OA?E?ANUeEEE AeA?AEAAIEE OI?AA?NEOAO

Ia i?aaao ?oeiieno

OAeE 539.234

Aeueyeiiaiei I?ia Eaii?ae?aia

Oi?ioaaiiy oiieeo ie?aie iio??eieo oaeueeiaai?aeieo niieoe, ye?

i?noyoue eoaeiee aeaiaio

01.04.07 — O?ceea oaa?aeiai o?ea

AAOI?AOA?AO

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?ceei-iaoaiaoe/ieo iaoe

Oa?e?a — 1999

Aeena?oaoe?y ? ?oeiienii

?iaioa aeeiiaia o Oa?e?anueeiio aea?aeaaiiio iie?oaoi?/iiio oi?aa?neoao?
I?i?noa?noaa ina?oe Oe?a?ie

Iaoeiaee ea??aiee: aeieoi? o?ceei-iaoaiaoe/ieo iaoe,

i?ioani?,

Aacaeooea Aieiaeeie? A?naio?eiae/,

(caa?aeoaa/ eaoaae?e caaaeueii? oa aenia?eiaioaeueii? o?ceee
Oa?e?anueeiai aea?aeaaiiai iie?oaoi?/iiai oi?aa?neoaoo)

Io?oe?ei? iiiiaioe: aeieoi? o?ceei-iaoaiaoe/ieo iaoe,

i?ioani?,

Aaey?aa Aeea ?aai?aia,

(ea??aiee a?aeae?eo e??iaaiii? iioeee ? niaeo?ineii?? O?ceei-oaoi?/iiai
?inoeoooo iecueeeo oaiia?aoo? ?i. A.?.A??e?ia IAI Oe?a?ie)

aeieoi? o?ceei-iaoaiaoe/ieo iaoe,

i?ioani?,

Aeiaaioae Ieeiea ?aaiiae/

(i?ioani? eaoaae?e oaa?aeio?eueii? aeaeo?ii?ee Oaeai?iaenueeiai
aea?aeaaiiai oi?aa?neoaoo)

I?ia?aeia onoaiiaa: Noinueeee aea?aeaaiee oi?aa?neoao

I?i?noa?noaa ina?oe Oe?a?ie,

eaoaae?a i?eeeaaeii? o?ceee

Caoeno a?aeaoaeaoueny “ 1 ” aeiaoiy 1999?. i 14 aiaeei? ia can?aeaii?
nioe?ae?ciaaii? a/aii? ?aaee Ae.64.051.03 o Oa?e?anueeiio aea?aeaaiiio
oi?aa?neoao? ca aae?anith: 310077, i. Oa?e?a-77, iaeae. Naiaiaee,4,
aoae. ?i.E.Ae. Neiaeueieeiaa

C aeena?oaoe??th iiaeia iciaeiieoenue o a?ae?ioaoe? Oa?e?anueeiai
aea?aeaaiiai oi?aa?neoaoo.

Aaoi?aoa?ao ?ic?neaiee “ 31 ” na?iiy 1999?.

A/aiee nae?aoa? niaoe?ae?ciaaii?

a/aii? ?aaee A.I. Iieaea

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeuei?noue oaie. ?iaioa iia’ycaia c ae??oaiiyi aeooaeueieo iaoeiaeo
caaaeaiue, ui noinothoueny io?eiaiiy, aea/aiiy aeanoeainoae ?
i?aeoe/iiai canoinoaaiiy iiaeo iaoa??ae?a — oiieeo ie?aie iio??eieo
neeiiiae?aieo oaeueeiaai?aeieo niieoe, ye? i?noyoue eoaeiee aeaiaio.

Oa?aeoa?ia aeey oeueiai eeano iai?aai?/ieo iaoa??ae?a i?ici??noue o
oe?ie?e niaeo?aeuei?e iaeano?, no?oeoo?ia iaiaeii??aei?noue,
oa?iiaeeiai?/ia ia??aiiaaaei?noue ? noeeuei?noue aei ia?aoiaeo a
neeiiiae?aiee noai aecia/athoue ?oi? oi?eaeuei? o?ce/i? aeanoeaino?.
Aoaeoeaia aeei?enoaiiy oaeueeiaai?aeieo niieoe o yeino? na?aaeiaeua aeey
caieno ?ioi?iaoe?? aecia/a?oueny iiaeeea?noth ?aae?coaaoe aenieo
?icae?eueio caeaoi?noue, aenieo ?ioi?iaoe?eio i?noe?noue ?
?aaa?neai?noue caieno. Iaeiae, ianoaa?euei?noue oaeeo ia’?eo?a ia
aeicaiey? a iiai?e i??? ?aae?coaaoe iayai? iiaeeeaino?.

Iniaeeaa i?noea na?aae iio??eieo neeiiiae?aieo oaeueeiaai?ae?a
caeiathoue oiie? ie?aee iio??eieo niieoe. ?ioa?an aei oe?o ia’?eo?a
iia’ycai ianaiia?aae c oei, ui oeyoii aa??aoe?? ?oiueiai o?i?/iiai
neeaaeo oa ci?ie ?aaeei?a io?eiaiiy iiaeia noai?eoe ia’?eoe c ??ciith
i??ith ?icii?yaeeoaaiiy ? c ??ciiiai?oiei eiiieaenii o?ce/ieo
aeanoeainoae, ui i?eioeeiiai iaiiaeeeai cae?enieoe ia aac? aeaiaioa?ieo
? a?ia?ieo niieoe. Iayai?noue eoaeiiai aeaiaioo a neeaae?
aaaaoieiiiiiaioieo niieoe a?aee?eaa? iiaeeeaino? aieeaaoe ia ci?io
noaa?eueiino? oeeo ooieoe?iiaeueieo iaoa??ae?a, noai?thth/e ye no?ee?,
oae ? /ooeea? aei ciai?oiueiai aieeao oiie? ie?aee, ui iiaeooue ciaeoe
oe?iea canoinoaaiiy a yeino? naini?ieo aeao/ee?a. Iaeiae, ieoaiiy
oi?ioaaiiy aii?oieo ie?aie, oa?aeoa? iiaeeo?eaoe?? ?oiuei? no?oeoo?e i?e
ci?i? o?i?/iiai neeaaeo ? aa??aoe?? oaoiieia?/ieo ?aaeei?a io?eiaiiy
caeeoathoueny aeeneon?eieie. A?aenooi? i?aoe?, a yeeo ia i?eeeaae?
iaei??? niieoee aoee a ?icaeyioo? aieea oiia eiiaeainaoe?? ia oi?ioaaiiy
o?aaiaio?a no?oeoo?e, a oaeiae ci?ia no?oeoo?e ? aeanoeainoae i?ae
aieeaii ciai?oi?o oiia.

O ca’yceo c oeei i?eioeeiiai aaaeeea? aenia?eiaioaeuei? aeine?aeaeaiiy
iniaeeainoae oi?ioaaiiy eiiaeainao?a iio??eieo oaeueeiaai?aeieo
neeiiiae?aieo niieoe, anoaiiaeaiiy caaaeueieo caeiiii??iinoae i?ae ?oi?i
neeaaeii, no?oeoo?ith ? aeanoeainoyie, a oaeiae ?icoi?iiy i?e?iaee ci?i
?oi?o o?ce/ieo oa?aeoa?enoee i?ae aieeaii ciai?oi?o oiia. E??i oiai,
aeine?aeaeai? iaoa??aee ? c?o/iei iiaeaeueiei ia,?eoii aeey c’ynoaaiiy
o?ceee oiieeo ie?aie, neiiaeainiaaieo c ?a/iaei, ye? ooai?ththoue neei.

Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie. Aeena?oaoe?y
aeeiiaia ia eaoaae?? caaaeueii? oa aenia?eiaioaeueii? o?ceee
Oa?e?anueeiai aea?aeaaiiai iie?oaoi?/iiai oi?aa?neoaoo ? aoiaeeea aei
iaoeiai-aeine?aeii? ?iaioe eaoaae?e c oaeeo oai: “?ic?iaea
ooiaeaiaioaeueieo iniia noai?aiiy ? oi?aae?iiy aeanoeainoyie iiaeo
ooieoe?iiaeueieo iaoa??ae?a ia aac? neeaaeieo oaeueeiaai?aeieo
iai?ai?ia?aeiee?a” (? aea?ae. ?a?no?aoe?? 0194U007420) ? “Aeine?aeaeaiiy
? ?ic?iaea c oaeineiiaeaiiy oaoiieia?? neeaaeieo iai?ai?ia?aeieeiaeo
ie?aeiaeo iaoa??ae?a” (“No?oeoo?a”) (? aea?ae. ?a?no?aoe?? 0194U012965),
“Ooiaeaiaioaeuei? aeine?aeaeaiiy caeiiii??iinoae ci?ie aeanoeainoae ?
no?oeoo?e neeaaeieo oaeueeiaai?aeieo iai?ai?ia?aeiee?a o ?acoeueoao?
ci?ie neeaaeo ? oiia io?eiaiiy” (? aea?ae. ?a?no?aoe?? 0196U026387).

