2

AeA?AEAAIEE OI?AA?NEOAO “EUeA?ANUeEA IIE?OAOI?EA”

CAAEAAeUeEI IEAIA AIAOIE??AIA

OAeE 541.64

E?iaoe/ia iiaeaeue o?eaei??ii? ?aaeeeaeueii?

iie?ia?ecaoe?? a aeioe?

02.00.06 — o?i?y aenieiiieaeoey?ieo niieoe

AAOI?AOA?AO

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?i?/ieo iaoe

EUeA?A-1998

Aeena?oaoe??th ? ?oeiien.

?iaioa aeeiiaia o A?aeae?eaii? o?ceei-o?i?? ? oaoiieia?? ai?th/eo
eiiaeei ?inoeoooo o?ce/ii? o?i?? ?i. E.A. Iena?aeaanueeiai IAI Oe?a?ie.

Iaoeiaee ea??aiee aeieoi? o?i?/ieo iaoe, i?ioani?
Oo?ianueeee Aiaoie?e Aioiiiae/, A?aeae?eaiiy o?ceei-o?i?? ? oaoiieia??
ai?th/eo eiiaeei ?inoeoooo o?ce/ii? o?i?? ?i. E.A. Iena?aeaanueeiai,
caa?aeoaa/ a?aeae?eo

Io?oe?ei? iiiiaioe aeieoi? o?i?/ieo iaoe, i?ioani?

A?ee Ieoaeei Oaiaei?iae/, Iaoe?iiaeueiee oi?aa?neoao Ee?ai- Iiaeeyinueea
aeaaeai?y,

i?i?aeoi? c iaoeiai? ?iaioe

aeieoi? o?i?/ieo iaoe,
i?ioani?

Oeaaiia Aieiaeeie? A?eoi?iae/

Oe?a?inueea aeaaeai?y ae?oea?noaa,

caa?aeoaa/ eaoaae?e o?i??

I?ia?aeia onoaiiaa ?inoeooo o?ceei-i?aai?/ii? o?i?? ?
aoaeao?i??

?i. E.I. Eeoaeiaiea IAI
Oe?a?ie, a?aeae?e

?aaeeeaeueieo i?ioean?a, i.Aeiiaoeuee

Caoeno a?aeaoaeaoueny 25 n?/iy 1999 ?ieo i 17 aiaeei? ia can?aeaii?
niaoe?ae?ciaaii? a/aii? ?aaee Ae35.052 .01 i?e Aea?aeaaiiio oi?aa?neoao?
Euea?anueea iie?oaoi?ea ( 290646, i.Euea?a-13, aoe.N.Aaiaea?e,12,
iaa/aeueiee ei?ion 8, aoaeeoi??y 240.)

C aeena?oaoe??th iiaeia iciaeiieoeny a a?ae?ioaoe? Aea?aeaaiiai
oi?aa?neoaoo Euea?anueea iie?oaoi?ea (i. Euea?a, aoe. I?ioani?nueea,1) .

Aaoi?aoa?ao ?ic?neaiee 24 a?oaeiy 1998 ?ieo

A/aiee nae?aoa? niaoe?ae?ciaaii?

a/aii? ?aaee Ae35.052 .01,

eaiaeeaeao o?i?/ieo iaoe
Nei?ioiaea A.E.

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeuei?noue ?iaioe. N?o/ano? iie?ia?e ia iniia? iie?ooieoe?iiaeueieo
(iao)ae?eeao?a iathoue oe?ii? aenieoaoaoe?ei? aeanoeaino? ? oe?iei
aeei?enoiaothoueny a ??cieo oaoiieia?yo, a oiio /ene? iie?a?ao?/i?e ?
?ioi?iaoe?ei?e. Coai?aiiy iioeiaeueieo oaoiieia?/ieo ?aaeei?a iio?aao?
aeaoaeueiiai aeine?aeaeaiiy iniaeeainoae o?eaei??ii? iie?ia?ecaoe??.
Aeey iiyniaiiy ? iienaiiy e?iaoeee o?eaei??ii? iie?ia?ecaoe??
i?iiiiothoueny aea? iniiai? eiioeaioe??. Ia?oa — eiioeaioe?y
aeeooc?eii-eiio?ieueiaaieo ?aaeoe?e (AeE?) — aaco?oueny ia i?eiouaii?
i?i aeeooc?eii-eiio?ieueiaaiee oa?aeoa? aeaiaioa?ieo ?aaeoe?e
iie?ia?ecaoe?eiiai i?ioeano, ye? iienothoueny eeane/iei e?iaoe/iei
??aiyiiyi. Aea ia?aiao?e oeueiai ??aiyiiy ? ooieoe??th aeiaaeeie ?
?ooeeaino? ?aaeeeae?a ? a?aeiia?aeii iioi/iiai noaio iiiiia?-iie?ia?iiai
?ic/eio. Oiio /eneaii? aa??aioe eiioeaioe?? AeE?, oi/a caeaoi?
e?euee?nii iienoaaoe o?eaei??io iie?ia?ecaoe?th aei aeeaieeo eiiaa?n?e,
iiaycai? c iaiao?aei?noth iiae?eyoe ?aeeiee i?ioean ia aeia?eueii
aeae?eai? ae?eyiee ? i?aeae?aoe aeey ieo ??ci? iaoai?cie aeeooc?eiiai
eiio?ieth ? a?aeiia?aei? ?i aiae?oe/i? caeaaeiino?, caeaa?eueoiai
iai?aaii??e/i?. Ae?oaa eiioeaioe?y — i?e?iaaoa?iaaiia iiaeaeue —
i?eionea?, ui iniiaiee aeeaae a e?iaoeeo i?ioeano aiineoue ia aiiioacia
iie?ia?ecaoe?y a iie?ia?-iiiiia?iiio ?ic/ei?, a aaoa?ioacia, yea
a?aeaoaa?oueny a ?aaeei? aaeue-aoaeoo ia iaae? oaa?aeee iie?ia? —
??aeeee iiiiia?. I?e?iaaoa?iaaiia iiaeaeue noai?th? a?eueo ynio ea?oeio
o?eaei??ii? iie?ia?ecaoe??, i?ae iiaeae? AeE?, aea ?? e?euee?nia noi?iia
i?aeoe/ii ia ?ic?iaeaia. Oiio aeooaeueiith ? e?euee?nia ?ic?iaea
i?e?iaaoa?iaaiii? iiaeae?.

Ca nai?th oaiaoeeith ?iaioa aoiaeeoue o a?aeii/o oaio IAI Oe?a?ie
“?ic?iaea iaoeiaeo iniia oi?ioaaiiy iie?ia?ieo iaia?ai ia aac?
o?ceei-o?i?/ieo aeine?aeaeaiue o?eaei??ii? ?aaeeeaeueii? iie?ia?ecaoe??
ie?aiia??a o oiieiio oa??”, yea aeeiio?oueny o A?aeae?eaii? o?ceei-o?i??
? oaoiieia?? ai?th/eo eiiaeei ?inoeoooo o?ce/ii? o?i?? ?i.E.A.
Iena?aeaanueeiai.

Iaoa ?iaioe. Noai?eoe e?iaoe/io iiaeaeue o?eaei??ii? ?aaeeeaeueii?
iie?ia?ecaoe?? iie?ooieoe?iiaeueieo iiiiia??a, yea iieno? i?ioean aei
aeeaieeo noaae?e ia?aoai?aiiy. Ioe?ieoe e?iaoe/i? ia?aiao?e aiiioaciiai
? aaoa?ioaciiai i?ioean?a.

