AeA?AEAAIEE OI?AA?NEOAO “EUeA?ANUeEA IIE?OAOI?EA”
Ia i?aaao ?oeiieno
IA?AEOIEI Oaia?a A?eoi??aia
OAeE 661.832; 661.846(088.8)
?ioaineo?eaoe?y i?ioean?a eiiieaenii? ia?a?iaee iie?i?ia?aeueieo
eae?eieo ?oae I?eea?iaooy canoinoaaiiyi i?aai?/ieo ?aa(aio?a ?
?ic/eiiee?a
05.17.01. Oaoiieia?y iai?aai?/ieo ?a/iaei
AAOI?AOA?AO
aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy
aeieoi?a oaoi?/ieo iaoe
EUeA?A – 1998
Aeena?oaoe?y ? ?oeiien.
?iaioa aeeiiaia a Aea?aeaaiiio oi?aa?neoao?
“Euea?anueea iie?oaoi?ea”
Iaoeiaee eiinoeueoaio Caneoaeaiee ae?y/ iaoee ? oaoi?ee Oe?a?ie,
aeieoi? oaoi?/ieo iaoe, i?ioani?
ssai?nueeee A?eoi? Oaio?eiae/
AeO “Euea?anueea iie?oaoi?ea”, caa. eao. OOI?
Io?oe?ei? iiiiaioe aeieoi? oaoi?/ieo iaoe, i?ioani?
A?aeca? Eaii?ae Ieeieaeiae/,
Iaeanueeee aea?aeaaiee iie?oaoi?/iee oi?aa?neoao, eaoaae?a;
aeieoi? oaoi?/ieo iaoe, i?ioani?
Naiaieoei ?aaai Ieoaeeiae/,
Aea?aeaaiee oi?aa?neoao
(Euea?anueea iie?oaoi?ea(,eaoaae?a O?IA;
aeieoi? oaoi?/ieo iaoe, i?ioani?
Oaaa? Ieeiea Aaneeueiae/,
AAO (I??aia(, i.Eaeoo, ?aaii-O?aie?anueei? iae., ia?oee
a?oea-i?aceaeaio.
I?ia?aeia onoaiiaa – Oa?e?anueeee aea?aeaaiee iie?oaoi?/iee oi?aa?neoao,
i. Oa?e?a.
Caoeno aeena?oaoe?? a?aeaoaeaoueny “” 1998 ?ieo i 14 aiae. ia can?aeaii?
niaoe?ae?ciaaii? a/aii? ?aaee Ae 35.052.09 i?e Aea?aeaaiiio oi?aa?neoao?
“Euea?anueea iie?oaoi?ea” ca aae?anith : 290646, i. Euea?a-13,
ie. Na. TH?a, 3/4, ei?ion 9, aoae.214.
C aeena?oaoe??th iiaeia iciaeiieoeny a a?ae?ioaoe? Aea?aeaaiiai
oi?aa?neoaoo “Euea?anueea iie?oaoi?ea”
Aaoi?aoa?ao ?ic?neaiee “ ” 1998?.
A/aiee nae?aoa? niaoe?ae?ciaaii?
?aaee, e.o.i., aeioeaio ss.?.Aaooea
Caaaeueia oa?aeoa?enoeea ?iaioe
Aeooaeuei?noue oaie . Oe?a?ia aieiae?? ?aeeiei ? iaeiei c iaea?eueoeo a
na?o? I?eea?iaonueeei ?iaeiaeuai iie?i?ia?aeueieo eae?eieo ?oae
noeueoaoiiai oeio, yea ca neeaaeii nieae oa oiiaaie ?o caeyaaiiy ia ia?
aiaei??a. Ca oiia eiiieaenii? ia?a?iaee oaeeo ?oae iiaeia, e??i
aacoei?eaeieo eae?eieo aeia?ea, iaea?aeoaaoe e ?io? aenieiye?ni?
i?iaeoeoe: ieneae ? oei?eae ia?i?th, iaoae?/iee ia?i?e, eooiiio n?eue,
oaoi?/iee oei?eae iao??th, eaonoe/io niaeo, oei? oiui.
Ianya aeaeiaoaaiiy ? ia?a?iaee iie?i?ia?aeueieo ?oae I?eea?iaooy
iaia?a?aii c?inoaa ? a /an iae?ioaineai?oi? aenieoaoaoe?? ?iaeiaeu (80-?
?iee) nyaioa ia Eaeonueeiio eiioea?i? “I??aia” 2,2 iei. o, a ia
Noaaieoeueeiio Aea?aeaaiiio a??ie/i-o?i?/iiio i?aei?e?inoa? (AeAOI)
“Iie?i?ia?ae” – iiiaae 2,5 iei. o ia ??e. I?e oeueiio ae?iaeyeinue 220
oen. o aeia?ea a ia?a?aooieo ia 100% E2I o aeaeyae? eae?ia?iac??
(noeueoaoo eae?th-ia?i?th), /anoeiai noeueoaoo eae?th oa
eae?eii-ia?i?eiaiai eiioeaio?aoo. I?ioa iaaeniea eiioeaio?aoe?y
ei?enii? ?a/iaeie (8…10% E2I), ?icia?o?noue i?ia?aeueiiai neeaaeo
(iiiaae 16 i?ia?ae?a), i?aeaeuaiee ai?no aeeienoeo ?a/iaei coiiaeee
iecueeee nooi?iue aeeo/aiiy ei?enieo eiiiiiaio?a ?oaee ?, cie?aia, nieae
eae?th (aei 50%), iaaenieo ye?noue eae?eieo aeia?ea a ae?th/eo
oaoiieia?yo. Oae, c iaei??? oiiie ia?a?iaeaii? ?oaee ooai?th?oueny
0,7…0,8 o a?aeoiae?a, ye? ? aeaea?aeii aeieia?/ii? iaaaciaee ?
