be, Mn, Ni, Co > V >F, Pb, Cr; h4a — As,
Mn, Co > Be, Ni > Hq, F, Pb, V, Cr; h3 — As, Be, Mn, Ni, Co >> Hq, F,
Pb, V, Cr; h21 — Be, Mn > Hq, F > Pb, V, Cr, Co;

ia cao?aei?e ieiu?: h8 — Mn, As, Ni ,Co >> Be, Pb, V, Cr; h7 — F, Mn, Co
> Hq, Be, V > Pb, Ni, Cr;

na?oa N25: k41 — Be > Hq, As, Pb, Co > F, Mn, Ni, V, Cr; k3 — Hq > As,
Be, Pb > F, Mn, Ni, V, Cr, Co; k22 — Hq > Be, F > Mn, Pb, Ni, V, Cr, Co;
k2 — Hq, V, Co > As, Be, Mn, Cr > F, Pb, Ni.

Ia ieiu? ?aeiio aoee anoaiiaeai? oae? iniiai? caeiiii??iino? ?iciiae?eo
oiene/ieo aeaiaio?a a aoa?ee? oa i?iaeoeoao caaaa/aiiy, oa ?o aaio?i?/i?
anioe?aoe??:

Hg. Eiao?oe??io cono??/? a aio?aoeeoao ?aeiio a?ae io 0 aei 80%.
Ia?aaeuaiiy AAeE a aoa?ee? ?aeiio ia a?aecia/aii, o ai?uoth/eo ii?iaeao
aiii oa?aeoa?ii aeey neaioe?a aoaeenoeo, aeeienoeo oa i?uaieo
i?ai?/ii-no?aeii? oa i?aaeaiii-cao?aeii? ieiu.

A anioe?aoe?th aoiaeyoue: S – eiao?oe??io ei?aeyoe?? a?ae 0,537 aei
0,741 ii ieanoao h11i, h7 i?ai?/ii?, h7 no?aeii?, h61 i?aaeaiii? ieiu oa
ieano?a na?oe N25. As – r a?ae 0,562 aei 0,593 ii ieanoao h11i i?ai?/ii?
oa h61 no?aeii? ieiu. V – r 0,518 ii ieanoo h7 no?aeii? ieiu?. Pb – r
0,521 ii ieanoo h21 i?aaeaiii? ieiu?. F – r 0,664 ii ieanoo h31 no?aeii?
ieiu?. Mn – r 0,673 ii ieanoo h21 i?aaeaiii? ieiu?.

Iaeneiaeueiee ai?no Hg a i?iaeoeoao caaaa/aiiy niinoa??aa?oueny o
o?aeoe?yo ?c

cieuei?noth 6,2 – 14,7%: a) OeCO “Ni?aeiyinueea” Hg = 7E – 06Ad3 –
0,0008Ad2 + 0,0245Ad + 0,1979,

R2 = 0,508; a) OeCO “Aeiiaoeueea” Hg = — 2E – 06Ad4 + 0,0002Ad3 –
0,0085Ad2 + 0,0931Ad + 0,268,

R2 = 0,768; a) OeCO ?i. E?nae?aa Hg = — 1E — 06Ad4 + 0,0002Ad3 –
0,0116Ad2 + 0,283Ad – 1,1765,

R2 = 0,898; a) OeCO “Oi?acueea” Hg = — 2E — 07Ad4 + 3E — 05Ad3 –
0,001Ad2 + 0,0112Ad + 0,1712,

R2 = 0,948; ae) AeCO “*a?aiia C??ea” Hg = — 5E — 06Ad3 + 0,0005Ad2 –
0,046Ad + 0,5381, R2 = 0,565.

As. Eiao?oe??io cono??/? — a?ae 0 aei 80%. A aoa?ee? ieano?a h8
i?ai?/ii? ieiu?, h7 no?aeii? oa cao?aeii?, h21 i?aaeaiii? ieiu? ai?noo
As ia a?aei?/aii. Ia?aaeuaiiy AAeE ? oa?aeoa?iei aeey aoa?eey ieano?a
h10a, h8 i?ai?/ii?, h3, h4a i?aaeaiii? ieiu. O ai?uoth/eo ii?iaeao
ia?aaeuaiue AAeE ia a?aei?/aii.

A anioe?aoe?th As aoiaeyoue: S – r a?ae 0,501 aei 0,689 ii ieanoao h10a
i?ai?/ii?, h61 no?aeii?, ieanoao i?aaeaiii?, h8 cao?aeii? ieiu, k22. Hq
– r a?ae 0,562 aei 0,593 ii ieanoao h11i i?ai?/ii?, h61 no?aeii? ieiu?.
Ni – r a?ae 0,567 aei 0,667 ii ieanoao h31 no?aeii?, h4a i?aaeaiii?
ieiu?. Pb – r a?ae 0,503 aei 0,663 ii ieanoao h7 oa h31 no?aeii?, h4a
i?aaeaiii?, ieanoao cao?aeii? ieiu?. Nr – r a?ae 0,560 ii ieanoo h4a
i?aaeaiii? ieiu?. Ni – r 0,952 ii ieanoo h7 cao?aeii? ieiu?. Be – r
0,510 ii ieanoo k3. Eiieo?oth/eie ?: F – a?ae 0.584 aei 0.617 ii ieanoao
h7 oa h21 no?aeii? ieiu?. V – r – 0.614 ii ieanoo h7 no?aeii? ieiu?.

Iaeneiaeueiee ai?no a i?iaeoeoao caaaa/aiiy ?c cieuei?noth 6,2 – 14,7%:
a) As = 0,0338Ad2 –

-3,4903Ad + 127,65, R2 = 0,729; a) As = 0,0107Ad2 – 1,2007Ad + 30,595,
R2= 0,737; a) As = —

-0,0012Ad3+ 0,1815Ad2 – 8,5903Ad + 148,58, R2 = 0,972; a) As = 2E- —
05Ad4 – 0,0036Ad3 + 0,2651Ad2 –

-7,0509Ad + 91,207, R2 = 0,971; ae) As = 0,0316Ad2 – 3,4991Ad + 105,16,
R2 = 0,885.

Be. Eiao?oe??io cono??/? — a?ae 45 aei 100%. Ia?aaeuaiiy AAeE aoei
a?aei?/aii aeey ieano?a h10a oa h7 i?ai?/ii? ieiu?. O ai?uoth/eo
ii?iaeao ia?aaeuaiiy ia a?aecia/aeinue.

Anioe?aoe?y: Mn – r a?ae 0,554 aei 0,691 ii ieanoao h8 i?ai?/ii?, h7
cao?aeii? ieiu oa k3. V — r a?ae 0,512 ii ieanoo h61 no?aeii? ieiu?. Ni
— r 0,722 ii ieanoo h61 no?aeii? ieiu?. Co – r a?ae 0,578 aei 0,936 ii
ieanoao h61 oa h31 no?aeii?, h3 i?aaeaiii? ieiu. Be – r 0,510 ieanoa k3.
Eiieo?oth/ei ?: Pb – r a?ae –0,603 aei –0,630 ii ieanoao h11i i?ai?/ii?
oa h61 i?aaeaiii? ieiu. Cr – r a?ae –0,536 aei 0,548 ii ieanoao h8
i?ai?/ii?, h7 no?aeii?, ieanoao cao?aeii?, h4a i?aaeaiii? ieiu. F – r
a?ae –0,554 aei –0,773 ii ieanoao h7, h31 no?aeii? ieiu?. V – r a?ae
–0,537 ii ieanoao h8 i?ai?/ii?, h61, h4a i?aaeaiii? ieiu.

Ciaioaiiy ai?noo Mn ii ieanoao h8 e h7 c i?ai?/ii? ieiu? ia cao?aeio
a?aeiia?aeii: a?ae 12,1 a/o oa 8,8 a/o aei 3,7 a/o oa 1,2a/o Ciaioaiiy
ai?noo ?c no?aeii? ieiu? ia cao?aeio iacia/ia — a?ae 1,8 a/o aei 1,2 a/o
ii ieanoo h7 cao?aeii? ieiu?.

