IAOe?IIAEUeIA AEAAeAI?ss IAOE OE?A?IE

?INOEOOO O?I?? AENIEIIIEAEOEss?IEO NIIEOE

NE?I*AIEI

Ieaia Aiaoie??aia

OAeE 541.64:539.2

OI?IOAAIIss ? AEANOEAINO? IAIIAIAIEO

IAI?AACA?III?IIEEIEO IIE?IA?IEO N?OIE

IA INIIA? IIE?AIIENEO?EACEI?A ?

IIE?O?AOAIO

02.00.06 – o?i?y aenieiiieaeoey?ieo niieoe

Aaoi?aoa?ao

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?i?/ieo iaoe

Ee?a-1999

Aeena?oaoe??th ? ?oeiien.

?iaioa aeeiiaia o a?aeae?e? aca?iii?iieeieo iie?ia?ieo n?oie ? nenoai
?inoeoooo o?i?? aenieiiieaeoey?ieo niieoe IAI Oe?a?ie.

Iaoeiaee ea??aiee:

aeieoi? o?i?/ieo iaoe Oaeieaea Ieaenaiae? Ia?eiae/,

?inoeooo o?i?? aenieiiieaeoey?ieo niieoe IAI Oe?a?ie, i?ia?aeiee
iaoeiaee ni?a?ia?oiee a?aeae?eo aca?iii?iieeieo iie?ia?ieo n?oie ?
nenoai

Io?oe?ei? iiiiaioe:

aeieoi? o?i?/ieo iaoe, i?ioani? Aaoueiai/oe TH??e Iao?iae/,

Ee?anueeee iaoe?iiaeueiee oi?aa?neoao ?iai? Oa?ana Oaa/aiea,

eaoaae?a o?i?? aenieiiieaeoey?ieo niieoe

aeieoi? o?i?/ieo iaoe, i?ioani? Oaiiaae Aaeeia Na?a??aia,

?inoeooo a?ii?aai?/ii? o?i?? oa iaooio?i?? IAI Oe?a?ie,

caa?aeoaa/ a?aeae?eo aeaeo?io?i?? i?aai?/ieo niieoe

I?ia?aeia i?aai?caoe?y:

Euea?anueeee aea?aeaaiee oi?aa?neoao ?iai? ?aaia O?aiea,

eaoaae?a o?ce/ii? ? eiei?aeii? o?i??, II Oe?a?ie

Caoeno a?aeaoaeaoueny « 6 » aeiaoiy 1999?. i 14 aiaeei? ia can?aeaii?
Niaoe?ae?ciaaii? a/aii? ?aaee Ae 26.179.01 i?e ?inoeooo? o?i??
aenieiiieaeoey?ieo niieoe IAI Oe?a?ie /253160, i.Ee?a, Oa?e?anueea oina,
48; oae. (044) 551-03-86, oaen (044) 552-40-64/.

C aeena?oaoe??th iiaeia iciaeiieoenue a a?ae?ioaoe? ?inoeoooo o?i??
aenieiiieaeoey?ieo niieoe IAI Oe?a?ie (Oa?e?anueea oina, 48).

Aaoi?aoa?ao ?ic?neaii « 2 » aa?aniy 1999 ?.

A/aiee nae?aoa? Niaoe?ae?ciaaii?

a/aii? ?aaee Ae 26.179.01,

aeieoi? o?i?/ieo iaoe
TH.I.I?caeuenueeee

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeuei?noue oaie. Iie?ia?i? nenoaie, noi?iiaai? ca i?eioeeiii AIN,
oe?iei aeei?enoiaothoueny ye niieo/ieee aeey iie?ia?ieo eiiiiceoe?eieo
iaoa??ae?a, aeanoeaino? yeeo aaaaoi a /iio caeaaeaoue a?ae aca?iiae??
eiiiiiaio?a niieo/iiai iaeei c iaeiei oa ?oiuei? aca?iiae?? c
iaiiaithaa/ai. A?aeiia?aeii aei oai?aoe/ieo oyaeaiue, ui ?icaeaathoueny
oeieith TH.N. E?iaoiaa, aeanoeaino? iaiiaiaieo AIN aecia/athoueny
aieiaiei /eiii aieeaii oaa?aei? iiaa?oi? iaiiaithaa/a ia e?iaoeeo
oi?ioaaiiy eiiiiiaio?a ? i?ioeane i?e?ioaciaiai ?icae?eaiiy a nenoai?.
Oiio aeine?aeaeaiiy i?ioean?a oi?ioaaiiy oaeeo aaaaoieiiiiiaioieo
nenoai, ye iaiiaiai? AIN, c iaoith c’ynoaaiiy iaoai?cio oi?ioaaiiy
oaeiai ?iaeo nenoai ? nea?iaaiiai ?aaoethaaiiy e?ioeaaeo aeanoeainoae
eiiiiceo?a ? aeooaeueiith.

Nooi?iue aeine?aeaeaiiy oaiaoeee. Ia?o? ?iaioe, i?enay/ai?
aeine?aeaeaiith aeanoeainoae iaiiaiaieo AIN aoee aeeiiai? TH.N.
E?iaoiaei ? E.I. Na?aa?aith a 1974 ?. An? ianooii? ?iaioe c iaiiaiaieo
AIN aeeiioaaeenue, a iniiaiiio, a ?OAN IAI Oe?a?ie. Aeaia ?iaioa
aeeiiaia a ?aieao aeine?aeaeaiue ?OAN IAI Oe?a?ie ca?aeii oaiai: «Iiooe
oeyo?a noai?aiiy eiiiiceoe?eieo iie?ia?ieo iaoa??ae?a ia iniia? iiaeo
aaaaoieiiiiiaioieo a’yaeo/eo ? iaiiaithaa/?a niaoe?aeueiiai i?ecia/aiiy»
(1993-1994), iiia? aea?aeaaii? ?a?no?aoe?? ?E-1093U040042; «I?eioeeie
noai?aiiy iiaeo iie?ia?-ie?aiia?ieo eiiiiceoe?e aeey iaea?aeaiiy
aca?iii?iieeieo iie?ia?ieo n?oie ? ooieoe?iiaeueieo iie?ia?ieo
eiiiiceo?a ia ?oi?e iniia?» (1995-1997), iiia? aea?aeaaii? ?a?no?aoe??
01.95.U003937.

Iaoa ? caaea/? ?iaioe. Iaoa ?iaioe iieyaaea o anoaiiaeaii? e?iaoe/ieo
caeiiii??iinoae oi?ioaaiiy o?eaceiai?nieo iai?a-AIN o i?enooiino?
iaiiaithaa/?a c ??ciith i?e?iaeith iiaa?oi?, aeine?aeaeaiiy oaciai?
no?oeoo?e ? aeayeeo aeanoeainoae iaea?aeoaaieo iaiiaiaieo iai?a-AIN.

O ca’yceo c oeei ?ica(ycoaaeenue oaee caaea/?:

— iaea?aeaiiy aeaio aeae?a iai?a-AIN: 1 — ia iniia? n?o/anoiai
eiiie?ia?o aeeoe?aiiaiai ao??o a?noaiieo A c aiieneie?aiia?ii AAe-20 ?
e?i?eiiai iie?o?aoaio (iai?a- AIN-1), 2 — ia iniia? n?o/anoiai
eiiie?ia?o oa?iiia?iaeaiiai 4,4′-aeeoai?eiaoai-ae??cioe?aiaoo c
aiieneie?aiia?ii AAe-20 ? e?i?eiiai iie?o?aoaio (iai?a-AIN-2);

— iaea?aeaiiy iaiiaiaieo aeenia?niei ? aieieienoei iaiiaithaa/aie
iai?a-AIN;

— aeine?aeaeaiiy o?i?/ieo ia?aoai?aiue ? e?iaoeee oi?ioaaiiy eiiiiiaio?a
o iaiaiiaiaieo ? iaiiaiaieo iai?a-AIN;

— aeine?aeaeaiiy aieeao iaiiaithaa/?a ia i?e?ioaciao no?oeoo?o
iai?a-AIN;

— i?iaaaeaiiy ii??aiyeueieo aeine?aeaeaiue aeayeeo aeanoeainoae
iaiaiiaiaieo ? iaiiaiaieo iai?a-AIN;

— aeine?aeaeaiiy aieeao iiaa?oiaai? iiaeeo?eaoe?? iaiiaithaa/a ia
e?iaoeeo oi?ioaaiiy ? aeanoeaino? iai?a-AIN ? ?o ?iaeea?aeoaeueieo
eiiiiiaio?a.