neeaaeoaaiiy yeeo aeiaaa? cia/ieo eioo?a. Iaea?aeaia eae?iaaiac?y ?
iecueeiye?niei ? iaeo?aioiicaeaoiei aeia?eaii, yea ia a?aeiia?aea?
aeiiaai aa?iaeieia?? oa caa?aaeaiiy (?oio?a, ia iiaea aiineoenue i?ae
oei?ioiai? n?euenueeiainiiaea?nuee? eoeueoo?e. Oeeie ianoaaeiaie ca oiia
caaaeueii? e?ece aeiiii?ee a e?a?i? iiynith?oueny oie oaeo, ui i?e
iio?aa? Oe?a?ie a 1,5…2,0 iei. o eae?eieo aeia?ea a ia?a?aooieo ia E2I
nueiaiaei? ae?iaey?oueny ?o o?eueee 100 oen. o ia ??e.
Iaeiei c aaaaoioiiaaeieo a?aeoiae?a ae?iaieoeoaa eae?eieo aeia?ea ?
eiioeaio?iaai? ?ic/eie oei?eaeo ia(i?th, iaeiie/aiiy yeeo aaeueio?
caeo/aiiy o ae?iaieoeoai iiaeo ia?niaeoeaieo ?iaeiaeu eae?eieo ?oae
I?eea?iaooy. A oie aea /an oe? ?ic/eie iiaeooue neoaeeoe ne?iaeiith aeey
iaea?aeaiiy aino?iaeao?oeeoiiai i?iaeoeoo – aenieiye?niiai ieneaeo
ia(i?th, yeiai Oe?a?ia ia ae?iaey? oe?eeii, ui aeanoue ciiao ia eeoa
caaeia?eueieoe ?nioth/ee iiieo ia oeae i?iaeoeo, a e cia/ii i?aeaeueoe
?aioaaaeuei?noue ae?iaieoeoaa eae?eieo aeia?ea.
Ioaea, aeey ?noioiiai iie?ioaiiy iieaciee?a ?iaioe eae?eieo i?aei?e?inoa
I?eea?iaooy iio??ai? iia? i?aeoiaee, ye? ae??oeee a ieoaiiy eiiieaeniiai
aeei?enoaiiy eiiiiiaio?a ne?iaeie, ?icoe?aiiy ani?oeiaioo oa yeino?
oiaa?ii? i?iaeoeoe??, aia?aicaa?aaeaiiy oa aeieia?/ii? aaciaee
ae?iaieoeoaa. Ae??oaiiy cacia/aieo caaaeaiue ia? aaaeeeaa iaoeiaa oa
ia?iaeiiainiiaea?nueea cia/aiiy, iaeiae, ye na?ae/eoue aeina?ae eae?eii?
i?iieneiaino? Oe?a?ie oa ?ioeo e?a?i, ?ica’ycaoe oeth i?iaeaio
o?aaeeoe?eieie oaoiiei(?/ieie aai oaoi?/ieie ??oaiiyie iaiiaeeeai.
Iaeia?niaeoeai?oei a oeueiio iai?yieo ? aeei?enoaiiy a i?ioeanao
o?aaeeoe?eii? aaeo?a?eii? oaoiiei(?? naeaeoeaieo ?aa(aio?a oa
?ic/eiiee?a, ye? caaacia/othoue ?icae?eaiiy neeaaeieo aaaaoieiiiiiaioieo
nenoai, ooai?aieo a i?ioeanao ia?a?iaee a?o/eciyii? iie?i?ia?aeueii?
eae?eii? ?oaee, iaea?aeaiiy aaaeaieo i?iaeoeo?a c aenieei aeoyaii ?
iaeaaeiith /enoioith, iie?auaiiy ?ioeo o?ceei-o?i?/ieo aeanoeainoae
iaea?aeaieo i?iaeoeo?a, ?ioaineo?eaoe?th i?ioean?a oa ciaioaiiy
aia?aiaeo?ao. Naia oeae oeyo aea?aiee iaie aeey ae??oaiiy
noi?ioeueiaaieo aeooaeueieo caaaeaiue eae?eii? i?iieneiaino?, /iio ?
i?enay/aia aeaia aeena?oaoe?eia ?iaioa.
Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie.
Aeena?oaoe?eia ?iaioa aeeiiaia o a?aeiia?aeiino? aei iai?yie?a
Aea?aeaaii? iaoeiai-oaoi?/ii? i?ia?aie 04.14.07 “Noai?aiiy iiaiai
oaoiiei??/iiai i?ioeano iaea?aeaiiy ieneaeo ia?i?th c ?ic/ei?a oei?eaeo
ia?i?th, aeieii?o?a oa ?ioi? ia?iac?aeueii? ne?iaeie” (Iinoaiiaa
Aea?aeaaiiai eii?oaoo Oe?a?ie c ieoaiue iaoee ? oaoiiei??e N52 a?ae
18.06.1993 ?.) oa “Noai?aiiy oaoiiei??? iaea?aeaiiy aacoei?eaeieo
eae?eieo aeia?ea ia iniia? aenieioei?eaeieo i?iaeoeo?a eae?eieo
ae?iaieoeoa I?eea?iaooy” (Iinoaiiaa AeEIO Oe?a?ie N110 a?ae 14.07.1994
?.), ieaio iaeaaaeeea?oeo iaoeiai-aeine?aeieo ?ia?o ii oai? “?ic?iaea
oaoiiei??/iiai i?ioeano iaea?aeaiiy ia?iac?? c ae?iaie/eo ?ic/ei?a
oei?eaeo ia?i?th” (iaeac I?iaoco ANNI O?N? N456 a?ae 15.12.1982 ?.),
??oaiue oaoi?/ii? ?aaee AI “Nithceae?e” (i?ioieie a?ae 26.04.1982 ?.),
Noaaieoeueeiai eae?eiiai caaiaeo (i?ioieiee a?ae 1.02.1984 ?. oa
14-19.06.1991 ?.), ieai?a iaoeiai-aeine?aeieo ?ia?o Aea?aeaaiiai
oi?aa?neoaoo “Euea?anueea iie?oaoi?ea”.