Iaoeiaa iiaecia ?iaioe. Cai?iiiiiaaia e?iaoe/ia iiaeaeue o?eaei??ii?
iie?ia?ecaoe?? iie?ooieoe?iiaeueieo iiiiia??a, yea ia’?aeio? e?iaoe/i?
noaie aiiioaciiai ? aaoa?ioaciiai i?ioean?a. Ia aac? aenia?eiaioaeueieo
aeaieo aeaaaeaii caaaeueia e?iaoe/ia ??aiyiiy noaoe?iia?iiai ?
ianoaoe?iia?iiai i?ioean?a o?eaei??ii? iie?ia?ecaoe??. Ioe?iai?
eiinoaioe oaeaeeinoae aiiioaciiai ? aaoa?ioaciiai i?ioean?a, a oaeiae
eiinoaioe ia?eao ia?aeiieo ? aoi?eiieo eaioetha?a o i?aeoaciiio oa??.

I?aeoe/ia oe?ii?noue ?iaioe. Cai?iiiiiaaia a ?iaio? e?iaoe/ia iiaeaeue
nooo?ai ?icoe?th? oa aeiiiaith? ooiaeaiaioaeuei? oyaeaiiy i?i e?iaoeeo
neeaaeieo i?ioean?a o?eaei??ii? iie?ia?ecaoe?? ? aeicaiey? ia
e?euee?niiio ??ai? aecia/eoe e?iaoe/i? oa?aeoa?enoeee aiii- ?
aaoa?ioacieo i?ioean?a. Ciaiiy e?iaoeee o?eaei??ii? iie?ia?ecaoe??
aeicaiey? ea?oaaoe i?ioeanii o aaaeaiiio iai?yieo c iaoith iaea?aeaiiy
iie?ia?ieo iaoa??ae?a c iaia?aae aecia/aieie o?ceei-o?i?/ieie
aeanoeainoyie oeyoii ?aaoethaaiiy neeaaeiee?a iiiiia?ii? eiiiiceoe??.

Ai?iaaoe?y ?iaioe. Iniiai? ?acoeueoaoe ?iaioe aeiiia?aeaeeny ia
iaoeiai-i?aeoe/ieo eiioa?aioe?yo “Euea?anuee? o?i?/i? /eoaiiy” (Euea?a,
1995 ?., 1997 ?.), Oe?a?inuee?e eiioa?aioe?? c aenieiiieaeoey?ieo niieoe
(Ee?a, 1996 ?.), 17-?e Oe?a?inuee?e eiioa?aioe?? c i?aai?/ii? o?i??
(Oa?e?a, 1995 ?.).

Ioae?eaoe??. Iaoa??aee aeena?oaoe?? i?aaenoaaeai? a 9 ae?oeiaaieo
i?aoeyo, o oiio /ene? a 3 noaooyo.

Ianya oa no?oeoo?a ?iaioe. Aeena?oaoe?y aeeeaaeaia ia 106 noi??ieao
ae?oeiaaiiai oaenoo. Neeaaea?oueny ?c anooio, 4-io ?icae?e?a, aeniiae?a,
nieneo aeei?enoaii? e?oa?aoo?e c 112 iaeiaioaaiue, i?noeoue 4 oaaeeoe? ?
40 ?enoie?a.

Iniaenoee aianie aaoi?a. Iinoaiiaea caaaeaiiy aeine?aeaeaiue ? aea?ae
e?iaoe/ieo iiaeaeae o?eaei??ii? iie?ia?ecaoe?? aeeiioaaeeny ca
aaciina?aaeiueith o/anoth aaoi?a. Aiae?c e?oa?aoo?ieo aeaea?ae,
aenia?eiaioaeuei? ?iaioe c oioi?i?oe?eiaaii? iie?ia?ecaoe??
a?ooieoe?iiaeueieo iiiiia??a oa ?ioa?i?aoaoe?y aenia?eiaioaeueieo aeaieo
ca?aeii c i?e?iaaoa?iaaiiith iiaeaeeth oa ioe?iea e?iaoe/ieo ia?aiao??a
ae-eiiai? aaoi?ii iniaenoi. Aaoi? aeneiaeth? ue?o iiaeyeo ca aeiiiiiao
i?ae /an ae-eiiaiiy aeena?oaoe?eii? ?iaioe ae.o.i. Iaaeaaaeaanueeeo TH.
A., e.o.i. Neaei?aieo A.A. ? e.o.i.Aa?e?io A?. A.

INIIAIEE CI?NO ?IAIOE

Ia’?eoaie aeine?aeaeaiiy aoee a?ooeoe?iiaeuei? iaoae?eeaoe:

IAeO-2: I [O(CH2CH2O)2C(O) C6H4C(O)]nO(CH2CH2O)2 I;

IAO-9: II (NH2CH2O)3 N(I) C6H4 C(I) (OCH2CH2)3 II ;

IEI-2: I-I (CH2)2ON(I) O(CH2)2O(CH2)2IC(I)O(CH2)2 I I;

Ooo I=NI2=N(NI3)N(I) ,

? ae?eeao AeAAAeA: CH2=CH C(I) O (CH2)2-O (CH2)2 O C(I) CH=CH2 .

sse oioi?i?oe?aoi? aeei?enoaiee 2,2 — aee?cii?iiieneaoeaoioaiii
(Ae?IAO). Neioac, ?aeaioeo?eaoe?y ? i/euaiiy Ae?IAO c?iaeai?
i?aoe?aieeaie eaoaae?e o?i?? Oe?a?inueei? aeaaeai?? ae?oea?noaa, i.
Euea?a.

Oioi?i?oe?eiaaia o?eaei??ia iie?ia?ecaoe?y aeine?aeaeoaaeany iaoiaeii
eaca?ii? ?ioa?oa?iiao???. sse aeaea?aei ?ioaa?aeueiiai OO-ii?ii?iaiiy
aeei?enoaii aaci?ic?yaeio ?oooii-eaa?oeaao eaiio Ae?O-400. I?ae /an
aenia?eiaioo ioe?ithaaee iioi/io (I) ? a?aie/ii aeinyaeio (I0) onaaeeo
oa?o eiiiiceoe??. Ca ?o ni?aa?aeiioaiiyi ia/enethaaee a?aeiinio
?ioaa?aeueio aeeaeio iie?ia?ecaoe??: P = I/I0. Oiaueio oa?o eiiiiceoe??
ciaoiaeeee c ae?aco: l= 2,2410-7H0 /, aea — eiao?oe??io onaaeee.

Aeine?aeaeaiiy noaoe?iia?ii? oioi?i?oe?eiaaii? iie?ia?ecaoe?? IAeO-2,
IEI-2 ? AeAAAeA i?iaaaeaii ca ??cieo oiauei oa?o l oioieiiiiceoe??,
iiooaeiino? A0 OO-aei?ii?ithaaiiy, yea iaaea? ia ?? iiaa?oith, a
oaeiae aeo?aeii? eiioeaio?aoe?? oioi?i?oe?aoi?a n0. An?
aenia?eiaioaeuei? e?iaoe/i? e?ea? iathoue oa?aeoa?io aeey
aaoieaoae?oe/ieo ?aaeoe?e /?oei ae?aaeaio S-iiae?aio caeaaei?noue
eiiaa?n?? ? a?ae /ano t (?en.1).

E?euee?niith iniiaith aeey iieno e?iaoe/ieo e?eaeo iiaea aooe ??aiyiiy:

d?/dt = k1(1-?)vi1/2 + k2?(1-?)vi.
(1)

aea p = A/A0 — a?aeiinia aeeaeia iie?ia?ecaoe??; A ? A0 – a?aeiia?aeii
iioi/ia eiiaa?n?y ? a?aie/ii aeinyaeia; k1 ? k2 — e?iaoe/i? noae?; vi —
oaeaee?noue ?i?oe?thaaiiy.

