AeI?I?IIAO?IANUeEEE AeA?AEAAIEE OI?AA?NEOAO

AAO NAEUe A?EssEUe IAOIOAe

OAeE 539.21+543.42

EIEEAAEUeI? NIAEO?E AI?IIEENEIO

OA ?O EIIIEAEN?A C IAOAEAIE

Niaoe?aeuei?noue 01.04.07 – o?ceea oaa?aeiai o?ea

Aaoi?aoa?ao aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?ceei-iaoaiaoe/ieo iaoe

Aei?i?iiao?ianuee – 1999

Aeena?oaoe??th ? ?oeiien.

?iaioa aeeiiaia a Aei?i?iiao?ianueeiio aea?aeaaiiio oi?aa?neoao?
I?i?noa?noaa ina?oe Oe?a?ie.

Iaoeiaee ea??aiee aeieoi? o?ceei-iaoaiaoe/ieo iaoe, i?ioani?

II?NA?IEI Aaneeue Ieeieaeiae/,

Aei?i?iiao?ianueeee aea?aeaaiee oi?aa?neoao,

caa?aeoaa/ eaoaae?e

Io?oe?ei? iiiiaioe: aeieoi? o?ceei-iaoaiaoe/ieo iaoe, i?ioani?

AIEIssINUeEEE Ieoaeei Aeieo?iae/,

Aei?i?iiao?ianueeee aea?aeaaiee oi?aa?neoao,

caa?aeoaa/ eaoaae?e

eaiaeeaeao o?ceei-iaoaiaoe/ieo iaoe, aeioeaio

AEAAIOEINUeEEE ?aaai A?e’yiiae/,

Caii??cueeee aea?aeaaiee oi?aa?neoao

I?ia?aeia i?aai?caoe?y: ?inoeooo o?ceee IAI Oe?a?ie (i.Ee?a), a?aeae?e
oioiaeoeaiino?.

Caoeno a?aeaoaeaoueny «19» eenoiiaaea 1999 ?. i 13:00 aiaeei? ia
can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee Ae 08.051.02 i?e
Aei?i?iiao?ianueeiio aea?aeaaiiio oi?aa?neoao? (320625, i.
Aei?i?iiao?ianuee, i?ia.Iaoeiaee, 13).

C aeena?oaoe??th iiaeia iciaeiieoeny a a?ae?ioaoe? Aei?i?iiao?ianueeiai
aea?aeaaiiai oi?aa?neoaoo.

Aaoi?aoa?ao ?ic?neaiee «15» aeiaoiy 1999 ?.

A/aiee nae?aoa?

niaoe?ae?ciaaii? a/aii? ?aaee NIE?EAeIIIAA ?.I.

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

AEOOAEUeI?NOUe OAIE

No/aniee noai o?ceee oaa?aeiai o?ea oa?aeoa?eco?oueny aea/aiiyi o?ce/ieo
aeanoeainoae ana a?eueo neeaaeieo ia symbol 162 \f «Symbol» \s 14 c
?eo?a i?aai?/iiai ? iai?aai?/iiai iioiaeaeaiiy. Iaeiei ?c ia?niaeoeaieo
iai?yie?a ? aea/aiiy iioe/ieo eieeaaeueieo niaeo??a iaeaaaeeea?oeo
ai?iieeneio oa ?o eiiieaen?a c iaoaeaie c iaoith io?eiaiiy ?ioi?iaoe??
i?i ?o no?oeoo?o oa aeeiai?eo ?ao?oee.

C iiceoe?e o?ceee oaa?aeiai o?ea ?ioa?an aei ai?iieeneio oa
iaoaeieiiieaen?a ia ?o iniia? iaoiiaeaiee iiaeeea?noth aea/aiiy
iniaeeainoae eieeaaeueieo niaeo??a iioe/ii aeoeaieo ?a/iaei, oe?ieeo
??ciiaeae?a aoaeo?a neeueiiai aiaa?iii?cio, ?aciiainieo aoaeo?a
(?aciiaine Oa?i?, Aeaaeaeiaa) a eieeaaeueieo niaeo?ao, ui ? aaaeeeaei
i?aaeiaoii aea/aiiy no/anii? eieeaaeueii? niaeo?ineii??. E??i oiai,
aea/aiiy oaeeo iioe/ieo yaeu ye eiia?iaoe?eia ?icn?thaaiiy na?oea oa
?io?a/a?aiia iiaeeiaiiy o ?a/iaeiao neeaaeii? aoaeiae aeicaiey? aeyaeoe
iia? caeiiii??iino? o ?o i?iya?, iaoiiaeai? iae?i?eieie aeanoeainoyie
oaeeo ia symbol 162 \f «Symbol» \s 14 c ?eo?a, ?icaeiooe oai?aoe/io oyao
i?i aeeiai?eo neeaaeieo iieaeoey?ieo nenoai.

C ae?oaiai aieo aea/aiiy eieeaaeueieo niaeo??a ai?iieeneio yaey? aaeeeee
?ioa?an aeey ?icoi?iiy ia iieaeoey?iiio ??ai? o?ce/ieo i?ioean?a o
aeeaeo i?aai?ciao [1-4]. ssaeyth/enue iiiii??ieie eaioethaaie a?ee?a,
ai?iieeneioe yaeythoue oi?eaeueio iiaeaeueio nenoaio aeey aea/aiiy
i?e?iaee nee i?aeiieaeoey?ii? aca?iiae??, ye? ? aecia/ath/eie o
i?ioeanao naiii?aai?caoe?? iaaeiieaeoey?ieo no?oeoo?.

?ioei aniaeoii oe??? i?iaeaie ? aea/aiiy aieeao ciai?oi?o cao?aiue
(oaiia?aoo?e, eaaoaaiiy ?iiaie iaoae?a, aeaeo?iiaai?oiiai
aei?ii?ithaaiiy ??cieo ae?aiacii?a) ia no?oeoo?o oa eieeaaeuei? niaeo?e
ai?iieeneio [5,6]. Oaieia? aoaeoe a a?ieia?/ieo nenoaiao iaea?eueo
aecia/ai? ? a?ae?a?athoue iaeaaaeeea?oo ?ieue a ?o aeeoo?caeaoiino?. Aea
?o aea/aiiy aeey iaei?ino?oeo a?iiieaeoe oa ?o no?oeoo?ieo aeaiaio?a
iaaeinoaoiuei. A?aeiii oaeiae, ui ai?iieeneioe iiaeooue ii?aeioaaoeny c
?iiaie iaoae?a, ooai?thth/e eiiieaene, ui /eiyoue nooo?aee aieea ia
i?inoi?iao aoaeiao ? ooieoe?? a?ee?a. Aeine?aeaeaiiy oaeeo
iaoaeieiiieaen?a iniaeeai aeooaeuei? a oiiaao caa?oaeiaiiy a?inoa?e
i?iaeoeoaie oaoi?/ii? ae?yeueiino? ethaeeie ?, ianaiia?aae, ?iiaie
??cieo iaoae?a. E??i oiai, aeaye? eiiieaene ai?iieeneio ? ioeea?iiaeo
eeneio c iaoaeaie aieiae?thoue iioaioe?eiith oa?iaeieia?/iith
aeoeai?noth ? aaea nueiaiaei? ciaoiaeyoue oe?iea canoinoaaiiy o
i?aeoe/i?e oa?ai??. Oae, iai?eeeaae, eiiieaene ai?iieeneioe oeenoa?ia c
o?iiii iineeththoue ae?th ?inoe?ia, aeoea?cothoue aoaeaaiaeiee iai?i i?e
ae?aaaoe/iiio noai? [7,8], a ieaoeiia? eiiieaene ioeea?iiaeo eeneio
aieiae?thoue yne?aai ae?aaeaiith i?ioeiooeeiiith ae??th, aeaiiino?othoue
oi?eaeueio caeaoi?noue aei coeaaiiy iieaeoe aeacien???aiioeea?iiai?
eeneioe (AeIE) [9]. C ae?oaiai aieo a?aeii? oaeoe aeaaioai?iiai aieeao
i?e?iao?iaiai ? noai?e?iao?iaiai aeaeo?iiaai?oiiai aei?ii?ithaaiiy ia
i?ioeane o aeeaeo i?aai?ciao [5]. A oie aea /an ei?ioeioaeeueiaa ?
symbol 103 \f «Symbol» \s 14 g -aei?ii?ithaaiiy aieiae?thoue ?oei?aiith
ae??th [6]. Iniaeeaee ?ioa?an aeey ?icoi?iiy ia iieaeoey?iiio ??ai?
iaoai?ci?a aieeao ciai?oi?o ae?yiue ia a?ieia?/i? ia’?eoe i?aaenoaaey?
aea/aiiy niaeo??a iecueeiaia?aaoe/ieo ?ao?oi/ieo eieeaaiue.

Ana aeuaneacaia i?aeoaa?aeaeo? aeooaeuei?noue aea?aii? oaie ?
iaiao?aei?noue iiaeaeueoeo aeine?aeaeaiue iaeaaaeeea?oeo ai?iieeneio oa
?o iiaeo eiiieaen?a c iaoaeaie.

I?aenoaaith aeey i?iaaaeaiiy aeine?aeaeaiue aoei ianooiia:

Eieeaaeuei? niaeo?e ?ao?oi/ieo iiae a?eueoino? iaeaaaeeea?oeo
ai?iieeneio o o??aeueii /enoiio ? ?aoeai?/iiio oaciaiio noai? ia
aeinoaoiuei aea/ai?. A?aenooiy ?ioi?iaoe?y i?i iiaaae?ieo ?ao?oi/ieo
iiae a iaeano? aenieeo oaiia?aoo?, aeeth/ath/e iaeanoue iiaeeco
oaiia?aoo?e ieaaeaiiy.

Iaei/enaeuei?noue aenia?eiaioaeueieo aeaieo i?i aieea ciai?oi?o
cao?aiue (oaiia?aoo?e, eaaoaaiiy ?iiaie iaoae?a) ia eieeaaeuei? niaeo?e
?ao?oi/ieo iiae ai?iieeneio.