Iaoa ? caaaeaiiy aeine?aeaeaiue. Iaoith ?iaioe aoei iaoeiaa
ia??oiooaaiiy ? i?aeoe/ia ?aae?caoe?y i?eioeeiiai iiaeo oaoiiei??e
ooee?caoe?? a?aeo?aeieo ?ic/ei?a eae?eieo ae?iaieoeoa ? iaeiiaeeoe?eiiai
iai?ai?iaeoeoo (oai?oo) o aenieiye?ni? oiaa?i? i?iaeoeoe – ieneae
ia?i?th oa eae?ei? aacoei?eaei? aeia?eaa – ca aeiiiiiaith i?aai?/ieo
?ic/eiiee?a ? ?aa?aio?a, ui caaacia/eoue ?ioaineo?eaoe?th i?ioean?a
eiiieaenii? ia?a?iaee iie?i?ia?aeueieo eae?eieo ?oae I?eea?iaooy.
Aeey aeinyaiaiiy iinoaaeaii? iaoe iaiao?aeii aoei ae??oeoe oae? iniiai?
caaaeaiiy:
– aeyaeoe iaaeie?ee ? ?aca?ae no/anii? oaoiiei??? eae?eieo aeia?ea ia
iniia? iie?i?ia?aeueieo eae?eieo ?oae I?eea?iaooy;
– aecia/eoe iaiao?aei? iai?yiee canoinoaaiiy oa ?ic?iaeoe
iaoiaeieia?/i? iniiae oe?eani?yiiaaiiai i?aeai?o naeaeoeaieo ?aa?aio?a ?
?ic/eiiee?a aeey ?ioaineo?eaoe?? i?ioean?a eiiieaenii? ia?a?iaee
iie?i?ia?aeueieo eae?eieo ?oae;
– cai?iiiioaaoe niiniae oa aoaeoeai? i?ioeane, ?ic?iaeoe o?ceei-o?i?/i?
iniiae ia?a?iaee a?aeo?aeieo oei?eaeia?i?eiaeo ?ic/ei?a eae?eii?
i?iieneiaino? o aeniei/enoee ieneae ia?i?th aoaiieai?iiaei niiniaii;
ooee?caoe?? caneeaaeiaaieo noeueoaoai?nieo ?ic/ei?a o aacoei?eaei?
eae?ei? aeia?eaa oa cianoeueoa/aiiy ae?iaie/eo ?ic/ei?a ca aeiiiiiaith
inaaeaeoaa/?a aea??eiai? ae??; iaea?aeaiiy aacoei?eaeieo eae?eieo
aeia?ea c aenieioei?eaeieo ae?iaie/eo iai?ai?iaeoeo?a aeno?aeoe??th
oei?eae?a i?aai?/ieie ?ic/eiieeaie;
– aecia/eoe iioeiaeuei? oaoiiei??/i? ia?aiao?e cai?iiiiiaaieo i?ioean?a,
noai?eoe a?aeiia?aei? oaoiiei??/i? noaie, aeaeaoe aeo?aei? aeai? ia
i?iaeooaaiiy aeine?aeieo ? aeine?aeii-i?iieneiaeo onoaiiaie;
– ia i?aenoaa? ?ic?aooie?a iniiaieo oaoi?ei-aeiiii?/ieo iieaciee?a
?ic?iaeaieo oaoiiei??e ioe?ieoe ?o aoaeoeai?noue ? ii??aiyoe c
?nioth/eie i?ioioeiaie o?aaeeoe?eii? iai?aai?/ii? oaoiiei???.
Iaoeiaa iiaecia iaea?aeaieo ?acoeueoao?a. A ?iaio? ie?aneaiee,
oai?aoe/ii ia??oioiaaiee ? i?aeoe/ii ?ic?iaeaiee iiaee iai?yiie
?ioaineo?eaoe?? i?ioean?a eiiieaenii? ia?a?iaee iie?i?ia?aeueieo
eae?eieo ?oae I?eea?iaooy, iniaeea?noue yeiai iieyaa? a canoinoaaii?
i?aai?/ieo ?aa?aio?a ? ?ic/eiiee?a naeaeoeaii? ae?? o cai?iiiiiaaieo
iiaeo oaoiiei??yo aeniei/enoiai ieneaeo ia?i?th, iiaii? ooee?caoe??
??aeeeo a?aeoiae?a eae?eieo ae?iaieoeoa oa iaea?aeaiiy eiiaeeoe?eieo
aacoei?eaeieo aeia?ea.