I?ae /an aeaiaeo (1) aeei?enoiaoaaee i?e?iaaoa?iaaiio iiaeaeue,
iieiaeaiiy yei? ie noi?ioethaaee oaeei /eiii: aenia?eiaioaeueia
oaeaee?noue iie?ia?ecaoe?? ? noiith oaeaeeinoae aiiioaciiai i?ioeano,
yeee i?io?ea? a ia’?i? ??aeeiai iiiiia?a ca eeane/iith e?iaoe/iith
noaiith c eaaae?aoe/iei ia?eaii eaioethaa, oa aaoa?ioaciiai i?ioeano,
yeee i?io?ea? o i?aeoaciiio oa?? a ?aaeei? aaeue — aoaeoo ia iaae?
oaa?aeee iie?ia? — ??aeeee iiiiia?; eeanoa?e oaa?aeiai iie?ia?o a
??aee?e iiiiia?i?e oac? ? eeanoa?e ??aeeiai iiiiia?o o oaa?ae?e
iie?ia?i?e oac? iathoue o?aeoaeueio no?oeoo?o; “eaoae?oe/ia” ?ieue
i?aeoaciiai oa?o, oiaoi aaeue-aoaeo, caiaeeoueny aei ciaioaiiy
oaeaeeino? caaeaae? ?aaeeeae?a, ui ? ?iaeoue i?ioean caaeaae? ?aaeeeae?a
e?i?ooth/ith noaae??th a caaaeueiiio i?ioean? iie?ia?ecaoe??.

Oaeei /eiii, oaeaee?noue i?ioeano, ui niinoa??aa?oueny, iiaeia
i?aaenoaaeoe ae?acii:

w = VwV +mwm
(2)

aea v ? m — ia’?ii? /anoee ??aeei? iiii- ia?ii? oace ? i?aeoaciiai oa?o;

wv ? wm — a?aeiia?aei? ieoii? oaeaeeino? iie?ia?ecaoe??.

?en.1 Aenia?eiaioaeuei? (oi/ee) ? ?ic?aoiaai? c ae?ac?a (14,17)
(nooe?euei? ? oo??oia? e?i??) e?iaoe/i? e?ea? oioi-iie?ia?ecaoe??
IAeO-2: n0,iieue/e= 0.105 (1-3,5), 0.021(4); l,i=310-4(1), 1.510-3 (2),
5.510-3 (3), 1.210-3 (4), 8.610-3(5).

Ia?o? aeiaeaiee a (1) ? (2) yaeythoue niaith oaeaeeino? iie?ia?ecaoe?? a
??aeeii?e iiiiia?i?e oac?, a ae?oa? — a i?aeoaciiio oa??. I?e oeueiio wV
? wm iieno?ii ye oaeaeeino? ?inoo eaioethaa:

wv =kpv[Mv][Rv], wm=kpm[Mm][Rm], (3)

aea [Mv], [Mm] ? [Rv], [Rm] — eiioeaio?aoe?y iiiiia?o ? ?aaeeeae?a
a?aeiia?aeii a ??aeeii?e oac? ? a i?aeoaciiio oa??; kpv ? kpm —
a?aeiia?aei? eiinoaioe oaeaeeino? ?inoo eaioethaa.

Oaeiae a?aoiaoaaee, ui aaea ia ?aii?e noaae?? aei/ii? iie?ia?ecaoe?? (ca
?=0.01) ??aeea iiiiia?ia oaca noa? iane/aiith a?aeiinii iiai? iie?ia?ii?
oace. Oiio eiioeaio?aoe?y iiiiia?o [Mv] a iane/aiiio iiiiia?-iie?ia?iiio
?ic/ei? iino?eia a /an? ? i?aeoe/ii ??aia aeo?aei?e: [Mv] = [M]0, aea
ia’?iia /anoea ??aeei? oace v ? ci?iiith aaee/eiith ? ci?ith?oueny c
aeeaeiith iie?ia?ecaoe?? ye: v = 1 — ?.

I?eionea?ii, ui i?ioean o?eaei??ii? iie?ia?ecaoe?? a ??aeei?e oac?
i?io?ea? ca eeane/iith e?iaoe/iith noaiith:

k

Iv + Rv Rv

(4)

Rv + Rv i?iaeoeo
ia?eao.

Ca?aeii c (4) noaoe?iia?ia eiioeaio?aoe?y ?aaeeeae?a aei??aith?: [Rv] =
(vi/ktv)1/2, a aianie aiiioaciiai i?ioeano iie?ia??caoe?? a noia?iee
ae?aaea?oueny ni?aa?aeiioaiiyi:

vwv = (kpv/ktv1/2)[M]0(1-?)vi1/2
(5)

I?ae /an ioe?iee ia’?iii? /anoee m i?aeoaciiai oa?o c a?aooaaiiyi
o?aeoaeueieo oa?aeoa?enoee iie?ia?ieo eeanoa??a o ??aeeii?e iiiiia?i?e
oac? ? ??aeeeo iiiiia?ieo eeanoa??a o oaa?ae?e iie?ia?i?e iao?eoe?
aeei?enoiaoaaee ai?ieneioaaeueio ooieoe?th:

m= h(Fs/Fv)?(1-?),
(6)

aea h -oiaueia i?aeoaciiai oa?o;

Fs/Fv- ona?aaeiaia o?aeoaeueia oa?aeoa?enoeea iiaa?oi? ? ia’?io
eeanoa??a.

I?iaaaeaiee iaie aiae?c aeicaiey? i?eionoeoe, ui iaea?eueo ?iia??iith
i?e/eiith aaeue-aoaeoo a i?aeoaciiio oa?? ? ia?ao?ae eiio?ieth ca
oaeaee?noth ia?eao eaioethaa aei oaeaeeino? eiai ?inoo. Ioaea, aeoe
?icaeoeo eaioethaa ? eiai ia?eao aenooiathoue ye aeaa ??cieo iane?aeee
aca?iiae?? aeoeaiiai ?aaeeeaeo Rm c ooieoe?iiaeueiith a?oiith iiiiia?o,
ye? aaaeooue aei ooai?aiiy aeoeaiiai ?aaeeeaeo Rm (?icaeoie eaioethao)
aai caii?iaeaiiai, oiaoi iaaeoeaiiai, ?aaeeeaeo Rz, ui iiaeia
a?aeia?aceoe noaiith:

kp1

R + Mm
(7)

kt1

Oaeaeeino? ?i?oe?thaaiiy o i?aeoaciiio oa?? vim ? a ??aee?e iiiiia?i?e
oac? iienothoueny ae?acaie vim=2kdfmc, viv = 2kdfvc, aea kd — eiinoaioe
oaeaeeino? ?iciaaeo oioi?i?oe?aoi?a; fm ? fv — eiao?oe??ioe
?i?oe?thaaiiy a?aeiia?aeii a i?aeoaciiio oa?? ? ??aeeee iiiiia?i?e oac?.
Ca?aene, yeui i?eeiyoe vi= viv, aeieeaa? ca’ycie : vim = (fm/fv)vi.
Oaia? oiiao noaoe?iia?iino? ca “aeeaeie” ?aaeeeaeaie iiaeia caienaoe
a?aeiia?aeii aei (7) o aeaeyae? (fm/fv)vi = kt1[Mm][Rm]. I?aenoaaeyth/e
oea ni?aa?aeiioaiiy o (3), iaea?aeeii

wm=(fm/fv)(kp1/kt1)vi (8)

Aeei?enoiaoth/e ai?ieneioaaeueio ooieoe?th (6), ioe?ieii aianie
aaoa?ioac-iiai i?ioeano iie?ia?ecaoe?? a noia?iee ae?acii:

mwm=(fm/ff)(kp1/kt1)h(Fs/Fv)?(1-?)vi (9)

Ia’?aeioth/e (5) ? (9) a ??aiyii? (2), io?eia?ii aeo?aeia e?iaoe/ia
??aiyiiy (1), a yeiio o?ce/iee ci?no e?iaoe/ieo noaeeo k1 ? k2
aecia/a?oueny ae?acaie

k1 = kpv/ktv1/2A0,
(10)

k2 =
h(Fs/Fv)(fm/fv)kp1/kt1A0[M]0 (11)