Iaoeiaa iiaecia. Aia?oa aoee aea/ai? o?i?/i? i?ioeane, ui i?io?eathoue
i?e neioac? eiiie?ia?o aeeoe?aiiaiai ao??o a?noaiieo A c
aiieneie?aiia?ii AAe-20 ? eiiie?ia?o oa?iiia?iaeaiiai
4,4′-aeeoai?eiaoaiae??cioe?aiaoo c aiieneie?aiia?ii AAe-20 o i?enooiino?
iaiiaithaa/?a. Iieacaii, ui a iaiiaiaieo nenoaiao oaeaee?noue ?aaeoe?e
aca?iiae?? aiieneaeieo a?oi ye ?c oe?aiaoieie, oae ? c ?cioe?aiaoieie
a?oiaie aeua o ii??aiyii? c iaiaiiaiaieie, i?e oeueiio oaeaee?noue
?aaeoe?? iie?oeeeeio?eia?ecaoe?? oe?aiao?a ? ?cioe?aiao?a ia ii/aoeiaeo
noaae?yo cieaeo?oueny. Anoaiiaeaii, ui oeae aoaeo a?eueo ae?aaeaiee i?e
aaaaeaii? iiaeeo?eiaaiiai iaiiaithaa/a ii??aiyii c aeo?aeiei. Aaaeeeao
?ieue o oeueiio aeiaaeeo a?ae?a?a? iiaeeea?noue aca?iiae?? iiaa?oiaaeo
a?oi iiaeeo?eiaaieo iaiiaithaa/?a ?c ?aaeoe?eiicaeaoieie a?oiaie
aeo?aeieo eiiiiiaio?a ia noaae?? oi?ioaaiiy eiiie?ia??a. Iieacaii, ui
aaaaeaiiy iaiiaithaa/?a o iai?a-AIN, ye i?aaeei, ca?eueoo? oaeaee?noue
aca?iiae?? ?aaeoe?eieo a?oi o nenoai?. Aeine?aeaeaiiy a’yceii?oaeieo
aeanoeainoae iaiiaiaieo iai?a-AIN iieacaei, ui aaaaeaiiy iaiiaithaa/?a
ca?eueoo? nooi?iue i?e?ioaciaiai ?icae?eaiiy eiiiiiaio?a iai?a-AIN. I?e
oeueiio aeey iai?a-AIN, iaiiaiaieo iiaeeo?eiaaieie iaiiaithaa/aie,
nooi?iue i?e?ioaciaiai ?icae?eaiiy ieae/ee, i?ae aeey iai?a-AIN,
iaiiaiaieo iaiiaeeo?eiaaieie iaiiaithaa/aie. Aia?oa aeyaeaii, ui
iaiiaiai? iiaeeo?eiaaiei aoaeaoeaaei aieieiii aeine?aeaeaii? iai?a-AIN
iathoue iii?oiee i’?ciaeaeo?e/iee aoaeo. Anoaiiaeaii, ui iaiiaiai?
oinoi?ai?niei aoaeaoeaaei aieieiii iai?a-AIN oa?aeoa?ecothoueny
i?aeaeuaiith aiaiano?ee?noth a ii??aiyii? c iaiaiiaiaieie iai?a-AIN.

I?aeoe/ia oe?ii?noue. Iaea?aeai? iai?a-AIN ia iniia? o?eaceiai?nieo
eiiie?ia??a iiaeooue aooe aeei?enoai? ye niieo/ieee aeey eiiiiceoe?eieo
iie?ia?ieo iaoa??ae?a. Aenia?eiaioaeuei? aeai? aeathoue iiaeeea?noue
i?iiiioaaoe aeei?enoiaoaaoe iaiiaiai? iai?a-AIN ia iniia? n?o/anoiai
eiiie?ia?o aeeoe?aiaoo c aiieneie?aiia?ii ? e?i?eiiai iie?o?aoaio ye
i’?ciaeaeo?ee.

Ai?iaaoe?y ?iaioe. Caaaeuei? iieiaeaiiy aeena?oaoe?eii? ?iaioe
aeiiia?aeaeenue ia VIII Oe?a?inuee?e eiioa?aioe?? c aenieiiieaeoey?ieo
niieoe (Ee?a, 1996), iaaeaeoia?iaeiie eiioa?aioeee «Ooiaeaiaioaeueiua
i?iaeaiu iaoee i iieeia?ao» (Iineaa, 1997), International Conference on
Polymer Characterization «POLYCHAR — 5» (Aeaioii, NOA, 1997), IUPAC
International Symposium on Advances in Polymer Science and Technology
Macro-98 (Iaae?an, ?iae?y, 1998), Anaoe?a?inuee?e eiioa?aioe??
«Aeooaeuei? ieoaiiy o?ceei-o?i?? aaoa?iaaiieo nenoai» (??aia, 1998).

Ioae?eaoe??. Iniiaiee ci?no aeena?oaoe?eii? ?iaioe aeeeaaeaiee o 13
ioae?eaoe?yo (7 iaoeiaeo noaooyo oa 6 oacao aeiiia?aeae).

No?oeoo?a oa ianya ?iaioe. Aeena?oaoe?y neeaaea?oueny c anooio, 3-o
aeaa, aeniiae?a, nieneo oeeoiaaii? e?oa?aoo?e. ?iaioa aeeeaaeaia ia 130
noi??ieao iaoeiiieniiai oaenoo ? i?noeoue 1 oaaeeoeth, 33 ?enoiee, 154
iineeaiue ia ?iaioe a?o/eciyieo oa ca?oa?aeieo aaoi??a.

Aeaeea?aoe?y iniaenoiai aianeo aaoi?a iieyaa? o ieaioaaii? aenia?eiaioo
oa aaciina?aaei?e o/ano? o i?iaaaeaii? oai?aoe/ieo ? aenia?eiaioaeueieo
aeine?aeaeaiue; aiae?c? oa ioi?ieaii? ?acoeueoao?a o aeaeyae?
ioae?eaoe?e, aeiiia?aeae; naiino?eiiio ocaaaeueiaii? ie?aieo aoai?a
aeine?aeaeaiiy oa oi?ioethaaii? iniiaieo aeniiae?a aeena?oaoe?eii?
?iaioe a oe?eiio.

Iaoiaeieia?y, iaoiaee aeine?aeaeaiue. Iniiai? ?acoeueoaoe ?iaioe
io?eiai? c aeei?enoaiiyi no/anieo iaoiaeee ? iaoiae?a aeine?aeaeaiiy:
?io?a/a?aiii? niaeo?ineii?? (?*-niaeo?ineii?y), aeeoa?aioe?aeueii?
neaioth/i? eaei?eiao??? (AeNE), aeeoa?aioe?aeueiiai oa?i?/iiai aiae?co
(AeOA), iaoiaeo aeeiai?/iiai iaoai?/iiai aiae?co (AeIA).

Ia’?eoaie aeine?aeaeaiue aoee aea? iaiaiiaiai? iai?a-AIN: ia iniia?
eiiie?-ia?o-1 (EIE-1) aeeoe?aiiaiai ao??o a?noaiieo A (AeOeAAA) c
aiieneie?aiia?ii AAe-20 ? e?i?eiiai iie?o?aoaio (IO) (iai?a-AIN-1); ia
iniia? EIE-2 oa?iiia?iaeaiiai 4,4′-aeeoai?eiaoaiae??cioe?aiaoo (OAe?Oe)
c aiieneie?aiia?ii AAe-20 ? e?i?eiiai IO (iai?a-AIN-2). A oaeiae
iaiiaiai? iai?a-AIN oeeo aea neeaae?a. sse iaiiaithaa/? aeei?enoiaoaaee:
aeenia?niee ii?ioie (-Fe2O3 ia?ee OE-eeneee ? aoaeaoeaaa aieieii (AA),
iaea?aeoaaia oeyoii ea?aii?caoe?? a?ae?aooeaetheicieo aieieii. Oaeiae
aeei?enoiaoaaee iiaeeo?eiaai? iaiiaithaa/?. Aeey oeueiai (-Fe2O3
ia?iaeyee iiaa?oiaai-aeoeaiith ?a/iaeiith – eae??aith n?eeth
ae?aee?eiie?ao?eaiae?eieaaiai ao??o oinoi?ii? eeneioe. Iiaeeo?eiaaia
oinoi?ai?noia aoaeaoeaaa aieieii (OAA) i?noeei ia iiaa?oi? oinoi?iieene?
a?oie, aeey /iai oinoaoe oeaetheice i?aeaeaaaee ea?aii?caoe?? a oiiaao,
aiaeia?/ieo iaea?aeaiith iaiiaeeo?eiaaieo aoaeaoeaaeo aieieii.