Ia ae??oaia ieoaiiy i?i aea?? aeiii?ieo oeaio??a oeenoa?io i?e
ooai?aii? eiiieaen?a c eaaei??i oa o?iiii. A?aenooiy aenia?eiaioaeueia
?ioi?iaoe?y i?i e?enoae?/io no?oeoo?o oa aeeiai?eo ?ao?oee aeey
a?eueoino? oaeaoieo eiiieaen?a oeenoa?io c eaaei??i ? o?iiii.

A?aenooi? aeai? i?i iniaeeaino? eiia?iaoe?eieo i?ioean?a o oaa?aeiio
oaciaiio noai? ai?iieeneio oa ?o eiiieaen?a c iaoaeaie.

Ia eaoaae?? iioiaeaeo?ii?ee o?ce/iiai oaeoeueoaoo Aei?i?iiao?ianueeiai
aea?aeaaiiai oi?aa?neoaoo ?nio? 20-oe ??/iee aeina?ae aeine?aeaeaiiy
niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea (E?), ?io?a/a?aiiiai (?*)
a?aeaeooy ? i?iioneaiiy o na?aaei?e ? aeaeuei?e iaeano? niaeo?o a
e?enoaeao neeaaeieo ieene?a, a?eueo?noue c yeeo iiaeia a?aeianoe aei
iaei?ino?oeo eii?aeeiaoe?eieo niieoe.

Ia iiiaio ii/aoeo aeine?aeaeaiue ia eaoaae?? iioiaeaeo?ii?ee aoee an?
iniiai? iaoiaeeee aeey eieeaaeueii? niaeo?ineii?? ? c?acee ?yaeo
iaeaaaeeea?oeo ai?iieeneio.

Ia eaoaae?? iai?aai?/ii? o?i?? o?i?/iiai oaeoeueoaoo
Aei?i?iiao?ianueeiai aea?aeaaiiai oi?aa?neoaoo aoa a?aei?aoeueiaaiee
neioac ? iaea?aeai? a ?iaeea?aeoaeueiiio noai? ?yae eiiieaen?a oeenoa?io
c eaaei??i ? o?iiii c ??ciith e?euee?noth oaeaoii ? iiiiaeaioaoii
eii?aeeiiaaiiai oeenoa?io.

I?ioyaii aeiaaio?eaaeiai /ano ia eaoaae?? iioiaeaeo?ii?ee i?iaiaeyoueny
oai?aoe/i? aeine?aeaeaiiy ii ?ic?aooieo neeiaeo noaeeo, /anoio ? oi?i
ii?iaeueieo eieeaaiue eii?aeeiaoe?eiiai aocea eiiieaen?a oeenoa?io c
oeeieii, eaaei??i, iaeaae??i, ieaoeiith ? o?iiii.

CA(ssCIE ?IAIOE C IAOEIAEIE I?IA?AIAIE, IEAIAIE, OAIAIE

Aeena?oaoe?eia ?iaioa aeeiiaia a ?aieao aea?aeathaeaeaoieo iaoeiaeo
aeine?aeaeaiue eaoaae?e iioiaeaeo?ii?ee ca oaiith “Aeine?aeaeaiiy
iioe/ieo ? iae?i?eii-iioe/ieo yaeu a ??cieo oaciaeo noaiao oaa?aeeo o?e
i?e eaca?iiio caoaeaeaii?”, yea aeeiio?oueny a?aeiia?aeii c iaeacii
I?i?noa?noaa ina?oe Oe?a?ie ?37 a?ae 13.02.97 ?., ? aoiaeeoue aei
eii?aeeiaoe?eiiai ieaio I?i?noa?noaa ina?oe Oe?a?ie o ?icae?e 6.5.
ssaeua ? i?ioeane o?ce/ii? iioeee ? eaca?ii? o?ceee. Oaiaoeea ?iaioe
o?nii iia’ycaia c i?ei?eoaoieie iai?yieaie ?icaeoeo iaoee oa oaoi?ee,
aecia/aieie iinoaiiaith Eaa?iaoa I?i?no??a Oe?a?ie ?429 a?ae 22.06.1994,
?icae?ee — 2. Caei?ia’y ethaeeie; 6. Iia? ?a/iaeie ? iaoa??aee.

IAOA ?IAIOE OA CAAeA*? AeINE?AeAEAIUe

Aei??thaaiiy oa aiae?c niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea ia
?ao?oi/ieo iiaeao o??aeueii /enoeo ? ?aoeai?/ieo oaciaeo noai?a
iaeaaaeeea?oeo ai?iieeneio.

Aea/aiiy aieeao oaiia?aoo?e oa eaaoaaiiy ?iiaie iaoae?a ia niaeo?e
eiia?iaoe?eiiai ?icn?thaaiiy na?oea ia ?ao?oi/ieo iiaeao iaeaaaeeea?oeo
ai?iieeneio.

Aei??thaaiiy niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea oa i?iioneaiiy
o na?aaei?e ? aeaeuei?e ?* iaeano? niaeo?a iiaeo eiiieaen?a oeenoa?io c
eaaei??i ? o?iiii aeey io?eiaiiy iiai? niaeo?ineii?/ii? ?ioi?iaoe?? i?i
eieeaaeuei? niaeo?e oa aeyaeaiiy aoaeo?a eii?aeeiaoe??.

Aiae?c iaea?aeaieo eieeaaeueieo niaeo??a ia iniia? ?ic?aooie?a /anoio
aioo??oi?o eieeaaiue eii?aeeiaoe?eiiai aocea a ?aieao ??cieo iiaeaeae
eiai aoaeiae c iaoith a?aeianaiiy niinoa??aa?ieo /anoio eieeaaiue ?
aeai?o iiaeae? aoaeiae, iaee?auei /eiii iienoth/i? aenia?eiaioaeueiee
eieeaaeueiee niaeo?.

Aea/aiiy i?e?iaee aoi?eiiiai aei?ii?ithaaiiy, yea i?iyaey?oueny o
niaeo?ao eiia?iaoe?eiiai ?icn?thaaiiy na?oea iaeaaaeeea?oeo ai?iieeneio
oa ?o eiiieaen?a c iaoaeaie.

IAOEIAA IIAECIA IAeA?AEAIEO ?ACOEUeOAO?A

A aeena?oaoe?ei?e ?iaio? i?iaaaeaii nenoaiaoe/ia aeine?aeaeaiiy
niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea iaeeo /anoio ?yaeo
iaeaaaeeea?oeo ai?iieeneio ? eieeaaeueieo niaeo??a iiaeo eiiieaen?a
oeenoa?io c eaaei??i ? o?iiii a iaeano? /anoio aioo??oi?o eieeaaiue
eii?aeeiaoe?eiiai aocea. Eieeaaeuei? niaeo?e eiiieaen?a oeenoa?io c
eaaei??i ? o?iiii a iaeano? /anoio aioo??oi?o eieeaaiue
eii?aeeiaoe?eiiai aocea aea/ai? aia?oa.

Anoaiiaeai? a?aei?iiino? niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea
iaeeo /anoio o??aeueii /enoeo ? ?aoeai?/ieo oaciaeo noai?a ?yaeo
iaeaaaeeea?oeo ai?iieeneio.

Anoaiiaeaii iayai?noue iaeiaeiaeo oa aeecueeeo /anoio o niaeo?ao
?ao?oi/ieo iiae ??cieo ai?iieeneio ? ?yaeo oa?iaoeaaoe/ieo i?aia?ao?a.
Iaea?aeai? ?acoeueoaoe i?iaiae?ciaai? a ?aieao ?aciiainii? aeeiai?/ii?
iiaeae? O?ueie?oa, yea iieno? i?ioeane iieaeoey?iiai i?ciaaaiiy.

Aei??yi? oaiia?aoo?i? caeaaeiino? niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy
na?oea iaeeo /anoio aeey ?yaeo iaeaaaeeea?oeo ai?iieeneio aae aei
oaiia?aoo?e ieaaeaiiy (?iceeaaeo). Aeyaeai? aoaeoe i???ioaoe?eiiai
ieaaeaiiy, ye? i?iyaeythoueny a eiioeioae?caoe?? ? cieeiaii? e?i?e E?,
a?aeiia?aeieo e?a?aoe?eiei eieeaaiiyi i?e caa?aaeaii? e?i?e E?,
coiiaeaieo o?aineyoe?eieie eieeaaiiyie, caaeiaai aei oi/ee o?ce/iiai
ieaaeaiiy (?iceeaaeo) ?a/iaeie.

Aeine?aeaeaii cao?thth/ee aieea ?ii?a eaaei?th oa o?iio ia niaeo? E?
iaeeo /anoio oeenoa?io, yeee i?iyaey?oueny a ?icieaaii? ? cieeiaii?
?yaeo e?i?e E? oa ca?eueoaii? ?ioaineaiino? ? oe?eie e?eea caoaeaeoth/i?
e?i?? aiane?aeie ?icoii?yaeeoaaiiy no?oeoo?e oeenoa?io.

Ca ?acoeueoaoaie i?iaaaeaiiai ?aioaaiioaciaiai aiae?co anoaiiaeaii, ui
eiiieaene oeenoa?io c eaaei??i ? o?iiii ciaoiaeyoueny a aii?oiiio
oaciaiio noai? ca aeeeth/aiiyi eiiieaeno [Cr(LH)3] symbol 183 \f
«Courier New» \s 14 · 3H2O, yeee /anoeiai ciaoiaeeoueny a e?enoae?/iiio
noai?.

Aeyaeaii aoaeoe eii?aeeiaoe?? o niaeo?ao E? oa ?*-i?iioneaiiy
eiiieaen?a oeenoa?io c eaaei??i ? o?iiii, ui i?iyaeythoueny o ci?i?
oa?aeoa?o niaeo?a a iaeano? /anoio aioo??oi?o eieeaaiue
eii?aeeiaoe?eiiai aocea.