Aia?oa a i?aeoe/iiio ?ioa?aae? ci?i ia?aiao??a ?ic?iaeai? o?ceei-o?i?/i?
iniiae cai?iiiiiaaieo i?ioean?a, a naia ciaeaeaii:
– iaoai?ci ? e?iaoe/i? oa?aeoa?enoeee inaaeaeaiiy a?ae?ieneaeo ia?i?th c
?ic/ei?a oei?eaeo ia?i?th aoaiieai?iaie;
– e?iaoe/i? ia?aiao?e i?ioeano aca?iiae?? oei?eaeo iiiiaoaiieaiii?th a
?ic/ei? c oaa?aeei ieneaeii eaeueoe?th;
– aeai? c ?ic/eiiino? a nenoaiao IAA-I2I-EN?, IAA-I2I-NaN?,
IAA-I2I-NaN?2, IAA-I2I-EN?-NaN?-NaN?2 ca oaiia?aoo? eei?iiy, a nenoaiao
AeAA-I2I-EN?, AeAA-I2I-NaN?, AeAA-I2I-NaN?2, AeAA-I2I-EN?-NaN?2 a
oaiia?aoo?iiio ?ioa?aae? 20…80iN, a nenoaiao IAA.IN?-I2I-EN?,
IAA.IN?-I2I-NaN?, IAA.IN?-I2I-E2SI4, IAA.IN?-I2I-IgSI4 a oaiia?aoo?iiio
?ioa?aae? 20…50iN; a’yce?noue oa aonoeio ??aeeeo oac a oeeo nenoaiao;
– eiioeaio?aoe?ei? oa oaiia?aoo?i? iaae? ?nioaaiiy ??aiiaaaeieo oaa?aeeo
oac a aeuacacia/aieo nenoaiao;
– aeai? c ia?i-??aeeiii? ??aiiaaae a nenoai? IAA-I2I a iaeano? oene?a,
ieae/eo a?ae aoiinoa?iiai; oa?aeoa?enoeee aieeao ?ic/eiaieo oei?eae?a
eae?th, iao??th ? eaeueoe?th ia a?aeiinio eaoe?noue aiaeyieo ia??a a
oe?e nenoai?;
– caeaaeiino? aieeao i?e?iaee i?aai?/iiai inaaeaeoaa/a oa eiai
e?eueeino? ia nooi?iue cianoeueoa/aiiy ?ic/ei?a;
– caeiiii??iino? ci?ie o?i?/iiai neeaaeo iaea?aeaiiai aeia?eaa a
caeaaeiino? a?ae i?e?iaee aeno?aaaioa, eiai eiioeaio?aoe??,
ni?aa?aeiioaiiy i?ae ??aeeith ? oaa?aeith oacaie, ia?aa?ao aoi?eiieo
?aaeoe?e a i?ioean? aeeo/aiiy oei?eae?a c oaa?aei? noi?o? nieae
aeno?aaaioaie ia iniia? IAA.
Iaea?aeai? iia? iaoeia? aeai? neeaee oai?aoe/io iniiao aeey aecia/aiiy
iioeiaeueieo ia?aiao??a ? noai?aiiy iiaeo oaoiiei??/ieo i?ioean?a
iaea?aeaiiy aeniei/enoiai ieneaeo ia?i?th c a?aeo?aeieo ?ic/ei?a oa
aacoei?eaeieo eae?eieo aeia?ea c iaeiiaeeoe?eieo oaa?aeeo
iai?ai?iaeoeo?a eae?eieo ae?iaieoeoa I?eea?iaooy.
Iaoa??aee aeeiiaieo aeine?aeaeaiue iiaeooue aooe aeei?enoai? aeey
aeiiiaiaiiy aeia?aeeiai? e?oa?aoo?e aeaieie c o?ceei-o?i?/ieo
aeanoeainoae ? aaoa?iaaiii? ??aiiaaae aea/aieo nieueiaeo nenoai o
aiaeii-i?aai?/iiio na?aaeiaeu?.
Oa?aeoa?i? iniaeeaino?, ei?eni?noue ? iiaecia iaea?aeaieo a ?iaio?
?acoeueoao?a i?aeoaa?aeaeai? 10 aaoi?nueeeie na?aeioeoaaie.
I?aeoe/ia cia/aiiy iaea?aeaieo ?acoeueoao?a. ?ic?iaeai? oaoiiei???
aeniei/enoiai ieneaeo ia?i?th, aacoei?eaeieo eae?eieo aeia?ea,
cianoeueoa/aiiy ae?iaie/eo ?ic/ei?a ae??oothoue aaaeeea? i?iaeaie
eiiieaenii? ia?a?iaee iie?i?ia?aeueieo eae?eieo ?oae I?eea?iaooy c oi/ee
ci?o ?ano?ni-, aia?aicaa?aaeaiiy oa aeieia??.
Cai?iiiiiaaia oaoiiei(?y ieneaeo ia?i?th aeniei? /enoioe aeanoue ciiao
iiai?noth ia?a?iaeoe a?aeo?aei? oei?eaeia?i?eia? ?ic/eie eae?eieo
i?aei?e?inoa ? caaacia/eoe iio?aae iaoaeo?a?eii?, aeaeo?i- oa
(oiioaoi?/ii? aaeocae i?iieneiaino? Oe?a?ie a oeueiio aeao?oeeoiiio
i?iaeoeo? aeniei? aa?oino?. Aeine?aeii-i?iieneiaa aei?iaoaaiiy
?ic?iaeaii? oaoiiei??? ieneaeo ia(i?th iieacaei ?? noaa?euei?noue,
iiaeeea?noue ?aae?caoe?? a na??eiiio a?o/eciyiiio iaeaaeiaii?, eaae?noue
?aaoethaaiiy ia?aiao??a. I?iieneiaa ao?eaiiy ?ic?iaeaii? oaoiiei(??
ia?aaeaa/aia a ieai? ?aeiino?oeoe?? Noaaieoeueeiai AeAOI “Iie?i?ia?ae”.
Aeine?aeia ia?o?y ieneaeo ia?i?th i?ieoea aei?iaoaaiiy a OeIAe? /i?ii?
iaoaeo?a?? ?i. ?.I.Aa?ae?ia (i.Iineaa) ye oa?iino?eea iie?eooy
aeaeo?ioaoi?/ieo noaeae c iiceoeaiei aeniiaeii uiaei eiai aeei?enoaiiy.