O anooi? aena?oeaii noai i?iaeaie, iaa?oioiaaii aeooaeuei?noue oaie
aeena?oaoe??, noi?ioeueiaaii iaoo oa caaaeaiiy aeine?aeaeaiue.

O ia?o?e aeaa? i?iaaaeaii e?eoe/iee aiae?c, ocaaaeueiaiiy ?
nenoaiaoecaoe?th e?oa?aoo?ieo aeaieo a oea?ei? AIN ia iniia?
aeeoe?aiao?a ? ae??cioe?aiao?a, a oaeiae iaiiaiaieo AIN.

O ae?oa?e aeaa? iienaii aeo?aei? niieoee e ?a/iaeie, ye? aeei?enoiaoaaee
a aenia?eiaio?, neioac eiiie?ia??a, iaea?aeaiiy iaiaiiaiaieo ?
iaiiaiaieo iai?a-AIN, o?ceei-o?i?/i? iaoiaee, ye? aeei?enoiaoaaee i?ae
/an aeeiiaiiy ?iaioe.

O o?ao?e aeaa? iaaaaeaii ?acoeueoaoe aenia?eiaioaeueieo aeine?aeaeaiue,
i?iaaaeaii ?oi?e aiae?c, c?iaeaii aeniiaee.

Aaoi? ue?i aeyeo? aeieoi?ia? o?i?/ieo iaoe, i?ioani?o Na?aa?a?e E.I. ?
eaiaeeaeaoia? o?i?/ieo iaoe A?iaeo I.I. ca iino?eio oaaao aei ?iaioe ?
aeiiiiiao i?e ?? aeeiiaii?.

INIIAI? ?ACOEUeOAOE AeINE?AeAEAIIss

Aeine?aeaeaiiy aieeao iaiiaithaa/?a ia e?iaoeeo oi?ioaaiiy eiiie?ia??a
aeeoe?aiaoo c aiieneie?aiia?ii ? ae??cioe?aiaoo c aiieneie?aiia?ii

Aea/aiiy aieeao iaiiaithaa/?a ia i?ioean oi?ioaaiiy n?o/anoeo
eiiie?ia??a aea/aee ca aeiiiiiaith iaoiaeo ?*-niaeo?ineii??.

sse iieacaee e?iaoe/i? aeine?aeaeaiiy (?en.1), o i?ioean? neioaco EIE-1
i?e oaiia?aoo?? 423 E a ?aaeoe?ei?e noi?o? nii/aoeo i?ioiaeeoue ?aaeoe?y
o?eueee ca o/anoth oe?aiaoieo a?oi – oeeeeio?eia?ecaoe?y oe?aiaoo c
ooai?aiiyi oe?aio?aoieo oeeee?a (noaia 1). I?ney aeo?eioaaii? i?ioyaii
150 oa. i?e oe?e aea oaiia?aoo?? a nenoaia ?icii/eia?oueny aca?iiae?y
oe?aiaoieo ? aiieneaeieo a?oi c ooai?aiiyi ienacie?iiaeo oeeee?a (noaia
2), i?i ui na?ae/?oue iaeii/ania c?inoaiiy oaeaeeinoe aeo?a/aiiy ye
oe?aiaoi?o, oae ? aiieneaeieo a?oi (?en.1). Ia ooai?aiiy oe?aio?aoieo
oeeee?a aeaco? iiyaa a niaeo?? EIE-1 nioa iiaeeiaiiy 1370 e 1566 ni–1,
aeey ienacie?iiaiai oeeeea oa?aeoa?ia nioaa i?e 1680 ni-1.

?en.1. Caeaaei?noue oaeaeeino? aeo?a/aiiy oe?aiaoieo (a) ? aiieneaeieo
(a) a?oi a?ae /ano aeey iaiaiiaiaiiai EIE-1 (1), iaiiaiaiiai 1.5 ia.% AA
(2) ? 1.5 ia.% OAA (3).

I?ney i?aeaeuaiiy oaiia?aoo?e aei 453 E oe?aiaoi? a?oie aeo?a/athoueny
oe?eeii, ia ui aeaco? cieeiaiiy nioa iiaeeiaiiy, ui a?aeiia?aeathoue
oe?aiaoiei a?oiai. Ia oeueiio aoai? ii/eia?oueny i?ioean ia?aoai?aiiy
ienacie?iiaeo oeeee?a a ienacie?ae?iiiia? (noaia 3). Oae? ia?aoai?aiiy
i?aeoaa?aeaeothoueny iiyaith nioae iiaeeiaiiy 1750 ni-1, yea oa?aeoa?ia
ienacie?ae?iiiiaiio oeeeeo.

Ia?aeaeueii i?e oaiia?aoo?? 453 E eaea iine?aeiaiee i?ioean ia?aoai?aiiy
oe?aio?aoieo oeeee?a i?e ?oi?e aca?iiae?? c aiieneaeieie a?oiaie a
?cioeeaio?aoi? e aeae? a ienacie?ae?iiiia? (noaia 4). Oeueiio i?ioeania?
a?aeiia?aea? c?inoaiiy oaeaeeino? aeo?a/aiiy aiieneaeieo a?oi a
?ioa?aae? /ano 360-400 oa., a ia niaeo?? EIE-1 — iiyaa nioae i?e 1696
ni-1.

Ia a?aei?io a?ae EIE-1, aeey yeiai ooai?aiiy ?cioe?aio?aoieo ?
ienacie?ae?iiiiaeo oeeee?a eaea /a?ac ieceo iine?aeiaieo ia?aoai?aiue,
i?e neioac? EIE-2 aiie ooai?ththoueny aaciina?aaeiuei i?e aca?iiae??
?aaeoe?eiicaeaoieo a?oi (noaia 5).

Anoaiiaeaii, ui aaaaeaiiy ye AA, oae ? OAA o EIE-1 ia noaae?? eiai
oi?ioaaiiy niia?eueith? oaeaee?noue ia?aoai?aiiy oe?aiaoieo a?oi ? aaaea
aei c?inoaiiy oaeaeeino? ?aaeoe?? ca o/anoth aiieneaeieo a?oi (?en.1).
Ne?ae cacia/eoe, ui oeae aoaeo a?eueo ae?aaeaiee i?e aaaaeaii? OAA, ui
iiynith?oueny iiaeeeaith o?i?/iith aca?iiae??th oinoi?iieeneeo a?oi OAA
?c oe?aiaoieie oa aiieneaeieie a?oiaie.

Iieacaii, ui aaaaeaiiy aeenia?niiai (-Fe2O3 o EIE-2 ca?eueoo?
oaeaee?noue aeo?a/aiiy aiieneaeieo a?oi, oaeaee?noue aeo?a/aiiy
?cioe?aiaoieo a?oi i?e oeueiio niia?eueith?oueny (?en.2).

?en.2. Caeaaei?noue oaeaeeino? aeo?a/aiiy ?cioe?aiaoieo (a) ?
aiieneaeieo (a) a?oi aeey iaiaiiaiaiiai EIE-2 (1), iaiiaiaiiai 0.5 ia.%
(-Fe2I3 (2) ? 21 ia.% (-Fe2I3 (3).