Aeey ?yaeo eiiieaen?a oeenoa?io c o?iiii c ??ciith e?euee?noth oaeaoii
oa iiiiaeaioaoii eii?aeeiiaaiiai oeenoa?io aoee anoaiiaeai?
caeiiii??iino? ci?ie niaeo?a aioo??oi?o eieeaaiue eii?aeeiaoe?eiiai
aocea. Ni?anoaaeaiiy aei??yieo niaeo??a c ?acoeueoaoaie ?ic?aooie?a
aeicaieeei i?iaanoe a?aeianaiiy niinoa??aa?ieo eieeaaiue ? aea?aoe
iiaeae? aoaeiae eiiieaen?a, ye? iaee?aua a?aeiia?aeathoue
niinoa??aa?iiio eieeaaeueiiio niaeo?o.

Aeey ai?iieeneio D-oe?iceio, D-o?eioioaio, L-aae?io ? iaoaeieiii-eaena
ae?aaici?eoeenoa?iaoo eaaei?th aeyaeaii yaeua aoi?eiiiai aei?ii?ithaaiiy
o niaeo?ao E? o aeaeyae? oe?iei? ?ioaineaii? nioae “oiio” c iaeneioiii o
noienia?e iaeano? niaeo?o ? aea/ai? caeiiii??iino? eiai i?iyao a
caeaaeiino? a?ae ?ioaineaiino? ? /anoioe caoaeaeoth/iai aei?ii?ithaaiiy.
Aeeeth/aii aieea aia?aoo?ieo aoaeo?a. Cai?iiiiiaaia iiaeaeue yaeua, yea
iniiaaia ia a?aooaaii? i?ioean?a ?iciaaeo iaaeath/iai oioiia ia aeaa
oioiia ? oiiii. Iieacaii, ui yaeua, yea niinoa??aa?oueny, iiaeia
?icaeyaeaoe ye e?i?eia o?ueiooioiiia eiia?iaoe?eia ?icn?thaaiiy na?oea.

I?AEOE*IA CIA*AIIss IAeA?AEAIEO ?ACOEUeOAO?A

Anoaiiaeai? caeiiii??iino? a eieeaaeueieo niaeo?ao ?ao?oi/ieo iiae
iaeaaaeeea?oeo ai?iieeneio a o??aeueii /enoiio ? ?aoeai?/iiio oaciaiio
noai?, ye? aeicaieythoue ia?aa??eoe oai?aoe/i? iiaeae? aeeiai?/ieo
iaoai?ci?a iieaeoey?iiai i?ciaaaiiy ? iiaeooue aooe aeei?enoai? i?e
c’ynoaaii? iine?aeiaiino? ai?iieeneio a a?eeao.

Aiae?c oa?aeoa?enoee niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea ia
?ao?oi/ieo iiaeao ai?iieeneio oa e?ea?nueeeo i?aia?ao?a aeicaieea
cai?iiiioaaoe iaoiae eaca?ii? ae?aaiinoeee a?ieia?/ii? aeoeaiino?
inoaii?o, yeee neeaaea?oueny a ioe?ioe? aoaeoeaiino? ?icn?yiiy ia
iaea?eueo iecueei/anoioieo iiaeao ? anoaiiaeaii? iayaiino? iaeiaeiaeo ?
aeecueeeo /anoio a niaeo?ao ?ao?oi/ieo iiae a?ieia?/ii aeoeaieo ?a/iaei
? ai?iieeneio.

Aeyaeai? aoaeoe i???ioaoe?eiiai ieaaeaiiy ai?iieeneio, aaaeeea? aeey
?icoi?iiy i?e?iaee nee i?aeiieaeoey?ii? aca?iiae??, a oaeiae aoaeo?a
oaiia?aoo?iiai aieeao ia no?oeoo?o ? ooieoe?? a?ee?a aeeaeo i?aai?ci?a.

Io?eiai? iia? niaeo?ineii?/i? aeai? i?i eieeaaeuei? niaeo?e ?yaeo
i?aeoe/ii aaaeeeaeo eiiieaen?a oeenoa?io c eaaei??i oa o?iiii.

Iaaia i?aeoe/ia cia/aiiy iathoue ?acoeueoaoe aeine?aeaeaiiy aoaeo?a
eii?aeeiaoe?? a eieeaaeueieo niaeo?ao iiaeo eiiieaen?a oeenoa?io c
eaaei??i ? o?iiii. Aiae?c io?eiaieo ?acoeueoao?a aeicaieea aea?aoe
iiaeae? aoaeiae eii?aeeiaoe?eiiai aocea ?yaeo eiiieaen?a, ye? iaee?aua
iienothoue aenia?eiaioaeuei? eieeaaeuei? niaeo?e, ui aaaeeeai aeey ?o
i?aeoe/iiai aeei?enoaiiy a iaoaeioaeaoi?e oa?ai??.

Cai?iiiiiaaia ?ioa?i?aoaoe?y yaeua aoi?eiiiai aei?ii?ithaaiiy a niaeo?ao
E? aeicaiey? i?iaiaeeoe eiai oe?eani?yiiaaia nenoaiaoe/ia aeine?aeaeaiiy
a ??cieo ?a/iaeiao c iaoith i?aeoe/iiai aeei?enoaiiy.

INIAENOEE AIANIE CAeIAOAA*A

Iniiai? aenia?eiaioaeuei? ?acoeueoaoe ? aeniiaee aeena?oaoe?? io?eiai?
iniaenoi aaoi?ii. Iinoaiiaea caaea/?, c symbol 162 \f «Symbol» \s 14 c
ynoaaiiy iai?yie?a aeine?aeaeaiue oa iaaiai?aiiy ?acoeueoao?a aeeiiai?
?acii c iaoeiaei ea??aieeii aeieoi?ii o?c.-iao. iaoe, i?io. Ii?na?iei
A.I.. Ni?aaaoi?e ioae?eaoe?e i?eeiaee o/anoue a iaaiai?aii? ?acoeueoao?a
?iaioe, neioac? aeine?aeaeoaaieo ?a/iaei, i?iaaaeaii? ?aioaaiioaciaiai
aiae?co.

AI?IAAOe?ss ?ACOEUeOAO?A ?IAIOE

Iniiai? ?acoeueoaoe aeena?oaoe?? aoee iiaeai? ia XIII oeie?-nai?ia??
“Niaeo?ineii?y iieaeoe oa e?enoae?a” (Noie, Oe?a?ia, 1997),
I?aeia?iaeieo eiioa?aioe?yo ii ?aiaiianuee?e niaeo?ineii?? ICORS-15
(I?oonao?a, NOA, 1996), ICORS-16 (Eaeioaoi, IA?, 1998), 3-io
I?aeia?iaeiiio neiiiceoi? “I?ia?an o ?io?a/a?aii?e ? ?aiaiianuee?e
niaeo?ineii?? ” (A?aeaiue, Aano??y, 1998).

IOAE?EAOe??

Ca iaoa??aeaie aeena?oaoe?eii? ?iaioe iioae?eiaaii 3 noaoo?, 3 i?aoe? oa
3 oace a iaoa??aeao eiioa?aioe?e.

NO?OEOO?A OA IA’?I AeENA?OAOe??

Aeena?oaoe?y neeaaea?oueny ?c anooio, i symbol 162 \f «Symbol» \s 14 c
yoe ?icae?e?a oa aeniiae?a. Caaaeueiee ia symbol 162 \f «Symbol» \s 14 c
?i neeaaea? 132 noi??iee, aeeth/ath/e 50 iaethie?a, 16 oaaeeoe? oa
nienie e?oa?aoo?e ?c 103 iaeiaioaaiue ia 11 noi??ieao.

INIIAIEE CI?NO ?IAIOE

O anooi? iaa?oioiaaia aeooaeuei?noue oaie aeena?oaoe?eii? ?iaioe,
noi?ioeueiaaia iaoa oa caaea/? aeine?aeaeaiue, i?eaaaeaii iniiai?
iaoeia? oa i?aeoe/i? ?acoeueoaoe ?iaioe.

O ia?oiio ?icae?e? ?icaeyioo? iniaeeaino? no?oeoo?e ? eieeaaiue ?ao?oee
iieaeoey?ieo e?enoae?a, no/ani? ?aciiaini? aeeiai?/i? iiaeae?
i?aeiieaeoey?ii? aca?iiae??, a?aeiia?aeaeuei? ca aoaeoe
i?aeiieaeoey?iiai i?ciaaaiiy a a?ieia?/ieo nenoaiao, i?ioeane neioaco
neeaaeieo a?iiie?ia??a i?e?iaeiiai iioiaeaeaiiy. Aeeeaaeai? iiaeaeuei?
oyaeaiiy i?i iaoai?cie aca?iiae?? a?ieia?/ii aeoeaieo iieaeoe c iaoaeaie
? iieacaia aaaeeeaa ?ieue ?ii?a iaoae?a o a?ieia?/ieo ooieoe?yo aeeaeo
i?aai?ci?a.