Ia a?aei?io a?ae ?nioth/i? oaoiiei??? cianoeueoa/aiiy ae?iaie/eo
?ic/ei?a eae?eieo ae?iaieoeoa ?ic/eiaie oei?eaeo eaeueoe?th a
cai?iiiiiaai?e ?ic?iaoe? c oe??th iaoith aeei?enoiao?oueny i?aai?/iee
inaaeaeoaa/. Oea ci?ia? c i?aei?e?inoa aaeeeo i?iaeaio ia?aaacaiiy
?ic/ei?a oei?eaeo eaeueoe?th oa neeaaeoaaiiy aaaaoioiiaaeieo a?aeoiae?a
a?ino, yeee ca?ac i?aeoe/ii ia aeei?enoiao?oueny. Aei?iaoaaiiy
cai?iiiiiaaii? oaoiiei??? cianoeueoa/aiiy ? iiaii? ia?a?iaee ?ic/ei?a
oainoinoiaeu, aeeiiaia ia oe?oiiai?e aeine?aei?e onoaiiaoe? eaoaae?e
o?i?? ? oaoiiei??? iai?aai?/ieo ?a/iaei AeOEI, iieacaei iiaio
?aeaioe/i?noue aeinyaiooeo oaoiiei??/ieo iieaciee?a iaea?aeaiei a
eaai?aoi?ieo oiiaao.
Oaoiiei??/iee i?ioean iaea?aeaiiy aacoei?eaeieo eae?eieo aeia?ea, aeione
yeeo a Oe?a?i? ca?ac i?aeoe/ii a?aenooi?e, a?aei?aoeueiaaiee a
eaai?aoi?ieo oiiaao. Aeaeai? ?aeiiaiaeaoe?? aeey i?iaeooaaiiy
aeine?aeii? onoaiiaee c aeei?enoaiiyi i?aai?/ieo aeno?aaaio?a aeey
iaea?aeaiiy eiiaeeoe?eieo aeia?ea.
An? cai?iiiiiaai? oaoiiei??? ia?aaeaa/athoue aeei?enoaiiy i?aai?/ieo
?aa?aio?a ? ?ic/eiiee?a a oeeee?, cae?eniththoueny a noaiaea?oiiio
iaeaaeiaii?, oa?aeoa?ecothoueny eaa?aei?noth oaoiiei??/iiai ?aaeeio.
Aeeiiaiee aiae?c ca oaoi?ei-aeiiii?/ieie iieacieeaie iieacaa aacoiiaio
ia?aaaao ? ia?niaeoeai?noue ?ic?iaeaieo iiaeo i?ioean?a a ii??aiyii? c
?nioth/eie i?ioioeiaie o?aaeeoe?eii? iai?aai?/ii? oaoiiei???.
Iniaenoee aianie caeiaoaa/a. Aeena?oaoe?eia ?iaioa ??oioo?oueny ia
iaoa??aeao iaoeiai-aeine?aeieo ?ia?o, aeeiiaieo aaoi?ii ca aeaniith
?i?oe?aoeaith, ye? aa?eoee a ieaie iaoeiai-aeine?aeii? ?iaioe aeeeaaea/a
AeO “Euea?anueea iie?oaoi?ea” ca 1975-1996 ?.?. Aaoi?o iaeaaeeoue
oai?aoe/ia ia??oiooaaiiy, aeeiiaiiy, ia?iaea, aiae?c oa ?ioa?i?aoaoe?y
?acoeueoao?a aenia?eiaioaeueieo aeine?aeaeaiue, ocaaaeueiaiiy
?ioi?iaoe?? oa oi?ioethaaiiy aeniiae?a. Caeiaoaa/ i?eeiaea
aaciina?aaeith o/anoue o aeine?aeieo oa aeine?aeii-i?iieneiaeo
aei?iaoaaiiyo ?ic?iaeaieo oaoiiei??e, aeaea/? aeo?aeieo aeaieo
aeine?aeieo oa aeine?aeii-i?iieneiaeo onoaiiaie.
*anoeia ?ia?o aeeiiaia ca ainiiaea?nueeeie ? aea?aeaaieie caiiaeaiiyie,
aea aeena?oaio aoea ea??aieeii aai a?aeiia?aeaeueiei aeeiiaaoeai. ?e
iaeaaeeoue ?ic?iaea i?ia?ai ? ieai?a oeeo ?ia?o oa ?o aaciina?aaei?
aeeiiaiiy.
O ni?eueieo ioae?eaoe?yo iniaenoee aianie aaoi?a ?iaioe ? aieiaiei.
Ai?iaaoe?y ?acoeueoao?a aeena?oaoe?? . ?acoeueoaoe aeine?aeaeaiue
aeiiia?aeaeenue ia Ananithcieo eiioa?aioe?yo c oaoiiei??? iai?aai?/ieo
?a/iaei ? i?ia?aeueieo aeia?ea (Aei?i?iiao?ianuee, 1976; Iiai/a?eanuee,
1978; *eieaio, 1981; Ai?ueeee, 1985; Euea?a, 1988; Eacaiue, 1991), ia
?anioae?eainuee?e eiioa?aioe?? c aeiiii?? iaeeaii-aia?aaoe/ieo ?ano?n?a
a o?i?/i?e, iaooi-o?i?/i?e ? iaooiia?a?iai?e i?iieneiaino? Oe?a?ie
(?aaii-O?aie?anuee, 1982), ia ?anioae?eainuee?e eiioa?aioe??