Oaeei /eiii, iacaeaaeii a?ae i?e?iaee iaiiaithaa/?a, aiie ye a EIE-1,
oae ? a EIE-2 ca?eueoothoue oaeaee?noue ?aaeoe?e ca o/anoth aiieneaeieo
a?oi — ooai?aiiy ienacie?iiaeo ? ienacie?ae?iiiiaeo oeeee?a, a ?aaeoe??
oeeeeio?eia?ecaoe?? oe?aiao?a ? ?cioe?aiao?a niia?eueiththoueny.
I?e/eiith oaeiai aieeao iaiiaithaa/?a ia e?iaoeeo oi?ioaaiiy EIE ?,
i/aaeaeii, i?ioeane aca?iiae?? a?aei?aaieo ?aaaaio?a aeey EIE c
iiaa?oiath iaiiaithaa/?a, ?oi?e ia?a?iciiae?e a ia’?i?, ui ni?ey? aai
i?enei?aiith, aai oiia?eueiaiith i?ioean?a aca?iiae?? ?aaaaio?a.

Aeine?aeaeaiiy aieeao iaiiaithaa/?a ia e?iaoeeo oi?ioaaiiy iai?a-AIN ia
iniia? eiiie?ia??a aeeoe?aiaoo c aiieneie?aiia?ii aai ae??cioe?aiaoo c
aiieneie?aiia?ii ? iie?o?aoaio

Oeae ?icae?e aeena?oaoe?? i?enay/aiee aiae?co ?acoeueoao?a
aeine?aeaeaiiy i?ioean?a, ui i?io?eathoue i?e oi?ioaaii? iaiaiiaiaieo ?
iaiiaiaieo iai?a-AIN ia iniia? aeine?aeaeoaaieo EIE. sse e?i?eiee
eiiiiiaio aeey iai?a-AIN aeei?enoiaoaaee IO II 40000 ia iniia? 4,4?-
aeeoai?eiaoaiae??cioe?aiaoo oa ie?aiaoo?eaiae?eieueaaeeieiaoo.

Iieacaii, ui i?e neioac? EIE-1 o i?enooiino? IO a nenoai? i?io?eathoue
?aaeoe??, aiaeia?/i? oei, ui niinoa??aathoueny i?e neioac?
?iaeea?aeoaeueiiai EIE-1: iie?oeeeeio?eia?ecaoe?y aeeoe?aiaoo, ?aaeoe?y
i?ae oe?aiaoiei ? aiieneaeieie a?oiaie c ooai?aiiyi ienacie?iiaeo
oeeee?a, ia?aoai?aiiy ienacie?iiaeo oeeee?a a ienacie?ae?iiiia?,
ia?aoai?aiiy oe?aio?aoieo oeeee?a a ?cioe?aio?aoi? e aeae? a
ienacie?ae?iiiia?. I?ioa, e?iaoe/i? aeine?aeaeaiiy iieacaee, ui o
i?enooiino? IO oi?ioaaiiy EIE-1 i?enei?th?oueny, ui iiaea aooe iiyniaia
aieeaii IO ye oaa?aei? oace.

Aiaeia?/io ea?oeio ca?eueoaiiy oaeaeeino? oi?ioaaiiy n?o/anoiai
eiiiiiaioo o i?enooiino? IO niinoa??aaee oaeiae ? i?e oi?ioaaii?
iai?a-AIN-2. Ne?ae cacia/eoe, ui o iai?a-AIN-2 e??i iniiaieo ?aaeoe?e,
ui i?io?eathoue a ?iaeea?aeoaeueiiio EIE-2, ooai?ththoueny aeioaiaoe a
?acoeueoao? ?aaeoe?? i?ae o?aoaiiaith oa ?cioe?aiaoiith a?oiaie. Ia oea
aeaco? iiyaa a niaeo?? iai?a-AIN-2 nioae iiaeeiaiiy i?e 1650 ni-1.

Anoaiiaeaii, ui aaaaeaiiy a aeine?aeaeoaai? iai?a-AIN iaiiaithaa/?a, ye
i?aaeei, aaaea aei i?enei?aiiy iniiaieo ?aaeoe?e. Oae, aaaaeaiiy a
iai?a-AIN-1 ye AA, oae ? OAA ni?ey? ca?eueoaiith oaeaeeino? aeo?a/aiiy
oe?aiaoieo ? aiieneaeieo a?oi o ii??aiyii? c iaiaiiaiaiith iai?a-AIN-1.
Ui noino?oueny aaaaeaiiy a iai?a-AIN-2 (-Fe2O3, oi oaeaee?noue
ia?aoai?aiiy ?cioe?aiaoieo a?oi c?inoa? o ii??aiyii? c iaiaiiaiaiith
iai?a-AIN-2, a ia oaeaee?noue ia?aoai?aiiy aiieneaeieo a?oi oeae
iaiiaithaa/ i?aeoe/ii ia aieeaa?. Oaeei /eiii, oaeaee?noue oi?ioaaiiy
EIE-1 ? EIE-2 a i?enooiino? ye IO (iaiaiiaiaia iai?a-AIN), oae ?
aeine?aeaeaieo iaiiaithaa/?a (iaiiaiaia iai?a-AIN), ye i?aaeei, c?inoa?.
Oea iiaea aooe iiyniaii aaeni?aoe?eiith aca?iiae??th ooieoe?iiaeueieo
a?oi ?aaeoe?eii? noi?o? c iiaa?oiath iaiiaithaa/?a ? i?aeaeuaiiyi
nooiaiy oii?yaeeoaaiiy iieaeoe, ui ?aaaothoue, a aaeni?aoe?eiiio oa??,
ui aaaea aei i?enei?aiiy ?aaeoe?? ? ia?a?iciiae?eo i?aeiieaeey?ieo
ca‘yce?a o iiaa?oiaaiio oa??. Ana oea a?aeaeaa?oueny ia oaciai?
no?oeoo?? iai?a-AIN.

Aeine?aeaeaiiy oaciai? no?oeoo?e iai?a-AIN

Aeey aeine?aeaeaiiy oaciai? no?oeoo?e iaea?aeoaaieo iai?a-AIN
aeei?enoiaoaaee iaoiae aeeiai?/iiai iaoai?/iiai aiae?co.

Aiae?c oaiia?aoo?ieo caeaaeiinoae iiaeoey ao?ao iieacaa, ui oi?ioaaiiy
n?o/anoeo eiiie?ia??a o i?enooiino? IO (oi?ioaaiiy nenoaie ca oeiii
iai?a-AIN) aieeaa? ia oa?aeoa? oeeo caeaaeiinoae ? aeeeeea? ci?uaiiy
oaiia?aoo?ii? iaeano?, a ye?e niinoa??aathoueny ?aeaenaoe?ei? i?ee
?iaeea?aeoaeueieo EIE ? IO.

Oae, aeey iai?a-AIN-1, ui i?noeoue 80 % EIE-1 i?e, ye?e a?aeiia?aea?
?iaeea?aeoaeueiiio EIE-1, cnoaa?oueny a iaeanoue a?eueo iecueeeo
oaiia?aoo?, a i?e, ui a?aeiia?aea? IO — a iaeanoue a?eueo aenieeo
oaiia?aoo? o ii??aiyii? c i?eaie aeey ?iaeea?aeoaeueieo EIE-1 ? IO
(?en.3). Oaeee oa?aeoa? caeaaeiino? iiaeoey ao?ao, c iaeiiai aieo,
aeaco? ia aeaioaci?noue nenoaie. C ?ioiai aieo — ia iaiiaia oaciaa
?icae?eaiiy. Inoaii? aaaea aei ooai?aiiy aaeeei? i?aeoacii? iaeano? (i?e
a ?ioa?aae? oaiia?aoo? 325 — 350 E). Aeey iai?a-AIN c ai?noii EIE-1 50%
niinoa??aa?oueny iaeei oe?ieee i?e, ui eaaeeoue i?ae i?eaie
?iaeea?aeoaeueieo EIE-1 ? IO. O ?aieao oi?iaeueiiai i?aeoiaeo oaeo
nenoaio iiaeia aoei a ioa?aeoa?ecoaaoe ye iaeiioacio. I?ioa, oaea
oaa?aeaeaiiy aoei a iai?aaii??iei, ine?eueee, ye iieacothoue e?iaoe/i?
aeine?aeaeaiiy, aeey iai?a-AIN-1 ?c ca?eueoaiiyi ai?noo IO oaeaee?noue
oi?ioaaiiy n?oee EIE-1 c?inoa?, ui oo?oaeith? i?e?ioaciaa ?icae?eaiiy o
?icaeyioo?e iai?a-AIN-1 ? aiia ia?aaoaa? a noai?, ui ia?aaeo?
i?e?ioaciaiio ?icae?eaiith. I?i oea na?ae/eoue oaeiae aeineoue oe?iea ia
eanoue oaiia?aoo?, o ye?e niinoa??aa?oueny ?aeaenaoe?eiee i?e. O
iai?a-AIN-1 ?c aaeeeei ai?noii IO (60 ? 80 %) niinoa??aa?oueny iaeei
?aeaenaoe?eiee i?e. ?iia??ii, a oeueiio aeiaaeeo EIE-1 ia ooai?th?
aacia?a?aii? oace ? a aeaieo iai?a-AIN-1 a?i ?iciiae?eaiee a ia’?i? IO
iao?eoe? o aeaeyae? aeeooc?eieo iaeanoae. Aeai? ?acoeueoaoe aeia?a
ei?aeththoue ?c ?acoeueoaoaie aeeoa?aioe?eii? neaioth/i? eaei?eiao???.