Iaoa ? caaaeaiiy aeine?aeaeaiiy. Iaoith oe??? ?iaioe aoea ?ic?iaea
iaoiaeeee io?eiaiiy oiieeo ie?aie iiaeo iio??eieo neeiiiae?aieo
oaeueeiaai?aeieo niieoe, ye? i?noyoue eoaeiee aeaiaio nenoai A1Ai (Ge)
NV1, (aea A1 — Li, K, Rb; CV1 — S, Se), aea/aiiy o?ce/ieo
caeiiii??iinoae oi?ioaaiiy a oaeeo eiiaeainaoao aii?oii? no?oeoo?e ?
anoaiiaeaiiy caeaaeiinoae aeanoeainoae ie?aie a?ae oiia io?eiaiiy,
no?oeoo?ieo ? oaciaeo ia?aoai?aiue, ui a?aeaoaathoueny a ieo i?ney
ia?aaoaaiiy a aoiinoa?iiio iia?o??, yeee i?noeoue aeii?oee ieneaeo
acioo, noai?aiiy ia iniia? oaeeo c?ace?a /ooeeaeo aeaiaio?a aeieia?/ieo
aeao/ee?a. O ca’yceo c oeei o ?iaio? noaaeeeny oae? caaaeaiiy:

— io?eiaoe aii?oi? ie?aee neeiiiae?aieo niieoe, a?aeiia?aei? aei
o?i?/iiai neeaaeo aeo?aeiiai iaoa??aeo A1Bi3NV15 ? K2GeCV13;

— aeine?aeeoe neeaae ? o?ce/i? caeiiii??iino? oi?ioaaiiy no?oeoo?e
ie?aie, io?eiaieo ca ??cieo oiia eiiaeainaoe??;

— aecia/eoe aieea aoiinoa?iiai iia?o?y c aeii?oeith ieneaeo acioo ia
e?iaoeeo ieeneaiiy, ia caeiiii??iino? ci?i no?oeoo?e oa iioe/ieo
aeanoeainoae aii?oieo ie?aie;

— aeei?enoaoe caeiiii??iino? ci?ie o?ce/ieo oa?aeoa?enoee io?eiaieo
eiiaeainao?a aeey noai?aiiy /ooeeaeo aeaiaio?a.

Iaoeiaa iiaecia io?eiaieo ?acoeueoao?a. Aia?oa io?eiai? aii?oi?
eiiaeainaoe ia iniia? iiaeo neeiiiae?aieo niieoe LiBi3Se5, KBi3Se5,
RbBi3Se5, LiBi3S5, KBi3S5, RbBi3S5, K2GeS3, K2GeSe3, Na2GeS3, Na2GeSe3,
o?i?/iee neeaae yeeo a?aeiia?aea? neeaaeo aeo?aeiiai iaoa??aeo ?
anoaiiaeaiee aieea ia?aiao??a eiiaeainaoe?? ia no?oeoo?o io?eiaieo
ie?aie. Iniaeeaino? no?oeoo?e aii?oieo eiiaeainao?a iio??eieo
oaeueeiaai?aeieo niieoe aaeaeiny iiynieoe aeei?enoiaoth/e o?ce/io
iiaeaeue neeiiiae?aiiai noaio. Aia?oa anoaiiaeaia ci?ia caeiiii??iinoae
ieeneaiiy oaeueeiaai?aeieo ie?aie, yea aeicaieeea anoaiiaeoe ci?io
caeiio ieeneaiiy oaeeo c?ace?a, iia’ycaio c iayai?noth a aoiinoa?iiio
iia?o?? aeii?oee ieneaeo acioo eiioeaio?aoe??th 1ia/i3. Iieacaii, ui
aieea ieneaeo acioo ia e?iaoeeo iiaa?oiaaeo i?ioean?a coiiaeaiee eiai
cia/ii a?eueoei i?ae o eenith eiao?oe??ioii i?eeeiaiiy. Aia?oa
anoaiiaeaiee aieea ieeneaiiy ia iioe/ia i?iioneaiiy aii?oieo ie?aie
iio??eieo oaeueeiaai?aeieo niieoe, ye? i?noyoue eoaeiee aeaiaio,
aeicaieea noai?eoe ia iniia? aeine?aeaeaieo ie?aie iiaee oei aeao/ee?a,
ye? eiio?ieththoue iayai?noue ieneaeo acioo a iaaeieeoiueiio
na?aaeiaeu?.

Iniiai? eiie?aoi? iaoeia? ?acoeueoaoe oa iieiaeaiiy, ye? aeiinyoueny ia
caoeno.

1. Iaoiaeeea ?acenoeaiiai aeia?iaoaaiiy c eaacecaieiaiiai ia’?io, yea
aeicaiey? a?aeoai?eoe a eiiaeainao? o?i?/iee neeaae iaaaaeee
neeiiiae?aieo niieoe nenoaie A1Bi(Ge)CV1, ui aeiaaaeaii
ian-niaeo?iiao?e/ieie aeine?aeaeaiiyie.

2. Eiiieaen iniaeeainoae no?oeoo?e aii?oieo ie?aie iio??eieo
oaeueeiaai?aeieo niieoe, ?oi?e aca?iica’ycie c oaoiieia?/ieie oiiaaie
eiiaeainaoe?? ? ii?yaeeiaei iiia?ii eoaeiiai aeaiaioo a neeaae?
?a/iaeie, ui aeia?iao?oueny, a oaeiae ?ioa?i?aoaoe?y a ?aieao eeanoa?ii?
iiaeae? aoaeiae neeiooai?thth/eo ?a/iaei.

3. Aenia?eiaioaeueii aeyaeai? caeiiii??iino? ieeneaiiy aii?oieo
eiiaeainao?a, ye? caeaaeaoue a?ae oiia iaea?aeaiiy ? iayaiino? aeii?oee
ieneaeo acioo a neeaae? aoiinoa?e.

4. Iniaeeaino? aca?iiae?? aaco aoiinoa?e c iiaa?oiath aii?oieo ie?aie
iio??eieo oaeueeiaai?aeieo niieoe, ui i?noyoue eoaeiee aeaiaio.
?acoeueoaoe aeine?aeaeaiiy oa?iiaeani?aoe??, ye? i?aeoaa?aeaeothoue
iniiaio ?ieue aeii?oee ieneaeo acioo a aoiinoa?? o oi?ioaaii? ieeniiai
oa?o: eiioeaio?oaaiiy ieneaeo acioo ia iiaa?oi? i?ecaiaeeoue aei
?oeioaaiiy ieeniiai oa?o oa ci?ie iaoai?cio ieeneaiiy.

5. Aenia?eiaioaeueia anoaiiaeaiiy aieeao ieeneaiiy ie?aie ia ca?eueoaiiy
iioe/iiai i?iioneaiiy, yea aeicaiey? ?a?no?oaaoe a?aie/ii aeiionoeio
eiioeaio?aoe?th ieneaeo acioo a aoiinoa??, ui noaei iniiaith noai?aiiy
ianeaiiai aeiceiao?a iiaiai oeio, yeee eiio?ieth? iayai?noue ieneaeo
acioo a iaaeieeoiueiio na?aaeiaeu?.

I?aeoe/ia cia/aiiy io?eiaieo ?acoeueoao?a. Aeaioiaeai? oiie? ie?aee
nenoaie A1Bi(Ge)CV1 ia neeyieo i?aeeeaaeeao, eiao?oe??io iioe/iiai
i?iioneaiiy yeeo ci?ith?oueny ca iayaiino? aeii?oie ieneaeo acioo a
iia?o??. Iiaeeea?noue iioe/ii? ?a?no?aoe?? a?aie/ii aeiionoeii?
eiioeaio?aoe?? ieneaeo acioo a aoiinoa?? aeicaiey? aeei?enoaoe ie?aee,
ui aeine?aeaeoaaeeny, a yeino? /ooeeaeo aeaiaio?a i?eeaae?a, ye?
eiio?ieththoue iayai?noue oe?aeeeaiai aaco a iaaeieeoiueiio na?aaeiaeu?.
Io?eiaiee iaoaio ia ianeaiee aeiceiao?, ui i?noeoue /ooeeaee aeaiaio o
aeaeyae? aii?oiiai oa?o aaeooiiiai eiiaeainaoo iio??eii?
oaeueeiaai?aeii? niieoee, aeicaiey? ni?inoeoe oa caeaoaaeoe i?ioean
aaciaiae?co aoiinoa?iiai iia?o?y ia ai?no o iueiio ieneaeo acioo.

Iniaenoee aianie caeiaoaa/a. Aaoi?ii aaciina?aaeiuei aeeiiaia ?ic?iaea
oaoiieia?? aeaioiaeaiiy ? aeaioiaeai? oiie? ie?aee neeaaeieo
oaeueeiaai?aeieo niieoe; i?iaaaeai ?ic?aooiie neeaaeo io?eiaieo c?ace?a;
aeaeo?iiii-i?e?ineii?/i? oa aeaeo?iiia?ao?/i? aeine?aeaeaiiy c?ace?a;
ia?iaea aenia?eiaioaeueieo aeaieo ? ?oi?e aiae?c; i?aeaioiaea iaoa??ae?a
aei ioae?eaoe??.