Iaeneiaeueiee ai?no a i?iaeoeoao caaaa/aiiy ?c cieuei?noth 6,2 – 14,5%:
ae) Be = — 2E – 0,5Ad4+ + 0,0027Ad3 – 0,1254Ad2 + 2,1668Ad – 9,948, R2 =
0,731; a) Be = 9E – 0,6Ad3 — 8E – 0,5Ad2 – 0,0757Ad+ + 3,6887, R2 =
0,939; a) Be = — 1E Ad3 + 0,0006Ad2 – 0,0789Ad + 4,157, R2 = 0,936; ii
?ioeo: a) Be = — -0,003Ad3 + 0,00382Ad2 – 1,1473Ad + 11,536, R2 =
0,684; a) Be = — 0,0001Ad3 + 0,0119Ad2 – 0,3725Ad+ + 5,1569, R2 = 0,556

iaea?eueoee ai?no o o?aeoe?yo cieuei?noth 35 – 42%.

F. Eiao?oe??io cono??/? — a?ae 33 aei 100%. Ia?aaeuaiiy AAeE a aoa?ee?
ia a?aecia/aii, o ai?uoth/eo ii?iaeao ia?aaeuaiiy AAeE a neaioeyo
aeeienoeo i?ai?/ii-no?aeii? oa i?aaeaiii-cao?aeii? ieiu; neaioeyo
i?uaieo i?aaeaiii-cao?aeii? ieiu?.

Anioe?aoe?y: Pb – r 0,949 ii ieanoo h10a i?ai?/ii? ieiu?. Ni – r 0,596
ii ieanoo h10a i?ai?/ii? ieiu?, S – r 0,654 ieanoa h10a i?ai?/ii? ieiu?.
Hq – r 0,664 ii ieanoo h31 no?aeii? ieiu?. Eiieo?oth/eie ?: As – r a?ae
–0,584 aei –0,617 ii ieanoao h7, h21 no?aeii? ieiu?. Mn – r –0,540 ii
ieanoo h31 no?aeii? ieiu?.

In. Eiao?oe??io cono??/? — 100%. Ia?aaeuaiiy AAeE aoei a?aecia/aia a
ieanoao i?aaeaiii? oa i?ai?/ii? ieiu, h7 oa h61, h31 no?aeii? ieiu?,
ieanoao cao?aeii? ieiu? oa k22. Ai?no Mn ia?aaeuo? AAeE o neaioeyo
aoaeenoeo oa aeeienoeo an?o ieiu, neaioeyo i?uaieo na?oe N25.

Anioe?aoe?th neeaaeathoue: Pb – r 0,712 ii ieanoo h21 no?aeii? ieiu?. Hq
– r a?ae 0,583 aei 0,673 ii ieanoao h11i i?ai?/ii?, h21 i?aaeaiii? ieiu.
Co – r 0,809 ii ieanoo h10a i?ai?/ii? ieiu?. Be – r a?ae 0,554 aei 0,619
ii ieanoao h8 i?ai?/ii?, h7 cao?aeii? ieiu oa ieanoa k3. V – r 0,507 ii
ieanoo k3. Ni – r 0,566 ii ieanoo k3. Eiieo?oth/eie ? :V – r a?ae –0,543
aei –0,713 ii ieanoao h8 i?ai?/ii?, h7, h21 no?aeii? ieiu. F — -0,540 ii
ieanoo h21 no?aeii? ieiu?. Cr – r a?ae –0,621 aei –0,685 ii ieanoao h7
no?aeii?, h61 i?aaeaiii? oa h7 cao?aeii? ieiu.

Iaeneiaeueiee ai?no a i?iaeoeoao caaaa/aiiy: ae) Mn = — 6E – 0,5Ad5 +
+0,0095Ad4 –

-0,5396Ad3 + 13,824Ad2 – 160,02Ad + 1040, R2 = 1; a) Mn = 2E – 0,5Ad5 –
0,003Ad4 + 0,1711Ad3 –

-4,3196Ad2 + 49,316Ad + 248,65, R2 = 1 — ?c cieuei?noth 6,2 – 14,5%, ii
?ioeo: a) Be = — 0,0002Ad5 + +0,0224Ad4 – 1,1599Ad3 + 26,776Ad2 –
267,41Ad + 1408,6, R2 = 1; a) Be = — 1E – 0,5Ad5 + +0,0027Ad4 –
0,2554Ad3 + 10,746Ad2 – 196,86Ad + 1599,6, R2 = 0,927; a) Mn = 2E –
0,5Ad5 – -0,003Ad4 + 0,1711Ad3 – 4,3196Ad2 + 49,316Ad + 248,65, R2 =
1wmetafile8? ??T?????????????
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???&??yyyy?????Ayyy¦yyya???AE?? ???&?
?MathType??P????&??yyyy????????????????????????????????????????????
?? ????????????????????????- ?c cieuei?noth 32,3 – 42,5%.

Pb. Eiao?oe??io cono??/? — 100%. A ieanoao i?ai?/ii? ieiu?, h7, h31 oa
h21 no?aeii? ieiu?, h8, h7 cao?aeii? ieiu?, ieanoao na?oe N25, a
neaioeyo i?ai?/ii-no?aeii? oa aoaeenoeo neaioeyo i?aaeaiii-cao?aeii?
ieiu niinoa??aa?oueny ia?aaeuaiiy AAeE.

A anioe?aoe?th aoiaeyoue: Ni – r a?ae 0,515 aei 0,825 ii ieanoao h10a,
h8, h7 i?ai?/ii? ieiu?, k41, k22, k2. S – r a?ae 0,507 aei 0,612 ii
ieanoao h10 i?ai?/ii?, h21 no?aeii?, h8 cao?aeii? ieiu. F – r 0,949 ii
ieanoo h10a i?ai?/ii? ieiu?. V – r 0,809 ii ieanoo h8 i?ai?/ii? ieiu?.
Cr – r a?ae 0,509 aei 0,929 ii ieanoao h10a, h8 i?ai?/ii?, h31 no?aeii?,
h61 i?aaeaiii? ieiu, k22. Ni – r a?ae 0,584 aei 0,594 ii ieanoao h7
i?ai?/ii? ieiu? oa k41. Mn – r 0,712 ii ieanoo h21 no?aeii? ieiu?. Hq –
r 0,521 ieanoa h21 no?aeii? ieiu?. As – r a?ae 0,503 aei 0,663 ii
ieanoao h7, h31 no?aeii? ieiu?, h8, h7 cao?aeii? ieiu. Eiieo?oth/?: Be

r a?ae –0,603 aei –0,630 ii ieanoao h11i i?ai?/ii? oa h61 i?aaeaiii?
ieiu. S – r a?ae –0,619 aei –0,622 ii ieanoao h61 oa h4a i?aaeaiii?
ieiu?. V – r a?ae 0,60 aei 0,603 ii ieanoo h61 i?aaeaiii? ieiu?. Co – r
–0,539 ii ieanoo h61 i?aaeaiii? ieiu?. Mn – r –0,691 ii ieanoo h8
i?ai?/ii? ieiu?.

A aoa?ee? ieano?a i?ai?/ii? ieiu?, h7, h3, h21 no?aeii?, h4a,
h21i?aaeaiii? ieiu, k3 aoa anoaiiaeaiee ei?aeyoe?eiee ca’ycie r – a?ae
0,618 aei 0,811 i?ae ai?noii Pb oa cieuei?noth. Aeey aoa?eey ieano?a
na?oe N25 ca’ycie iieno?oueny oi?ioeith: Pb = — 4E – 05Ad3 + 0,0037Ad2 +
0,4192Ad + 3,1998, R2 = =0,531; aeey aoa?eey ieano?a na?oe N25 Pb =
33,198e-1,8359Ad, R2 = 0,503.

Iaeneiaeueiee ai?no a i?iaeoeoao caaaa/aiiy a cieueieo o?aeoe?yo 60 –
70%: a) Pb ? 10,975 lnAd – 11,68, R2 = 0,808; a) Pb = 4,964 ln Ad +
2,566, R2 = 0,848; a) Pb = 8,9934 lnAd – 9,966, R2 = =0,964; a) Pb =
7,944 lnAd – 5,6, R2 = 0,715; ae) Pb = 9,1611lnAd – 14,159, R2 = 0,888.

V. Eiao?oe??io cono??/? — 100%. Ia?aaeuaiiy AAeE a ieanoao i?ai?/ii?
ieiu?, h7, h31 no?aeii? ieiu? oa ieano?a N25,o ai?uoth/eo ii?iaeao: o
neaioe?a aoaeenoeo oa aeeienoeo an?o ieiu, neaioeyo i?uaieo
i?aaeaiii-cao?aeii? ieiu? oa na?oe N25.