?en.3. Oaiia?aoo?i? caeaaeiino? iiaeoey ao?ao

aeey iai?a-AIN-1 c ai?noii EIE-1% 100 (a),

80 (a), 50 (a), 40 (a), 20 (ae), 0 % (a).

?en.4. Oaiia?aoo?i? caeaaeiino? iiaeoey ao?ao aeey iai?a-AIN-1 c
ai?noii EIE-1 50 %, iaiiaiaii? AA (1) ? OAA (2) c ??ciei ai?noii
iaiiaithaa/a.

Aaaaeaiiy AA a iai?a-AIN-1 ?c ai?noii EIE-1 50 % aeeeeea? ca?eueoaiiy
i?e?ioaciaiai ?icae?eaiiy a nenoai? o ii??aiyii? c iaiaiiaiaiith, ia ui
aeaco? iiyaa ia oaiia?aoo?ieo caeaaeiinoyo iiaeoey ao?ao aeaio i?e?a, ui
a?aeiia?aeathoue ?iaeea?aeoaeueiei eiiiiiaioai iai?a-AIN (?en.4). Oea ?
iane?aeeii ia?aaaaeii? aca?iiae?? iaiiaithaa/a c iaeiei ?c eiiiiiaio?a
iai?a-AIN. Ne?ae cacia/eoe, ui aaaaeaiiy iaa?oue iaeeo e?eueeinoae
iaiiaithaa/a aaaea aei iiyae i?ea, ui a?aeiia?aea? One IO. A?aoiaoth/?,
ui ?ioaineai?noue ?aeaenaoe?eieo iaeneioi?a iaaiei /eiii ei?aeth? c
ia’?iiith /anoeith oace, iiaeia i?eionoeoe, ui a aeaiiio aeiaaeeo ia
iaiiaithaa/? ia?aaaaeii aaeni?ao?oueny IO, ui aaaea aei ca?eueoaiiy eiai
iic??iiai ia’?io ca ?aooiie /anoie iaiiaithaa/a. E??i oiai, One IO a
iaiiaiaieo iai?a-AIN-1 ia? oaiaeaioe?th aei ca?eueoaiiy ii??aiyii c
?iaeea?aeoaeueiei IO, ui iiynith?oueny ciaioaiiyi iieaeoey?ii?
?ooeeaino? a aaeni?aoe?eieo oa?ao iie?ia?o. Ine?eueee AA aaiaeeee ia
noaae?? oi?ioaaiiy iai?a-AIN, aaeni?aoe?y ii/eia?oueny aaea i?e ci?oaii?
eiiiiiaio?a ?c iaiiaithaa/ai. Oea ni?ey? ca?eueoaiith nooiaiy
i?e?ioaciaiai ?icae?eaiiy. Iiaeeo?eaoe?y iaiiaithaa/?a ci?ith? ?oith
iiaa?oiaao aia?a?th, yea ? aaaiiei /eiieeii, ui aieeaa? ia oa?aeoa?
no?oeoo?, ui oi?iothoueny. Oa?aeoa? oaiia?aoo?ieo caeaaeiinoae iiaeoey
ao?ao aeey iaiiaiaii? iai?a-AIN-1 aeicaiey? noaa?aeaeoaaoe, ui i?e
aaaaeaii? OAA nooi?iue i?e?ioaciaiai ?icae?eaiiy eiiiiiaio?a iai?a-AIN-1
ieae/a, i?ae i?e aaaaeaii? AA (?en.4). Ne?ae cacia/eoe, ui o aeaiiio
aeiaaeeo ia? i?noea i?ioean oaiini?aoe??: ia noaae?? oi?ioaaiiy
iai?a-AIN OAA aca?iiae?? c aeo?aeieie eiiiiiaioaie n?o/anoiai
eiiie?ia?o, ui ciaioo? aieea aieieia ia i?ioeane i?e?ioaciaiai
?icae?eaiiy.

Aaaaeaiiy (-Fe2O3 a iai?a-AIN-2 oaeiae ni?ey? i?aeaeuaiith nooiaiy
i?e?ioaciaiai ?icae?eaiiy ii??aiyii c iaiaiiaiaiith iai?a-AIN-2. I?i oea
na?ae/eoue c?inoaiiy eiao?oe??ioa naa?aaaoe??, ye?e ? e?euee?niith
ioe?ieith nooiaiy i?e?ioaciaiai ?icae?eaiiy (?en.5).

I?ioa, nooi?iue i?e?ioaciaiai ?ic- ae?eaiiy i?aeoe/ii ia ci?ith?oueny
i?e eiioeaio?aoe?? iaiiaithaa/a aeua 10 ia.%. Iieacaii, ui iai?a-AIN-2,
iaiiaiaia (-Fe2O3, iiia?aaeiuei ia?iaeaiei iiaa?oiaai-aeoeaiith
?a/iaeiith, oa?aeoa?eco?oueny iaioei nooiaiai i?e?ioaciaiai ?icae?eaiiy
a ii??aiyii? c iai?a-AIN-2, iaiiaiaii? aeo?aeiei (-Fe2O3. I?e/eiith
oeueiai, ?iia??ii, ? ciaioaiiy iiaa?oiaai? aia?a?? iaiiaithaa/a oa
aiane?aeie oeueiai ciaioaiiy eiai aieeao ia i?ioeane i?e?ioaciaiai
?icae?eaiiy.

?en.5. Caeaaei?noue eiao?oe??ioa naa?aaaoe?? a?ae

eiioeaio?aoe?? (-Fe2I3 o iai?a-AIN-2.

Niaoeeo?/i? aeanoeaino? iaiiaiaieo aoaeaoeaaeie aieieiaie iai?a-AIN-1
(ia iniia? eiiie?ia?o aeeoe?aiaoo c aiieneie?aiia?ii ? e?i?eiiai
iie?o?aoaio)

Ine?eueee OAA oa AA, ye? aeei?enoiaoaaee aeey iaiiaiaiiy iai?a-AIN-1, ?
ieceiiiaeoeueieie oa a?aeiinyoueny aei oeio aieieii c iniaeeaeie
aeanoeainoyie, aoei i?iaaaeaii aea/aiiy aeayeeo niaoeeo?/ieo
aeanoeainoae iaiiaiaieo aoaeaoeaaei aieieiii iai?a-AIN-1:
i‘?ciaeaeo?e/ieo oa ai?th/ino?. Iieacaii, ui iai?a-AIN-1, iaiiaiai? OAA,
i?e aeineoue aenieiio ai?no? inoaiiueiai (aeua 30 ia. %) aieiae?thoue
iii?oiei i‘?ciaeaeo?e/iei aoaeoii; aaaaeaiiy OAA o iai?a-AIN-1 cieaeo?
ai?th/?noue: /an ai??iiy iaiiaiaii? eiiiiceoe?? i?e aeianaii? c iieoi’y
iaeueieea ciaioo?oueny a 5-9 ?ac?a o ii??aiyii? c iaiaiiaiaiith
iai?a-AIN-1.