Iaa?oioiaaii aea?? ia symbol 162 \f «Symbol» \s 14 c ?eo?a
aeine?aeaeaiue. Iieacaii, ui iaeaaaeeea?o? ai?iieeneioe yaeythoue niaith
iaei?ino?o? a?iiieaeoee ? iiaeooue aooe iiaeaeueieie ia symbol 162 \f
«Symbol» \s 14 c ?eoaie aeey aea/aiiy aieeao ciai?oi?o cao?aiue ia
a?ieia?/i? ia?’eoe, cie?aia oaiia?aoo?ieo aoaeo?a oa iaoai?ci?a
aca?iiae?? a?ieia?/ieo iieaeoe c iaoaeaie. C?iaeaiee aeaoaeueiee
aiae?oe/iee iaeyae iayaieo aeaiieo ii aea/aiith no?oeoo?e ? eieeaaeueieo
niaeo??a ai?iieeneio oa ?o eiiieaen?a c iaoaeaie. I?eaaaeai?
iaei/enaeuei? aeai? ii aieeao oaiia?aoo?e, eaaoaaiiy ?iiaie iaoae?a,
aeaeo?iiaai?oiiai aei?ii?ithaaiiy ??cieo ae?aiacii?a ia eieeaaeuei?
niaeo?e iaeaaaeeea?oeo ai?iieeneio. ?icaeyioo? a e?oa?aoo?iiio iaeyae?
aeai? na?ae/aoue i?i iaaeinoaoith aea/ai?noue niaeo??a ?ao?oi/ieo iiae
iaeaaaeeea?oeo ai?iieeneio, iniaeeai a oiiaao ciai?oi?o cao?aiue,
a?aenooi?noue aeaieo i?i no?oeoo?o ? eieeaaeuei? niaeo?e eiiieaen?a
oeenoa?io c eaaei??i ? o?iiii, i?i iaiaeiicia/io ?ioa?i?aoaoe?th
eieeaaeueieo niaeo??a ?ioeo eiiieaen?a ai?iieeneio c iaoaeaie. Oea
iaoiiaeaii ye neeaaei?noth aoaeiae aeacaieo ia symbol 162 \f «Symbol» \s
14 c ?eo?a, oae ? iaaeinoaoiueith aea/ai?noth ?o no?oeoo?e o oaa?aeiio
oaciaiio noai?.

C i?aeoe/ii? oi/ee ci?o, aeai? i?i niaeo? iecueeiaia?aaoe/ieo
eieeaaeueieo noai?a ai?iieeneio aaaeeea? aeey ?icoi?iiy i?e?ineii?/ieo
iaoai?ci?a aieeao ciai?oi?o oaeoi??a ia ooieoe?? a?ieia?/ieo nenoai,
cie?aia iaoai?ci?a aca?iiae?? i?e?iao?iaiai aeaeo?iiaai?oiiai
aei?ii?ithaaiiy c aeeaeie i?aai?ciaie, aeeth/ath/e iiceoeaiee
oa?aiaaoe/iee aoaeo. Aeai? i?i niaeo?e eieeaaeueieo noai?a eiiieaen?a
iaeaaaeeea?oeo ai?iieeneio c iaoaeaie aaaeeea? aeey c’ynoaaiiy
iaoai?ci?a ca symbol 162 \f «Symbol» \s 14 c ycoaaiiy oiene/ieo iaoae?a
a aeeaeo i?aai?ciao, a oaeiae i?e?iaee ?o a?ieia?/ii? aeoeaiino?.

C?iaeaiee aeaoaeueiee iaeyae ?acoeueoao?a ?ic?aooieiai-oai?aoe/ii?
?ioai?aoaoe?? aioo??oi?o eieeaaiue eii?aeeiaoe?eiiai aocea eiiieaen?a
ai?iieeneio c iaoaeaie. Iieacaii, ui iaea?eueo nooo?a? ci?ie a niaeo?ao
i?e eiiieaeniooai?aii? neeaaeathoueny a i?iyaao /anoio eieeaaiue
iaoae-e?aaiae, ia?a?iciiae?eo niaeo?aeueieo ?ioaineaiinoae ? ?icuaieaii?
?*-nioa, ye? a?aeiia?aeathoue eieeaaiiyi e?aaiae?a aiane?aeie ci?ie ?o
eieaeueii? neiao???.

Iaa?oioiaaia iinoaiiaea caaea/ aeine?aeaeaiiy aeena?oaoe??.

O ae?oaiio ?icae?e? iienai? iniiai? iaoiaeeee ? oaoi?ea aenia?eiaioo,
ye? aeei?enoiaoaaeenue i?e aeeiiaii? aeaii? ?iaioe, iaoiaee i?eaiooaaiiy
c?ace?a aeey aeine?aeaeaiue. A?eueo aeaoaeueii ?icaeyiooi iaeaaeiaiiy
i?ea?iaeueiiai eaca?iiai niaeo?iiao?a eiia?iaoe?eiiai ?icn?thaaiiy
na?oea (E?), a oaeiae ianoaiaea?oi? iaoiaee i?eaiooaaiiy c?ace?a aeey
aei???a niaeo??a i?iioneaiiy o aeaeuei?e ?*-iaeano? niaeo?a.

O o?aoueiio ?icae?e? i?aaenoaaeai? ?acoeueoaoe oai?aoeei-a?oiiaiai
aiae?co ?ao?oi/ieo eieeaaiue ai?iieeneio, a oaeiae ?acoeueoaoe
aeine?aeaeaiiy niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea iaeeo /anoio
a o??aeueii /enoeo (e?aeo (L) ? i?aaeo (D)) oa ?aoeai?/ieo (DL) oaciaeo
noaiao iaeaaaeeea?oeo ai?iieeneio: L- ? DL-aae?io, D- ? DL-o?eioioaio,
D-oe?iceio, DL-iao?ii?io, L-ania?aa?iiai? eeneioe, L-?cieaeoeeio,
L-oeenoa?io. Iieacaii, ui niaeo?e E? ia ?ao?oi/ieo iiaeao aeacaiieo
ai?iieeneio neeaaeathoueny ?c aaeeei? e?eueeino? aca?iii
ia?ae?eaath/eony nioa ? aocueeeo e?i?e, ye? iaoiiaeai? inoeeeyoe?yie aai
ia?aaaeueiiaaieie eieeaaiiyie ie?aieo iieaeoe oa ?o /anoei a?aeiinii
iaeia iaeiiai a i?ioean? o?aineyoe?eieo ? e?a?aoe?eieo ?oo?a. I?e
oeueiio nai? iecueei/anoioi? e?i?? E? (ieae/a 100 ni-1) aieiae?thoue
a?eueo aenieith aeia?ioi?noth, a oie /an ye e?i?? c /anoioaie aeua 100
ni-1 iathoue aeaeyae oe?ieeo nioa. Anoaiiaeaii, ui niaeo?e E? e?ai? ?
i?aai? oi?i e?enoae?a i?aeoe/ii oioiaei?. A oie aea /an niaeo?e E?
?aoeai?/ieo oaciaeo noai?a iii?oii a?ae??ciythoueny. C iaoith aeyaeaiiy
e?euee?nieo a?aei?iiinoae a niaeo?ao o??aeueii /enoeo ? ?aoeai?/ieo
oaciaeo noai?a ai?iieeneio aoee i?iaaaeai? aeaoaeuei? aei??e niaeo??a E?
aeey aae?ia ? o?eioioaia. ?c aei??yieo niaeo??a ae?aoiaoaaany ??aaiue
oiio, aeeth/ath/e e?eei caoaeaeoth/i? e?i??. Aeey oi/iiai aecia/aiiy
inoeeeyoi?ieo ia?aiao??a eieeaaiue i?iaiaeeany o?oo?ia aei??yieo
niaeo??a c aeei?enoaiiyi ae?aco

eq J(w,T) = [n(w,T)+1] \o(S;\s\do11(j)) I\s\do5(j) \f(W\s(2;j) G\s( ;j)
w; \b\bc\[( \b\bc(W\s(2;j)- w\s(2; ))\s\up10(2) + G\s(2;j) w\s(2; )))
\s\up2 ( + B) , (1)

aea [n( symbol 119 \f «Symbol» \s 14 w ,T) + 1] — oaeoi? Aica-Aeiooaeia,
symbol 73 \f «Symbol» \s 14 I j — ?ioaa?aeueia ?ioaineai?noue a e?i??
E?, symbol 87 \f «Symbol» \s 14 W j e symbol 71 \f «Symbol» \s 14 G j
— /anoioa ? caaanaiiy eieeaaiiy, A — ??aaiue oiio.

Io?eiaii, ui aeey L- ? DL-aae?io, D- ? DL-o?eioioaio aenia?eiaioaeueii
aeyaeaia e?euee?noue eieeaaiue iaiueoa, i?ae iiaeiia aooe a?aeiia?aeii
aei ?acoeueoao?a oai?aoeei-a?oiiaiai aiae?co. E?euee?ni? a?aei?iiino?
inoeeeyoi?ieo ia?aiao??a eieeaaiue aeey o??aeueii /enoeo ? ?aoeai?/ieo
oaciaeo noai?a iaoiiaeai? a?aei?ii?noth ?o e?enoae?/ieo no?oeoo?, ye?
a?ae??ciythoueny oeeaaeeith aiaioeiii?oieo iieaeoe iaiaeiaeiai?
o??aeueiino?.

C iaoith c symbol 162 \f «Symbol» \s 14 c ynoaaiiy i?eaeaoiino?
aeeiai?/ii? iiaeae? i?aeiieaeoey?ii? aca?iiae?? O?ueie?oa aei iieaeoe
ai?iieeneio aoa i?iaaaeaiee aiae?c /anoio eieeaaiue ?ao?oi/ieo iiae aeey
an?o aea/aieo ai?iieeneio, ui ciaoiaeyoueny a o??aeueii /enoeo oaciaeo
noaiao. Io?eiaii, ui a on?o aeiaaeeao niinoa??aathoueny aeecuee? aai
ca?aei? /anoioe. C oe??th ae iaoith i?iaiaeeeinue ii??aiyiiy niaeo??a
iaeeo /anoio a?iiaoe/ii? ai?iieeneioe D-oe?iceio ? ?yaeo e?ea?nueeeo
i?aia?ao?a, iieaeoee yeeo i?noyoue a?iiaoe/i? a?oie. ? a oeueiio
aeiaaeeo aoee aeyaeai? ca?aei? /anoioe a niaeo?ao E? aeey iiaiea?io ?
noeuea?io, c iaeiiai aieo, ? aeey D-o?eioioaio, c ?ioiai. Iaea?aeai?
?acoeueoaoe a?aeiia?aeii iiaeae? O?ueie?oa aeacothoue ia iiaeeea?noue
aoaeoeaii? acaiiae?? i?ae oaeeie iieaeoeaie, ui a naith /a?ao iiaea
iiynieoe aieea aeacaieo e?ea?nueeeo i?aia?ao?a ia i?ioeane a a?eeiaeo
no?oeoo?ao ? ia?aiaeo oeaieiao. E??i oiai, iayai?noue aenieiaeia?ioieo
e?i?e a niaeo?ao E? ia ?ao?oi/ieo iiaeao e?ea?nueeeo i?aia?ao?a
a?aee?eaa? iiaeeea?noue ia?oeioth/iai eiio?ieth ?o eiioi?iaoe?eiiai ?
o?i?/iiai neeaaeo.