O aa??aio? oioi?i?oe?eiaaii? iie?ia?ecaoe?? vi, ? ? dp/dt ? ooieoe?yie
ia o?eueee /ano, aea ? eii?aeeiaoe oa?o o a?ae iiaa?oi? (o=0)
oioieiiiiceoe??, yea ii?ii?ith?oueny OO-na?oeii, oiaoi aenooiathoue
aeeoa?aioe?eieie oa?aeoa?enoeeaie i?ioeano ii aeeaei? oa?o o, odo.
Ia?ao?ae a?ae aeeoa?aioe?eieo oa?aeoa?enoee ?(o,t) ? dp(o,t)/dt
aecia/a?oueny ?ioaa?aeueieie ia?aoai?aiiyie:

l
l

W = dP/dt = l-1 (dp/ dt)dx ; P= l-1 pdx.
(12)

0 0

Aeeoa?aioe?eia oaeaee?noue oioi?i?oe?thaaiiy ye ooieoe?y eii?aeeiaoe
oa?o o ? /ano t iieno?oueny ae?acii:

vi=n0J0e-y0[1+e-y0(e-1)]-2
(13)

aea y0 = n0l, = J0t. Ooo J0 — ?ioaineai?noue na?oea, yea iaaea? ia
iiaa?oith oioieiiiiceoe??; c0 — ii/aoeiaa eiioeaio?aoe?y
oioi?i?oe?aoi?a; — iiey?iee eiao?oe??io aenoeieoe?? oioi?i?oe?aoi?a; —
eaaioiaee aeo?ae.

Aeei?enoiaoth/e (1), (12), (13) c o?aooaaiiyi oai?aie i?i na?aaei?
iaea?aeeii:

W=dP/dt= k1(1-P)Int(1) + k2P(1-P)Int(2)
(14)

Int(1)=2l-1(J0/c0)1/2(e/(e-1))1/2arctg[(e-1)1/2(1-e-y0/2)/(1+e-y0/2(e-1)
] (15)

Int(2) = l-1J0[(1- e-y0)/(1 + e-y0(e-1)]
(16)

*anoeia? aa??aioe iiaeae? (14-16) ?icaeyiooi aeey c?noaaeaiiy c
aenia?eiaioaeueieie aeaieie c oioi?i?oe?eiaaii? iie?ia?ecaoe??. Ia?oee
aa??aio — iiaeaeue ii/aoeiai? noaae?? i?ioeano — aaco?oueny ia
i?eiouaiiyo n = n0 ? vi = const, ye? ni?aaaaeeea? aeey
aeiaaieaioethaiaeo i?ioean?a ca oiiae 1. Ca?aeii c oeeie i?eiouaiiyie c
(14-16) iaea?aeeii:

dP/dt =l-1[2k-1(J0/n0)1/2(1-e-y0/2)(1-P)+k2J0(1-e-y0)P(1-P)]
(17)

C aiae?co (17) ia aeno?aioi ciaoiaeeii, ui i?aeeiaoa oi/ee ia?aaeio
e?iaoe/ii? e?eai? ?1 aecia/a?oueny ni?aa?aeiioaiiyi:

P1 = (A — 1)/2A (18)

aea

A = (k2/2k1)(n0 J0)1/2(1-e-y0)(1-e- y0/2)
(19)

Ca?aeii c aenia?eiaioaeueieie aeaieie aeey IAeO-2 P1 1/2, oiio c
ioe?iee (19) i?eeia?ii, ui A>>1. Oiae? aeey iaeneiaeueii? oaeaeeino?
iie?ia?ecaoe??, yea a?aeiia?aea? oi/oe? ia?aaeio e?iaoe/ii? e?eai?,
aeoiaey/e c (17) iaea?aeeii:

W0 = (k2J0/4l) (1-e-y0) (20)

C (20) aeaeii, ui i?e eiioeaio?aoe?? oioi?i?oe?aoi?a n0 ? iaei? oiaueie
oa?o eiiiiceoe?? y0 = c0J0<< 1 iaeneiaeueia oaeaee?noue oioiiie?ia?ecaoe?? iaoeia ia?oee ii?yaeie ca oioi?i?oe?aoi?ii W0 k2n0J0/4, a i?e aaeee?e oiauei? oa?o y0 = n0l>>1 — ioeueiaee: W0
k2J0/4l. Aenia?eiaioaeuei? aeai? c oioi?i?oe?eiaaii? iie?ia?ecaoe??
IAeO-2 i?aeoaa?aeaeothoue oeth caeaaei?noue (?en.2). Oaeiae
aenia?eiaioaeueii aeiaaaeaii ia?oee ii?yaeie ca ?ioaineai?noth
OO-aei?ii?ithaaiiy, ui iaaea? ia iiaa?oith eiiiiceoe??. I?aeae?ath/e
ia?aiao?e ? k2, ?ic?aooaaee ca (20) oai?aoe/i? caeaaeiino? W0 a?ae l
(?en. 2).