Ai?iaaoe?y ?acoeueoao?a aeena?oaoe??. ?acoeueoaoe ?iaioe ii?eethaeiai?,
aeiiia?aeaeeny e iaaiai?thaaeeny ia oaeeo eiioa?aioe?yo: 1
iaoeiai-oaoi?/ia eiioa?aioe?y “I?iaeaie, aeinyaiaiiy ? i?aeoe/iee
aeina?ae o aaeoc? i/enoee iia?o?y a?ae ?acoeueoao?a ae?yeueiino?
??ciiiai?oieo ae?iaieoeoa”, Naieo-Iaoa?ao?a, 1992; Iaoeiai-oaoi?/iee
nai?ia? «No/ani? oaoi?/i? caniae ? iaoiaee eiio?ieth i?e ioi?ii?
iaaeieeoiueiai na?aaeiaeua», Iaica, 1992; Oe?a?inueea eiioa?aioe?y
«O?ceea ? oaoiieia?y oiieeo ie?aie iai?ai?ia?aeiee?a», Oaeai?iae, 1992;
1994; 2 Oe?a?inueea eiioa?aioe?y ”Iaoa??aeiciaanoai ? o?ceea
iai?ai?ia?aeieeiaeo oac ci?iiiai neeaaeo», I?aeei, 1993; 1 Oe?a?inueea
eiioa?aioe?y «No?oeoo?a i oice/ii aeanoeainoi iaaii?yaeeiaaieo nenoai»,
Euea?a, 1993; Aaeooiia eiioa?aioe?y, OOO?, Oa?e?a, 1993; I?aeia?iaeia
iaoeiai-oaoi?/ia eiioa?aioe?y “Eiii’thoa?: iaoea, oaoi?ea, oaoiieia?y,
caei?ia’y”, Oa?e?a.-1994-1998; I?aeia?iaeia eiioa?aioe?y “Oiceea i
oaoiieiaiy oiieeo ieiaie”, ?aaii-O?aie?anuee, 1993, 1995; 1997;
I?aeaaeocaaee iaoeiai-oaoi?/iee nai?ia? “Aaeooiia iaoae?caoe?y”, Oa?e?a,
1996; Second International School-conference “Physical Problems in
material science of Semiconductors”, Chernivtsi, Ukraine, 1997; XV1
Iaiaeae??anueeee c’?cae, N.-Iaoa?ao?a, 1998.

Ia iaoa??aee aeena?oaoe?? io?eiaiee iaoaio, iioae?eiaaii 4 noaoo? a
iaoeiaeo aeo?iaeao, 10 oac ? 7 noaoae o iaoa??aeao i?aoeue eiioa?aioe?e.

No?oeoo?a oa ianya aeena?oaoe??. Aeena?oaoe?y neeaaea?oueny c anooio,
i’yoe ?icae?e?a, aeniiae?a ? nieneo aeaea?ae, ui aeei?enoaeeny c 125
iaeiaioaaiue. Aiia i?noeoue 150 noi??iie, aeeth/ath/e 6 oaaeeoeue ? 36
?enoie?a.

INIIAIEE CI?NO ?IAIOE

O anooi? iaa?oioiaaia aeooaeuei?noue oaie, aecia/aia iaoa oa caaaeaiiy
aeine?aeaeaiiy, ui i?aaenoaaey?oueny. Ia?a?aoiaai? iniiai? eiie?aoi?
?acoeueoaoe oa iieiaeaiiy, ye? aeiinyoueny ia caoeno, a?aecia/aia
iaoeiaa iiaecia ? i?aeoe/ia oe?ii?noue io?eiaieo ?acoeueoao?a. Iaaaaeai?
iien no?oeoo?e ?iaioe ? aeai? i?i ?? ai?iaaoe?th.

O ia?oiio ?icae?e? “Iio??ei? oaeueeiaai?aei? niieoee oa ?oi? oa?aeoa?i?
iniaeeaino?” i?aaenoaaeaiee e?oa?aoo?iee iaeyae, ui ioiieth? oai?aoe/i?
e aenia?eiaioaeuei? aeine?aeaeaiiy, ui noinothoueny niaoeeo?ee aii?oieo
eiiaeainao?a neeaaeieo oaeueeiaai?aeieo niieoe. ?icaeyioo? iniaeeaino?
aoaeiae oa iiaeeea? oeyoe ci?ie ?oiuei? no?oeoo?e ? aeanoeainoae.
Oneeaaeiaiiy o?i?/iiai neeaaeo caaacia/o? oe?o? iiaeeeaino? aa??aoe??
aeeaeiueiai ii?yaeeo, a cia/eoue, no?oeoo?e ? eiiieaeno o?ce/ieo
aeanoeainoae o ii??aiyii? c aeaiaioa?ieie oa a?ia?ieie nenoaiaie.
Ia??aiiaaaei?noue no?oeoo?e aaaaoieiiiiiaioieo niieoe ?noioii
oneeaaeith? anoaiiaeaiiy ooiaeaiaioaeueieo caeiiii??iinoae, i?eoaiaiieo
aeaiiio eeano iaoa??ae?a, ? coiiaeth? iaiao?aei?noue eiio?ieth neeaaeo
iaea?aeaieo c?ace?a. Iniaeea?noth iio??eieo oaeueeiaai?aeieo niieoe, ye?
a?ae??ciythoue ?o a?ae aeaiaioa?ieo ? iiaea?eieo aiaeia?a, ? eaae?noue
ia?aoiaeo a neeiiiae?aiee noai. No/ani? oyaeaiiy i?i no?oeoo?o
iai?aai?/iiai neea aacothoueny ia ??cieo iiaeaeyo. Ca?aeii c eeanoa?iith
iiaeaeeth no?oeoo?o neea iiaeia ii??aiyoe c no?oeoo?ith
iie?e?enoae?/iiai oaa?aeiai o?ea. Ia a?aei?ii?noue a?ae iie?e?enoaeo
i?aeeeanoa?iee ei?aeii o nee? ia i?noeoue ia?aiai?oaeaieo aai ia??aaieo
ca,yce?a, a nai eeanoa? ia ia? e?enoae?/ii? neiao??? aiane?aeie
iaaii?yaeeiaaiiai ii?aeiaiiy o?i?/ieo ca,yce?a c a?aei?iieie ia?aiao?aie
(aeiaaeeiaie oa eooaie). Aeai? i?i aieea oa?aeoa?ieo iniaeeainoae
neeiiiae?aieo iaoa??ae?a ia e?iaoeeo iiaa?oiaaeo i?ioean?a o e?oa?aoo??
a?aenooi?. Aeine?aeieee aaeni?aoe?? aac?a iiaa?oiyie e?enoae?/ieo
iai?ai?ia?aeiee?a aeathoue aeniiaie i?i iiaeeea?noue aeei?enoaiiy oaeeo
ia,?eo?a o yeino? naeaeoeaieo aeao/ee?a ia i?e?iaeii?oee. ? a?aeiiino?,
ui iaaii?yaeeiaaia iiaa?oiy ia? a?eueoo aaeni?aoe?eio caeaoi?noue, i?ae
oii?yaeeiaaia. Aea/aiiy aca?iiae?? aoiinoa?ieo aeii?oie c?
neeiiiae?aieie niieoeaie iio??eieo oaeueeiaai?ae?a, iaaii?yaeeiaaia
no?oeoo?a yeeo iiaea ni?eyoe ca?eueoaiith ?o /ooeeaino? aei
aaeni?aoe?eiiai aieeao, oe?eaaa c iaoeiai? ? c i?aeoe/ii? oi/ie ci?o.
Aeine?aeaeaiiy oeeo ooieoe?iiaeueieo iaoa??ae?a a?aee?eaa? iiaeeeaino?
noai?thaaoe ye noaa?euei?, oae ? /ooeea? aei ciai?oiueiai aieeao oa?e,
ye? iiaeooue ciaeoe oe?iea canoinoaaiiy a yeino? /ooeeaeo aeaiaio?a
i?eeaae?a. O ca,yceo c oeei aeey ?ic?iaee iniia noai?aiiy oaeeo
iaoa??ae?a aaeeea cia/aiiy iathoue aenia?eiaioaeuei? aeine?aeaeaiiy
iniaeeainoae oi?ioaaiiy eiiaeainao?a neeaaeieo oaeueeiaai?aeieo niieoe,
a oaeiae ci?ie ?o o?ce/ieo oa?aeoa?enoee i?ae aieeaii ciai?oi?o ae?e. Ia
i?aenoaa? aiae?oe/iiai iaeyaeo e?oa?aoo?e iinoaaeaia caaaeaiiy
aeena?oaoe??.

O ae?oaiio ?icae?e? “Aenia?eiaioaeuei? iaoiaee aeaioiaeaiiy ?
aeine?aeaeaiiy eiiaeainao?a o?eeiiiiiaioieo oaeueeiaai?aeieo ?a/iaei”
?icaeyioo? iaoiaee/i? iniaeeaino? io?eiaiiy oiieeo aii?oieo ie?aie
iio??eieo oaeueeiaai?aeieo niieoe, ye? i?noyoue eoaeiee aeaiaio, ?
aenia?eiaioaeueiiai aeine?aeaeaiiy neeaaeo, oaciaiai noaio, no?oeoo?e ?
o?ce/ieo caeiiii??iinoae ieeneaiiy io?eiaieo c?ace?a. Aeey io?eiaiiy
ie?aie aoee aeei?enoai? iaoiaee aeaeo?iiii-i?iiaiaaiai aeia?iaoaaiiy,
?acenoeaiiai aeia?iaoaaiiy c /iaieea oa ?acenoeaiiai aeia?iaoaaiiy
?a/iaeie c eaacecaieiaiiai ia,?io. Aenia?eiaioe aeeiiai? c aeiiiiiaith
noaiaea?oii? aaeooiii? onoaiiaee c ie?eiith nenoaiith a?aeea/ee, yea
caaacia/o? io?eiaiiy aaeooio 10-3Ia, ? iaaeaenieiaaeooiii? onoaiiaee.
Iiia?aaeiy a?aeea/ea cae?enithaaeany ca aeiiiiiaith e??iaaiiiai ianino,
iio?i aeei?enoaee ianin oeio II?Ae-250, iaaeaenieee aaeooi (10-7Ia)
caaacia/oaaany aaoa?i?iiiei ianinii oeio »I?a?o?ii». C o?aooaaiiyi
i?oaeiino? ia?o aeia?iaoaaii? ?a/iaeie ?iai/ee aaeooi neeaaeaa 10-5Ia.
Eiio?ieue neeaaeo io?eiaieo oiieiie?aeiaeo c?ace?a cae?enithaaee ia
eaca?iiio aia?aiian-aiae?caoi?? AIAE-2. Aieea aoiinoa?iiai iia?o?y c
aeii?oeith ieneaeo acioo i?iaiaeeany a aaeni?aoe?eiiio ina?aaeeo,
oe??ieaiiio ia iaaeaenieiaaeooii?e onoaiiaoe?. Iioa?iaee aiae?c neeaaeo
ie?aie iio??eieo oaeueeiaai?aeieo niieoe cae?enithaaany iaoiaeii
ian-niaeo?iiao??? aoi?eiieo ?ii?a. Eiioeaio?aoe?th oa aia?a?th
ca’ycoaaiiy eenith oa ieneaeo acioo aecia/aee iaoiaeii i?ia?aiiaaii?
oa?iiaeani?aoe??. Iioe/ia i?iioneaiiy aei??thaaee ia niaeo?ioioiiao??.