Aeeeaaeai? ?acoeueoaoe oaiia?aoo?ieo aei???a niaeo??a E? iaeeo /anoio
aeey ?yaeo iaeaaaeeea?oeo ai?iieeneio. C iaoith c’ynoaaiiy aieeao
oaiia?aoo?e ia niaeo?e ?ao?oi/ieo eieeaaiue iaeaaaeeea?oeo ai?iieeneio
aoee i?iaaaeai? aei??e niaeo??a E? iaeeo /anoio aeey D-o??ic?io a
ae?aiacii? oaiia?aoo? 100 — 300E, aeey ai?iieeneio L-oeenoa?io,
DL-iao?ii?io, L-ania?aa?iiai? eeneioe, D- ? DL-o?eioioaio – a ae?aiacii?
oaiia?aoo? 300E – 450E.

Io?eiaii, ui i?e i?aeaeuaii? oaiia?aoo?e a?ae 100E niaeo? E? D-o??ic?io
caa??aaa naith no?oeoo?o, iaeiae oa?aeoa?enoeee aeayeeo e?iee
i?aoa?i?aaee iii?oi? ci?ie. Iaea?eueo neeueia ciaioaiiy /anoioe c
iaa??aaiiyi caciaaaea aenieiaeia?ioia e?i?y c symbol 119 \f «Symbol» \s
14 w =35 ni-1, a iaea?eueo iii?oia c?inoaiiy /anoioe – e?i?y c symbol
119 \f «Symbol» \s 14 w =166 ni-1. A a?oi? e?i?e a iaeano? 80 – 140 ni-1
niinoa??aaany ia?a?iciiae?e niaeo?aeueii? ?ioaineaiino? E?:
?ioaineai?noue e?i?? c /anoioith symbol 119 \f «Symbol» \s 14 w =100
ni-1 iii?oii c?inoaea. ?aooa e?i?e caciaaaea eeoa iii?oia oaiia?aoo?ia
?icoe?aiiy. Ci?ia inoeeeyoi?ieo ia?aiao??a ?ao?oi/ieo eieeaaiue a
D-o??ic?i? a?aeia?aaea? /ooeea?noue i?aeiieaeoey?ieo aca?iiae?e aei
c?inoaiiy oaiia?aoo?e. Oea iniaeeai iii?oii aeey iaea?eueo
iecueei/anoioieo o?aineyoe?eieo eieeaaiue. Aeey e?a?aoe?eieo eieeaaiue
oa?aeoa?ii iii?oia c?inoaiiy caaanaiiy i?e ii??aiyii iaaaeeee?e ci?i?
/anoioe.

O aeiaaeeo L-oeenoa?io oa DL-iao?ii?io niaeo?e E? iaeeo /anoio noaaaee
aeeoocieie aaea i?e O=363E. Iaeiae oa?aeoa?enoeee aeayeeo e?i?e c
/anoioaie (ni-1) 11, 154 (aeey L-oeenoa?io) e 14, 24, 60 (aeey
DL-iao?ii?io) i?aeoe/ii ia ci?ithaaeenue. Ia a?aei?io a?ae oeueiai
niaeo? E? iaeeo /anoio L-ania?aa?iiai? eeneioe a iaeano? /anoio 0 – 150
ni-1 caa??aaa naith no?oeoo?o ca aeeeth/aiiyi ia?a?iciiae?eo
niaeo?aeueii? ?ioaineaiino? i?ae o?ueiia iaea?eueo iecei/anoioieie
e?i?yie. Iaea?eueo iai/ii aaiethoe?y niaeo?a E? iaeeo /anoio i?e
iaa??aaii? i?iyaey?oueny aeey D- e DL-o?eioioaio. Cia/ia ?icieooy
a?eueoino? e?i?e E? o oeueiio aeiaaeeo niinoa??aaeinue aaea i?e O=363E,
a ?o iiaia cieeiaiiy — i?e O=423E. I?e oeueiio a niaeo?ao caeeoaany ?yae
e?i?e c /anoioaie (ni-1) 12, 35, 100 (aeey D-o?eioioaio) ? 30, 54, 98
(aeey DL-o?eioioaio). Oe? oaeoe aeicaieythoue a?aeianoe iaea?eueo
iecueei/anoioi? e?i??, ye? caa??aathoueny a niaeo?? E? ai?iieeneio i?e
iaa??aaii?, aei o?aineyoe?eieo eieeaaiue, oiae? ye a?eueo aeniei/anoioi?
e?i??, ye? caciathoue neeueia ?icieooy c iiaeaeueoei cieeiaiiyi, — aei
e?a?aoe?eieo eieeaaiue. Aeey on?o aeine?aeaeaieo ai?iieeneio, ca
aeiyoeii L-ania?aa?iiai? eeneioe, niaeo?e E? iaeeo /anoio iaaaaeoaaee
niaeo? iieaeoey?iiai e?enoaeo a noai? i?aaeieaaeaiiy caaeiaai aei
oaiia?aoo?e o?ce/iiai ieaaeaiiy (?iceeaaeo). C iaoith aecia/aiiy
e?euee?noieo ci?i oa?aeoa?enoee e?i?e i?e iaa??aaii? i?iaiaeeeinue
?iceeaaeaiiy niaeo??a E? aeey D-o?eioioaio ia niaeo?aeuei? neeaaeia? ca
aeiiiiiaith ae?aco (1). Niinoa??aa?i? aoaeoe a niaeo?ao E? ia ?ao?oi/ieo
iiaeao ai?iieeneio iiaeooue aooe ?ioa?i?aoiaai? ye aoaeoe
i???ioaoe?eiiai ieaaeaiiy, ye? caaeiaai ia?aaeothoue o?ce/iiio
ieaaeaiith.

O /aoaa?oiio ?icae?e? i?aaenoaaeai? ?acoeueoaoe aeine?aeaeaiiy niaeo??a
E? a iaeano? /anoio ?ao?oi/ieo eieeaaiue (0 – 200 ni-1), a oaeiae E? ?
?*-i?iioneaiiy eiiieaen?a oeenoa?io c eaaei??i ? o?iiii a iaeano? /anoio
aioo??oi?o eieeaaiue eii?aeeiaoe?eiiai aocea (300 — 650 ni-1). C iaoith
iaea?aeaiiy iiia?aaeiuei? ?ioi?iaoe?? i?i no?oeoo?o eiiieaen?a
i?iaiaeeany ?o ?aioaaiioaciaee aiae?c. Anoaiiaeaii, ui an?
iaoaeieiiieaene ciaoiaeyoueny a aii?oiiio oaciaiio noai?, ca
aeeeth/aiiyi [Cr(LH)3] 3H2O, aea [LH2] — oeenoa?i.

Aea/aii cao?thth/o ae?th ?ii?a eaaei?th oa o?iio ia niaeo?e E? ia
?ao?oi/ieo iiaeao ai?iieeneioe oeenoa?io, yea i?iyaey?oueny a ?icieoo? ?
cieeiaii? ?yaeo e?i?e E? oa ca?eueoaii? ?ioaineaiino? ? oe?eie e?eea
caoaeaeoth/i? e?i??, caaaeyee ?icoii?yaeeoaaiith e?enoae?/ii? no?oeoo?e
oeenoa?io. Ca?aeii c ?acoeueoaoaie ?ic?aooieo /anoio aioo??oi?o
eieeaaiue eii?aeeiaoe?eiiai aocea a iaeano? /anoio 300 – 650 ni-1
iiaeii? aeyaeyoeny aoaeoe eii?aeeiaoe??. Aeey ?o aecia/aiiy aoee
aei??yi? niaeo?e E? eiiieaen?a oeenoa?io c eaaei??i a oe?e iaeano?
/anoio, ye? ii??aithaaeeny ?c niaeo?ii iie?e?enoae?/iiai oeenoa?io.

Iaea?aeaii, ui ia a?aei?io a?ae niaeo?a E? oeenoa?io, niaeo?e eiai
eiiieaen?a c eaaei??i iathoue eiioeioaeueiee oa?aeoa? c? neaai
ae?aaeaiieie iaeneioiaie. Aeey ae?aaici?eoeenoa?iaoo eaaei?th ??aaiue
oiio aoa o 20 ?ac?a a?eueoa, i?ae a oeenoa?i?. O oe?eiio iaea?aeai?
?acoeueoaoe ei?aeththoue c aeaieie ?aioaaiioaciaiai aiae?co ? oa?aeoa?i?
aeey niaeo??a E? aii?oieo ?a/iaei. Iayai?noue neaaei ae?aaeaieo
iaeneioi?a o niaeo?ao E? iaoaeieiiieaen?a iiaea na?ae/eoe i?i iayai?noue
iacia/ii? e?eueeino? ?a/iaeie a iie?e?enoae?/iiio noai?.