Ioe?ieo eaaioiaiai aeoiaeo ca aenia?eiaioaeueieie aeaieie i?iaaee a
ae?oaiio iaaeeaeaii?, yea a?aeiia?aea? iiaeae? iane?i/aiii oiieiai oa?o,
ui aaco?oueny ia oiia? y0 = c0l <<1. Aeey aaciaaeii oiieiai oa?o aeeoa?aioe?ei? oa ?ioaa?aeuei? oa?aeoa?enoeee ca?aathoueny, oiio oaeaee?noue oioiiie?ia?ecaoe?? iiaeia iienoaaoe aeo?aeiei ??aiyiiyi (1), a yeiio vi = c0J0exp(-J0t), ? aiia, a?aeiia?aeii, ? ooieoe??th a?ae /ano: dP/dt = k1(c0J0)1/2(1-P)e-/2 + k2c0J0P(1-P) e- (21) Aiae?c aenia?eiaioaeueieo aeaieo ia iaeneioi i?eaaaeaii? oaeaeeino? oioiiie?ia?ecaoe?? ca (21) aeicaieea ia/eneeoe . Ca?aene ioe?ieee /eneia? cia/aiiy aeaio iniiaieo ia?aiao??a aeo?aeiiai e?iaoe/iiai ??aiyiiy k1 ? k2 (aeea. oaaeeoeth 1). I?aeeiaoa oi/ee ia?aaeio e?iaoe/ieo e?eaeo iie?ia?ecaoe?? aee(iao)ae?eeao?a IEI-2 ? AeAAAeA, yea a?aeiia?aea? iaeneioio oaeaeeino? ?aaeoe??, iaioa cia/aiiy eiiaa?n?? ?1=0.5. Oiio a aiae?c? oeeo aeaieo ia iiaeia aeei?enoiaoaaoe oiiao A1. Aeey ieo caycie i?ae iaeneiaeueiith oaeaee?noth i?ioeano iie?ia?ecaoe?? W0 oa i?aeeiaoith oi/ee ia?aaeio e?iaoe/ii? e?eai? ?1 anoaiiaeth?oueny ye: W0/(1-P1)2 = (k2J0/l)[1-a -y0] (22) Ia ?en.3 cia?aaeai? caeaaeiino? aenia?eiaioaeueii ciaeaeaieo cia/aiue W0/(1-P1)2 a?ae oiaueie oa?o eiiiiceoe?? (l). ?en.2 Aenia?eiaioaeuei? (oi/ee) ? ?ic?aoiaai? c ae?aco (20) (nooe?euei? e?i??) caeaaeiino? W0 oioiiie?ia?ecaoe?? IAeO-2 a?ae l i?e ??cieo n0, iieue/e: 0.105 (1); 0.064 (2); 0.040 (3); 0.021 (4); A0=40.6Ao/i2 ?en.3 Aenia?eiaioaeuei? (oi/ee) ? ?ic?aoiaai? c ae?aco (22) (nooe?euei? e?i??) caeaaeiino? W0/(1-P1)2 oioiiie?ia?ecaoe?? IEI-2 a?ae l i?e ??cie n0, iieue/e: 0.6 (1); 0.4 (2); 0.20 (3); 0.16(4). A0=40.6 Ao/i2 Iiaeaeueoa aeei?enoaiiy iiaeae? ii/aoeiai? noaae?? i?ioeano (21) ? iiaeae? iane?i/aiii oiieiai oa?o (17) aeicaieeei aeaoe ioe?ieo iniiaieo ia?aiao??a i?e?iaaoa?iaaiii? iiaeae? aeey oioi?i?oe?eiaaio? iie?ia?ecaoe?? IEI-2 ? AeAAAeA. Iaea?aeai? ioe?iee noaeeo e?iaoe/ii? iiaeae? o?eaei??ii? iie?ia?ecaoe?? aeine?aeaeaieo aee(iao)ae?eeao?a caaaeaii a oaae. 1. Cia/aiiy k1, k2, , oa o?eaei??ii? oioiiie?ia?ecaoe?? IAeO - 2, IEI - 2, AeAAAeA aoee caeeaaeai? o iaaeeaeaia e?iaoe/ia ??aiyiiy (21) iiaeae? iane?i/aiii oiieiai oa?o ? caaaeueia e?iaoe/ia ??aiyiiy (14) aeey i?yiiai ?ic?aooieo e?iaoe/ieo e?eaeo P = f(t) /eneiaei ?ioaa?oaaiiyi. sse aeaeii c ?en.1, ?ic?aoiaai? caeaaeiino? P=f(t) caaeia?eueii ocaiaeaeothoueny c aenia?eiaioaeueieie e?iaoe/ieie e?eaeie. Oaaeeoey 1 E?iaoe/i? ia?aiao?e o?eaei??ii? oioi-?i?oe?eiaaii? iie?ia?ecaoe?? aee(iao)ae?eeao?a k1102 i3iieuen)12k210 i3iieue i3iieuei IAeO-20.82.4870.9IEI-24.32.11600.85AeAAAeA6.42.31600.84Oaeiae cacia/eii, ui aaaii? a?aoiaioe ia ei?enoue aeciaiiy a?aeiia?aeiino? cai?iiiiiaaieo e?ia-oe/ieo iiaeaeae aenia?eiaioaeue-iei aeaiei iiaeia ciaeoe c ii??aiyiiy /eneiaiai cia/aiiy k1, ciaeaeaiiai iaie aeey oioiiie?ia-?ecaoe?? IAeO-2, c a?aeiieie a e?oa?aoo??. Aea/aii e?iaoeeo iinoiie?ia-?ecaoe?? IEI-2, IAeO-2, IAO-9 ? AeAAAeA a oe?ieiio ae?aiacii? eiiaa?n?e aei ii/aoeo oaiiiaiai i?ioeano, ca ??cieie oiaueiaie oa?o eiiiiceoe??, ?ioaineaiino? OO-aei?ii?ithaaiiy, ? eiioeaio?aoe?? oioi?i?oe?aoi?a Ae?IAO. Oeiia? e?iaoe/i? e?ea? iinoiie?ia?ecaoe?? iiaeai? ia ?en. 4. Ia ieo niinoa??aa?oueny aea? noaae?? i?ioeano: oaeaeea ? ei?ioeio?eaaea c /anii ?aeaenaoe?? 10 n oa iia?eueia ? aeiaaio?eaaea c /anii ?aeaenaoe?? 100n. C?noaaeaiiy cai?iiiiiaaii? e?iaoe/ii? iiaeae? (1) c aenia?eiaioaeueieie aeaieie aeey iinoiie?ia?ecaoe?? aeaco? ia iaiiaiioo e?iaoe/ii? noaie (4). Ia ?? iniia? iiaeia iiynieoe iayai?noue o?eueee ia?oi?, oaeaeei? ? ei?ioei? ae?eyiee iinoiie?ia?ecaoe?eii? e?eai?. Oiio ie i?eeiyee, ui ca o?eaaeo ? iia?eueio iinoiie?ia?ecaoe?th a?aeiia?aeathoue caii?iaeai? ?aaeeeaee Rz, ? aeiiiaieee e?iaoe/io noaio i?ioeano a i?aeoaciiio oa?? noaae??th iaeeaeaiiy caii?iaeaieo ?aaeeeae?a Rz c ooai?aiiyi aoi?eiiiai eaioethaa, iiaoaeiaaiiai ia ?aaeeeaee Rm, yeee iaeea. Rz + Mm Rm (23) Rm Rz ?en. 4. Aenia?eiaioaeuei? (oi/ee) ? ?ic?aoiaai? (e?i??) ca ??aiyiiyi (36) caeaaeiino? ooieoe?? Y = P0(1-P0)ln[P(1-P0)/P0(1-P)] a?ae /ano iinoiie?ia?ecaoe??. IAeO-2: l,i = 2,5.10-4 (1), 2,7.10-4 (2); P0 = 0,42 (1), 0.46 (2). c0 = 0.064 iieue/e, E0= 40,6Ao/i2; IEI-2: l,i = 1,6.10-4 (1), 6,0.10-4 (2); P0 = 0,48 (1), 0.19 (2). c0 = 0.40 iieue/e, E0= 40,6Ao/i2; Ca?aeii c aeaiith noaiith, ia?aeiiee (7) ? aoi?eiiee (24) aeoe ?icaeoeo eaioethaa ? ?o ia?eao aenooiathoue ye aeaa ??ci? iane?aeee aca?iiae?? aeoeaieo ?aaeeeae?a Rm ? Rm c ooieoe?iiaeueiith a?oiith iiiiia?a, ye? aaaeooue, a?aeiia?aeii, ciiao aei ooai?aiiy aeoeaieo ?aaeeeae?a (?icaeoie eaioethaa) /e ?o caii?iaeoaaiiy (e?i?eiee ia?ea eaioethaa), oiaoi aei ooai?aiiy iaaeoeaieo ?aaeeeae?a Rz ? Rz. Ia iniia? noai (7) ? (24), aeieeaa? ni?aa?aeiioaiiy: kp1[Rz] = kt1[Rm] ? kp2[Rz ] = (kt2)[Rm] (25) Ca?aeii c (7), (24) ? (25) e?iaoeea iaa?iiaaeaeaiiy aeoeaieo ia?aeiieo ? aoi?eiieo ?aaeeeae?a o i?aeoaciiio oa?? iieno?oueny ??aiyiiyie: d[Rm]/dt = vim - [Rm], (26) d[Rm?]/dt = (km/kp1)[Rm] - [Rm?]. (27) Ooo =kt1[Mm], = kt2[Mm], (28) Aeey noaoe?iia?ii? e?iaoeee i?ioeano iaea?aeo?ii: [Rm] = vim/, [Rm] = (km/kp1)vim/ (29) wm = kp1[Mm][Rm] + kp2[Mm][Rm] (30) I?aenoaaeyth/e cia/aiiy [Rm] ? [Rm] c (29) o (30) c a?aooaaiiyi (28), iaea?aeeii: wm = (kp1/kt1 + kmkp2/kp1kt2)vim (31) C aiae?co ae?aco (31) aeieeaa?, ui aeeaae i?ioeano a i?aeoaciiio oa??, yeee aei??aith? mwm, a noia?iee, ciiao aoaea i?aaenoaaeaiee ae?oaei aeiaeaieii ??aiyiiy (1), aea ca ?ioiai cia/aiiy e?iaoe/iiai ia?aiao?a k2: k2 = h(Fs/Fv)(fm/fv)(kp1/kt1 + kmkp2/kp1kt2)/[M]0A0 (32) Oaeei /eiii, e?iaoe/ia noaia (7), (23) - (24) caa??aa? iiia?aaei?e aeaeyae noaoe?iia?iiai ??aiyiiy (1) i?e ci?i? o?eueee o?ce/iiai ci?noo ia?aiao?a k2. Aeey ianoaoe?iia?ii? e?iaoeee iaooo?ii aeeaaeii aiiioaciiai i?ioeano a iinoiie?ia?ecaoe?th, oiaoi i?eeia?ii w mw. ?icaycie ??aiyiue (26) ? (27) iiaeia caienaoe o aeaeyae?: [Rm] = (vim0/) (33) [Rm]=[(km/kp1)vim0/( - )][-exp(-t) + (/)exp(-t)] (34) Ooo /an t a?ae?aoiao?oueny a?ae ii/aoeo (t=0) oaiiiaiai ia??iaeo, a vim0 ? oaeaee?noth ?i?oe?thaaiiy o i?aeoaciiio oa?? a e?ioe? noaoe?iia?iiai na?oeiaiai ia??iaeo, yeee a?aeiia?aea? ii/aoeo oaiiiaiai i?ioeano. I?aenoaaeyth/e aeae? (33) ? (34) a (30) ? c o?aooaaiiyi (28) ca oiiae >> , yea aeieeaa? c aenia?eiaioaeueieo aeaieo, iaea?aeeii ae?ac aeey
ieoiii? oaeaeeino? iinoiie?ia?ecaoe??:

d?/dt = p(1-?)vi0[(1-)exp(-t) + exp(-t)],
(35)

aea k2 aecia/a?oueny c (33).