Anoaiiaeaii, ui aaaaeaiiy OAA o iai?a-AIN-1 ia noaae?? ?oiueiai
oi?ioaaiiy aaaea aei ?noioieo ci?i on?o aeaeo?io?ce/ieo iieaciee?a
i?iaeoeo?a, ui ooai?ththoueny. Ca?eueoaiiy ai?noo OAA o eiiiiceoe?yo
aaaea aei cia/iiai ca?eueoaiiy ieoiiiai ia’?iiiai iii?o, ??cei c?inoa?
/an ae?aeaeo?e/ii? ?aeaenaoe??. Oe? ?acoeueoaoe na?ae/aoue i?i
ia?a?iciiae?e aioo?e- ? i?aeiieaeoey?ieo aca?iiae?e o iai?a-AIN-1, ui
oi?iothoueny a i?enooiino? aeine?aeaeaiiai aieieienoiai iaiiaithaa/a.

INIIAI? AENIIAEE

?icaeyae ? aiae?c ?ia?o, i?enay/aieo aieeao iaiiaithaa/?a ia aeanoeaino?
AIN, iieacaa, ui oey i?iaeaia a aeaiee /an ? aeooaeueiith, ??
?ica(ycaiiy aeicaiey? i?iaiicoaaoe o?ceei-o?i?/i? oa?aeoa?enoeee
iaiiaiaieo AIN, ui aeoaea aaaeeeai i?e iaea?aeaii? eiiiiceoe?eieo
iie?ia?ieo iaoa??ae?a. O aeai?e ?iaio? aeine?aeaeaii i?ioeane, ui
i?ioiaeyoue i?e oi?ioaaii? o?eaceiai?nieo iai?a-AIN o i?enooiino?
aeenia?niiai ? aieieienoiai iaiiaithaa/?a c ??ciith i?e?iaeith iiaa?oi?,
aeine?aeaeaii aeanoeaino? iaiiaiaieo iai?a-AIN.

1. Aia?oa io?eiai? iaiiaiai? iai?a-AIN aeaio aeae?a: 1 — ia iniia?
n?o/anoiai eiiie?ia?o aeeoe?aiiaiai ao??o a?no?iieo A c aiieneie?aiia?ii
AAe-20 ? e?i?eiiai iie?o?aoaio; 2 — ia iniia? n?o/anoiai eiiie?ia?o
oa?iiia?iaeaiiai 4,4‘-ae?oai?eiaoaiae??cioe?aiaoo c aiieneie?aiia?ii
AAe-20 ? e?i?eiiai iie?o?aoaio. Aeine?aeaeaii e?iaoeeo oi?ioaaiiy,
oaciao no?oeoo?o oa aeaye? aeanoeaino? iaiaiiaiaieo ? iaiiaiaieo
iai?a-AIN oa ?oi?o ?iaeea?aeoaeueieo eiiiiiaio?a.

2. Aea/aiiy o?i?/ieo i?ioean?a, ui i?io?eathoue i?e neioac? eiiie?ia?o
aeeoe?aiiaiai ao??o a?noaiieo A ? aiieneie?aiia?o AAe-20 o i?enooiino?
aieieienoiai iaiiaithaa/a ? eiiie?ia?o oa?iiia?iaeaiiai
4,4(-ae?oai?eiaoaiae??cioe?aiaoo ? aiieneie?aiia?o AAe-20 o i?enooiino?
aeenia?niiai iaiiaithaa/a iieacaei, ui iaiiaithaa/? i?enei?ththoue
?aaeoe?? aca?iiae?? aiieneaeieo a?oi ye ?c oe?aiaoieie, oae ? c
?cioe?aiaoieie a?oiaie, a oaeaee?noue ?aaeoe?? oe?eeio?eia?ecaoe??
cieaeo?oueny, i?e/iio oeae aoaeo a?eueo ae?aaeaiee i?e aaaaeaii?
iiaeeo?eiaaiiai iaiiaithaa/a a ii??aiyii? c aeo?aeiei iaiiaithaa/ai.

3. Anoaiiaeaii, ui iaiiaithaa/, aaaaeaiee o iai?a-AIN, aieeaa? ia
oi?ioaaiiy n?o/anoiai eiiiiiaioa, aeeeeeath/e aei i?enei?aiiy iniiaieo
?aaeoe?e. I?e/eiith oeueiai iiaea aooe aaeni?aoe?eia aca?iiae?y
ooieoe?iiaeueieo a?oi ?aaeoe?eii? noi?o? c iiaa?oiath iaiiaithaa/a, ui
aaaea aei c?inoaiiy oii?yaeeoaaiiy iieaeoe a aaeni?aoe?eiiio oa??.

4. Ia i?aenoaa? ?acoeueoao?a aeine?aeaeaiue, i?iaaaeaieo iaoiaeaie
aeeiai?/iiai iaoai?/iiai aiae?co ? aeeoa?aioe?aeueii? neaioth/i?
eaei?eiao??? aeiaaaeaii, ui iai?a-AIN ? aeaioacieie nenoaiaie. Aaaaeaiiy
a iai?a-AIN iaiiaithaa/?a ni?ey? iiaeeaeaiith i?ioeano i?e?ioaciaiai
?icae?eaiiy, ui iiynith?oueny naeaeoeaiith aaeni?aoe??th iaeiiai c
eiiiiiaio?a ia iiaa?oi? iaiiaithaa/a. Anoaiiaeaii, ui iiaeeo?eiaai?
iaiiaithaa/? ((-Fe2O3, ia?iaeaiee iiaa?oiaai-aeoeaiith ?a/iaeiith ?
iiaeeo?eiaaia aoaeaoeaaa aieieii c oinoi?iieeneeie a?oiaie ia iiaa?oi?)
ni?eythoue ciaioaiith nooiaiy i?e?ioaciaiai ?icae?eaiiy a ii??aiyii? c
nenoaiaie, iaiiaiaieie aeo?aeieie iaiiaithaa/aie.

5. Iieacaii, ui iaiiaiaia aaeeeith e?euee?noth oinoi?ai?niiai
aoaeaoeaaiai aieieia (aeua 30 ia. %) iai?a-AIN ia iniia? eiiie?ia?o
aeeoe?aiiaiai ao??o a?noaiieo A c aiieneie?aiia?ii AAe-20 ? e?i?eiiai
iie?o?aoaio aieiae?thoue iii?oiei i(?ciaeaeo?e/iei aoaeoii, i?aeaeuaiith
aiaiano?ee?noth o ii??aiyii? c iaiaiiaiaiith iai?a-AIN.

INIIAIEE CI?NO AeENA?OAOe?? AEEEAAeAII A ?IAIOAO

1. A?iaei I.I., Na?a??aa E.I., Ne?i/aiei I.A., Oaeieaea I.I.,
Iaaeaoe?anueea I.N. Aieea iaiiaithaa/a ia noi?ni?noue eiiiiiaio?a o
iai?aaca?iii?iieeieo iie?ia?ieo n?oeao // Eiiiiceoeeiiiua iieeia?iua
iaoa?eaeu. – 1996. – 57. – N. 28 – 35.

2. Na?aaaaa E.I., Neei/aiei A.A., A?iaei A.A., Oaeieaea A.I.,
Iaaeaoeianeay I.N. Aeeyiea (-Fe2O3 ia iee?ioaciaia ?acaeaeaiea a
iieoacaeiii?iieeathueo iieeia?iuo naoeao ia iniiaa iieeo?aoaia e
iieeyiieneecioeeaio?aoa // Aunieiiieae. niaae. Na?.A. – 1996. – O.38,
N5. – N. 913 – 918.

3. Brovko O.O., Sergeeva L.M., Slinchenko O.A., Fainleib O.M. Dinamic
Mechanical Study of Filled Semi-Interpenetrating Polymer Networks:
Influence of (-Fe2O3 on Microphase Structure // Polymer International. –
1996. – 40. – P. 299 – 305.