Aeeeaaeai? ?acoeueoaoe aeine?aeaeaiiy niaeo??a ?*-i?iioneaiiy aeey
eiiieaen?a oeenoa?io c eaaei??i ? o?iiii o na?aaei?e ? aeaeuei?e
iaeanoyo niaeo?o. Aecia/ai? /anoioe iaea?eueo ?ioaineaieo nioa
iiaeeiaiiy. C iaoith a?aeianaiiy niinoa??aa?ieo /anoio eieeaaiue aeey
?yaeo aea/aieo eiiieaen?a oeenoa?io c eaaei??i ? o?iiii i?iaiaeeeiny ?o
ii??aiyiiy c ?acoeueoaoaie ?ic?aooie?a /anoio aeey aioo??oi?o eieeaaiue
eii?aeeiaoe?eiiai aocea a ?aieao ??cieo iiaeaeae eiai aoaeiae. Aeey
iaeiicia/iiai aeai?o iiaeae? aoaeiae eii?aeeiaoe?eiiai aocea a
eiiieaenao oeenoa?io c eaaei??i ? o?iiii iaiao?aeia ieeueia c?noaaeaiiy
aei??yieo ? ?ic?aooieiaeo /anoio eieeaaiue. I?e oeueiio iaiao?aeii
a?aoiaoaaoe iiaeeeaee eiioi?iaoe?eiee neeaae niieoee, a oaeiae aoaeoe
neeueiiai aiaa?iii?cio. Iiia?aaei? aeai? i?i eii?aeeiaoe?ei? oi?ioee
aeine?aeaeo?ieo ?a/iaei aoee io?eiai? ?ai?oa ia iniia? ?acoeueoao?a
aeaiaioiiai aiae?co, aiiieia?/ieo ia?aoai?aiue, aea/aiiy e?iaoeee
?aaeoe?e ?icieeaiiy ? caieeaiiy oeeee?a, aei??o aeaeo?ii?ia?aeiino? a
?ic/ei?, a oaeiae niaeo??a ?*-i?iioneaiiy a na?aaei?e iaeano? niaeo?o
(400 – 4000 ni-1 ) [10]. Aei??aiiy eieeaaeueieo niaeo??a a iaeano?
/anoio eii?aeeiaoe?eiiai aocea (90 – 650 ni-1) i?aeoe/ii ia
i?iaiaeeeenue.

Aiae?c niaeo??a E? oa ?*-i?iioneaiiy a iaeano? /anoio 200 – 600 ni-1
aeey eiiieaen?a oeenoa?io c eaaei??i aeicaiey? c?iaeoe ne?aeoth/?
aeniiaee.

Aeey on?o aea/aieo eiiieaen?a oeenoa?io c eaaei??i a ?* niaeo?ao
i?iyaey?oueny 4 — 5 nioa iiaeeiaiiy, na?aae yeeo o?eueee iaeia
?ic?aooieiaa /anoioa eieeaaiiy Cd-S (342 ni-1) i?iyaey?oueny a eiiieaen?
[Cd(L/H)2]. Ae?oaa ?ic?aooieiaa /anoioa eieeaaiiy Cd-S (416 ni-1)
i?iyaey?oueny o?eueee a niaeo?ao E? eiiieaen?a [CdL] ? [Cd(LH)2].

?ic?aooieiaa /anoioa eieeaaiiy Cd-O (505,6 ni-1) i?iyaey?oueny a
niaeo?ao E? aeey on?o eiiieaen?a. Ae?oaa ?ic?aooieiaa /anoioa Cd-O (558
ni-1) i?iyaey?oueny o?eueee a ?* niaeo?ao eiiieaen?a [CdL] ? [Cd(L/H)2].

I?eaaaeai? aeua ?acoeueoaoe c o?aooaaiiyi neiao??? eieeaaiue Cd-S ?
Cd-O oa ?o aeoeaiino? a niaeo?ao ?* ? E? aeicaieythoue c?iaeoe aeniiaie,
ui aeey eiiieaen?a [Cd(LH)2] ? [Cd(L/H)2] iaea?eueo eiia??ii
?aae?co?oueny iiaeaeue eii?aeeiaoe?eiiai aocea o aeaeyae? o?ain-oi?ie
ieineiai eaaae?aoo. Iaeiae, a iaio aeiaaeeao o oaa?aeiio oaciaiio noai?
iiaeooue iaoe i?noea ??ci? niioai?aiiy no?oeoo?e eii?aeeiaoe?eiiai
aocea, ui i?iyaey?oueny a iaaaeee?e a?aei?i? aenia?eiaioaeueieo ?
?ic?aooieiaeo /anoio eieeaaiue oa ?o aeoeaiino? a niaeo?ao ?* ? E?. Aeey
eiiieaena [CdL] ?aae?co?oueny iiiiaeaioaoia eii?aeeiaoe?y /a?ac aoii
eenith.

Aiae?c ?* niaeo??a aeey eiiieaen?a o?iia iaio iaeiicia/iee. Iaeiae ? a
oeueiio aeiaaeeo iiaeeeai c?iaeoe ne?aeoth/? aeniiaee.

Aeey a?eueoino? aea/aieo eiiieaen?a i?iyaeythoueny /anoioe
aeaoi?iaoe?eieo eieeaaiue symbol 100 \f «Symbol» \s 14 d (O-Cr-O), ui
iiaea na?ae/eoe ia ei?enoue eii?aeeiaoe?? /a?ac aoii eenith.

?ic?aooieia? /anoioe eieeaaiue symbol 100 \f «Symbol» \s 14 d s(N-Cr-N)
e symbol 110 \f «Symbol» \s 14 n s(Cr-N) i?iyaeythoueny
aenia?eiaioaeueii o?eueee aeey eiiieaeno [Cr(LH)3] 3H2O, ui aeicaiey?
aiai?eoe i?i i?aaii??i?noue iiaeae? eiai aoaeiae, yea aeeth/a? ca’ycee
e?aaiae?a c aoiiii o?iio /a?ac aoiie eenith ? acioo.

Caieiai? oeeeee c eii?aeeiaoe??th /a?ac aoiie eenith ? acioo ?niothoue
o?eueee a eiiieaen? [Cr(LH)3] 3H2O. A ?ioeo aeiaaeeao iathoue i?noea
?ic?ieiai? oeeeee c eii?aeeiaoe??th o?eueee /a?ac aoiie eenith.

O i symbol 162 \f «Symbol» \s 14 c yoiio ?icae?e? i?aaenoaaeai?
?acoeueoaoe aea/aiiy yaeua aoi?eiiiai aei?ii?ithaaiiy (“oiio”) o
niaeo?ao E? o aeaeyae? oe?iei? ?ioaineaii? neiao?e/ii? nioae c
iaeneioiii o noienia?e iaeano? niaeo?o. Aeacaia aoi?eiia aei?ii?ithaaiiy
niinoa??aaeinue aeey ai?iieeneio D-o??iceio, D-o?eioioaio, L-aae?io, a
oaeiae aeey eiiieaeno oeenoa?io c eaaei??i — ae?aaici?eoeenoa?iaoa
eaaei?th. Aaaeeeai a?aei?oeoe, ui an? aeacai? ai?iieeneioe ciaoiaeeeeny
a e?enoae?/iiio noai?, a ae?aaici?eoeenoa?iao eaaei?th — a aii?oiiio. A
on?o aeiaaeeao niaeo?e ?a?no?oaaeeny a iaeiaeiaeo oiiaao. Aea/ai?
caeaaeiino? niaeo?a “oiio” a?ae iiooaeiino?, aaniethoii? /anoioe
caoaeaeoth/iai aei?ii?ithaaiiy ? a?ae o?i?/ii? i?e?iaee ?a/iaeie.
I?iaaaeaiee aiae?c aieeao aoaeoeaiino? aeeo?aeoe?eii? ?ao?oee ?
niaeo?aeueii? /ooeeaino? oioieaoiaea aeei?enoaiiai oioiaeaeo?iiiiai
iiiaeieea ia aeaeyae niaeo?a “oiio”. Cai?iiiiiaaia ?ioa?i?aoaoe?y
niinoa??aa?iiai iioe/iiai yaeua a oa?i?iao aaaaoieaaioiaeo iioe/ieo
i?ioean?a.

Iieacaii, ui iniiai? caeiiii??iino? yaeua iiaeooue aooe iiyniai? a
?aieao iiaeae? ?iciaaeo iaaeath/iai oioiio ia aeaa oioiia ? oiiii. Oaeei
/eiii, aoi?eiia aei?ii?ithaaiiy, yea niinoa??aa?oueny, iiaea aooe
eeaneo?eiaaia ye e?i?eia o?ueiooioiiia eiia?iaoe?eia ?icn?thaaiiy
na?oea.

INIIAI? ?ACOEUeOAOE OA AENIIAEE

I?iaaaeai? nenoaiaoe/i? aei??thaaiiy niaeo??a eiia?iaoe?eiiai
?icn?th-aaiiy na?oea (E?) ia ?ao?oi/ieo iiaeao ?yaeo iaeaaaeeea?oeo
ai?iieeneio o oaa?aeiio oaciaiio noai?.

Anoaiiaeai? a?aei?iiino? niaeo??a eiia?iaoe?eiiai ?icn?thaaiiy na?oea
iaeeo /anoio o??aeueii /enoeo ? ?aoeai?/ieo oaciaeo noai?a ?yaeo
iaeaaaeeea?oeo ai?iieeneio.

A niaeo?ao E? ia ?ao?oi/ieo iiaeao ??cieo ai?iieeneio ? ?yaeo
oa?iaoeaaoe/ieo i?aia?ao?a aeyaeai? iaeiaeia? ? aeecuee? /anoioe.
Iaea?aeai? ?acoeueoaoe i?iaiae?ciaai? a ?aieao ?aciiainii? aeeiai?/ii?
iiaeae? O?ueie?oa, yea iieno? iaoai?ci i?aeiieaeoey?ii? aca?iiae??.

Aei??yi? oaiia?aoo?i? caeaaeiino? niaeo??a E? iaeeo /anoio ?yaeo
iaeaaaeeea?oeo ai?iieeneio a ae?aiacii? 100 – 450E. Aeyaeai? aoaeoe
i???ioaoe?eiiai ieaaeaiiy, ye? i?iyaeythoueny a ?icieoo? ? cieeiaii?
e?i?e E?, ui a?aeiia?aeathoue e?a?aoe?eiei eieeaaiiyi, i?e caa?aaeaii?
e?i?e E?, ui a?aeiia?aeathoue o?aineyoe?eiei eieeaaiiyi, caaeiaai aei
oi/ee o?ce/iiai ieaaeaiiy (?iceeaaeo) ?a/iaeie.