“I?aeaeuaiiy aoaeoeaiino?, aaeineiiaeaiiy i?ioean?a oa aia?ao?a o?i?/ieo
ae?iaieoeoa (Euea?a, 1988), ia Ananithci?e ia?aae? “I?iaeaie
nieueaaoaoe?? ? eiiieaeniooai?aiiy a ?ic/eiao” (?aaiiai, 1989), ia
Ananithci?e eiioa?aioe?? “??aeeiii-oacia? iaoa??aee” (?aaiiai, 1990), ia
Ananithci?e eiioa?aioe?? “?ioaineai? ? aaca?aeoiaei? oaoiiei??? oa
iaeaaeiaiiy” (Aieaia?aae, 1991), ia Ananithci?e ia?aae? c
o?ceei-o?i?/iiai aiae?co (Na?aoia, 1991), ia Oe?a?inuee?e eiioa?aioe?? c
iai?aai?/ii? o?i?? (Oaeai?iae, 1992), ia iaoeiai-oaoi?/i?e eiioa?aioe??
“Eae?ei? aeia?eaa Oe?a?ie, noai ? ia?niaeoeae” (Eaeoo, 1994), ia
I?aeia?iaei?e nieueia?e ia?aae? “I?iaeaie oi?ioaaiiy oa aeei?enoaiiy
?iaeiaeu ei?enieo eiiaeei nieueiaeo aanaei?a” (Naieo-Iaoa?ao?a, 1994),
ia ui??/ieo iaoeiaeo eiioa?aioe?yo “Euea?anueei? iie?oaoi?ee”, ia
iaoeia?e eiioa?aioe?? “Euea?anuee? o?i?/i? /eoaiiy-97”, ia oaoi?/ieo
?aaeao Aea?aeeii?oaoo Oe?a?ie c ieoaiue iaoee ? oaoiiei??e.
Ioae?eaoe?? . Iniiai? iieiaeaiiy aeena?oaoe?? iioae?eiaai? o 76
iaoeiaeo i?aoeyo, a o./. 10 aaoi?nueeeo na?aeioeoaao.
Ianya oa no?oeoo?a ?iaioe. Aeena?oaoe?y neeaaea?oueny c anooio, 7
?icae?e?a, aeniiae?a, nieneo aeei?enoaieo e?oa?aoo?ieo aeaea?ae oa
aeiaeaoe?a. Iiaiee ianya aeena?oaoe?? noaiiaeoue 306 noi??iie
iaoeiiieniiai oaenoo, a o./. 96 ?enoie?a, 57 oaaeeoeue ? 6 aeiaeaoe?a ia
103 noi??ieao, a oaeiae 253 iacae aeei?enoaieo e?oa?aoo?ieo aeaea?ae ia
26 noi??ieao.
Iniiaiee ci?no ?iaioe
A ia?oiio ?icae?e? ia i?aenoaa? aeaoaeueiiai ? anaa?/iiai aiae?co
e?oa?aoo?ieo ? iaoaioieo iaoa??ae?a, i?enay/aieo oai??? ? i?aeoeoe?
oaoiiei(?? nieae, aeina?aeo ?iaioe eae?eieo ae?iaieoeoa oiui
ia(?oioiaaii i?eioeeiiai iiaee i?aeo?ae aei oaoiiei(?? ia?a?iaee
iie?i?ia?aeueieo eae?eieo ?oae I?eea?iaooy – canoinoaaiiy i?aai?/ieo
?ic/eiiee?a ? ?aa(aio?a naeaeoeaii? ae??.
A ae?oaiio ?icae?e? ?iaioe ia i?aenoaa? aiae?co o?ceei-o?i?/ieo
aeanoeainoae i?aai?/ieo ?ic/eiiee?a ? ?aa(aio?a a aniaeo? ?o
canoinoaaiiy a oaoiiei(?? eiiieaenii? ia?a?iaee a?o/eciyii? eae?eii?
ne?iaeie cai?iiiiiaai? oae? iniiai? iai?yiee e?ea?aeaoe?? (aocueeeo(
i?noeue ae?th/i? aaeo?a?eii? oaoiiei(?? c aeei?enoaiiyi i?aai?/ieo
?a/iaei:
1) inaaeaeaiiy a?ae?ieneaeo ia?i?th c a?aeo?aeieo oei?eaeia?i?eiaeo
?ic/ei?a oa iaea?aeaiiy c iueiai aeniei/enoiai ieneaeo ia?i?th ?c
caaeaieie aeanoeainoyie;
2) aeno?aeoe?y oei?eae?a c aenieioei?eaeiiai ae?iaie/iai oai?oo c
iaea?aeaiiyi aacoei?eaeiiai eae?eii-ia?i?eiaiai aai eiiieaeniiai
noeueoaoii-i?o?aoiiai aeia?eaa;
ia?a?iaea a?aeo?aeieo nieueiaeo ?ic/ei?a oainoinoiaeu ?icae?eaiiyi
noeueoao?a ? oei?eae?a eae?th, iao??th ? ia?i?th.
Iieacaii, ui i?aai?/ieie ?aa(aioaie, ye? iaea?eueoa a?aeiia?aeathoue
cacia/aiei aeiiaai ? iae/ano?oa aeei?enoiaothoueny a oaoiiei(?? eae?eieo
aeia?ea, ? ae?oaoe/i? nie?oe oa iae??ciiiai?oi?o? ai?ie, cie?aia, ia?o?
aeaa i?aaenoaaieee aiiieia?/iiai ?yaeo aoaiieai?i?a: IAA ? AeAA.
Anoaiiaeaii, ui nie?oe aeno?aaothoue iai?aai?/i? nie? ia?aaaaeii ca
iaoai?ciii o?ce/iiai ?iciiae?eo, eiee aeeo/aia iai?aai?/ia niieoea
naeaeoeaii ?ic/eiy?oueny a iaaiiio i?aai?/iiio aeno?aaaio? aac aeaeeii?
o?i?/ii? aca?iiae?? i?ae ieie. Noiniaii ai?i?a, aeae?eaii aeaa iniiaieo
iaoai?cie aeno?aaoaaiiy:
1. I?e?aeiaiiy iai?aai?/iiai ai?iia ? i?ioiia aei a?eueiiai ai?io o
aiaeiiio ?ic/ei? iai?aai?/ii? nie?
m(RxH3-xN)o + Men+ + An- + mH+ + mOH- ( (RxH4-xN)m+An- + Me(OH)m. (1)
2. Ai?iiiee iai?i i?ae n?eeth ai?io ? iai?aai?/iith n?eeth
m[(RxH4-xN)n+An-] + mMen+ + nB- ( n[(RxH4-xN)m+ B-] + mMen+ + mAn-,
(2)
aea x, m, n = 1; 2.