I?e oioi?i?oe?eiaai?e iie?ia?ecaoe?? ??aiyiiy (35) i?aeaea?ii
?ioaa?aeueiiio ia?aoai?aiith (12) c a?aooaaiiyi ae?aco (13) ? ca
oai?aiith i?i na?aaeia iaea?aeeii:

dP/dt = (P(1-P) Wm0[(1-)exp(-t) + exp(-t)])/P0(1-P0).
(36)

I?e c?noaaeaii? c aenia?eiaioaeueieie aeaieie c iinoiie?ia?ecaoe??
a?eueo c?o/ii aeei?enoiaoaaoe ?ioaa?aeueio oi?io (36):

lnP(1-P0)/P0(1-P)=[Wm0[(1-(1-e-t))/+(1-e-t)/]]/P0(1-P0)
(37)

??aiyiiy (36) ?icaeyaeaee ye 4-o ia?aiao?iaa ? /eneia? cia/aiiy Wm0, ,
? aecia/aee iaoiaeii iioei?caoe?? ca aenia?eiaioaeueieie e?eaeie
iinoiie?ia?ecaoe??.

Ia ?en.4 aeaeii, ui aenia?eiaioaeuei? caeaaeiino?
P0(1-P0)ln[P(1-P0)/P0(1-P)] a?ae /ano ? ?ic?aoiaai? ca ??aiyiiyi (36)
aeia?a ocaiaeaeothoueny. Noaoenoe/ia ia?iaea io?eiaiiai
aenia?eiaioaeueiiai iaoa??aeo aeicaieeea aecia/eoe na?aaei? cia/aiiy ?
noaiaea?oi? a?aeoeeaiiy ia?aiao??a , ? , ye? i?aaenoaaeai? a oaae.(2).

Oaaeeoey 2

?ic?aoiaai? na?aaei? cia/aiiy ia?aiao??a ,,

? ?o noaiaea?oi? a?aeoeeaiiy

().102

().102,

n-1

().103,

n-1*enei e?iaoe/- ieo e?eaeoIAeO-2

IAO-9

IEI-2

AeAAAeA11.0 1.0

12.1 2.0

10.7 1.0

3.1 0.5 11.5 0.8

10.6 2.5

10.5 1.7

34.1 4.6 8.6 0.5

6.9 2.1

5.3 0.7

9.9 2.3 2

7

14

7

C aaee/ei ia?aiao?a aeaeii (oaae.2), ui aeey an?o aeeiaoae?eeao?a
a?aeiiniee aeeaae aoi?eiiiai eaioethaa a noia?io noaoe?iia?io e?iaoeeo a
i?aeoaciiio oa?? iaeee ? i?aeoe/ii iaeei ? oie naiee — 10%; aeey
aeeae?eeaoo oeae iieaciee ua iaioee — 3%. Ca cia/aiiyie ? aia?oa
ioe?iaii eiinoaioe oaeae-einoae e?i?eiiai ia?eao ia?aeiiiai ? aoi?eiiiai
eaioethaa a i?aeoaciiio oa?? (oaae.3).

Oaaeeoey 3

?ic?aoiaai? eiinoaioe oaeaeeinoae ia?eao a i?aeoaciiio oa??

[M]0,

iieuei3kt1.105,

i3 iieue.n kt2.106,

i3

iieue.n IAeO-2

IAO-9

IEI-2

AeAAAeA1700

2060

2890

80206.8

5.2

3.6

4.35.1

3.4

1.8

1.2Ia iniia? aeuaiaaaaeaieo aeaieo ? aiae?co aeaieo c e?oa?aoo?ieo
aeaea?ae, iaaiai?aii iiaeeea?noue aeeooc?eiiai eiio?ieth iaae
oaeae-einoyie ?icaeoeo ? ia?eao eaioethaa a ??aeeee iiiiia?i?e oac? ?
i?aeoaciiio oa??. Cacia/aii, ui eiinoaioe oaeaeeinoae ?inoo eaioethaa a
i?aeoaciiio oa?? ? ??aee?e iiiiia?i?e oac? c oi/i?noth aei ii?yaeeo
iaeiaeia? ? ia eiio?ieththoueny aeeooc??th; e?i?eiee ia?ea eaioetha?a a
i?aeoaciiio oa?? aenooia? ye aeo “naiicaoi?iiaiiy” aeoeaieo ?aaeeeae?a,
ui niinoa??aa?oueny a iiaeae? aeoeaiue, ye? naiiiaia?aoeiathoueny.

AENIIAEE

1. Cai?iiiiiaaii e?iaoe/io iiaeaeue oa?ii?i?oe?eiaaii? o?eaei??ii?
iie?ia?ecaoe??, yea aaco?oueny ia iniiaieo iieiaeaiiyo i?e?iaaoa?iaaiii?
eiioeaioeee: aenia?eiaioaeueia oaeaee?noue iie?ia?ecaoe?? ? noiith
oaeaeeinoae aiiioaciiai i?ioeano, ui i?io?ea? a ia’?i? ??aeeiai iiiiia?o
ca eeane/iith e?iaoe/iith noaiith c eaaae?aoe/iei ia?eaii eaioethaa, ?
aaoa?ioaciiai i?ioeano, yeee i?io?ea? o i?aeoaciiio oa?? ia a?aieoe?
oaa?aeee iie?ia? — ??aeeee iiiiia? a ?aaeei? aaeue-aoaeoo. Ia ?? iniia?
c o?aooaaiiyi a?aae??ioo ina?oeaiiy ii aeeaei? oa?o eiiiiceoe?? io?eiaii
e?iaoe/ia ??aiyiiy o?eaei??ii? iie?ia?ecaoe?? iie?ooieoe?iiaeueieo
ie?aiia??a a aeioe? ? eiai /anoeia? aa??aioe — iiaeae? ii/aoeiai?
noaae?? i?ioeano ? iiaeae? iane?i/aiii oiieiai oa?o.

2. Ia iniia? aenia?eiaioaeueieo aeaieo ioe?iaii ia?aiao?e iiaeae?:
eiao?oe??io aenoeioe?? oioi?i?oe?aoi?a, eaaioiaee aeo?ae eiai ?iciaaeo,
a oaeiae eiinoaioe oaeaeeinoae aiiioaciiai ? aaoa?ioaciiai i?ioean?a
iie?ia?ecaoe??. C?noaaeaiiy ca aeaiei iaai?ii ia?aiao??a ?
aenia?eiaioaeueieo e?iaoe/ieo e?eaeo aeaco? ia o?eueee ia caaeia?eueia
ocaiaeaeaiiy iiaeae? c ?ic?aooieiaeie ? aenia?eiaioaeueieie aeaieie, aea
e ia oeoeooaoe?eio caeaaei?noue oaeaeeino? o?eaei??ii? iie?ia?ecaoe??,
yea i?iyaey?oueny ye iane?aeie i?e?iaaoa?iaaiiino? i?ioeano, aeoeaii?
?ie? a oeueiio i?ioean? i?aeoaciiai oa?o ia a?aieoe? oaa?aeee iie?ia? —
??aeeee iiiiia? ? oeoeooaoe?eiiai iaoai?cio eiai ooai?aiiy.