Aea/aii cao?thth/o ae?th ?ii?a iaoae?a ia niaeo?e E? iaeeo /anoio
oeenoa?io ia i?eeeaae? ?yaeo eiai eiiieaen?a c eaaei??i ? o?iiii.
Anoaiiaeai? aoaeoe ?icoii?yaeeoaaiiy no?oeoo?e oeenoa?io, ye?
i?iyaeythoueny a ?icieoo? oa cieeiaii? ?yaeo e?i?e E?, coiiaeaieo
?ao?oi/ieie eieeaaiiyie, oa a ca?eueoaii? ?ioaineaiino? ? oe?eie e?eea
caoaeaeoth/i? e?i??.

I?iaaaeaii ?aioaaiioaciaee aiae?c eiiieaen?a ai?iieeneioe oeenoa?io c
eaaei??i ? o?iiii. Iayai?noue ?icieoeo aeeo?aeoe?eieo iaeneioi?a
aeyaeaii o?eueee a eiiieaen? [Cr(LH)3] 3H2O. ?aioaai?anuee?
aeeo?aeoia?aie ?aooe eiiieaen?a iathoue eiioeioaeueiee oa?aeoa? ?
a?aeiia?aeathoue aii?oiiio oaciaiio noaio.

Aeyaeai? aoaeoe eii?aeeiaoe?? o niaeo?ao E? ? ?*-i?iioneaiiy iiaeo
eiiieaen?a oeenoa?io c eaaei??i ? o?iiii, ye? i?iyaeythoueny o ci?iao
oa?aeoa?o niaeo?a a iaeano? /anoio aioo??oi?o eieeaaiue
eii?aeeiaoe?eiiai aocea.

I?iaaaeaii c?noaaeaiiy aei??yieo eieeaaeueieo niaeo??a c ?acoeueoaoaie
?ic?aooie?a /anoio aioo??oi?o eieeaaiue eii?aeeiaoe?eiiai aocea a ?aieao
??cieo iiaeaeae eiai aoaeiae. C?iaeaii a?aeianaiiy eieeaaiue oa
anoaiiaeaia i?eaeaoi?noue aeayeeo ?icaeyiooeo iiaeaeae aoaeiae aei ?yaeo
eiiieaen?a.

Io?eiaii, ui aeey eiiieaen?a [Cd(LH)2] ? [Cd(L/H)2] ?aae?co?oueny
ii-aeaeue eii?aeeiaoe?eiiai aocea o aeaeyae? o?ain-oi?ie ieineiai
eaaae?aoo.

Anoaiiaeaii, ui c on?o eiiieaen?a oeenoa?io c o?iiii caieioo? oeeeee c
eii?aeeiaoe??th /a?ac aoiie eenith ? acioo ?aae?cothoueny o?eueee a
eiiieaen? [Cr(LH)3] 3H2O.

Aeey ai?iieeneio D-oe?iceio, D-o?eioioaio, L-aae?io oa eiiieaena
oeenoa?io c eaaei??i [Cd(L/H)2] aeyaeaii yaeua aoi?eiiiai
aei?ii?ithaaiiy a niaeo?ao E? oa aea/ai? caeiiii??iino? eiai i?iyaeaiiy
a caeaaeiino? a?ae ?ioaineaiino? ? /anoioe caoaeaeoth/iai
aei?ii?ithaaiiy.

Cai?iiiiiaaia iiaeaeue yaeua aoi?eiiiai aei?ii?ithaaiiy a niaeo?ao E?,
yea iniiaaia ia o?aooaaii? i?ioean?a ?iciaaeo iaaeath/iai oioiia ia aeaa
oioiia ? oiiii.

INIIAI? ?ACOEUeOAOE AeENA?OAOe?? IIOAE?EIAAI? A ?IAIOAO

Iienaaiei A.I., Oaaoe O.A., Aao Naeue A. Eiiaeiaoeeiiiia ?annayiea naaoa
ia ?aoaoi/iuo iiaeao oaa?aeioaeueiuo aeieiae/anee-aeoeaiuo aauanoa //
A?niee AeAeO. O?ceea. ?aae?iaeaeo?ii?ea. – 1998. – O.1, aei. 3. – N.
159-163.

Iienaaiei A.I., Aao Naeue A., Caaaeaea A.Ae., Aeie/aiei E.A., Ii?icia
A.I., Eaoeia A.O. Eieaaaoaeueiua niaeo?u eiiieaenia oeenoaeia n Cd e Cr
a iaeanoe /anoio eii?aeeiaoeeiiiiai ocea // A?niee AeAeO. O?ceea.
?aae?iaeaeo?ii?ea. – 1999. – O.1, aei.4. – N. 75-79.

Ai?aeee A.N., Iienaaiei A.I., Oaaoe O.A., Aao Naeue A. I aiciiaeiinoe
eiiaeiaoeeiiiiai ?annayiey naaoa n ?aniaaeii iaaeathuaai oioiia ia aeaa
oioiia e oiiii // Iioeea e niaeo?ineiiey. – 1999. – O.86, ? 1. – N.
77-79.

Ii?na?iei A.I., Oaaoeue O.A., Ai?ae?e A.N., Aao Naeue A., Eaiaoaiue I.I.
// 13 oeiea-nai?ia? “Niaeo?ineii?y iieaeoe oa e?enoae?a”. – Noie
(Oe?a?ia). – 1997. – N. 198.

Moiseenko V.N., Shvets T.V., Gorelik V.S., Abu Sal B. The Low Frequency
Raman Spectra of Solid Pharmaceutical Preparation with Aromatic Groups
// Proceedings of the Fifteenth International Conference on Raman
Spectroscopy. – Pittsburgh, PA (USA). – 1996. – P. 1140 – 1141.

Moiseenko V.N., Zegzhda G.D., Morozov V.P., Abu Sal B., Katkov V.F.
Effects of Coordination in Raman Spectra of Metallocomplexes of Cysteine
// Proceedings of the Sixteenth International Conference on Raman
Spectroscopy. – Cape Town (South Africa). – 1998.

Moiseenko V.N., Gorelik V.S., Shvets T.V., Abu Sal B. About Possibility
of Raman Scattering with Disintegration of Exited Photon on Two Photons
and Phonon // Proceedings of the Sixteenth International Conference on
Raman Spectroscopy. – Cape Town (South Africa). – 1998.

Moiseenko V.N., Abu Sal B., Zegzhda G.D. Infrared Spectra of Cd and Cr
Complexes of Cysteine in Amorphous Solid State // Abstracts of the 3rd
International Symposium on Advanced Infrared and Raman Spectroscopy. –
Vienna (Austria). – 1998. – P. 220.

Moiseenko V.N., Abu Sal B., Shvets T.V., Setov E. Linear Three-Photon
Raman Scattering // Abstracts of the 3rd International Symposium on
Advanced Infrared and Raman Spectroscopy. – Vienna (Austria). – 1998. –
P. 222.

NIENIE OeEOIAAII? E?OA?AOO?E

Aioa O.E., Aeiaaaoei A.E., Eeoaeiia A.N. Eieaaaoaeueiua niaeo?u
iaeioi?uo aieiieeneio a iecei/anoioiie iaeanoe // Aeiiieeia?u e eeaoea.
— 1991. — O.7, ?6. — N. 48-57.

Aa?aaeeineee E.E., Aeiaaaoei A.E., Eeneoea I.I., Eeoaeiia A.N.
Eieaaaoaeueiua niaeo?u e?enoaeee/aneiai symbol 98 \f «Symbol» \s 14 b
-aeaieia a aeeaeiae e aeaeueiae eio?ae?aniie iaeanoe // Aeiiieeia?u e
eeaoea. — 1991.-O.7, ?6. — N. 57-64.

?aae/aiei A.Ae., ?aaa E.Ae., Ieioioie/aiei A.I., Noaiaiueyi N.A., Oaiia
A.A., Aeaaie TH.I. Eco/aiea iieaeoey?iie no?oeoo?u aeeoeeia iaoiaeii
EE-niaeo?ineiiee a e?eiiao?eoeao // Aeiiieeia?u e eeaoea. — 1992. — O.8,
?1. — N.62-72.

Zlobina L.I., Gorelik V.S. and Sheglov V.A. Lattice Raman Scattering of
Light in bioorganic crystal // J. of Zlobina L.I., Gorelik V.S., and
Sheglov V.A. Lattice Raman Scattering of Light in bioorganic crystal //
J. Russian Laser Research. — 1996. — V.17, ?2. — P. 191-218.

Aiae?aaa I.I., Aa?aaeeineee E.E. ?aciiainiue ioeeee eieaaaoaeueiuo
ia?aoiaeia a e?enoaeeao aieiieeneio ia aicaeaenoaea ieeeeiao?iaiai
eceo/aiey // Aeiiieeia?u e eeaoea.-1992. — O.8, ? 9. — N. 43-46.

Gorelik V.S. and Zlobina L.I. Influence of Perturbation on the Lattice
Spectra of Crystalline Amino Acids // J. of Russian Laser
Research.-1996. — V.17, ?2. — P. 119-132.

Copoea A.?., Aaeu/aaa I.A., Aaaeooeeay A.I., Aaeu/aaoeaaa E.A.
Ei??aeoeey aeioeie/aneeo eciaiaiee eiiiui e eiiieaenii-naycaiiui o?iiii
i?e aeeienaiiaii aeeaaaoa. // Yiaeie?eiieiaey. — 1989. — O.19. — N.
45-49.

Naaeueiaa I.Ae., Ai?eniaa H.H. Aeeyiea eii?aeeiaoeeiiiuo niaaeeiaiee
Na(III) ia iieacaoaeue oaeaaiaeiiai iaiaia i?e yenia?eiaioaeueiii
aeeaaaoa. // Oacenu eiioa?aioeee “Aiaeec, neioac e oa?iaeieiae/aneia
eco/aiea iaeioi?uo oeceieiae/anee-aeoeaiuo aauanoa”.-Oaoeaio
(Ocaaeenoai) -1987. — N. 13-16.

Eiiu iaoaeeia a aeieiae/aneeo nenoaiao. Aiaeaaeaioiua naienoaa
ioeeaioeaeia./ Iiae ?aae. Ceaaey O. — I.: Ie?, 1982. — 168 n.