Anioe?aoe?th neeaaeathoue: Hq – r 0,518 ii ieanoo h7 i?ai?/ii? ieiu?. Be
– r 0,512 ii ieanoo h61 no?aeii? ieiu?. Mn – r 0,507 ii ieanoo k3. Pb –
r 0,809 ii ieanoo h8 i?ai?/ii? ieiu?. Ni – r a?ae 0,511 aei 0,805 ii
ieanoao i?ai?/ii? ieiu?, h61 i?aaeaiii? ieiu?, ieanoao na?oe N25. Cr – r
a?ae 0,501 aei 0,814 ii ieanoao h11i, h8 i?ai?/ii?, ieanoao no?aeii?,
h8, h7 cao?aeii? ieiu. Eiieo?oth/eie ?: Be – r a?ae –0,537 aei –0,542 ii
ieanoao h8 no?aeii? oa h61, h4a i?aaeaiii? ieiu. Mn – r a?ae –0,543 aei
–0,713 ii ieanoao h8 i?ai?/ii? oa h7, h21 no?aeii? ieiu, Pb – r –0,603
ii ieanoo h61 i?aaeaiii? ieiu?.

I?ae ai?noii V oa cieuei?noth aoa onoaiiaeaiee ei?aeyoe?eiee ca’ycie c
eiao?oe??ioii a?ae 0,501 aei 0,887 o aoa?ee? ieano?a h8, h7 i?ai?/ii?,
h7, h61 no?aeii?, h21 i?aaeaiii?, h8, h7 cao?aeii? ieiu, k41, k3, k22.
Aeey aoa?eey ieano?a na?oe N23 ca’ycie iieno?oueny oi?ioeith: V = — 6E –
0,7Ad4 –

-0,0002Ad3 + 0,0211Ad2 + 0,2826Ad + 34,834, R2 = 0,539; aeey ieano?a
na?oe N25 V = 1E – 05Ad4 –

-0,0019Ad3 + 0,1017Ad2 – 0,3542Ad + 26,687, R2 = 0,5696.

Iaeneiaeueiee ai?no a i?iaeoeoao caaaa/aiiy ?c cieuei?noth 60 – 70%: a)
V = =33,355 lnAd –

-50,217, R2 = 0,938; a) V = 21,542 lnAd – 10,35, R2 = 0,688; a) V =
34,742 lnAd – 46,255, R2 = 0,885;

a) V = 18,162 lnAd – 0,244, R2 = 0,834; ae) V = =33,548 lnAd – 59,947,
R2 = 0,80.

Ni. Eiao?oe??io cono??/? — 100%. A aoa?ee? ia?aaeuaiiy AAeE
a?aecia/a?oueny o?eueee ii ieanoo k41. A neaioeyo aeeienoeo ia?aaeuaiiy
niinoa??aa?oueny ia an?e oa?eoi??? ?aeiio

Anioe?aoe?th Ni neeaaeathoue: Pb – a?ae 0,515 aei 0,825 ii ieanoao h10a,
h8, h7 i?ai?/ii? ieiu?, ieanoao na?oe N25. F – r 0,596 ii ieanoo h10a
i?ai?/ii? ieiu?. Mn – 0,596 ii ieanoo k3. As – r 0,952 ii ieanoo h7
cao?aeii? ieiu?. Be — r 0,722 ii ieanoo h61 no?aeii? ieiu? Cr – r a?ae
0,501 aei 0,773 ii ieanoao i?ai?/ii? ieiu?, ieanoao na?oe N25. V – r

a?ae 0,511 aei 0,805 ii ieanoao i?ai?/ii?, h61 i?aaeaiii? ieiu, ieanoao
na?oe N25.Ia ieiu? ieano?a i?ai?/ii? ieiu?, h7, h61 h3 no?aeii?, h4a,
h21 i?aaeaiii?, h8, h7 cao?aeii? k41, k3 aoa onoaiiaeaiee ei?aeyoe?eiee
ca’ycie ?c cieuei?noth c eiao?oe??ioii ei?aeyoe?? a iaaeao 0,534 –
0,706. Aeey aoa?eey ieano?a na?oe N23 iieno?oueny oi?ioeith: Ni = 3E –
09Ad6 – 9E – 07Ad5 + 8E – 05Ad4 – 0,0026Ad3 + +0,0176Ad2 + 0,9622Ad +
14,57; R2 = 0,5231, aeey aoa?eey na?oe N25 Ni = — 6034,2Ad5 + 13039Ad4 –

-9849,8Ad3 + 3068,9Ad2 – 393,65Ad + 59,101; R2 = 0,501.

Iaeneiaeueiee ai?no a i?iaeoeoao caaaa/aiiy ?c cieuei?noth 40 – 50%: a)
Ni = =16,66lnAd –

-14,472, R2 = 0,953; a) Ni = 11,412lnAd – 3,7267, R2 = 0,877; a) Ni =
13,412lnAd – 5,7832, R2 = 0,985; a) Ni = 12,034lnAd + 1,247, R2 = 0,875;
ae) Ni = 12,92lnAd – 10,624, R2 = 0,930.

Cr. Eiao?oe??io cono??/? — 100%. Ia?aaeuaiiy AAeE ? o aoa?ee? ieanoa h8
i?ai?/ii? ieiu? oa na?oe N25. O ai?uoth/eo ii?iaeao ia?aaeuaiiy
niinoa??aa?oueny a neaioeyo i?uaieo oa aeeienoeo ia an?e ieiu? ?aeiio;
neaioeyo i?uaieo i?aaeaiii-cao?aeii? ieiu?.

A anioe?aoe?th aoiaeyoue: As – r 0,560 ii ieanoo h4a i?aaeaiii? ieiu?.
Mn – r 0,515 ii ieanoo k3. Pb – r a?ae 0,509 aei 0,929 ii ieanoao h10a,
h8 i?ai?/ii? ieiu?, h31 no?aeii?, h61 i?aaeaiii? ieiu, ieanoa k22. Ni —
r a?ae 0,501 aei 0,773 ii ieanoao h11i, h10a, h8, h7 i?ai?/ii?, h7
cao?aeii? ieiu, na?oe N25. V – r a?ae 0,501 aei 0,814 ii ieanoao h11i,
h8 i?ai?/ii?, no?aeii?, cao?aeii? ieiu. Co – r a?ae 0,513 aei 0,573 ii
ieanoao h11i i?ai?/ii? oa h61 no?aeii? ieiu. Eiieo?oth/eie ?: Be – r
a?ae –0,536 aei –0,548 ii ieanoao h8 i?ai?/ii?, h7 no?aeii? a, h4a
i?aaeaiii? oa h7 cao?aeii? ieiu?, Mn – r a?ae –0,621 aei –0,685

ii ieanoao h7 no?aeii?, h61 oa h21 i?aaeaiii?, h7 cao?aeii? ieiu.

I?ae cieuei?noth oa ai?noii Cr aoa onoaiiaeaiee ei?aeyoe?eiee ca’ycie c
eiao?oe??ioii ei?aeyoe?? a?ae 0,533 aei 0,850 a aoa?ee? ieano?a
i?ai?/ii?, h7, h3 no?aeii?, h4a, h3, h21 i?aaeaiii?, h8, h7 cao?aeii?
ieiu, k41, k3, k22. Aeey aoa?eey na?oe N23 ca’ycie iieno?oueny
oi?ioeith: Cr = 3E – 06Ad4 –

-0,006Ad3 + 0,00238Ad2 + 0,6748Ad + 2,0528, R2 = 0,571; aeey aoa?eey
na?oe N25 Cr = -3E – 09Ad5 + 2E- – 05Ad4 – 0,0024Ad3 + 0,0831Ad2 +
1,404Ad + 18,51, R2 = 0,526.wmetafile8? ??T?????????????
???????????yyy????.????1?????? ???????  
???&??yyyy?????Ayyy¦yyya???AE?? ???&?
?MathType??P????&??yyyy????????????????????????????????????o???t????
?? ????????????????????????

Iaeneiaeueiee ai?no a i?iaeoeoao caaaa/aiiy ?c cieuei?noth 60 – 70%: a)
Cr = 39,28lnAd –

-64,926, R2 = 0,978; a) Cr = 31,646lnAd – 34,317, R2 = 0,986; a) Cr =
32,111lnAd – 42,662, R2 = 0,986

a) Cr = 30,665lnAd – 36,246, R2 = 0,994, ae) Cr = 35,431lnAd – 53,938,
R2 = 0,997.