O o?aoueiio ?icae?e? “Neeaae ? no?oeoo?a o?eeiiiiiaioieo
oaeueeiaai?aeieo ie?aie, ui i?noyoue eoaeiee aeaiaio” anoaiiaeaii, ui
i?e ?acenoeaiiio aeia?iaoaaii? c eaacecaieiaiiai ia,?io neeaae
eiiaeainao?a a?aeiia?aea? neeaaeo aeia?iaoaaii? ?a/iaeie, ui aeiaaaeaii
ian-niaeo?iiao?e/iei aiae?cii. I?iaaaeaia aeaeo?iiii-i?e?ineii?/ia
aeine?aeaeaiiy caeaaeiino? no?oeoo?e oiieeo ie?aie o?eeiiiiiaioieo
oaeueeiaai?aeieo niieoe, ye? i?noyoue eoaeiee aeaiaio, a?ae ?aaeei?a
eiiaeainaoe??. Aiae?c ?acoeueoao?a aeey ??cieo ?aaeei?a aeicaieea
anoaiiaeoe iioeiaeuei? oiiae io?eiaiiy aii?oieo ie?aie neeiiiae?aieo
oaeueeiaai?aeieo ?a/iaei: oaeaee?noue inaaeaeaiiy 0.1-0.5 ii/n ia neeyi?
i?aeeeaaeee i?e O=300E. Aeaeo?iiii-i?e?ineii?/i? aeine?aeaeaiiy
iieacaee, ui ie?aee, ae?iuai? o aaeooi? 10-3 ? 10-5Ia, eiiaeainothoueny
nooe?eueiei oa?ii aeey an?o aeine?aeaeaieo oiauei (ii/eiath/e c 5ii).
No?oeoo?a ie?aie, io?eiaieo o aaeooi? 10-3Ia, yaey? niaith iaeano? c
aenieith ? iecueeith i?ici??noth eiiaeainaoo, ye? iathoue ??ciiiai?oio
oi?io ? ?ici??e. Aii?oi? ie?aee, io?eiai? o aaeooi? 10-5Ia, ?
aiiiaaiieie ? ia aeathoue eiio?anoo ia aeaeo?iii-i?e?ineii?/iiio
cia?aaeaii? i?e ?ic??ciai? 1ii. Oe? iniaeeaino? ia aeeaaeathoueny a
o?aaeeoe?ei? oyaeaiiy i?i oi?ioaaiiy aii?oieo ie?aie.

No?oeoo?i? iniaeeaino?, ui niinoa??aathoueny o ie?aie, io?eiaieo c
iio??eieo oaeueeiaai?aeieo niieoe, ye? i?noyoue eoaeiee aeaiaio,
o?aeoothoueny a oa?i?iao iiaeae? neeiiiae?aiiai noaio, ui ?ic?iaey?oueny
N.A.Aeaiaianueeei,1990?.: iaeano? aeniei? u?eueiino? yaeythoue niaith
eeanoa?e, a iaeano? iecueei? u?eueiino? — i?aeeeanoa?i? ei?aeiie.
I?aeeeanoa?i? ei?aeiie a nee? oi?iothoueny ca ?aooiie i’yeeo
o?eoeaio?iaeo ca’yce?a, a nai eeanoa? ia ia? e?enoae?/ii? neiao???
aiane?aeie iaaii?yaeeiaaiiai ii?aeiaiiy eiaaeaioieo ca’yce?a c
ia?aiao?aie, ui ?ic??ciythoueny (aeiaaeeiaie ? eooaie).

Ii i??? c?inoaiiy ie?aee oi?io?oueny noiai/anoa i??ino?oeoo?a c
aa?oeeaeueii ?icoaoiaaieie ei?aeiiaie, ui a?aeaeaa? nooi?iue ai?cio?ii??
ia’?eoo, ui aea/a?oueny, ? ni?ey? iieaaoaiith cae?eniaiiy aeeooc?eieo
i?ioean?a eaaeeie eaiaeaie a iai?yieo, ia?iaiaeeeoey?iiio ieiuei?
ie?aee.

Anoaiiaeaiee aca?iica’ycie ii?yaeeiaiai iiia?a eoaeiiai aeaiaioo c
?ici??ii eeanoa??a aii?oieo ie?aie iio??eieo oaeueeiaai?aeieo niieoe, ui
i?noyoue eoaeiee aeaiaio. Niinoa??aa?oueny oaiaeaioe?y aei ca?eueoaiiy
na?aaei?o ?ici???a eeanoa??a (iaioa 1 ii aeey eiiaeainao?a LiBi3S5, 7 ii
aeey ie?aie KBi3S5 ? 9 ii aeey ie?aie RbBi3S5) a ?yae? niieoe LiKRb ?c
ca?eueoaiiyi ?aae?ono ?iio eoaeiiai aeaiaioo.

O /aoaa?oiio ?icae?e? “Aea/aiiy oi?ioaaiiy iiaa?oiaaiai ieeniiai oa?o”
?icaeyioo? o?ce/i? i?ioeane, ui a?aeaoaathoueny ia iiaa?oi? aii?oieo
eiiaeainao?a. I?iaaaeaia aea/aiiy caeiiii??iinoae ieeneaiiy oiieeo
ie?aie iio??eieo oaeueeiaai?ae?a A1Ai(Ge)NV1 c aeei?enoaiiyi iaoiaeo
ian-niaeo?iiao??? aoi?eiieo ?ii?a (iaethiie 1). Iioa?iaee aiae?c
iieacaa, ui ia’?eoe, ui aeine?aeaeothoueny, ieeneththoueny a aoiinoa?? c
ooai?aiiyi oiieiai caoeniiai oa?o ieneaeo (caeaaei?noue 1). Caoeniee oa?
ieneaeo a?niooo (aa?iai?th) oiaueiith 10 ii, ui ooai?eany, neoaeeoue
aeeooc?eiei aa?’??ii aeey iiaeaeueoiai ieeneaiiy ie?aie iio??eieo
oaeueeiaai?aeieo

?en.1. E?iaoeea ieeneaiiy ie?aie KBi3S5: iaea?aeaieo o aaeooi? 10-5Ia
(1); iaea?aeaieo o a aaeooi? 10-5Ia (2) ? 10-3Ia (3) oa aeo?eiaieo a
aoiinoa?? c aeii?oeith ieneaea acioo eiioeaio?aoe??th 1ia/i3..

niieoe. Oi?ioaaiiy caoeniiai oa?o ieneaeo a?niooo ia?aoeiaeaea?
ieeneaiith ie?aie, oiio aeey c?ace?a, io?eiaieo a oiiaao aaeooio 10-5Ia,
ia a?aeaoaa?oueny ieeneaiiy ca o?eoeaio?iaeie ca’yceaie, ui i?ecaiaeeoue
aei a?aenooiino? eiio?anoo ia aeaeo?iii-i?e?ineii?/iiio cia?aaeaii?.

Ca iayaiino? a aoiinoa?? ieneaeo acioo caeiiii??iino? ieeneaiiy ie?aie
caeaaeaoue a?ae nooiaiy aaeooio i?e eiiaeainaoe??.

Aeey ia’?eo?a, ui aeine?aeaeothoueny, ia?aaoaaiiy a aoiinoa??, yea
i?noeoue aeii?oee ieneaeo acioo eiioeaio?aoe??th 1ia/i3, i?ecaiaeeoue
aei ci?ie caeiio ieeneaiiy. Aeey ie?aie KBi3S5, io?eiaieo a oiiaao
aaeooio ?=10-5Ia (caeaaei?noue 2), ia? i?noea aeeooc?eiee aa?’??, ui
oneeaaeith? ia?aiin aaco ? ?a/iaeie, iaeiae iiai?noth ia ia?aoeiaeaea?
?aaeoe?? i?aeoacii? aca?iiae??. Ie?aee KBi3S5, io?eiai? a oiiaao aaeooio
?=10-3Ia, ieeneththoueny c iino?eiith oaeaee?noth (caeaaei?noue 3), i?e
oeueiio caoeniee oa? ia ooai?th?oueny, aeinooi eenith aei iiaa?oi? i?/ei
ia oneeaaeiaiee ? ieeneaiiy ?iciianthaeaeo?oueny ii an?e oiauei? c?acea,
oiaoi e?i?ooth/ith noaae??th ? ia aeeooc?y, a ?aaeoe?y ia ei?aeii? oac.
I?ae aieeaii ciai?oi?o oiia ? ?aaeeio io?eiaiiy ie?aie a?aeaoaa?oueny
ci?ia iaoai?cio ieeneaiiy. I?e oeueiio ci?ith?oueny ni?aa?aeiioaiiy
eoo?a iaoeeo oaeaeeinoae ieeneaiiy aeey caeaaeiinoae 1 ? 2, a
caeaaei?noue 3 o?ainoi?io?oueny o i?yio.