Aeie/aiei E.A., Caaaeaea A.Ae., Ieithoei I.A., *a?iooaiei A.A. ?aaeoeee
?aciueaiey oeeeeia a o?en-aeae?ioeenoaeiaoa o?iia (III) // AEo?iae
iai?aaie/aneie oeiee. — 1993. — O.38, ?1. – N. 87-91.

AIIOAOe?ss

Aao Naeue A.I. Eieeaaeuei? niaeo?e ai?iieeneio oa ?o eiiieaen?a c
iaoaeaie. ( ?oeiien.

Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa
o?ceei-iaoaiaoe/ieo iaoe ca niaoe?aeuei?noth 01.04.07 – O?ceea oaa?aeiai
o?ea. Aei?i?iiao?ianueeee aea?aeaaiee oi?aa?neoao, Aei?i?iiao?ianuee,
1999.

Aeena?oaoe?th i?enay/aii aeine?aeaeaiith iioe/ieo eieeaaeueieo niaeo??a
?yaeo iaeaaaeeea?oeo ai?iieeneio oa eiiieaen?a oeenoa?io c iaoaeaie.
Aea/aii aieea oaiia?aoo?e oa eaaoth/eo aeii?oie ?ii?a iaoae?a ia niaeo?e
eiia?iaoe?eiiai ?icn?thaaiiy na?oea ia ?ao?oi/ieo eieeaaiiyo
ai?iieeneio. Iaaiai?aii niaeo?e ?*-i?iioneaiiy oa niaeo?e
eiia?iaoe?eiiai ?icn?thaaiiy na?oea eiiieaen?a oeenoa?io c eaaei??i oa
o?iiii a iaeano? /anoio eieeaaiue eii?aeeiaoe?eiiai aocea ia iniia?
?ic?aooie?a /anoio. Aeyaeaii oe?ieo ?ioaineaio neiao?e/io nioao “oiio” o
niaeo?ao E? aeayeeo ai?iieeneio oa eiiieaen?a oeenoa?io c eaaei??i. Oea
yaeua iiyniaii ye o?ueiooioiiiee i?ioean eiia?iaoe?eiiai ?icn?thaaiiy
na?oea c ?iciaaeii caoaeaeoth/eo oioii?a ia aeaa oioiia ? oiiii.

Eeth/ia? neiaa: iaeaaaeeea?o? ai?iieeneioe, eiiieaene ai?iieeneio c
iaoaeaie, eiia?iaoe?eia ?icn?thaaiiy na?oea, ?io?a/a?aiia niaeo?ineii?y,
iioe/i? eieeaaeuei? niaeo?e, aaaaoioioiii? i?ioeane ?icn?thaaiiy.

AIIIOAOeEss

Aao Naeue A.I. Eieaaaoaeueiua niaeo?u aieiieeneio e eo eiiieaenia n
iaoaeeaie. – ?oeiienue.

Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa
oeceei-iaoaiaoe/aneeo iaoe ii niaoeeaeueiinoe 01.04.07 – Oeceea
oaa?aeiai oaea. Aeiai?iiao?ianeee ainoaea?noaaiiue oieaa?neoao,
Aeiai?iiao?iane, 1999.

Aeenna?oaoeey iinayuaia yenia?eiaioaeueiiio eco/aieth iioe/aneeo
eieaaaoaeueiuo niaeo?ia ?yaea aaaeiaeoeo aieiieeneio e eiiieaenia
aieiieeneiou oeenoaeia n iaoaeeaie. Ecia?aiu niaeo?u eiiaeiaoeeiiiiai
?annayiey naaoa (E?) ia ?aoaoi/iuo iiaeao ?yaea aaaeiaeoeo aieiieeneio a
oe?aeueii /enoii e ?aoeaie/aneii oaciaii ninoiyiee, a oaeaea eiiieaenia
oeenoaeia n eaaeieai e o?iiii. Onoaiiaeaiu ioee/ey niaeo?ia E? ia
?aoaoi/iuo iiaeao aeey oe?aeueii /enouo e ?aoeaie/aneeo oaciauo
ninoiyiee. Eco/aiu caeiiiia?iinoe oaiia?aoo?iiai iiaaaeaiey niaeo?ia E?
iaeuo /anoio aieiieeneio, eioi?ua eioa?i?aoe?iaaiu eae yooaeou
i?eaioaoeeiiiiai ieaaeaiey.

Enneaaeiaaii aeeyiea eiiia iaoaeeia ia niaeo? E? iaeuo /anoio oeenoaeia.
Aeaia eioa?i?aoaoeey iaaethaeaaiuo a niaeo?ao eciaiaiee a oa?ieiao
?acoii?yaei/aiey e?enoaeee/aneie no?oeoo?u oeenoaeia. Eco/aiu niaeo?u E?
e EE i?iioneaiey eiiieaenia oeenoaeia n eaaeieai e o?iiii a iaeanoe
/anoio aaeaioiuo e aeaoi?iaoeeiiiuo eieaaaiee eii?aeeiaoeeiiiiai ocea.
Ii?aaeaeaiu inoeeeeyoi?iua ia?aiao?u eieaaaiee. N?aaiaiea ecia?aiiuo
/anoio aioo?aiieo eieaaaiee eii?aeeiaoeeiiiiai ocea eiiieaenia oeenoaeia
n eaaeieai e o?iiii n ?acoeueoaoaie ?an/aoa /anoio eieaaaiee iicaieeei
naeaeaoue eo ioianaiea e aua?aoue iiaeaee no?iaiey ?yaea eiiieaenia.
Iieo/aiiua ?acoeueoaou iicaieytho caeeth/eoue, /oi aeey eiiieaenia
[Cd(LH)2] e [Cd(L/H)2] iaeaieaa aa?iyoii ?aaeecoaony iiaeaeue
eii?aeeiaoeeiiiiai ocea a aeaea o?ain-oi?iu ieineiai eaaae?aoa. Iaeiaei,
a iaieo neo/ayo a oaa?aeii oaciaii ninoiyiee iiaoo eiaoue ianoi
?acee/iua eneaaeaiey no?oeoo?u eii?aeeiaoeeiiiiai ocea, /oi i?iyaeyaony
a iaaieueoii ioee/ee yenia?eiaioaeueiuo e ?an/aoiuo /anoio eieaaaiee.
Aeey eiiieaena [CdL] nei?aa anaai ?aaeecoaony iiiiaeaioaoiay
eii?aeeiaoeey /a?ac aoii eenei?iaea. Aeey aieueoeinoaa eco/aiiuo
eiiieaenia oeenoaeia n o?iiii i?iyaeythony /anoiou aeaoi?iaoeeiiiuo
eieaaaiee symbol 100 \f «Symbol» \s 14 d (O-Cr-O), /oi iiaeao
naeaeaoaeuenoaiaaoue a iieueco eii?aeeiaoeee /a?ac aoii eenei?iaea.
?an/aoiua /anoiou eieaaaiee symbol 100 \f «Symbol» \s 14 d s(N-Cr-N) e
symbol 110 \f «Symbol» \s 14 n s(Cr-N) i?iyaeythony yenia?eiaioaeueii
oieueei aeey eiiieaena [Cr(LH)3] 3H2O, /oi iicaieyao aiai?eoue i
i?aaiia?iinoe iiaeaee aai no?iaiey, aeeth/athuae nayce eeaaiaeia n
aoiiii o?iia /a?ac aoiiu eenei?iaea e acioa. Onoaiiaeaii, /oi caieiooua
oeeeeu n eii?aeeiaoeeae /a?ac aoiiu eenei?iaea e acioa nouanoaotho
oieueei a eiiieaena [Cr(LH)3] 3H2O. A inoaeueiuo neo/ayo eiatho ianoi
?aciieiooua oeeeeu n eii?aeeiaoeeae oieueei /a?ac aoiiu eenei?iaea. A
noieniaie iaeanoe niaeo?ia E? ?yaea aieiieeneio, a oaeaea a
iaoaeeieiiieaena aeeaaicieeoeenoaeiaoa eaaeiey iaaethaeaeinue yaeaiea
aoi?e/iiai eceo/aiey a aeaea oe?ieie neiiao?e/iie iieinu “oiia”.
I?aaeeiaeaia iiaeaeue yoiai yaeaiey, iniiaaiiay ia o/aoa i?ioeannia
?aniaaea aicaoaeaeathueo oioiiia ia aeaa oioiia e oiiii. A ?aieao
i?aaeeiaeaiiie iiaeaee iaaethaeaaiia yaeaiea aoi?e/iiai eceo/aiey iiaeii
o?aeoiaaoue eae eeiaeiia o?aooioiiiia eiiaeiaoeeiiiia ?annayiea naaoa.

Eeth/aaua neiaa: aaaeiaeoea aieiieeneiou, eiiieaenu aieiieeneio n
iaoaeeaie, eiiaeiaoeeiiiia ?annayiea naaoa, eio?ae?aniay niaeo?ineiiey,
iioe/aneea eieaaaoaeueiua niaeo?u, iiiaioioiiiua i?ioeannu ?annayiey.

ANNOTATION

Abu Sal B.M. Vibration Spectra of Amino Acids and their complexes with
metals. – Manuscript.

Thesis to obtain a scientific degree of Candidate of Physical –
Mathematical Sciences on a speciality 01.04.07 – Solid State Physics.
Dnieropetrovsk State University, Dniepropetrovsk, 1999.

The dissertation is devoted to investigation of optical vibration
spectra of amino acids and cysteine complexes with metals. The influence
of temperature and metal ion dopants on the Raman spectra in the band of
amino acid lattice vibrations are studied. The IR transmission and Raman
spectra of cysteine complexes with Cd and Cr in the band of coordination
unit vibrations are discussed on the basis of phonon calculations. The
phenomenon of a wide intensive symmetric band of the “background” in
Raman spectra of some amino acids and [Cd(L/H)2] complex was observed.
This phenomenon was explained as a three photon Raman process with
disintegration of exciting photon on two photons and phonon.

Key words: major amino acids, complexes of amino acids with metals,
Raman scattering, infrared spectroscopy, optical vibration spectra,
multiphoton process of scattering.

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