4. A?iaei I.I., Na?aa?aa E.I., Ne?i/aiei I.A., Oaeieaea I.I.,
Iaaeaoe?anueea I.N. Iaiiaiai? (-Fe2O3 iai?aaca?iii?iieee? iie?ia?i?
n?oee ia iniia? iie?o?aoaio ? iie?aiien??cioe?aio?aoo // Oe?. oei.
aeo?iae. –1996. – O.62, N10. – N.133-139.

5. Naiaiiae/ A.I., Oaeieaea A.I., Na?aaaaa E.I., Iaaeaoeianeay I.N.,
Neei/aiei A.A. Enneaaeiaaiea aeeyiey (-ieene aeaeaca ia i?ioeannu,
i?ioaeathuea a nenoaia iieeo?aoai – aeeecioeeaiao – yiieneaeeaiiaue
ieeaiia? // Aunieiiieae. niaae. Na?.A. – 1997. – O.39, N11 – N. 1755 –
1760.

6. Bartolotta A., Di Marco G., Lanza M., Carini G., D’Angelo G., Tripodo
G., Fainleib A., Slinchenko E., Privalko V. Molecular Mobility in
Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Networks //
J. Adhesion. – 1997. – Vol. 64. – P. 269 – 286.

7. Aeoaeiaa A.E., Iaaaneay I.E., Na?aaaaa E.I., Neei/aiei A.A.,
Eoeueaeoeeay E.A. Aeene?aoii a?ie?iaaiiua oinoi?oaea?iaeiuie aieieiaie
iieo-AIN ia iniiaa niiieeia?ia yiieneoeeaiaoa // Iaoa?eaeu, oaoiieiaee e
eino?oiaiou. – 1998. – N4. – N. 69-73.

8. Fainleib A.M., Seminovych H.M., Slinchenko E.A., Brovko A.A.,
Sergeeva L.M. Kinetic Regularities of Synthesis of Carbon – Fiber
Reinforced Thermostable Polyepoxytriazines // Macromolecules New
Frontiers. Vol. 2 – New Delhi: Allied Publishiers Limited, 1998. – P.
818-822.

9. Bartolotta A., Di Marco G., Lanza M., Carini G., D’Angelo G., Tripodo
G., Fainleib A.M., Slinchenko E.A., Shtompel V.I., Privalko V.P.
Synthesis and Physical Characterization of Semi-IPNs of Linear
Polyurethane and Heterocyclic Network // International Conf. on Polymer
Characterization («Polychar-5»), Programm and Book of Abstracts. –
Denton. – 1997. – P-08.

10. Neei/aiei A.A. Aeeyiea oaea?iaeiuo aieieii ia eeiaoeeo oi?ie?iaaiey
e ayceioi?oaea naienoaa niiieeia?a aeeoeeaiiaiai yoe?a aenoaiiea A e
yiieneaeeaiiaiai ieeaiia?a // O?ceea eiiaeainiaaieo aenieiiieaeoey?ieo
nenoai. Iaoeia? caienee ??aiainueeiai iaae?inoeoooo. – ??aia: ?AeI?. —
1998. – Aei.4. – N. 28 – 30.

11. Ne?i/aiei I.A., Oaioae?e O.A., Oaeieaea I.I. N?o/ano? iie?ia?e ?
iai?a-AIN ia iniia? oa?ii?aaeoeaieo ie?aiienacie?ioe?aio?ao?a // Ainueia
Oe?a?inueea eiioa?aioe?y c aenieiiieaeoey?ieo niieoe. Oace aeiiia?aeae.
– Ee?a. — 1996. – N. 68.

12. Ne?i/aiei I.A., A?iaei I.I., Oaeieaea I.I. Aeanoeaino? oa oaciaa
no?oeoo?a iai?a-AIN, iaiiaiaieo aoaeaoeaaei aieieiii // Ainueia
Oe?a?inueea eiioa?aioe?y c aenieiiieaeoey?ieo niieoe. Oace aeiiia?aeae.
– Ee?a. — 1996. – N. 202.

13. Oaeieaea A.I., Oaioaeee O.A., Neei/aiei A.A., Na?aaaaa E.I.
Eiieo?e?othuea ?aaeoeee i?e neioaca iiaeeoeoee?iaaiiuo iieeo?eaceiia //
Iaaeaeoia?iaeiay eiioa?aioeey «Ooiaeaiaioaeueiua i?iaeaiu iaoee i
iieeia?ao». Oacenu aeieeaaeia. – Iineaa. – 1997. — N. N1-76.

Aiioaoe?y

Ne?i/aiei I.A. Oi?ioaaiiy ? aeanoeaino? iaiiaiaieo iai?a-aca?iii?iieeieo
iie?ia?ieo n?oie ia iniia? iie?aiieneo?eacei?a ? iie?o?aoaio. — ?oeiien.

Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaith eaiaeeaeaoa o?i?/ieo iaoe
ii niaoe?aeueiino? 02.00.06 – o?i?y aenieiiieaeoey?ieo niieoe. —
?inoeooo o?i?? aenieiiieaeoey?ieo niieoe IAI Oe?a?ie, Ee?a, 1999.

Aeena?oaoe?th i?enay/aii ieoaiiyi aeine?aeaeaiiy i?ioeano oi?ioaaiiy
iaiiaiaieo o?eaceiai?nieo iai?a-AIN. Aea/aiiy o?i?/ieo i?ioean?a, ui
i?io?eathoue i?e neioac? iaiiaiaieo eiiie?ia??a aeeoe?aiaoo c
aiieneie?aiia?ii oa ae??cioe?aiaoo c aiieneie?aiia?ii iieacaei, ui a
oaeeo nenoaiao oaeaee?noue ?aaeoe?? ooai?aiiy ienacie?iia?o oa
ienacie?ae?iiiia?o oeeee?a aeua o ii??aiyii? c iaiaiiaiaieie, ?aaeoe??
iie?oeeeeio?eia?ecaoe?? oe?aiao?a ? ?cioe?aiao?a niia?eueiththoueny.
Iieacaii, ui aaaaeaiiy iaiiaithaa/?a a iai?a-AIN, ye i?aaeei, ca?eueoo?
oaeaee?noue aca?iiae?? ?aaeoe?eieo a?oi o nenoai?. Aeine?aeaeaiiy
a’yceii?oaeieo aeanoeainoae iaiiaiaieo iai?a-AIN iieacaei, ui aaaaeaiiy
iaiiaithaa/?a ca?eueoo? nooi?iue i?e?ioaciaiai ?icae?eaiiy eiiiiiaio?a
iai?a-AIN. Iieacaii, ui iiaa?oiaaa iiaeeo?eaoe?y iaiiaithaa/?a ?noioii
aieeaa? ia i?e?ioaciaa ?icae?eaiiy o iai?a-AIN.

Eeth/ia? neiaa: iai?aaca?iii?iieei? iie?ia?i? n?oee, iaiiaithaa/,
i?e?ioaciaa ?icae?eaiiy, e?iaoeea oi?ioaaiiy, iie?o?eacei, ienacie?i,
ienacie?ae?iii.

Aiiioaoeey

Neei/aiei A.A. Oi?ie?iaaiea e naienoaa iaiieiaiiuo
iieo-acaeiii?iieeathueo iieeia?ieo naoie ia iniiaa iieeyiieneo?eaceiia
e iieeo?aoaia. — ?oeiienue.

Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa oeie/aneeo iaoe ii
niaoeeaeueiinoe 02.00.06 – oeiey aunieiiieaeoey?ieo niaaeeiaiee. —
Einoeooo oeiee aunieiiieaeoey?iuo niaaeeiaiee IAI Oe?aeiu, Eeaa, 1999.

?anniio?aiea e aiaeec ?aaio, iinayuaiiuo aeeyieth iaiieieoaeae ia
naienoaa AIN, iieacae, /oi aeaiiay i?iaeaia a ianoiyuaa a?aiy
aeooaeueia, aa ?aoaiea iicaieyao i?iaiice?iaaoue oeceei-oeie/aneea
oa?aeoa?enoeee iaiieiaiiuo AIN, /oi aanueia aaaeii i?e iieo/aiee
eiiiiceoeeiiiuo iieeia?iuo iaoa?eaeia. A aeaiiie ?aaioa enneaaeiaaiu
i?ioeannu, i?ioiaeyuea i?e oi?ie?iaaiee o?eaceiniaea?aeaueo iieo-AIN a
i?enoonoaee iaiieieoaeae, enneaaeiaaiu iaeioi?ua naienoaa iaiieiaiiuo
iieo-AIN.