E?i?eia caeaaei?noue oiaueie ieeniiai oa?o a?ae /ano ocaiaeaeo?oueny c
?acoeueoaoaie aeaeo?iii-i?e?ineii?/ieo aeine?aeaeaiue, ca?aeii c yeeie
i?ney eiioaeoo c aoiinoa?ith, ui i?noeoue ieneae acioo, ie?aee, io?eiai?
o aaeooi? 10-5Ia, aeyaeythoue eeanoa?io no?oeoo?o.

Caeiiii??iino? ieeneaiiy ie?aie iiyniththoueny iniaeeainoyie aca?iiae??
aoiinoa?e c iiaa?oiath iio??eieo oaeueeiaai?aeieo niieoe.
Oa?iiaeani?aoe?ei? aeine?aeaeaiiy iieacaee, ui i?e aca?iiae??
aoiinoa?iiai iia?o?y, yea i?noeoue aeii?oeo ieneaeo acioo, c ieeneaiieie
ie?aeaie ia iiaa?oi? oi?io?oueny oa? aaeni?aaoo, yeee neeaaea?oueny c
eenith e ieneaeo acioo. Anoaiiaeai? eiao?oe??ioe i?eeeiaiiy oa aia?a??
ca’ycoaaiiy eenith e ieneaeo acioo. *a?ac cia/ii a?eueoee eiao?oe??io
i?eeeiaiiy NO o ii??aiyii? c eiao?oe??ioii i?eeeiaiiy I2, iacia/ia
aeii?oea ieneaeo acioo a aoiinoa?iiio iia?o?? (N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) i?ecaiaeeoue aei ?noioiiai ca?eueoaiiy eiai eiioeaio?aoe?? a
iiaa?oiaaiio oa??. Eiioeaio?oaaiiy ieneaeo acioo ia iiaa?oi? ie?aee
i?ecaiaeeoue aei ?oeioaaiiy iiaa?oiaaiai caoeniiai oa?o ieneaeo, ui
aeyaey?oueny o aeieeiaii? niieoee KNO2 a oa?iiaeani?aoe?eiiio niaeo??.
?oeioaaiiy caoeniiai oa?o ni?ey? ?iciianthaeaeaiith i?ioeano ieeneaiiy,
ui i?ecaiaeeoue aei iiyae niieoe A1NV1I, aea (A — eoaeiee aeaiaio, N —
oaeueeiaai) ii an?e oiauei? eiiaeainaoo. Oaeei /eiii, ?acoeueoaoe
aeine?aeaeaiiy oa?iiaeani?aoe?? i?aeoaa?aeeee iniiaio ?ieue aeii?oee
ieneaeo acioo a aoiinoa?? o oi?ioaaii? ieeniiai oa?o oa ci?i? iaoai?cio
ieeneaiiy.

O i’yoiio ?icae?e? “Ci?ia o?ce/ieo oa?aeoa?enoee o?eeiiiiiaioieo
oaeueeiaai?aeieo ie?aie o i?enooiino? ieneaeo acioo oa ?oi? i?aeoe/ia
canoinoaaiiy” ?icaeyaea?oueny aeaa?aaeaoe?y o?eeiiiiiaioieo
oaeueeiaai?aeieo ie?aie, i?aeaeaieo i?ioyaii aiaeeie aieeao aoiinoa?e,
ui i?noeoue ieneae acioo eiioeaio?aoe??th 1ia/i3. I?iaaaeaia
aeine?aeaeaiiy aieeao ieenethaaeueiiai na?aaeiaeua ia iioe/ia
i?iioneaiiy ie?aie nenoaie A1Ai(Ge)NV1. Iaaaaeai? ?acoeueoaoe
aeaeo?iii-i?e?ineii?/iiai aeine?aeaeaiiy no?oeoo?e ?icaeyiooeo ia’?eo?a,
i?aeaeaieo aieeao aoiinoa?e c aeii?oeith ieneaeo acioo.

Aaaeeeaei aeniiaeii oeueiai aeine?aeaeaiiy ? oa, ui ianoaa?euei?noue
iio??eieo oaeueeiaai?aeieo neeiiiae?aieo niieoe, ui i?noyoue eoaeiee
aeaiaio, i?ecaiaeeoue aei oaciaeo ? no?oeoo?ieo ci?i, ui aieeaa? ia
aeanoeaino? oiieeo ie?aie. Ca?eueoaiiy iioe/iiai i?iioneaiiy, aeeeeeaia
ieeneaiiyi eiiaeainao?a o ?acoeueoao? aaeni?aoe?? aeii?oeiaeo aac?a
aoiinoa?e aea? iiaeeea?noue iioe/ii? ?a?no?aoe?? a?aie/ii aeiionoeii?
eiioeaio?aoe?? ieneaeo acioo a aoiinoa??, ui aeicaiey? aeei?enoaoe
io?eiai? ie?aee aeey noai?aiiy /ooeeaiai aeaiaioo i?eeaae?a, ye?
eiio?ieththoue iayai?noue oe?aeeeaiai aaco a iaaeieeoiueiio na?aaeiaeu?

O aeniiaeao i?aenoiiaai? iniiai? ?acoeueoaoe, io?eiai? a ?iaio?.

1. Anoaiiaeaii, ui o?i?/iee neeaae o?eeiiiiiaioieo oaeueeiaai?aeieo
niieoe LiBi3Se5, KBi3Se5, RbBi3Se5, LiBi3S5, KBi3S5 , RbBi3S5, K2GeS3,
K2GeSe3, Na2GeS3, Na2GeSe3, aeia?iaoaaieo ?acenoeaii c eaacecaieiaiiai
ia’?io c? oaeaee?noth 0.1-0.5 ii/n o aaeooi? 10-3-10-5Ia
a?aeoai?th?oueny a eiiaeainao?, ui aeiaaaeaii ian-niaeo?iiao?e/ieie
aeine?aeaeaiiyie.

2. Iioeiaeueiei ?aaeeiii io?eiaiiy aii?oieo eiiaeainaoia neeiiiae?aieo
?a/iaei ? inaaeaeaiiy c eaacecaieiaiiai ia’?io c? oaeaee?noth 0.1-0.5
ii/n ia neeyi? i?aeeeaaeee i?e O=300E.

3. Aeyaeai? aenia?eiaioaeuei? iniaeeaino? no?oeoo?e, oa?aeoa?i? aeey
neeiiiae?aiiai aii?oiiai noaio. Ie?aee, ae?iuai? o aaeooi? 10-3 ? 10-5Ia
eiiaeainothoueny nooe?eueiei oa?ii ia an?o aeinooiieo aeey
aenia?eiaioaeueiiai niinoa?aaeaiiy oiaueiao (ii/eiath/e c 5ii). Aii?oi?
ie?aee, io?eiai? o aaeooi? 10-3 Ia, ? iaeanoyie c aenieith ? iecueeith
i?ici??noth eiiaeainaoo. Aii?oi? ie?aee, io?eiai? o aaeooi? 10-5Ia, ?
aiiiaaiieie ? ia aeathoue eiio?anoo ia aeaeo?iiii-i?e?ineii?/iiio
cia?aaeaii?, ui ia aeeaaea?oueny a o?aaeeoe?ei? oyaeaiiy. Oe?
iniaeeaino? ? i?aenoaaith aeey iieno no?oeoo?e aii?oieo ie?aie iio??eieo
oaeueeiaai?aeieo niieoe o ?aieao eeanoa?ii? iiaeae? neea.

4. Ii i??? c?inoaiiy ie?aee a i?e oi?io?oueny noiai/anoa i?e?ino?oeoo?a
c aa?oeeaeueii ?icoaoiaaieie ei?aeiiaie, yea a?aeaeaa? nooi?iue
ai?cio?ii?? ia’?eoo, ui aea/a?oueny, ? ni?ey? iieaaoaiith aeeooc?eieo
i?ioean?a ii eaaeei eaiaeai o iai?yieo, ia?iaiaeeeoey?iiio ieiuei?
ie?aee.

5. Anoaiiaeaiee aca?iica’ycie ii?yaeeiaiai iiia?a eoaeiiai aeaiaioo a
?yae? niieo/aiue LiKRb c ?ici??ii eeanoa??a aii?oieo ie?aie iio??eieo
oaeueeiaai?aeieo niieoe, ui i?noyoue eoaeiee aeaiaio.

6. Iaoiaeii ian-niaeo?iiao??? aoi?eiieo ?ii?a anoaiiaeaii, ui ia’?eoe,
ye? aeine?aeaeothoueny, ieeneththoueny a aoiinoa?iiio iia?o?? c
ooai?aiiyi oiieiai caoeniiai oa?o ieneaeo a?niooo (aa?iai?th) aeeaeiith
aei 10ii, yeee neoao? aeeooc?eiei aa?’??ii aeey iiaeaeueoiai ieeneaiiy
ie?aie.