3. Ia aac? ?icoe?aii? e?iaoe/ii? noaie i?ioeano a i?aeoaciiio oa??, yea
aeeth/a? ?aaeoe?? ?inoo ? ia?eao ia?aeiiiai ? aoi?eiiiai eaioetha?a, a
oaeiae ?aaeoe?th ca?iaeaeaiiy aoi?eiieo ?aaeeeae?a ?c ia?aeiii
ca?iaeaeaieo, iaea?aeaii caaaeueia e?iaoe/ia ??aiyiiy o?eaei??ii?
iie?ia?ecaoe?? a aa??aio? noaoe?iia?iiai ? ianoaoe?iia?iiai
(iinoiie?ia?ecaoe?eiiai) i?ioean?a.

4. Anoaiiaeaii aeia?a ocaiaeaeaiiy e?iaoe/ii? iiaeae? c
aenia?eiaioaeueieie aeaieie c e?iaoeee iinoiie?ia?ecaoe??, ui aeicaieeei
aia?oa ioe?ieoe cia/aiiy eiinoaio oaeaeeinoae e?i?eiiai ia?eao
ia?aeiiiai ? aoi?eiiiai eaioetha?a o i?aeoaciiio oa??. Eiinoaioe
oaeaeeinoae ?inoo eaioetha?a a ??aeeii?e iiiiia?i?e oac? ? i?aeoaciiio
oa?? c oi/i?noth aei iaeiiai ii?yaeeo ? iaeiaeiaeie ? ia
eiio?ieththoueny aeeooc??th; e?i?eiee ia?ea eaioetha?a a i?aeoaciiio
oa?? aenooia? ye aeo naiicaoi?iiaiiy aeoeaieo ?aaeeeae?a, ye?
niinoa??aathoueny a iiaeae? aeoeaiue, ui naiiiaia?aoeiathoueny.

Iniiaiee ci?no aeena?oaoe?? aeeeaaeaii a oaeeo ioae?eaoe?yo:

1. U.G. Medvedevskikh, E.A. Zagladko, A.A. Turovski, G.E. Zaikov.
Kinetics of three-dimensional thermopolymerization // International
Journal of Polymeric Materials. -1997.- V.38.- P.329-337.

2. U.G. Medvedevskikh, E.A. Zagladko, A.A. Turovski, G.E. Zaikov.
Kinetics of three-dimensional photopolymerization // International
Journal of Polymeric Materials.- 1998. -V.41.- P.1-12.

3. E.A. Zagladko, U.G. Medvedevskikh, A.A. Turovski, G. Zaicov. The
kinetic of the three-dimensional photopolymerization some
di(meth)acrylats of the microheterogenous model // International Journal
of Polymeric Materials.- 1998.- V.38.-P.227-236.

4. TH.A. Iaaeaaaeaanueeeo, A?. A. Aa?eei, I.A. Caaeaaeueei.
Oioi?i?oe?eiaaia iie?ia?ecaoe?y i?e aeainoi?iiiueiio ina?oeaii? ieineiai
oa?o ??aeei? eiiiiceoe?? // Oace aeiiia?aeae. Iaoeiai-i?aeoe/ia
eiioa?aioe?y “Euea?anuee? o?i?/i? /eoaiiy”.- Euea?a. — 1995.- N.71.

5. I.A. Caaeaaeueei, A.A. Oo?ianueeee, TH.A. Iaaeaaaeaanueeeo. E?iaoeea
oioi?i?oe?eiaaii? iie?ia?ecaoe?? ie?aiao??ae?eeao?a ia ii/aoeia?e
noaae?? i?ioeano // Oace aeiiia?aeae. 17 Oe?a?inueea eiioa?aioe?y c
i?aai?/ii? o?i??.- Oa?e?a. — 1995.- O.2.- N. 450.

6. TH.A. Iaaeaaaeaanueeeo, I.A. Caaeaaeueei, A.A. Oo?ianueeee. E?iaoe/ia
??aiyiiy o?ea?i??ii? iie?ia?ecaoe?? iie?ooieoe?iiaeueieo ie?aiia??a //
Oace aeiiia?aeae. 8 Oe?a?inueea eiioa?aioe?y c aenieiiieaeoey?ieo
niieoe.-Ee?a.- 1996.-N.18.

7. TH.A. Iaaeaaaeaanueeeo, I.A. Caaeaaeueei, A.A. Oo?ianueeee.
Oioi?i?oe?eiaaia iie?ia?ecaoe?y a?ooieoe?iiaeueieo ie?aiao??ae?eeao?a //
Oace aeiiia?aeae.8 Oe?a?inueea eiioa?aioe?y c aenieiiieaeoey?ieo
niieoe.- Ee?a.- 1996.- N.17.

8. I.A. Caaeaaeueei, TH.A. Iaaeaaaeaanueeeo, A.A. Oo?ianueeee.
Iniaeeaino? o?eaei??ii? oioi?i?oe?eiaaii? iie?ia?ecaoe??
aee(iao)ae?eeao?a // Oace aeiiia?aeae. Iaoeiai-i?aeoe/ia eiioa?aioe?y
“Euea?anuee? o?i?/i? /eoaiiy”.- Euea?a. — 1997. — N.136.

9. TH.A. Iaaeaaaeaanueeeo, I.A. Caaeaaeueei, A.A. Neaei?aiei, A.A.
Oo?ianueeee. Iino-aoaeo a ?aaeoe?yo oioi?i?oe?eiaaii? iie?ia?ecaoe??
aee(iao)ae?eeao?a// Oace aeiiia?aeae. Iaoeiai-i?aeoe/ia eiioa?aioe?y
“Euea?anuee? o?i?/i? /eoaiiy”. –Euea?a. — 1997.- N. 81.

Caaeaaeueei Ieaia Aiaoie??aia. E?iaoe/ia iiaeaeue o?eaei??ii?
?aaeeeaeueii? iie?ia?ecaoe?? a aeioe?. — ?oeiien.

Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa o?i?/ieo iaoe ca
niaoe?aeueiinoth 02.00.06 — o?i?y aenieiiieaeoey?ieo niieoe.-
Aea?aeaaiee oi?aa?neoao “Euea?anueea iie?oaoi?ea”, Euea?a, 1998 ?.

Ia aac? oyaeaiiy i?i i?e?iaaoa?iaaii?noue nenoaie, yea iie?ia?eco?oueny,
cai?iiiiiaaii e?iaoe/io noaio ?aaeeeaeueii? o?eaei??ii? iie?ia?ecaoe?? a
aeioe?, yea aeeth/a? e?iaoe/i? noaie aiiioaciiai ? aaoa?ioaciiai
i?ioean?a. Ia iniia? aiae?co aenia?eiaioaeueieo aeaieo aeaaaeaii
caaaeueia e?iaoe/ia ??aiyiiy noaoe?iia?iiai ? ianoaoe?iia?iiai i?ioean?a
o?eaei??ii? iie?ia?ecaoe??. Ioe?iaii eiinoaioe oaeaeeinoae aiiioaciiai ?
aaoa?ioaciiai i?ioean?a, a oaeiae eiinoaioe oaeaeeinoae ia?eao ia?aeieo
? aoi?eieo eaioetha?a o i?aeoaciiio oa?? aeey oioi?i?oe?eiaaii?
o?eaei??ii? iie?ia?ecaoe?? ?yaeo aee(iao)ae?eeao?a.

Eeth/ia? neiaa: o?eaei??ia iie?ia?ecaoe?y, oioi?i?oe?eiaaia
iie?ia?ecaoe?y, i?e?iaaoa?iaaiia iiaeaeue, e?iaoe/ia iiaeaeue, ae?eeaoe,
iaoae?eeaoe.