A caeeth/i?e /anoei? aeeiiaiiai iaeyaeo c?iaeaii aeniiaie, ui
ai?iaaaeaeaiiy iiaeo oaoiiei??e c aeei?enoaiiyi i?aai?/ieo ?ic/eiiee?a ?
?aa?aio?a a i?ioeane eiiieaenii? ia?a?iaee iie?i?ia?aeueieo eae?eieo
?oae I?eea?iaooy aeanoue iiaeeea?noue ?ioaineo?eoaaoe oe? i?ioeane,
ca?eueoeoe nooi?iue aeeo/aiiy oe?iieo eiiiiiaio?a ?oaee, iaea?aeaoe
/eno? oiaa?i? i?iaeoeoe.
O?ao?e ?icae?e ?iaioe i?enay/aiee ?ic?iaoe? iaoeiaeo canaae oa iniiaieo
noaae?e oaoiiei??? ieneaeo ia?i?th – inaaeaeaiiy a?ae?ieneaeo ia?i?th c
oei?eaeia?i?eiaeo ?ic/ei?a ca aeiiiiiaith IAA ? AeAA oa i?iieaaiiy
inaaeaeaiiai i?iaeoeoo. Ia ii/aoeo ?icae?eo iaaaaeaia caaaeueia
oa?aeoa?enoeea ?nioth/eo oaoiiei??e ieneaeo ia?i?th ooee?caoe??th
?ic/ei?a oei?eaeo ia?i?th (niaeiai?, aaiiyii?, inaaeaeaiiyi ?aeeei
iao?ii oa ai?aeii, oa?i?/ii?). Iieacaii, ui aeiaeia c ieo ia ?
oi?aa?naeueiith ? aeineiiaeith, a /eneaii? iaaeie?ee ia aeathoue ciiae
ai?iaaaeeoe ?o a eae?eio i?iieneia?noue I?eea?iaooy. Cai?iiiiiaaia iiaa
oaoiiei(?y ieneaeo ia(i?th (?oioo?oueny ia inaaeaeaii? a?ae?ieneaeo
ia?i?th aoaiieai?iaie, yea a caaaeueiiio aeaeyae? iieno?oueny ??aiyiiyie
MgCI2 + 2RNH2 + 2H2O ( Mg(OH)2( + 2RNH3 CI,
(3)
MgCI2+ 2R2NH + 2H2O ( Mg(OH)2( + 2R2NH2CI,
(4)
aea R = -CH2-CH2-IH.
Noeoii?noue iaea?aeaieo aenia?eiaioaeueieo caeaaeiinoae nooiaiy
inaaeaeaiiy, oaeaeeino? i?ioeano ? o?eueo?oaaeueieo aeanoeainoae
a?ae?ieneaeo ia?i?th a?ae iniiaieo oaoiieia?/ieo ia?aiao??a aeaea ciiao
aecia/eoe iioeiaeuei? oiiae inaaeaeaiiy, a naia:
ianiaa ni?aa?aeiioaiiy aoaiieai?i: oei?eaeia?i?eiaee ?ic/ei =
1:1…1:1,5; 2) oaiia?aoo?a – 323 E; 3) o?eaae?noue inaaeaeaiiy –
30…40 oa; 4) ?ioaineai?noue ia?ai?ooaaiiy (Rea?aeoe ): aeey IAA
– (2,0…3,0)(103 ; aeey AeAA – (1,0…1,5)(102 ; 5) ia’?iia aeo?aoa
[i3/(i3(n)]: aeey IAA – 4,5(10-3 ; aeey AeAA – 4,7(10-4 .
I?e oeueiio anoaiiaeaiee iai?ioiee oa?aeoa? ?aaeoe?e inaaeaeaiiy, i?i ui
na?ae/aoue cia/ii aeu? cia/aiiy ??aiiaaaeiiai nooiaiy aeeo/aiiy ?ii?a
ia?i?th ?c canoinoaaiiyi iaaeeeoeo inaaeaeoaa/a. Aoaiieai?ie
aenooiathoue a i?ioean? inaaeaeaiiy a?ae?ieneaeo ia?i?th iaeii/anii ye
?aa?aioe, aeniethaa/? oa aa?a?oth/? ?a/iaeie, i?e oeueiio IAA ia?
aacia?a/i? oaoiiei??/i? ia?aaae iaae AeAA i?e i?iieneiaiio aeei?enoaii?
aiane?aeie aeuiai nooiaiy inaaeaeaiiy, ieae/i? a’yceino? ?ic/ei?a,
a?eueoeo ?ici???a /anoeiie oa aa?a?ao?a c ieo, a, ioaea, cia/ii a?eueoi?
oaeaeeino? o?eueo?oaaiiy inaaeo. E?iaoe/i? aenia?eiaioaeuei? aeai?
inaaeaeaiiy caaeia?eueii iienothoueny e?iaoe/iei ??aiyiiyi ae?oaiai
ii?yaeeo. ?c ca?eueoaiiyi ii/aoeiaiai aaniethoiiai ia?ane/aiiy ?
c?inoaiiyi oaiia?aoo?e cia/aiiy eiinoaioe oaeaeeino? i?ioeano
ca?eueoo?oueny. Ci?ia a?ae?iaeeiai?/iiai ?aaeeio inaaeaeaiiy aea? ciiao
cae?enithaaoe i?ioean a ??cieo iaeanoyo: aeeooc?ei?e aai e?iaoe/i?e.