Co. cao?eniaaii ii an?o i?iaao. Ia?aaeuaiiy AAeE a aoa?ee? o?eueee ii
ieanoo k41, a ai?uoth/eo ii?iaeao — a neaioeyo aeeienoeo oa aoaeenoeo
na?oe N25.

A anioe?aoe?th aoiaeyoue: As – r a?ae 0,567 aei 0,667 ii ieanoao h31
no?aeii? oa h4a

i?aaeaiii? ieiu. Be – r a?ae 0,578 aei 0,935 ii ieanoao h61, h31
no?aeii? oa h3 i?aaeaiii? ieiu. Mn – r 0,809 ii ieanoo h10a i?ai?/ii?
ieiu?. Pb – r a?ae 0,584 aei 0,594 ii ieanoao h7 i?ai?/ii? ieiu? oa e41.
Ni — r a?ae 0,508 aei 0,932 ii ieanoao no?aeii?, h4a, h21 i?aaeaiii?
ieiu?., h7 cao?aeii? ieiu? oa k41. Cr – r a?ae 0,513 aei 0,573 ii
ieanoao h11i i?ai?/ii? oa h61 no?aeii? ieiu. Eiieo?oth/ei ? Pb n r
–0,538 ii ieanoo 61 i?aaeaiii? ieiu?.

Iaeneiaeueiee ai?no a i?iaeoeoao caaaa/aiiy ?c cieuei?noth 60 – 70 %: a)
Co = 5,0025lnAd –

-1,322, R2 = 0,955; a) Co = 2,7736lnAd + 5,9822, R2 = 0,548; a) Co =
3,1563lnAd + 5,7258, R2 = 0,935; a) Co = 4,8259lnAd + 0,8057, R2 =
0,892; ae) Co = 5,263lnAd – 2,7515, R2 = 0,855.

Ia?aaaiaoe/i? anioe?aoe?? oiene/ieo aeaiaio?a iiyniththoueny
aeecuee?noth eiaaeaioieo ?aae?on?a aoii?a, aaee/eiaie
aeaeo?iiaaaoeaiino?, eii?aeeiaoe?eieie /eneaie, cia/aiiyie i?aeaoiiieo
a?aenoaiae, aca?iiith eiiiainaoe??th i?e ?ciii?o?ci?, aoiaeaeaiiyi a
e?enoae?/i? ?ao?oee noeueo?ae?a.

Aecia/ai? ia ieiu? *enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai ?aeiio
caeiiii??iino? ?iciiae?eo oa anioe?aoe?? oiene/ieo aeaiaio?a
aeicaieythoue i?iaiicoaaiiy ai?no oeeo aeaiaio?a o aoa?ee?.

?ICAe?E 4

I?IAIICOAAIIss OIENE*IINO? A??IE*I? IANE OA I?IAeOEO?A CAAAA*AIIss,
EIIO?IEUe OA IIAeAETHAAIIss AI?NOO OIENE*IEO AEAIAIO?A

Ca /anii iiia?aaeaeaiiy i?iaiicoaaiiy ?icae?ey?oueny ia: ei?ioeino?ieiaa
(aeey ae?th/eo i/enieo oa i?aeaioia/eo caai?a) oa na?aaeiueino?ieiaa
(aeey ae?eueieoeue, ye? ieaiothoueny aei aeaeiaooeo). Ao?aeieie aeaieie
ei?ioeino?ieiaiai i?iaiicoaaiiy ?: AOA a aoa?ee?, ii??aeieo i?ioa?eao,
caeo/aieo a aeaeiaooie ai?uoth/eo ii?iaeao, u?euei?noue oa iiooaei?noue.

Ii/aoeiaei aoaiii ei?ioeino?ieiaiai i?iaiicoaaiiy oiene/iino? a??ie/i?
iane ? aecia/aiiy AOA a aoa?eueiiio ieano?:

wmetafile8? ??????????????
???????????yyy????.????1?????? ???????
@a???&??yyyy?????Ayyy®yyy ??i?? ???&? ?MathType??0
???u?????????»????-?????p—???p†???u?y??????aea AOAie
ai?no oiene/iiai aeaiaioo a ieano?; ia – iiooaei?noue aoa?eey, i.; da –
u?euei?noue aoa?eey, o/i3; AOA – ai?no oiene/iiai aeaiaioo a aoa?ee?;
iii – iiooaei?noue ii?iaeieo i?ioa?e?a, i; d – u?euei?noue ii?iaeieo
i?ioa?e?a, o/i3; AOAii – ai?no oiene/iiai aeaiaioo a ii?iaeieo
i?ioa?eao.

Oaeoe/ia caeo/aiiy ai?uoth/eo ii??ae aecia/a?oueny eiio?ieueiei
aei??thaaiiyi aaee/ei caa?oaeiaiiy i a caaiyo. AOA a a??ie/?e ian?
?ic?aoiao?oueny:

aeey i/enieo caai?a:

wmetafile8? ??????????????
???????????yyy????.????1?????? ???????
a????&??yyyy?????Ayyy?yyyA??’?? ???&? ?MathType??
???u?????????»????-?????P+???P????u?y??????aea AOAai
–ai?no oiene/iiai aeaiaioo a a??ie/?e ian?; iie – iiooaei?noue ieanoa,
i; die iiooaei?noue ieanoa, o/i3; AOAie ai?no oiene/iiai aeaiaioo a
aoa?eueiiio ieano?; iai iiooaei?noue ai?uoth/eo ii??ae, aeo/aieo a
aeaeiaooie, i; dai – iiooaei?noue ai?uoth/eo ii??ae, aeo/aieo a
aeaeiaooie, o/i3; AOAai ai?no oiene/iiai aeaiaioo o ai?uoth/eo ii?iaeao,
aeo/aieo a aeaeiaooie.

aeey i?aeaioia/eo caai?a:

wmetafile8? ??A???????????
???????????yyy????.????1?????? ???????
?@???&??yyyy?????Ayyy¦yyy???&?? ???&? ?MathType??0
???u?????????»????-?????°???°n

???u?y??????aea E? — eiao?oe??io ?icoaiaeaiiy.

Aeey ?ic?aooieo AOA ii aoa?eueiiio i?aei?e?inoao iaiao?aei? aeai? i?i
aeaeiaooie a??ie/i? iane c caai?a. Aecia/aiiy AOA i?iaiaeeoueny ca
oi?ioeith:

wmetafile8? ??c???????????
???????????yyy????.????1?????? ???????
?`???&??yyyy?????Ayyy®yyy ??®?? ???&? ?MathType??
???u?????????»????-?????p«???p???u?y??????aea D
e?euee?noue aeaeiaooeo c caai?a, o.

Eiio?ieue AOA a a??ie/ee ian? i?e caa?oaeiaii? aoa?eey oiene/ieie
aeaiaioaie ai?uoth/eo ii??ae i?iaiaeeoueny o aeiaaeeao AOAai,ai ? AAeE c
?ic?aooieii aaee/eie ia?aaeuaiiy AOA ca oi?ioeith:

wmetafile8? ??u????????????
???????????yyy????.????1?????? ???????
 @???&??yyyy?????Ayyy3/4yyy???^?? ???&?
?MathType???????u@th??????aea AOAia?aa – ia?aaeuaiiy ai?noo oiene/ieo
aeaiaio?a ii?i AAeE.

C ?ic?aooieii oaeoe/iiai i?e?iuaiiy iiooaeiino?, ui aeeia?oueny:

wmetafile8? ??‘???????????
???????????yyy????.????1?????? ??????? ?
???&??yyyy?????Ayyy?yyya????? ???&? ?MathType??
???u?????????»????-?????p„???pOe???u@th??????I?e
ia?aaeuai? ii?i AOA ?ic?aoiao?oueny i?e?iuaiiy oiene/iino?, iaoiiaeaia
iaaei??iei ai?noii ii?iaee, ui iio?aieea a aoa?eey:

wmetafile8? ??r???????????
???????????yyy????.????1?????? ???????
aA.???&??yyyy?????Ayyy?yyy?.????? ???&? ?MathType??@
???u?????????»????-??????O?????