Caaeaaeueei Aeaia Aiaoieueaaia. Eeiaoe/aneay iiaeaeue o??oia?iie
?aaeeeaeueiie iieeia?ecaoeee a aeiea. – ?oeiienue

Aeenna?oaoeey ia nieneaiea o/aiie nooiaie eaiaeeaeaoa oeie/aneeo iaoe ii
niaoeeaeueiinoe 02.00.06 — oeiey aunieiiieaeoey?iuo niaaeeiaiee.-
Ainoaea?noaaiiue oieaa?neoao “Eueaianeay iieeoaoieea”, Eueaia, 1998 a.

I?aaeeiaeaia eeiaoe/aneay iiaeaeue ?aaeeeaeueiie o?aoia?iie
iieeia?ecaoeee iieeooieoeeiiaeueiuo aee(iao)ae?eeaoia a aeiea, eioi?ay
aeeth/aao aiaeec e auaiae eeiaoe/aneiai o?aaiaiey i?ioeanna. Ec
i?eaaaeaiiiai aiaeeca neaaeoao, /oi i?aaeeiaeaiiia o?aaiaiea niaeanoaony
n ecaanoiuie yenia?eiaioaeueii onoaiiaeaiiuie eeiaoe/aneeie
caeiiiia?iinoyie o?aoia?iie iieeia?ecaoeee. Auaiae o?aaiaiey aace?oaony
ia eiioeaioeee iee?iaaoa?iaaiiie iiaeaee e neaaeothueo iniiaiuo
iieiaeaieyo: nei?inoue o?aoia?iie iieeia?ecaoeee yaeyaony noiiie
nei?inoae aiiioaciiai i?ioeanna, i?ioaeathuaai a iauaia aeeaeeiai
ieeaiia?a, e aaoa?ioaciiai, i?ioaeathuaai a iaaeoaciii neia ia a?aieoea
oaa?aeue iieeia? — aeeaeeee ieeaiia? a ?aaeeia aaeue-yooaeoa; eieoeeaoi?
?aaiiia?ii ?ani?aaeaeai iaaeaeo oacaie e iaaeoaciui neiai; eeanoa?u
oaa?aeiai iieeia?a a aeeaeeie ieeaiia?iie oaca e eeanoa?u aeeaeeiai
ieeaiia?a a oaa?aeie iieeia?iie iao?eoea eiatho o?aeoaeueioth no?oeoo?o;
«eaoaeeoe/aneay» ?ieue iaaeoaciiai neiy naiaeeony e oiaiueoaieth
eiinoaiou nei?inoe aeaaee ?aaeeeaeia e ia?aoiaeo eiio?iey ca nei?inoueth
ia?uaa oeaie e nei?inoe aa ?inoa.

Ia aaca iee?iaaoa?iaaiiie iiaeaee e n o/aoii a?aaeeaioa inaauaiiinoe ii
neith iieo/aii eeiaoe/aneia o?aaiaiea oioieieoeee?iaaiiiie o?aoia?iie
iieeia?ecaoeee a aeiea. Aai /anoiua aa?eaiou — iiaeaee ia/aeueiie
noaaeee i?ioeanna e aaneiia/ii oiieiai neiy — niiinoaaeaiu n
yenia?eiaioaeueiuie aeaiiuie oioiiieeia?ecaoeee aeooieoeeiiaeueiuo
(iao)ae?eeaoia, iieo/ai-iuie a oe?ieii aeeaiaciia eciaiaiey
eiioeaio?aoeee oioieieoeeaoi?a, oieueiu neiy eiiiiceoeee e eioaineaiinoe
iaaeathuaai ia aa iiaa?oiinoue naaoa. Ai anao neo/ayo i?aaeneacuaaaiua
o?aaiaieai caaeneiinoe niaeanothony n yenia?eiaioaeueii iaaethaeaaiuie.
Iaeaeaiu ia?aiao?u iiaeaee: eiyooeoeeaio yenoeioeee oioieieoeeaoi?a,
eaaioiaue auoiae aai ?aniaaea, eiinoaiou nei?inoae aiiioaciiai e
aaoa?ioaciiai i?ioeannia iieeia?ecaoeee. Niiinoaaeaiea ?an/aoiuo ii
aeaiiiio iaai?o ia?aiao?ia e yenia?eiaioaeueiuo eeiaoe/aneeo e?eauo
oeacuaaao ia oieueei ia oaeiaeaoai?eoaeueiia niioaaonoaea i?aaeeiaeaiiie
iiaeaee yenia?eiaioaeueiui aeaiiui, ii e ia oeoeooaoeeiiioth
caaeneiinoue nei?inoe o?aoia?iie iieeia?ecaoeee, i?iyaeythuothny eae
neaaenoaea iee?iaaoa?iaaiiinoe i?ioeanna, aeoeaiie ?iee a iai
iaaeoaciiai neiy oaa?aeue iieeia? — aeeaeeee ieeaiia? e oeoeooaoeeiiiiai
iaoaiecia aai ia?aciaaiey.

Yeia?eiaioaeueii eco/aia eeiaoeea iinoiieeia?ecaoeee aeooieoeeiiaeueiuo
(iao)ae?eeaoia a oe?ieii aeeaiaciia ia/aeueiuo aeey oaiiiaiai ia?eiaea
eiiaa?nee. Ana eeiaoe/aneea e?eaua iinoiieeia?ecaoeee ninoiyo ec aeaoo
o/anoeia: auno?iai e ei?ioeiai, iaaeeaiiiai e aeeeoaeueiiai,
naeaeaoaeuenoaoy i aeaoo oa?aeoa?enoe/aneeo a?aiaiao i?ioeanna. Aeey
iienaiey yenia?eiai oaeueiiai iaoa?eaea i?eaea/aia eeiaoe/aneay
iiaeaeue, aace?othuayny ia eiioeaioeee iee?iaaoa?iaaiiinoe
iieeia?ecothuaeny nenoaiu e iniaie ?iee iaaeoaciiai neiy ia a?aieoea
oaa?aeue iieeia? – aeeaeeee iiiiia?. Onoaiiaeaii oi?ioaa niioaaonoaea
eeiaoe/aneie iiaeaee yenia?eiaioaeueiui aeaiiui, /oi iicaieeei aia?aua
ioeaieoue eiinoaiou nei?inoae eeiaeiiai ia?uaa ia?ae/iie e aoi?e/iie
oeaiae a iaaeoaciii neia. Ioia/aii, /oi eiinoaiou nei?inoae ?inoa oeaie
a iaaeoaciii neia e aeeaeeie iiiiia?iie oaca c oi/iinoueth aei ii?yaeea
iaeeiaeiau e ia eiio?iee?othoueny aeeooceae; eeiaeiue ia?ua oeaiae a
iaaeoaciii neia aunooiaao eae aeo “naiicaoi?iiaiey” aeoeaiuo ?aaeeeaeia,
iaaethaeaaiue a iiaeaee naiiiaia?anaeathueony aeoaeaeaiee.

Eeth/aaua neiaa: o??oia?iay iieeia?ecaoeey, oioieieoeee?iaaiiay
iieeia?ecaoeey, iee?iaaoa?iaaiiay iiaeaeue, eeiaoe/aneay iiaeaeue,
ae?eeaou, iaoae?eeaou.

Zagladko O.A. The kinetic model of the three-dimensional radical
polymerization in bulk.- Manuscript.

Thesis for a candidates degree by speciality 02.00.06 — polymer
chemistry, Lviv State University “Lviv Politechnic”.- Lviv, 1998.

The kinetic scheme of the three — dimensional radical polymerization in
bulk is created according to the principal conception of
microheterogeneous model. The scheme contains both homo- and heterophase
processes. On the base of the experimental date a total kinetic equation
of the steady state and unsteady state processis of the three —
dimensional polymerization is proposed. The constants of the rates of
homo- and heterophase processes rates and the constants of the primary
and secondary chains growth rates in the interphase layer is evaluated
for the three-dimensional photopolymerization for series of
di(meth)acrylates.

Keywords: three-dimensional polymerization, photopolymerization,
microheterogenous model, kinetic model, acrylates, methacrylates.

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