7. Ca iayaiino? a aoiinoa?? ieneaeo acioo caeiiii??iino? ieeneaiiy
caeaaeaoue a?ae nooiaiy aaeooio i?e eiiaeainaoe??. Aeey ie?aie KBi3S5,
io?eiaieo a oiiaao aaeooio ?=10-5Ia iathoue i?noea aea? oaeaeeino?
ieeneaiiy: ia?oa a?aeiia?aea? aeoeaiiio ieeneaiith; ae?oaa oaeaee?noue
na?ae/eoue i?i oa, ui ia? i?noea aeeooc?eiee aa?’??, yeee oneeaaeith?
ia?aiin aaco ? ?a/iaeie, iaeiae iiai?noth ia ia?aoeiaeaea? ?aaeoe??
iaaeoacii? aca?iiae??. Ie?aee KBi3S5, io?eiai? a oiiaao aaeooio
?=10-3Ia, ieeneththony c iino?eiith oaeaee?noth, ? ieeneaiiy
?iciianthaeaeo?oueny ii an?e oiauei? c?acea.

8. Ci?ia iaoai?cio ieeneaiiy iiynith?oueny iniaeeainoyie aca?iiae??
aac?a aoiinoa?e c iiaa?oiath neeaaeieo oaeueeiaai?aeieo niieoe. I?e
aca?iiae?? aoiinoa?iiai iia?o?y c aeii?oeith ieneaeo acioo c ieeneaieie
ie?aeaie ia ?oi?e iiaa?oi? oi?io?oueny oa? aaeni?aaoo, yeee
neeaaea?oueny c eenith e ieneaeo acioo. I?e oeueiio eenaiue
aaeni?ao?oueny c aia?a??th ca’ycoaaiiy Aca=1,5aA ? eiao?oe?aioii
i?eeeiaiiy s=2,2 10-4, ieneae acioo aaeni?ao?oueny c aia?a??th
ca’ycoaaiiy Aca=1,65aA ? eiao?oe??ioii i?eeeiaiiy s=0,3, ui i?ecaiaeeoue
aei eiioeaio?oaaiiy ieneaeo acioo a iiaa?oiaaiio oa??. I?enooi?noue
niieoee KNO2 o oa?iiaeani?aoe?eiiio niaeo?? aeaco? ia ?aaeoe?th ieneaeo
acioo c iiaa?oiaaei oa?ii. ?oeioaaiiy caoeniiai oa?o ni?ey?
?iciianthaeaeaiith i?ioeano ieeneaiiy ii an?e oiauei? eiiaeainaoo.

9. Aieea aoiinoa?e c aeii?oeith ieneaeo acioo i?ecaiaeeoue aei
no?oeoo?ieo ci?i a ie?aeao oaeueeiaai?aeieo niieoe, ui aeyaey?oueny a
ca?eueoaii? na?aaeiuei? oiaueie i?aeeeanoa?ieo i?ioa?e?a aeey ie?aie,
io?eiaieo a aaeooi? 10-3Ia. Ie?aee, io?eiai? o aaeooi? 10-5Ia,
aeyaeythoue eeanoa?io no?oeoo?o, ui iiaiaeaeo?oueny c e?i?eiith
caeaaei?noth oiaueie ieeniiai oa?o a?ae /ano. E?enoae?caoe?y aii?oieo
ie?aie a eieii? aeaeo?iiiai i?e?ineiio aeicaiey? aeyaeoe ieeni? oace
K2S2O7, K2S3O10..

10. O ?acoeueoao? iauaiiiai ieeneaiiy ci?ith?oueny iioe/ia u?euei?noue
c?ace?a, ui i?ecaiaeeoue aei ci?ie eiao?oe??ioo iioe/iiai i?iioneaiiy ia
15% o aeaeei?e iaeano? niaeo?o. Iiiioiiia niaeo?aeueia caeaaei?noue O
() aeicaiey? iaeiicia/ii iia’ycaoe iioe/io u?euei?noue ie?aee c?
nooiaiai ?? ieeneaiiy.

11. Aenia?eiaioaeueii anoaiiaeaia iiaeeea?noue iioe/ii? ?a?no?aoe??
a?aie/ii aeiionoeii? eiioeaio?aoe?? (AAeE=1ia/i3) ieneaeo acioo a
aoiinoa?? aeicaiey? noai?eoe ia iniia? aeine?aeaeaieo ie?aie nenoaie
A1Ai(Ge)NV1 i?eioeeiiai iiaee oei ianeaieo aeiceiao??a, eiio?iethth/eo
iayai?noue oe?aeeeaiai aaco a iaaeieeoiueiio na?aaeiaeu?.

NIENIE IIOAE?EIAAIEO I?AOeUe CAeIAOAA*A CA

OAIITH AeENA?OAOe??

1. Iao.20404A Oe?aeia, IEE G01N21/17,30/00 Ianneaiue aeiceiao? aeey
ecia?aiey niaea?aeaiey ieneaea acioa a aoiinoa?iii aicaeooa /
A.A.Aacaeooea, I.E.Aieaeao, I,E.Aeueyeiiaiei, A.A.Ionnee, E.A.Iao?aiei,
A.A.?ya/oi.; Cayae.25.04.94; Iioae.15.07.97. IEE. -5n. Oa?ueeianeee
iieeoaoie/aneee oieaa?neoao. UA.

2. Aeeyiea aaeooiiuo oneiaee iieo/aiey ieaiie ia eeiaoeeo i?ioeannia
ieeneaiey /Aacaeooea A.A, Aieaeao I.E,. Aeueyeiiaiei I.E,. ?ya/oi A.A.
Aii?inu aoiiiie iaoee e oaoieee. ssaea?ii-oece/aneea
enneaaeiaaiey.-OOOE. — 1994.-Aui.1(27). -N.74-76.

3. Iniaaiiinoe ieeneaiey aaeooiiuo eiiaeainaoia KBi3S5/Aacaeooea A.A.,
?ya/oi A.A., Aeueyeiiaiei I.E., Oaeano E.A Aii?inu aoiiiie iaoee e
oaoieee. ssaea?ii-oece/aneea enneaaeiaaiey. -OOOE. — 1998. -N. 226-228.

4. Coiea/aoay no?oeoo?a aii?oiuo ie?iie nenoaiu AIBi3CVI3 /Aacaeooea
A.A., ?ya/oi A.A., Aeueyeiiaiei I.E., Oaeano E.A., Aaeica?oeaaa A.E.
Ooieoeeiiaeueiua iaoa?eaeu. -1999. -?1.-Aui.6.-N.151-153.

5. Acaeiiaeaenoaea eenei?iaea e ieneaea acioa n ieaieaie neiaeiuo
oaeueeiaaieaeiuo iieoi?iaiaeieeia/?ya/oi A.A., Aeueyeiiaiei I.E., Oaeano
E.A., E?eaiiin N.N. / Aanoiee OAIO. -1999. -Aui.26. -N.103-106.

6. Noano?oeoo?a oaeueeiaaieaeiuo noaeeiia?aciuo oiieeo ieaiie /Aacaeooea
A.A., ?ya/oi A.A., Aeueyeiiaiei I.E., Oaeano E.A., Aonaeiia I. E. O?oaeu
Iaaeaeoia?. eiio. “MicroCAD’97 International Meeting of Information
Technology”. — Oa?ueeia. -1997. -C. 349.

7. No?oeoo?a aii?oiuo ie?iie nenoaiu AIBi3CVI5Aacaeooea A.A., ?ya/oi
A.A., Aeueyeiiaiei I.E., Oaeano E.A., Aonaeiia I.E. //O?oaeu Iaaeaeoia?.
eiio. “Eioi?iaoeeiiiua oaoiieiaee: iaoea, oaoieea, oaoiieiaey,
caei?iauea”, -*anoue 4.-Aui 6. — Oa?ueeia. -1998. -N.245-249.

8. Eco/aiea acaeiiaeaenoaey aoiinoa?u, niaea?aeauae ieneae acioa n
ieaieaie K2GeSe3 /?ya/oi A.A., Aacaeooea A.A., Aeueyeiiaiei I.E.,
Aieaeao I.E. O?oaeu Oe?aeineiai aaeooiiiai iauanoaa. -Oii 1. — Eeaa. —
1995.-N.300-305.

9. Aicaeaenoaea aaciaie oacu ia iiaeaioiaeo iiaa?oiinoe neiaeiuo
oaeueeiaaieaeiuo iieoi?iaiaeieeia e iaoaeeecaoeee /Aacaeooea A.A.,
?ya/oi A.A, Aeueyeiiaiei I.E., Aieaeao I.E. O?oaeu Oe?aeineiai
aaeooiiiai iauanoaa. Oii 2. -Oa?ueeia. -1996. -N.186-191.

10. I?iaiioai? ieneaea acioa oiieiieaii/iuie aaeni?aaioaie ia iniiaa
oaeueeiaaieaeiuo iieoi?iaiaeieeia/Aacaeooea A.A., ?ya/oi A.A.,
Aeueyeiiaiei I.E., I.A.Eiaoo. O?oaeu naieia?a «Nia?aiaiiua oaoie/aneea
n?aaenoaa e iaoiaeu eiio?iey i?e io?aia ie?oaeathuae n?aaeu».- Iaica.-
1992 — C.10.

11. Enneaaeiaaiea oiieeo ieaiie oaeueeiaaieaeiuo iieoi?iaiaeieeia ia
iniiaa aeniooa /Aacaeooea A.A., Aieaeao I.E., ?ya/oi A.A.,. Aeueyeiiaiei
I.E. .Iaoa?iaee aeiiiaiaeae V-? Oe?aiinueei? eiio. «Oiceea i oaoiieiaiy
oiieeo ieiaie neeaaeieo iaiiai?iaiaeieeia».- Oaeai?iae.-1992. -N.65-66.