????n ?????-???u@th??????aea iai (i.) – anoaiiaeaia ii?ia
caa?oaeiaiiy aoa?eey ai?uoth/eie ii?iaeaie, yea aecia/a?oueny ca
oi?ioeith:

wmetafile8? ??*???????????
???????????yyy????.????1?????? ???????
 ????&??yyyy?????Ayyy3/4yyyA??^?? ???&?
?MathType???????u?y??????Iiaeaethaaiiy AOA a aoa?ee?, ai?uoth/eo
ii?iaeao, a??ie/ee ian? i?iaiaeeoueny c iaoith iaaeiiouaiiy aeoiaeo
a??ie/i? iane c ia?aaeuaiiyi ii?i AAeE a ?aaeei? ona?aaeiaiiy, aeeth/a?
ooieoe?th oa iaiaaeai? oiiae:

wmetafile8? ??A???????????
???????????yyy????.????1?????? ???????
Aa+???&??yyyy?????Ayyycyyy +??b?? ???&?
?MathType??????u@th??????aea Qi (a, ai, ai) -, AOA eio?eo ia?aaeuo?
ii?ie AAeE, o; Qj (a, ai, ai) – caieaiiaaiee aeaeiaooie ae?eueieoeue ,
AOA eio?eo ia ia?aaeuo? ii?ie AAeE, o.,

Neooaoe?eia iiaeaeue aeaeiaooeo a ?aaeei? ona?aaeiaiiy aeeth/a?
oe?eueiao ooieoe?th oa iaiaaeo? aeiiae ii ianyao aeaeiaooeo c
o?aooaaiiyi o?ainii?oieo oa oaoiieia?/ieo iaiaaeaiue:

wmetafile8? ??u????????????
???????????yyy????.????1?????? ???????
a ???&??yyyy?????Ayyy?yyy`????? ???&?
?MathType???????u th??????aea Qi0 — oaeoe/iee aeaeiaooie c
ae?eueieoeue c ia?aaeuaiiyi AAeE; Qi – aeaeiaooie c ae?eueieoeue c
ia?aaeuaiiyi AAeE, ui ieaio?oueny.

Aeo?aeieie aeaieie na?aaeiueino?ieiaiai i?iaiicoaaiiy oiene/iino?
a??ie/i? iane ? iiooaei?noue, u?euei?noue oa AOA aoa?eey ? ai?uoth/eo
ii??ae, i?e?iuaiiy iiooaeiino?, ui aeeia?oueny (Di), iaoiiaeaii?
i?enooi?noth “oeaii?” iie??ae? oa i?eoe?aiiyi ai?uoth/eo ii??ae a
i?ioean? aeaeiaooeo:

Aeey iano?eeeo ii??ae aecia/aiiy Di i?iaiaeeoueny ca oi?ioeith:

Dwmetafile8? ??????????????
???????????yyy????.????1?????? ??????? `?

???&??yyyy?????Ayyy·yyy@

???? ???&? ?MathType??`????u@th??????A oiiaao no?eeeo oa
na?aaei?no?eeeo ii??ae aeey aecia/aiiy ca’yceo AOAai oa AOAie
aeei?enoiaothoueny cia/aiiy Di, ye? ?ic?aoiaai? ie?aii aeey oe?iei — oa
aocueeicaoaaoii? oaoi?ee, ca iiooaei?noth ?icae?eai? ia a?oie: 0,5 –
0,7, 0,7 – 1,0, 1,0 –1,3, 1,3 – 1,6, 1,6 – 1,9 i.

I?ney aecia/aiiy Di ?ic?aooiie AOAai i?iaiaeeoueny a?aeiia?aeii oi?ioe 1
— 4.

Aeo?aeieie aeaieie i?iaiicoaaiiy AOA a i?iaeoeoao caaaa/aiiy ?
oiene/i?noue a??ie/i? iane oaoo, aeo?ae i?iaeoeo?a caaaa/aiiy oa ?o
AOA..

Aeei?enoiaoth/e ?icae?eaiiy aaeaino eiiiiiaio?a ia i?ia?aeueio oa
i?aai?/io /anoeie ?ic?aoiao?oueny AOA a i?iaeoeoao caaaa/aiiy:

1. I?e caaaa/aii? a??ie/i? iane c aeae?eaiiyi aeaio i?iaeoeo?a —
eiioeaio?aoo oa a?aeoiae?a ??aiyiiy aaeaino ia? oaeee aeaeyae:

wmetafile8? ??2???????????
???????????yyy????.????1?????? ???????
? ???&??yyyy?????Ayyy3/4yyy`??>?? ???&?
?MathType??p????u?y??????aea Oe – aeo?ae eiioeaio?aoo; AOAe – ai?no
oiene/iiai aeaiaioo a eiioeaio?ao?; oaae – aeo?ae a?aeoiae?a; AOAaae –
ai?no oiene/iiai aeaiaioo o a?aeoiaeao.

Ioaea, AOA noaiiaeoue:

a eiioeaio?ao?:

wmetafile8? ??B???????????
???????????yyy????.????1?????? ??????? ?`
???&??yyyy?????Ayyy3/4yyy ??>?? ???&?
?MathType??p????u?y??????o a?aeoiaeao:

wmetafile8? ??B???????????
???????????yyy????.????1?????? ??????? ?`
???&??yyyy?????Ayyy3/4yyy ??>?? ???&?
?MathType??p????u?y??????2. I?e caaaa/aii? a??ie/i? iane c
aeae?eaiiyi o?ueio i?iaeoeo?a — eiioeaio?aoo, i?iii?iaeoeo?a oa
a?aeoiae?a — ??aiyiiy aaeaino ia? oaeee aeaeyae:

wmetafile8? ??S???????????
???????????yyy????.????1?????? ???????
?@!???&??yyyy?????Ayyy·yyy?!??7?? ???&?
?MathType??p????u?y??????aea Oii – aeo?ae i?iii?iaeoeoo; AOAaae –
ai?no oiene/iiai aeaiaioo o a?aeoiaeao.

?ic?aooiie AOA i?iaiaeeoueny ie?aii aeey oiene/ieo aeaiaio?a
i?ia?aeueii? oa i?aai?/ii? /anoei. A ia?oiio aeiaaeeo AOA ca?eueoo?oueny
a ?yaeo:

wmetafile8? ?????????????
???????????yyy????.????1?????? ???????
?A???&??yyyy?????Ayyy3/4yyy???>?? ???&?
?MathType??p????u?y??????A ae?oaiio aeiaaeeo:

wmetafile8? ??3???????????
???????????yyy????.????1?????? ???????  
???&??yyyy?????Ayyy3/4yyya??^?? ???&? ?MathType??p?
???u?????????»????-?????B?.???PI???PI???^.???u?
y???????ic?aooiie AOA a i?iaeoeoao caaaa/aiiy oiene/ieo aeaiaio?a
i?ia?aeueii? /anoeie:

a eiioeaio?ao?:

wmetafile8? ??i???????????
???????????yyy????.????1?????? ???????
?`5???&??yyyy?????Ayyy3/4yyy 5??>?? ???&?
?MathType??p????uey????a i?iii?iaeoeo?:

wmetafile8? ??i???????????
???????????yyy????.????1?????? ???????
??5???&??yyyy??[email protected]??>?? ???&?
?MathType??p????uey????o a?aeoiaeao:

wmetafile8? ??i???????????
???????????yyy????.????1?????? ???????
?`5???&??yyyy?????Ayyy3/4yyy 5??>?? ???&?
?MathType??p????uey?????ic?aooiie AOA a i?iaeoeoao caaaa/aiiy
oiene/ieo aeaiaio?a i?aai?/ii? /anoeie:

a eiioeaio?ao?:

wmetafile8? ??i???????????
???????????yyy????.????1?????? ???????
??5???&??yyyy??[email protected]??>?? ???&?
?MathType??p????uey????a i?iii?iaeoeo?:

wmetafile8? ??i???????????
???????????yyy????.????1?????? ???????
?`5???&??yyyy?????Ayyy3/4yyy 5??>?? ???&?
?MathType??p????uey????o a?aeoiaeao:

wmetafile8? ??N???????????
???????????yyy????.????1?????? ??????? ?
3???&??yyyy?????Ayyy·yyya2??7?? ???&?
?MathType??p????uny????Iiaeaethaaiiy AOA a i?iaeoeoao caaaa/aiiy
i?iaiaeeoueny c iaoith iaaeiiouaiiy aeoiaeo i?iaeoeo?a ia?a?iaee aoa?eey
c ia?aaeuaiiyi ii?i AAeE.

Iiaeaeue ci?ie AOA aeeth/a? ooieoe?th oa iaiaaeai? oiiae:

wmetafile8? ??‰???????????
???????????yyy????.????1?????? ??????? `
???&??yyyy?????Ayyy3/4yyya??