Oeaeueth ianoiyuae ?aaiou auei onoaiiaeaiea eeiaoe/aneeo caeiiiia?iinoae
oi?ie?iaaiey o?eaceiniaea?aeaueo iieo-AIN a i?enoonoaee aeenia?niiai e
aieieienoiai iaiieieoaeae n ?aciie i?e?iaeie iiaa?oiinoe, enneaaeiaaiea
oaciaie no?oeoo?u e iaeioi?uo naienoa iieo/aaiuo iaiieiaiiuo iieo-AIN.

Iauaeoaie enneaaeiaaiee auee aeaa iaiaiieiaiiua iieo-AIN: ia iniiaa
nao/aoiai niiieeia?a aeeoeeaiiaiai yoe?a aenoaiiea A n yiieneieeaiia?ii
e eeiaeiiai iieeo?aoaia; ia iniiaa nao/aoiai niiieeia?a
oa?iiia?aaioaiiiai 4,4′-aeeoaieeiaoaiaeeecioeeaiaoa n yiieneieeaiia?ii e
eeiaeiiai iieeo?aoaia. A oaeaea iaiieiaiiua iieo-AIN yoeo aea ninoaaia.
Iaiieieoaeyie neoaeeee: aeenia?niue ii?ioie (-Fe2O3 ia?ee OE-eeneue e
oaea?iaeiia aieieii, iieo/aaiia iooai ea?aiiecaoeee aeae?aooeaeetheiciuo
aieieii.

Iniiaiua ?acoeueoaou ?aaiou iieo/aiu n eniieueciaaieai nia?aiaiiuo
iaoiaeee e iaoiaeia enneaaeiaaiee: eio?ae?aniie niaeo?ineiiee,
aeeooa?aioeeaeueiie neaie?othuae eaei?eiao?ee, aeeooa?aioeeaeueiiai
oa?ie/aneiai aiaeeca, aeeiaie/aneiai iaoaie/aneiai aiaeeca.

A ?acoeueoaoa i?iaaaeaiiuo enneaaeiaaiee aia?aua iieo/aiu iaiieiaiiua
iieo-AIN ia iniiaa nao/aouo o?eaceiniaea?aeaueo niiieeia?ia e eeiaeiiai
iieeo?aoaia.

Eco/aiea oeie/aneeo i?ioeannia, eioi?ua i?ioaeatho i?e neioaca aeaoo
niiieeia?ia: niiieeia?a aeeoeeaiiaiai yoe?a aenoaiiea A n
yiieneieeaiia?ii YAe-20 a i?enoonoaee aieieienoiai iaiieieoaey e
niiieeia?a oa?iiia?aaioaiiiai 4,4’-aeeoaieeiaoaiaeeecioeeaiaoa n
yiieneieeaiia?ii YAe-20 a i?enoonoaee aeenia?niiai iaiieieoaey iieacaei,
/oi iaiieieoaee oaaee/eaatho nei?inoue ?aaeoeee acaeiiaeaenoaey
yiieneaeiuo a?oii eae n oeeaiaoiuie, oae e n ecioeeaiaoiuie a?oiiaie,
nei?inoue aea ?aaeoeee oeeeeio?eia?ecaoeee i?e yoii nieaeaaony. I?e/ai
aaee/eia yoiai yooaeoa auoa i?e aaaaeaiea iiaeeoeoee?iaaiiiai
iaiieieoaey ii n?aaiaieth n iaiiaeeoeoee?iaaiiui. Yoi iauyniyaony
aiciiaeiui acaeiiaeaenoaeai ?aaeoeeiiiiniiniaiuo a?oii aieieia n
yiieneaeiuie e oeeaiaoiuie a?oiiaie a i?ioeanna neioaca niiieeia?a.

Onoaiiaeaii, /oi iaiieieoaeue, aaaaeaiiue a iieo-AIN, aeeyao ia
oi?ie?iaaiea nao/aoiai eiiiiiaioa, i?eaiaey e onei?aieth iniiaiuo
?aaeoeee.

Ia iniiaaiee ?acoeueoaoia enneaaeiaaiee, i?iaaaeaiiuo iaoiaeaie
aeeiaie/aneiai iaoaie/aneiai aiaeeca e aeeooa?aioeeaeueiie neaie?othuae
eaei?eiao?ee iieacaii, /oi iieo-AIN yaeythony aeaoooaciuie nenoaiaie.
Aaaaeaiea a iieo-AIN iaiieieoaeae niinianoaoao oaeoaeaieth i?ioeanna
iee?ioaciaiai ?acaeaeaiey, /oi iauyniaii ecae?aoaeueiie aaeni?aoeeae
iaeiiai ec eiiiiiaioia ia iiaa?oiinoe iaiieieoaey. Onoaiiaeaii, /oi
iiaeeoeoee?iaaiiua iaiieieoaee ((-Fe2I3, ia?aaioaiiue
iiaa?oiinoiiaeoeaiui aauanoaii e oaea?iaeiia aieieii n oinoi?iieeneuie
a?oiiaie ia iiaa?oiinoe) niinianoaotho oiaiueoaieth o?iaiy iee?ioaciaiai
?acaeaeaiey ii n?aaiaieth n nenoaiaie, iaiieiaiiuie enoiaeiuie
iaiieieoaeyie.

Iieacaii, /oi iaiieiaiiay aieueoei eiee/anoaii oinoi?niaea?aeauaai
oaea?iaeiiai aieieia (auoa 30 ia.%) iieo-AIN ia iniiaa eeiaeiiai
iieeo?aoaia e nao/aoiai niiieeia?a aeeoeeaiiaiai yoe?a aenoaiiea A n
yiieneieeaiia?ii YAe-20 iaeaaeaao caiaoiui iueaciyeaeo?e/aneei yooaeoii,
iiauoaiiie iaianoieeinoueth ii n?aaiaieth n iaiaiieiaiiie iieo-AIN.

?acoeueoaou enneaaeiaaiee oi?ie?iaaiey e naienoa iaiieiaiiuo iieo-AIN
iiaoo auoue eniieueciaaiu i?e iieo/aiee eiiiiceoeeiiiuo iieeia?iuo
iaoa?eaeia ia eo iniiaa. Yenia?eiaioaeueiua aeaiiua aeatho aiciiaeiinoue
?aeiiaiaeiaaoue iaiieiaiiua iieo-AIN ia iniiaa nao/aoiai niiieeia?a
aeeoeeaiiaiai yoe?a aenoaiiea A n yiieneieeaiia?ii YAe-20 e eeiaeiiai
iieeo?aoaia a ea/anoaa iueaciyeaeo?eea.

Eeth/aaua neiaa: iieoacaeiii?iieeathuea iieeia?iua naoee, iaiieieoaeue,
iee?ioaciaia ?acaeaeaiea, eeiaoeea oi?ie?iaaiey, iieeo?eacei, ienacieei,
ienacieeaeeiii.

Summary

Slinchenko O.A. Formation and properties of filled semi-interpenetrating
polymer networks based on polyepooytriazines and polyurethane. –
Manuscript.

Thesis for a Candidate of Chemical Sciences Degree, Speciality 02.00.06
– Nhemistry of Macromolecular Compounds. – Institute of Macromolecular
Chemistry of NAS of Ukraine, Eyiv, 1999.

The dissertation is devoted to design topics connected with the
investigation of formation process of triazinecontaning semi-IPNs.
Investigation of chemical process( of synthesis of filled copolymer
based on dicyanate and epooyoligomer and filled copolymer based on
diisocyanate and epooyoligomer shows the increasing of speed of response
ooazoline/ooazolidinone formation while the speed of triazines formation
decreases in comparison with unfilled copolymers. Introduction of the
filler into the semi-IPNs during formation have been shown to increase
the speed of interaction reactive groups in system. It is shown that a
modification of filler surface affects on the microphase segregation in
filled semi-IPNs.

Eey words: semi-interpenetrating polymer networks, filler, microphase
segregation, formarion kinetic, polytriazine, ooazoline, ooazolidinone.

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