12. Aacaeooea A.A., Aeueyeiiaiei I.E., Iiaeuy/ay A.I. Iniaaiiinoe
o?ieiuo iaiieiiaaeaioiuo oaeueeiaaieaeiuo iieoi?iaiaeieeia e niaoeeoeea
eo oiieiieaii/iie oaoiieiaee // O?oaeu 4-e Iaaeaeoia?iaeiie eiioa?aioeee
«Oeceea e oaoiieiaey oiieeo ieaiie». -*anoue1. — Eaaii-O?aieiane.
-1993.-N.191.

13. ?ac?aaioea oiieiieaii/iuo oaiini?aoeeiiiuo yeieiae/aneeo aeao/eeia
ia aaca neiaeiuo oaeueeiaaieaeiuo iieoi?iaiaeieeia /?ya/oi A.A.,
Aeueyeiiaiei I.E., Aacaeooea A.A., Aieaeao I.E. O?oaeu 4-e
Iaaeaeoia?iaeiue eiio. «Oeceea e oaoiieiaey oiieeo ieaiie». -*anoue 1.-
Eaaii- O?aieiane. — 1993.-N.135.

14. Aacaeooea A.A., Aeueyeiiaiei I.E., Iiaeuy/ay A.I. Oaciaua ia?aoiaeu
a niaaeeiaieyo A1GeCV1e A!Ge2CV1// O?oaeu 2-e Oe?. eiio.
”Iaoa?iaeiciaanoai i oiceea iaiiai?iaiaeiieiaeo oac ciiiiiai neeaaeo».
-*anoue 3. — Iaaeei. — 1993.-N.379.

15. Eciaiaiea iioe/aneie ieioiinoe aii?oiuo ieaiie A1A1V(BV)CV1 iiae
aicaeaenoaeai ieneaea acioa /Aacaeooea A.A., Aieaeao I.E., ?ya/oi A.A.,
Aeueyeiiaiei I.E. O?oaeu 1-e Oe?aeineie .eiioa?aioeee «No?oeoo?a i
oice/ii aeanoeainoi iaaii?yaeeiaaieo nenoai». -*anoue 2. —
Eueaia.-1993.-N.9.

16. ?ani?aaeaeaiea aani?ae?iaaiiuo aacia a ieaieao KBi3S5 /?ya/oi A.A.,
Aacaeooea A.A., Aeueyeiiaiei I.E., Ieeeothe A.A O?oaeu Iaaeaeoia?. eiio.
“MicroCAD’94 International Meeting of Information Technology”. —
Oa?ueeia — 1994.-N.143.

17. TEM and layer by layer mass spectrometry investigation of thin films
of three compounds incompletevalent chalcogenide semiconducters
/Ryabchun A.A., Bazakutza V.A., Dyakonenko N.L., Gnidash N.I.
Proceedings. International Workshop on Advanced Technologies of
Multicomponent Solid Films and Structures. -Uzhgorod. -Ukraine. -1994.
-P.64-65.

18. Aicaeaenoaea oneiaee aaeooiiie eiiaeainaoeee ieaiie EBi3S5 ia
eeiaoeeo i?ioeannia ieeneaiey /Aacaeooea A.A., ?ya/oi A.A., Aieaeao
I.E., Aeueyeiiaiei I.E. O?oaeu Iaaeaeoia?. eiio. ii oeceea e oaoiieiaee
oiieeo ieaiie. -*anoue2.- Eaaii-O?aieiane. — 1995.-N.271.

19. Iiaeaee?iaaiea iaaeoaciie iiaa?oiinoe a nenoaia NOI-aac. /?ya/oi
A.A., Aacaeooea A.A., Aeueyeiiaiei I.E. Aieaeao I.E. O?oaeu Iaaeaeoia?.
eiio. “MicroCAD’96 International Meeting of Information Technology”. —
Oa?ueeia — 1996.-N.349.

20. Bazakutsa V.A., Ruabchun A.A., Dyakonenko N.L. The Substructure of
chalcogenide Glass Thin Films // ?roc. Second International
School-Conference Physical Problems in Material Science of
Semiconductors. — Chernivtsi, Ukraine.- 1997.- P.163.

21. ?ac?aaioea oiieiieaii/iuo oaiini?aoeeiiiuo yeieiae/aneeo aeao/eeia
ia aaca neiaeiuo oaeueeiaaieaeiuo niaaeeiaiee /Aacaeooea A.A., Aieaeao
I.E., ?ya/oi A.A, Aeueyeiiaiei I.E., Oaeano E.A. O?oaeu XV1
Iaiaeaeaaaneiai nuacaea ii iauae e i?eeeaaeiie oeiee.-N.-Iaoa?ao?a.-
/.3.-1998. — N. 19.

22. I?iaiioai? ieneaea acioa oiieiieaii/iuie aaeni?aaioaie ia iniiaa
oaeueeiaaieaeiuo iieoi?iaiaeieeia /Aacaeooea A.A., Aieaeao I.E., ?ya/oi
A.A., Aeueyeiiaiei I.E. 1-y iao/ii-oaoie/aneay eiioa?aioeey “I?iaeaiu,
aeinoeaeaiey e i?aeoe/aneee iiuo a iaeanoe i/enoee aicaeooa io
?acoeueoaoia aeayoaeueiinoe ?acee/iuo i?iecaiaenoa”, N-Iaoa?ao?a,
-1992.-N.43-52.

————————————————————————
———

Aeueyeiiaiei I.E. Oi?ioaaiiy oiieeo ie?aie iio??eieo oaeueeiaai?aeieo
niieoe, ye? i?noyoue eoaeiee aeaiaio. -?oeiien.

Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa
o?ceei-iaoaiaoe/ieo iaoe ca niaoe?aeuei?noth 01.04.07. — o?ceea
oaa?aeiai o?ea. — Oa?e?anueeee aea?aeaaiee oi?aa?neoao, Oa?uee?a, 1999.

Aei caoenoo i?aaenoaaeai? aenia?eiaioaeuei? aeine?aeaeaiiy oi?ioaaiiy
oiieeo ie?aie iio??eieo oaeueeiaai?aeieo niieoe nenoai A1Ai(Ge)NV1, aea
A1- Li, K, Rb; CV1 — S, Se), ye? aoee i?iaaaeai? ca aeiiiiiaith iaoiae?a
eaca?ii? ian-niaeo?iiao???, i?ina?/oth/i? yeaeo?iii? i?e?ineii??,
oa?iiaeani?aoe??, ian-niaeo?iiao??? aoi?eiieo ?ii?a, iioe/ii?
nia?eo?ioioiiao???. Ie?aee neeaae?a, ye? aeine?aeaeoaaeenue,
neiiaeainiaai? ia neeyi? i?aeeeaaeee c? oaeaee?noth 0.1-0.5 ii/n i?e
O=300E c’yaeythony aii?oieie oa neeaaeathoueny c iaeanoae aeniei? ?
iecueei? aonoeie eiiaeainaoo. Anoaiiaeaia aecia/ath/a ?ieue e?iaoeee
aaeni?aoe?? aac?a o oi?ioaaii? ieeniiai oa?o aii?oieo oaeueeiaai?aeieo
ie?aie neeaaeiiai neeaaeo. A neeo cia/ii a?eueoiai eiao?oe?aioo
i?eeeiaiiy NO o ii??aiyii? c eiao?oe?aioii i?eeeiaiiy I2, iacia/ia
aeii?oea ieneaeo acioo a aoiinoa?iiio iia?o?? (N=1ia/i3) i?ecaiaeeoue
aei eiai cia/iiai eiioeaio?oaaiiy o iiaa?oiaaiio oa??. Anoaiiaeaii ci?ie
caeiiii??iinoae ieeneaiiy aii?oieo ie?aie i?ae aieeaii aoiinoa?e, yea
i?noeoue ieneae acioo. Cai?iiiiiaaii i?aeoe/ia aeei?enoaiiy aeyaeaiiai
aoaeoo.

Eeth/ia? neiaa: oaeueeiaai?aei? niieoee, aii?oi? ie?aee, iaoiaee
eiiaeainaoe??, eeanoa?e, noiai/anoa i?e?ino?oeoo?a, aaeni?aoe?y,
oa?iiaeani?aoe?y, ieeneaiiy, oacia? ia?aoai?aiiy.

Aeueyeiiaiei I.E. Oi?ie?iaaiea oiieeo ie?iie o?ieiuo oaeueeiaaieaeiuo
niaaeeiaiee, niaea?aeaueo uaei/iie yeaiaio. — ?oeiienue.

Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa
oeceei-iaoaiaoe/aneeo iaoe ii niaoeeaeueiinoe 01.04.07. — oeceea
oa??aeiai oaea. Oa?ueeianeee ainoaea?noaaiiue oieaa?neoao, Oa?ueeia,
1999.