?? ???&? ?MathType??`? ???u?????????»????-?????B?
???o???u?y????aea O – aeo?ae i?iaeoeoo caaaa/aiiy; O –
e?euee?noue i?iaeoeoo caaaa/aiiy.

C iaiaaeaieie oiiaaie:

wmetafile8? ??¬???????????
???????????yyy????.????1?????? ???????
AA$???&??yyyy?????Ayyycyyy?$??b?? ???&?
?MathType??????u@th??????aea Oj – aeo?ae i?iaeoeoo caaaa/aiiy c
ia?aaeuaiiyi AAeE; Oj – e?euee?noue i?iaeoeoo c ia?aaeuaiiyi AAeE; Oi –
aeo?ae i?iaeoeoo caaaa/aiiy a iaaeao AAeE; Oi – e?euee?noue i?iaeoeoo a
iaaeao AAeE.

I?iaaaeai? aenia?eiaioaeuei? ?iaioe iieacaee caaeia?eueio noi?ni?noue
i?iaiicieo oa oaeoe/ieo cia/aiue c a?aeiiniith iioeaeith: aeey
ei?ioeino?ieiaiai i?iaiicoaaiiy – 10%, na?aaeiueino?ieiaiai
i?iaiicoaaiiy – 30%, i?iaiicoaaiiy AOA a i?iaeoeoao caaaa/aiiy – 25%.

AENIIAEE

I?e aeeiiaii? aeena?oaoe?eii? ?iaioe aoee io?eiai? ianooii? iniiai?
iaoeia? oa i?aeoe/i? ?acoeueoaoe:

1. Ia ieiu? *enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai ?aeiio aoee
aeyaeai? ?yaee nii??aeiaiino? oiene/ieo aeaiaio?a c i?aai?/iith
/anoeiith aoa?eey, anoaiiaeai? caeiiii??iino? ci?ie AOA a caeaaeiino?
a?ae cieueiino?; a i?iaeoeoao caaaa/aiiy; ii niaaeo oa i?inoyaaiith;
aeyaeai? aaio?i?/i? anioe?aoe?? aoa?eey, i?iaaaeaia oei?caoe?y
ai?uoth/eo ii??ae.

2. ?ic?iaeai? iaoiaeeee i?iaiicoaaiiy AOA:

a) a a??ie/ee ian?, ye? a?ae??ciythoueny ca /anii iiia?aaeaeaiiy:
ei?ioeino?ieiaa — aeey ae?th/eo caai?a, na?aaeiueino?ieiaa — aeey
ae?eueieoeue, ui ieaiothoueny aei aeaeiaooeo. A iniia? i?iaiicoaaiiy —
aeai? i?i iiooaei?noue, u?euei?noue oa AOA a aoa?ee?, ai?uoth/eo
ii?iaeao. A?aei?ii?noue i?iaiicoaaiiy — o aecia/aii? iiooaeiino? oa?o,
yeee caa?oaeith? aoa?eey. Ei?ioeino?ieiaa aaco?oueny ia oaeoe/iiio
cia/aii? i a ae?th/eo caaiyo, na?aaeiueino?ieiaa — ia aecia/aiiio
cia/aii? i i?e aeei?enoaii? ai?iaiaaiiai ia oaooao ?aeiio
aaieiai-noaoenoe/iiai iaoiaeo;

a) a i?iaeoeoao caaaa/aiiy c o?aooaaiiyi aaiaoe/ieo ca’yce?a oeeo
aeaiaio?a c i?aai?/iith oa i?ia?aeueiith /anoeiaie aoa?eey.

3. Cai?iiiiiaaia o aeiaaeeao ia?aaeuaiiy ii?i AAeE oiene/ieie aeaiaioaie
ai?uoth/eo ii??ae iaoiaeeea eiio?ieth c ?ic?aooieii ii?ie caa?oaeiaiiy.

4. ?ic?iaeai? iaoiaeeee iiaeaethaaiiy AOA:

a) a a??ie/ee ian? c iaiaaeaiiyi ianyao iane, ui aeiaoaa?oueny c
o?aooaaiiyi o?ainii?oieo oa oaoiieia?/ieo iaiaaeaiue a ?aaeei?
ona?aaeiaiiy

a) a i?iaeoeoao caaaa/aiiy c iaiaaeaiiyi ianya?a a??ie/i? iane oaoo, ye?
a?aea?oaeathoue i?iaeoeoe?th ia caaaa/oaaeuei? oaa?eee c o?aooaaiiyi
i?i?iaeueii? oa iaeneiaeueii? i?iaeoeoeaiino? aeeaeeueieea aoiea?a.

I?iaaaeai? aenia?eiaioaeuei? ?iaioe iieacaee caaeia?eueio noi?ni?noue
i?iaiiciaaieo oa oaeoe/ieo cia/aiue c a?aeiiniith iioeaeith: aeey
ei?ioeino?ieiaiai i?iaiicoaaiiy – 10%, na?aaeiueino?ieiaiai
i?iaiicoaaiiy – 30%, i?iaiicoaaiiy AOA a i?iaeoeoao caaaa/aiiy – 25%.

Ia iniia? i?eaaaeaieo ?acoeueoao?a aaoi? ?aeiiaiaeo? oe?iei
aeei?enoiaoaaoe iaoeia? oa i?aeoe/i? ?acoeueoaoe i?e i?iaaaeaii?
aaieiai?ica?aeoaaeueieo oa aoaeaaeiaoaieo ?ia?o ia ieiu?
*enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai ?aeiio, ui ni?eyoeia
i?aeaeuaiith ye aoaeoeaiino? ?ica?aeoaaeueieo ?ia?o, oae ? aeieia?/ii?
aaciaee aeiaooiai aoa?eey.

NIENIE IIOAE?EIAAIEO I?AOeUe CA OAIITH AeENA?OAOe??

Iniiai? iieiaeaiiy aeeiiaieo aeine?aeaeaiue aeeeaaeai? o 13 noaooyo
iaoeiaeo aeo?iae?a, 2 oacao aeiiia?aeae. O oao?aieo aeaeaiiyo
iioae?eiaaii:

1. Aeia?iai?neee I.A., Eo?iaeaa E.E., Oaa/aiei A.I. ?acoeueoaou
enneaaeiaaiey oiene/iinoe ii?iaeiiai ioaaea oaoou “Eaniay”. // Oaieue
Oe?aeiu. -1998. — ?8-9. -N. 25-26.

2. Aeia?iai?neee I.A., Nao?iiia E.E., Eo?iaeaa E.E., Oaa/aiei A.I.
Oiene/iinoue i?iaeoeoeee oaoo *enoyeiai-Niaaeiyineiai
aaieiai-i?iiuoeaiiiai ?aeiia Aeiiaanna. // Oaieue Oe?aeiu. -1999. — ?7.
-N. 41-42.

3. Eo?iaeaa E.E. I?iaiic niaea?aeaiee oiene/iuo yeaiaioia a i?iaeoeoao
iaiaauaiey (oai?aoe/aneee aaeain). // Ca. iaoe. i?. IAA Oe?a?ie
“Aeooaeueiua i?iaeaiu aaieiaee”, -Aei?i?iiao?ianuee: ?AE IAAO, -1999.
O.1, -?6. -N. 186–187.

4. Aeia?iai?neee I.A., Oaa/aiei A.I., Eo?iaeaa E.E. Iioeiecaoeey
ii?iaiaaiey ieanoia e aiauathueo ii?iae (*enoyeiai-Niaaeiyineee ?aeii
Aeiiaanna). // Ca. iaoe. i?. IAA Oe?a?ie “Aeooaeueiua i?iaeaiu
aaieiaee”, -Aei?i?iiao?ianuee: ?AE IAAO, -1999. O.1, -?6. -N. 187 – 192.

5. Aeia?iai?neee I.A., Eo?iaeaa E.E., Oaa/aiei A.I. Iiaeaee?iaaiea
niaea?aeaiee oiene/iuo yeaiaioia a ai?iie ianna oaoo. // Ca. iaoe. i?.
IAA Oe?a?ie “Aeooaeueiua i?iaeaiu aaieiaee”, -Aei?i?iiao?ianuee: ?AE
IAAO, -1999. O.2, -?6.

-N. 134.