?aaioa naycaia n ?aoaieai aeooaeueiuo iao/iuo caaea/, eanathueony
iieo/aiey, eco/aiey naienoa e i?aeoe/aneiai i?eiaiaiey iiauo iaoa?eaeia
— oiieeo ie?iie o?ieiuo noaeeiia?aciuo oaeueeiaaieaeiuo niaaeeiaiee,
niaea?aeaueo uaei/iie yeaiaio. Oa?aeoa?iay aeey yoiai eeanna
iai?aaie/aneeo iaoa?eaeia i?ic?a/iinoue a oe?ieie niaeo?aeueiie iaeanoe,
no?oeoo?iay iaiaeii?iaeiinoue, oa?iiaeeiaie/aneay ia?aaiiaaniinoue e
neeiiiinoue e ia?aoiaeo a noaeeiia?aciia ninoiyiea ii?aaeaeytho eo
oieeaeueiua oece/aneea naienoaa. Iaeiaei, ianoaaeeueiinoue oaeeo
iauaeoia ia iicaieyao a iieiie ia?a ?aaeeciaaoue eiathueany
aiciiaeiinoe.

Eioa?an e oiieei ie?ieai o?ieiuo niaaeeiaiee e iei naycai n oai, /oi
ioo?i aa?eaoeee oeie/aneiai ninoaaa e eciaiaiey ?aaeeiia iieo/aiey
iiaeii nicaeaoue iauaeou n ?acee/iie noaiaiueth ?acoii?yaei/aiey e n
?aciiia?aciui eiiieaenii oece/aneeo naienoa, /oi i?eioeeieaeueii
iaaiciiaeii inouanoaeoue ia aaca yeaiaioa?iuo e aeia?iuo niaaeeiaiee.
Iaee/ea uaei/iiai yeaiaioa a ninoaaa iiiaieiiiiiaioiuo niaaeeiaiee
ioe?uaaao aiciiaeiinoe aeeyoue ia eciaiaiea noaaeeueiinoe yoeo
ooieoeeiiaeueiuo iaoa?eaeia, nicaeaaay eae onoie/eaua, oae e
/oanoaeoaeueiua e aiaoiaio aicaeaenoaeth oiieea ieaiee, eioi?ua iiaoo
iaeoe oe?ieia i?eiaiaiea a ea/anoaa naini?iuo aeao/eeia. Iaeiaei,
aii?inu oi?ie?iaaiey aii?oiuo ie?iie, oa?aeoa? iiaeeoeeaoeee eo
no?oeoo?u i?e eciaiaiee oeie/aneiai ninoaaa e aa?eaoeee oaoiieiae/aneeo
?aaeeiia iieo/aiey inoathony aeeneonneiiiuie.

A nayce n yoei i?eioeeieaeueii aaaeiu yenia?eiaioaeueiua enneaaeiaaiey
iniaaiiinoae oi?ie?iaaiey eiiaeainaoia o?ieiuo oaeueeiaaieaeiuo
noaeeiia?aciuo niaaeeiaiee, onoaiiaeaiea iaueo caeiiiia?iinoae iaaeaeo
eo ninoaaii, no?oeoo?ie e naienoaaie, a oaeaea iiieiaiea i?e?iaeu
eciaiaiee eo oece/aneeo oa?aeoa?enoee iiae aicaeaenoaeai aiaoieo
oneiaee. E?iia oiai, enneaaeoaiua iaoa?eaeu yaeythony aeaaiaea?iui
iiaeaeueiui iauaeoii aeey iiieiaiey oeceee oiieeo ieaiie,
neiiaeaine?iaaiiuo ec noaeeiia?acothueo aauanoa.

Oeaeueth ianoiyuae ?aaiou auei ?ac?aaioea iaoiaeeee iieo/aiea oiieeo
ie?iie iiauo o?ieiuo noaeeiia?aciuo oaeueeiaaieaeiuo niaaeeiaiee,
niaea?aeaueo uaei/iie yeaiaio nenoai A1Ai(Ge)NV1, (aaea A1- Li, K, Rb;
CV1 — S, Se), eco/aiea oece/aneeo caeiiiia?iinoae oi?ie?iaaiey a oaeeo
eiiaeainaoao aii?oiie no?oeoo?u e onoaiiaeaiea caaeneiinoae naienoa
ie?iie io oneiaee iieo/aiey, no?oeoo?iuo e oaciauo i?aa?auaiee,
i?ienoiaeyueo a ieo iinea i?aauaaiey a aoiinoa?a, niaea?aeauae i?eianue
ieneaea acioa, nicaeaiea ia iniiaa oaeeo ia?acoeia /oanoaeoaeueiuo
yeaiaioia yeieiae/aneeo aeao/eeia.

E caueoa i?aaenoaaeaiu yenia?eiaioaeueiua enneaaeiaaiey oi?ie?iaaiey
oiieeo ie?iie neiaeiuo oaeueeiaaieaeiuo niaaeeiaiee auiieiaiiua n
iiiiuueth iaoiaeia eaca?iie iann-niaeo?iiao?ee, i?inaa/eaathuae
yeaeo?iiiie iee?ineiiee, oa?iiaeani?aoeee, iann-niaeo?iiao?ee aoi?e/iuo
eiiia, iioe/aneie nia?eo?ioioiiao?ee. Aia?aua iieo/aiu aii?oiua
eiiaeainaou ia iniiaa iiauo noaeeiia?aciuo niaaeeiaiee, oeie/aneee
ninoaa eioi?uo niioaaonoaoao ninoaao enoiaeiiai iaoa?eaea e onoaiiaeaii
aeeyiea ia?aiao?ia eiiaeainaoeee ia no?oeoo?o iieo/aiiuo ieaiie.
Iniaaiiinoe no?oeoo?u aii?oiuo eiiaeainaoia o?ieiuo oaeueeiaaieaeiuo
niaaeeiaiee oaeaeinue iiiyoue a ?aieao oece/aneie iiaeaee
noaeeiia?aciiai ninoiyiey. Onoaiiaeaii eciaiaiea caeiiiia?iinoae
ieeneaiey oaeueeiaaieaeiuo ieaiie, naycaiiia n iaee/eai a aoiinoa?a
i?eiane ieneaea acioa eiioeaio?aoeeae 1ia/i3. Iieacaii, /oi aeeyiea
ieneaea acioa ia eeiaoeeo iiaa?oiinoiuo i?ioeannia iaoneiaeaii aai
cia/eoaeueii aieueoei ii n?aaiaieth n eenei?iaeii eiyooeoeeaioii
i?eeeiaiey. Aia?aua iaia?oaeaiiia aeeyiey ieeneaiey ia iioe/aneia
i?iioneaiea aii?oiuo ieaiie o?ieiuo oaeueeiaaieaeiuo niaaeeiaiee,
niaea?aeaueo uaei/iie yeaiaio, iicaieeei nicaeaoue ia iniiaa
enneaaeiaaiiuo ieaiie iiaue oei aeao/eeia, eiio?iee?othueo iaee/ea
ieneaea acioa a ie?oaeathuae n?aaea.

I?aeoe/aneia cia/aiea iieo/aiiuo ?acoeueoaoia ninoieo a neaaeothuai.
Ecaioiaeaiu oiieea ie?iee nenoaiu A1Bi(Ge)CV1 ia noaeeyiiuo iiaeeiaeeao,
eiyooeoeeaio iioe/aneiai i?iioneaiey eioi?uo eciaiyaony i?e iaee/ee
i?eianae ieneaea acioa a aicaeooa. Aiciiaeiinoue iioe/aneie ?aaeno?aoeee
i?aaeaeueii aeiionoeiie eiioeaio?aoeee ieneaea acioa a aoiinoa?a
iicaieyao eniieueciaaoue enneaaeiaaiiua ieaiee a ea/anoaa
/oanoaeoaeueiuo yeaiaioia i?eai?ia, eiio?iee?othueo iaee/ea a?aaeiiai
aaca a ie?oaeathuae n?aaea. Iieo/ai iaoaio ia ianneaiue aeiceiao?,
niaea?aeauee /oanoaeoaeueiue yeaiaio a aeaea aii?oiiai neiy aaeooiiiai
eiiaeainaoa o?ieiiai oaeueeiaaieaeiiai niaaeeiaiey, iicaieythuee
oi?inoeoue e oaeaoaaeoue i?ioeann aaciaiaeeca aoiinoa?iiai aicaeooa ia
niaea?aeaiea a iai ieneaea acioa.

Eeth/aaua neiaa: oaeueeiaaieaeiua niaaeeiaiey, aii?oiua ie?iee, iaoiaeu
eiiaeainaoeee, eeanoa?u, noiea/aoay iee?ino?oeoo?a, aaeni?aoeey,
oa?iiaeani?aoeey, ieeneaiea, oaciaua i?aa?auaiey.

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————

Dyakonenko. N. L The formation of three-compound halcogenides thin films
containing the alkali metal. — Manuscript.

Thesis for a candidate degree in physical and mathematical science by
speciality 01.04.07. — physics of solid, Eharkov state university,
Kharkov, 1999.

The results of experimental studying of thin films A1Ai(Ge)NV1, where
A1- Li, K, Rb; CV1 — S, Se, formation obtained by means of laser
mass-spectrometry, TEM, thermodesorbtion, SIMS and other methods are
presented. Thin films of investigated compositions condensed on glass
substrates at the speed of 0.1-0.5 nm/s at O=300E are amorphous and
represent fields of high and low layer density. The main role of gas
adsorption kinetic in the formation of the oxide layer of amorphous
complex composition films was established. As the sticking coefficient
of NO is much stronger than that of I2, the slight addition of oxide
nitrogen in atmosphere (N=1mg/m3) leads to its concentration on the film
surface. The amorphous films oxidation conformities under the influence
of the atmosphere, containing nitrogen oxide, were established. The
application of the detected phenomenon is proposed.

Key words: halcogenides compounds, amorphous films, codensation,
clusters, column microstructure, adsorption, themodesorbtion, oxidation,
phase transformations.

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