6. Aeia?iai?neee I.A., Oaa/aiei A.I., Eo?iaeaa E.E. Oi?ie?iaaiea ieia?a-

eueiie /anoe oaeaaeiau/e iin?aaenoaii iiaeoeueiie eeanneoeeaoeee
(*enoyeiai-Niaaeiyineee ?aeii Aeiiaanna). // Ca. iaoe. i?. IAA Oe?a?ie
“Aeooaeueiua i?iaeaiu aaieiaee”, -Aei?i?iiao?ianuee: ?AE IAAO, -1999.
O.2, -?6. -N. 135-136..

7. Eoeia A.A., Eo?iaeaa E.E. I i?iaiica niaea?aeaiee oiene/iuo yeaiaioia
a i?iaeoeoao oaeaaeiau/e *enoyeiai-Niaaeiyineiai aaieiai-i?iiuoeaiiiai
?aeiia Aeiiaanna // Iaoeiaee a?niee Iaoe?iiaeueii? a??ie/i? aeaaeai??
Oe?a?ie. –1999. ?2. –N. 42-46.

8. Eoeia A.A., Eo?iaeaa E.E. Iniaaiiinoe ?ani?aaeaeaiey oiene/iuo
yeaiaioia a oaeyo *enoyeiai-Niaaeiyineiai aaieiai-i?iiuoeaiiiai ?aeiia
Aeiiaanna // Iaoeiaee a?niee Iaoe?iiaeueii? a??ie/i? aeaaeai?? Oe?a?ie.
–1999. ?3. –N. 41-49.

A ?ioeo iaoeiaeo aeo?iaeao:

9. Aeia?iai?neee I.A., Oaa/aiei A.I., Eo?iaeaa E.E. E aii?ino i
oiene/iinoe iooiaeia oaeaaeiau/e. // I?eaei?i?ianueeee iaoeiaee a?niee.
–1998. -? 83. -N. 49-50.

10. Aeia?iai?neee I.A., Eo?iaeaa E.E., Oaa/aiei A.I. Yeieiai —
yeiiiie/aneea e nioeeaeueiua aniaeou i?iaeaiu ooeeecaoeee iooiaeia
oaeaiaiaauaiey. // I?eaei?i?ianueeee iaoeiaee a?niee. –1998. -?83. -N.
100-101.

11. Aeia?iai?neee I.A., Eo?iaeaa E.E., Oaa/aiei A.I.
Nioeeaeueii-yeieiae/aneea i?iaeaiu Aeiiaanna eae ?acoeueoao
aeayoaeueiinoe oaieueiie i?iiuoeaiiinoe. // I?eaei?i?ianueeee iaoeiaee
a?niee. –1998. -? 105. -N. 84-85.

Oace aeiiia?aeae:

12. Eoeia A.A., Nao?iiia E.E., Iineaeaiei A.A., Eo?iaeaa E.E.
Eiiieaeniia inaiaiea oaoiiaaiiuo ianoi?iaeaeaiee — aaaeiaeoee oaeoi?
?anoe?aiey ieia?aeueii-nu?ueaaie aacu ai?iiaeiauaathuae i?iiuoeaiiinoe
Oe?aeiu // Iaoa??aee 2 Anaoe?. iaoe.-iaoiae. eiioa?aioe??.. “Aeieia?y oa
?iaeaia??y, noai, iane?aeee, oeyoe noai?aiiy aeieia?/ii /enoeo
oaoiieia?e”, -Aei?i?iaeca?aeeinuee. –1998. -N. 46.

13. Eoeia A.A., Nao?iiia E.E., Eo?iaeaa E.E., Iineaeaiei A.A.
Iiaeaeaeiinoue oiene/iuo e iioaioeeaeueii-oiene/iuo yeaiaioia ec
iooiaeia oaeaiaiaauaiey Aeiiaanna // Iaoa??aee 2 Anaoe?. iaoe.-iaoiae.
eiioa?aioe?? “Aeieia?y oa ?iaeaia??y, noai, iane?aeee, oeyoe noai?aiiy
aeieia?/ii /enoeo oaoiieia?e”, -Aei?i?iaeca?aeeinuee. –1998. -N.
168-169.

AIIOAOe?ss

Eo?iaeueia ?.?. Ioe?iea oa i?iaiicoaaiiy ai?noo oiene/ieo aeaiaio?a a
nenoai?

aoa?eey – a??ie/a iana – i?iaeoeoe caaaa/aiiy (ia i?eeeaae?
*enoyeiai-Ni?aeiyinueeiai aaieiai-i?iieneiaiai ?aeiio). – ?oeiien.

Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa aaieia?/ieo iaoe
ca niaoe?aeuei?noth 04.00.16 – aaieia?y oaa?aeeo iaeeaieo eiiaeei –
Iaoe?iiaeueia a??ie/a aeaaeai?y Oe?a?ie, Aei?i?iiao?ianuee, 1999.

Aeena?oaoe?y i?enay/aia aaio?i?/iei anioe?aoe?yi oa caeiiii??iinoyi
?iciiae?eo oiene/ieo aeaiaio?a, i?iaiicoaaiith ?o ai?noo a a??ie/?e
ian?, ye? ?ic??ciythoueny ca /anii iiia?aaeaeaiiy: ei?ioeino?ieiaa –
aeey ae?th/eo caai?a, na?aaeiueino?ieiaa — aeey ae?eueieoeue, ui
ieaiothoueny aei aeaeiaooeo. Cai?iiiiiaaii iaoiaeeeo i?iaiicoaaiiy
ai?noo aeaiaio?a a i?iaeoeoao caaaa/aiiy (oai?aoe/iee aaeain) aoa?eey c
o?aooaaiiyi aaiaoe/ieo ca’yce?a oeeo aeaiaio?a c i?aai?/iith oa
i?ia?aeueiith /anoeiaie aoa?eey. Iaoiaee iiaeaethaaiiy ai?noo
aeicaieythoue ia?aaeaa/eoe aeeiiaiiy oaoiieia?/ieo caoiae?a aei
cieaeaiiy ai?noo oeeo aeaiaio?a a a??ie/ee ian? oa i?iaeoeoao caaaa/aiiy
aoa?eey iaioa ii?i AAeE.

Eeth/ia? neiaa: oiene/i? aeaiaioe, aaio?i?/i? anioe?aoe??,
i?iaiicoaaiiy.

AIIIOAOeEss

Eo?iaeaa E.E. Ioeaiea e i?iaiice?iaaiea niaea?aeaiee oiene/iuo yeaiaioia
a nenoaia oaieue – ai?iay ianna – i?iaeoeou iaiaauaiey (ia i?eia?a
*enoyeiai-Niaaeiyineiai aaieiai-i?iiuoeaiiiai ?aeiia). – ?oeiienue.

Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa aaieiae/aneeo iaoe
ii niaoeeaeueiinoe 04.00.16. – aaieiaey oaa?aeuo ai?th/eo eneiiaaiuo. –
Iaoeeiiaeueiay ai?iay aeaaeaiey Oe?aeiu, Aeiai?iiao?iane, 1999.

Aeenna?oaoeey iinayuaia aaioeie/aneei annioeeaoeeyi e caeiiiia?iinoyi
?ani?aaeaeaiee oiene/iuo yeaiaioia, i?iaiice?iaaieth eo niaea?aeaiee a
ai?iie ianna e i?iaeoeoao iaiaauaiey.

N oeaeueth iiauoaiey aeinoiaa?iinoe enneaaeoaiuo oa?aeoa?enoee
?ani?aaeaeaiee oiene/iuo yeaiaioia i?iaaaeaii ?aeiie?iaaiea, iniiaiui
e?eoa?eai eioi?iai yaeyeenue ai?ii-aaieiae/aneea e oaeaiao?ia?aoe/aneea
iniaaiiinoe oaooiieanoia. A ?acoeueoaoa auee auaeaeaiu iyoue oaeaiiniuo
ieiuaaeae e 3 eeoieiai-aaioeie/aneea a?oiiu aiauathueo ii?iae.

Aeey aeinoeaeaiey iinoaaeaiiie oeaee auei enneaaeiaaii 876 aiaeecia ia
niaea?aeaiea oiene/iuo yeaiaioia a oaeyo e aiauathueo ii?iaeao,
iieo/aiiuo i?e ia?ana/aiee ?acaaaei/iuo neaaaeei, 121 aiaeec ia
niaea?aeaiea yoeo yeaiaioia a ai?iie ianna e 169 aiaeecia ia
niaea?aeaiea yeaiaioia a i?iaeoeoao iaiaauaiey. I?iaiaeece?iaaii 287
ea?ioaaeiuo aeeaa?aii e ii?iaeueiuo no?aoea?aoe/aneeo ?ac?acia. Aaoi?ii
ioia?aii ia oaooao ?aeiia aeey enneaaeiaaiee niaea?aeaiee oiene/iuo
yeaiaioia: a oaeyo 48 i?ia, 31 i?iaa a ai?iie ianna, 39 i?ia a
i?iaeoeoao iaiaauaiey, 25 i?ia ia oaieueiuo neeaaeao.

Noaoenoe/aneay ia?aaioea ?acoeueoaoia aeeth/aea ?an/ao iniiaiuo
noaoenoe/aneeo oa?aeoa?enoee yiie?e/aneeo ?ani?aaeaeaiee oiene/iuo
yeaiaioia. Aeey onoaiiaeaiey nayce iaaeaeo yeaiaioaie eniieueciaaeny
eiyooeoeeaio eeiaeiie e aaiia-ei??aeyoeee, eiyooeoeeaio, Eaiaeaeea,
Nie?iaia, /oi iicaieeei auyaeoue annioeeaoeee

aac o/aoa ooieoeee ?ani?aaeaeaiey e ?acoeueoaou, ia caaenyuea io
eniieuecoaiuo aaeeieoe ecia?aiey. I?e ioeaiea nayce oiene/iuo yeaiaioia
n i?aaie/aneie e ieia?aeueiie /anoueth oaey eniieueciaaeenue
eiyooeoeeaiou: n?iaenoaa n i?aaie/aneei aauanoaii, i?eaaaeaiiie
eiioeaio?aoeee, i?eaaaeaiiiai ecaea/aiey. Aiaeec ?acoeueoaoia
aeene?eieiaioiiai e eeanoa?iiai aiaeecia iicaieee onoaiiaeoue ?yaeu
n?iaenoaa oiene/iuo yeaiaioia n i?aaie/aneie e ieia?aeueiie /anoueth
oaey ii ieanoai e i?iaanoe oeiecaoeeth aiauathueo ii?iae, eae
iaiaauathueo eee ?acoaiaeeaathueo ai?ioth ianno oiene/iuie yeaiaioaie.

Aiaeec iiaa?oiinoae o?aiaeia aii?ieneie?othueo niaea?aeaiey yeaiaioia a
oaeyo e aiauathueo ii?iaeao *enoyeiai-Niaaeiyineiai ?aeiia iicaieee
onoaiiaeoue caeiiiia?iinoe eo i?ino?ainoaaiiiai eciaiaiey e
i?iaiice?iaaoue niaea?aeaiey yoeo yeaiaioia a oaea, ai?iie ianna e
i?iaeoeoao iaiaauaiey n o/?oii ieiuaaeiiai ?ani?aaeaeaiey oaieueiiai
ieanoa e aiaeaeaaiuo a aeiau/o aiauathueo ii?iae aac i?eaea/aiey
aeiiieieoaeueiuo eaai?aoi?iuo enneaaeiaaiee.

?ac?aaioaiu iaoiaeeee i?iaiice?iaaiey niaea?aeaiee oiene/iuo yeaiaioia a
ai?iie ianna: e?aoein?i/iia i?iaiice?iaaiea – aeey aeaenoaothueo caaiaa,
e n?aaeian?i/iia i?iaiice?iaaiea — aeey o/anoeia, iaia/aaiuo e
io?aaioea. A iniiaa iaoiaeee – ?an/ao niaea?aeaiee oiene/iuo yeaiaioia a
ai?iie ianna eniieuecoy aeaiiua i iiuiinoe, iauaiiii aana e
niaea?aeaieyo yeaiaioia a oaeyo e aiauathueo ii?iaeao, aiaea/aiiuo a
aeiau/o. ?acee/ey: e?aoein?i/iia i?iaiice?iaaiea eniieuecoao aeaiiua i
iiuiinoe aiaea/aiiuo a aeiau/o aiauathueo ii?iae ia iniiaa ecia?aiiuo
cia/aiee aaee/ei cani?aiey e n?aaeian?i/iia i?iaiice?iaaiea eniieuecoao
aaieiai–noaoenoe/aneee iaoiae i?iaiica aaee/ei cani?aiey, auiieiaiiue
?acaeaeueii aeey aiauathueo ii?iae ?acee/iie onoie/eainoe.

I?iaiice?iaaiea niaea?aeaiee oiene/iuo yeaiaioia a i?iaeoeoao iaiaauaiey
onoaiaaeeaaao oai?aoe/aneee aaeain n o/aoii aaiaoe/aneie nayce yeaiaioia
n ieia?aeueiie e i?aaie/aneie /anoueth oaeae e ii?aaeaeyao eo
niaea?aeaiea a i?iaeoeoao ?anni?oe?iaee i?e eaeaaeueiii ?acaeaeaiee ia
iniiaaiee naiaeiuo aeaiiuo o?aeoeeiiiiai aiaeeca.

?ac?aaioaiu iaoiaeeee iiaeaee?iaaiey niaea?aeaiee oiene/iuo yeaiaioia:

a) a ai?iie ianna — i?aaeeaaaaony eniieueciaaoue iiaeaeue eciaiaiee
niaea?aeaiee oiene/iuo yeaiaioia i?e oi?aaeaiee aeiau/ae a ?aaeeia
on?aaeiaiey n ia?aie/eoaeueiuie oneiaeyie e ii?aaeaeaieai eiee/anoaa
naa?oii?iaoeaiiai i?aauoaiey IAeE ia ieaie?oaiue ia?eiae aeey oaey,
ai?iie iannu, aiauathueo ii?iae, aiaeaeaaiuo a aeiau/o. Eniieueciaaiea
iiaeaee iicaieyao ii?aaeaeeoue iioeiaeueiua ieaiiaua iaa?ocee ia
i/enoiua caaie e nieceoue niaea?aeaiey yeaiaioia ieaea ii?i IAeE.

a) a i?iaeoeoao iaiaauaiey — ?ac?aaioaia iiaeaeue eciaiaiey a ?aaeeia
on?aaeiaiey n ia?aie/eoaeueiuie oneiaeyie. Eiee/anoai ai?iie iannu,
iinooieaoae ia iaiaaoeoaeueioth oaa?eeo, ia?aie/eaaaony ii?iaie IAeE,
ieieiaeueiie e iaeneiaeueiie i?iecaiaeeoaeueiinoueth ieoaoaey aoiea?a.
Iniiaiie oeaeueth iiaeaee?iaaiey niaea?aeaiee oiene/iuo yeaiaioia a
i?iaeoeoao iaiaauaiey yaeyaony iaaeiiouaiea auoiaea i?iaeoeoia
iaiaauaiey n i?aauoaieai IAeE.

Eniieueciaaiea iaoiaeee iiaeaee?iaaiey niaea?aeaiee oiene/iuo yeaiaioia
iicaieytho caaeaaia?aiaiii i?aaeoniio?aoue auiieiaiea oaoiieiae/aneeo
ia?ii?eyoee ii nieaeaieth niaea?aeaiee yoeo yeaiaioia a ai?iie ianna e
i?iaeoeoao iaiaauaiey oaey.

I?iaaaeaiiua yenia?eiaioaeueiua ?aaiou iieacaee oaeiaeaoai?eoaeueioth
noiaeeiinoue i?iaiiciuo e oaeoe/aneeo cia/aiee n ioiineoaeueiie
iia?aoiinoueth: aeey e?aoein?i/iiai i?iaiice?iaaiey – 10%,
n?aaeian?i/iiai i?iaiice?iaaiey – 30%, i?iaiice?iaaiey niaea?aeaiee
oiene/iuo yeaiaioia a i?iaeoeoao iaiaauaiey – 25%.

ANNOTATION

Kurmelyov I.I. Toxic elements’ contents in the system of coal-rock
mass-dressing products evaluation and forecasting
(Tchistyakovo-Snezhnyanski geological and industrial region). –
Manuscript.

Theses for the degree of candidate of science (Geology) (speciality
04.00.16 – the geology of solid fuels). – National Mining University of
Ukraine, Dnepropetrovsk, 1999.

The subject of investigation deals with geochemical associations and
their contents forecasting in the time of warning – for the operating
collieries and shafts. The methods of forecasting elements content in
dressing products taking into account genetic ties of these elements
with the organic and mineral parts of coal are offered in the paper.
Modelling methods make it possible to provide the technological
processes realization aimed at lowering these elements content in the
rock mass and in dressing products.

Key words: toxic elements, geochemical associations, forecasting.

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