A iiaeaeueoeo aeine?aeaeaiiyo inaaeaeaiiy a?ae?ieneaeo ia(i?th
cae?enithaaee c ae?iaie/iai oei?eaeia(i?eiaiai ?ic/eio, yeee i?noea
(ian.%): MgCl2 25,25; KCl 3,30; NaCl 1,50; CaCl2 0,95.
Ia i?aenoaa? ii??aiyiiy ?acoeueoao?a i?iieaaiiy inaaeaeaiiai
a?ae?ieneaeo ia?i?th aaaaoinoaae?eiei aeo?niaiiyi ? ?aioeueiaoe??th
aea?aiee inoaii?e iaoiae. *enoioa e?ioeaaiai i?iaeoeoo ei?aeoo?oueny
/eneii noaae?e i?iieaaiiy. Iioeiaeueiei ianiaei ni?aa?aeiioaiiyi i?ae
i?iieaiith aiaeith ? inaaeii ? 2,0…2,5. I?ioeoa/?eia i?iieaaiiy aea?
aeaui ieae/o /enoioo i?iaeoeoo (97,72% MgO) ii??aiyii c iiaea/ath aiaee
ia eiaeio noaae?th i?iieaaiiy (99,66% MgO), iaeiae naia aiii aaea i?ney
/ioe?ueio noaae?e i?iieaaiiy caaacia/o? iaea?aeaiiy eiiaeeoe?eiiai
i?iaeoeoo aeuiai (aooieo yeino?, a oaeiae eiioeaio?iaaii? i?iieaii?
aiaee, yea i?aeeyaa? ?aaaia?aoe?? ?acii c iaoi/iei ?ic/eiii.
C iaoith ciaioaiiy ai?noo ??aeei? oace o a?aeo?eueo?iaaieo ia
aaeooi-o?eueo?? inaaeao a?ae?ieneaeo ia?i?th, yeee ia iaaea? ieae/a
75…85%, oa nooo?aiai iie?auaiiy aiane?aeie oeueiai oaoi?ei-aeiiii?/ieo
iieaciee?a ae?iaieoeoaa aeine?aeeee oaaeaooaaiiy iai?iieoeo ? i?iieoeo
/ioe?e?aciaith ?aioeueiaoe??th inaae?a oa oeaio?eooaoaaiiy noniaic??
a?ae?ieneaeo ia?i?th ia o?eueo?oaaeuei?e oeaio?eooc? OeOI-1. ?acoeueoaoe
aeine?aeaeaiue iieacaee, ui iaeaeaa oe? caoiaee caaacia/othoue ciaioaiiy
e?ioeaaiai aieiaiai?noo inaae?a a?ae?ieneaeo ia?i?th a na?aaeiueiio ia
10…12%. Oea, a naith /a?ao, ciaioo? ao?aoe IAA o ae?iaie/iio oeeee? a
1,8…1,9 ?ace oa aeo?aoo iaeeaa ia noo?iiy a 2,5 ?ace. Oaaeaooaaiiy,
ie??i oiai, aea? ciiao cieceoe ieeaaeianaiiy IgO c i?iaea?thaaeueii?
ia/? a?eueo ye a 3 ?ace.
Aecia/aii, ui oaeaee?noue o?eueo?oaaiiy noniaic?? a?ae?ieneaeo ia?i?th
c?inoa? a 1,4…1,8 ?ace i?ney ?? aeaeo?iia?iaee a iino?eiiio
aeaeo?e/iiio iie? i?ae oeoaiiaeie aeaeo?iaeaie. Oea iiynith?oueny ye
aeaeo?ieia?oeyoe??th /anoeiie inaaeo i?ae aieeaii a?ae?ieneaeo oeoaio,
yeee ooai?th?oueny aiane?aeie i?iaeaaiiy caoeniiai oa?o ieneae?a ia
iiaa?oi? aeaeo?iaeo, oae ? iineeaiiyi aeaeo?ioi?aco iaoi/ii? ??aeeie.
Aeeiiaieie aeine?aeaeaiiyie iieacaii, ui ieneae ia?i?th, iaea?aeaiee
iiiiaoaiieai?iiaei niiniaii, iaeaaeeoue aei eaaeeo ni?o?a – eiai ia’?iia
aonoeia eieeaa?oueny a iaaeao 0,16…0,21 a/ni3. ?c ciaioaiiyi ia’?iii?
ianeiii? aonoeie ca?eueoo?oueny aeoeai?noue ? e?io?euei?noue i?iaeoeoo,
ye? a iioeiaeueieo oiiaao noaiiaeyoue a?aeiia?aeii 20 n ? 5,8 ni3. Ia
aeoeai?noue iaea?aeaiiai i?iaeoeoo iaea?eueoee aieea ?iaeoue oaiia?aoo?a
i?iaea?thaaiiy: i?iaeoeo, i?iaea?aiee i?e 1273 E ia? a 4…7 ?ac?a
ieae/o aeoeai?noue, i?ae i?iaea?aiee i?e 773 E.
*aoaa?oee ?icae?e i?enay/aiee ?ic?iaoe? o?ceei-o?i?/ieo ? oaoiiei(?/ieo
canaae ?aaaia?aoe?? aoaiieai?i?a c a?aei?aoeueiaaieo ?ic/ei?a ?
iiaa?iaiiy inaaeaeoaa/a a oeeee. Aeey aea?eueiaiiy ai?i?a
aeei?enoiaoaaee iaeaeaoaaoee c eoa?a – iaaaoaia aaiii. A oeueiio ?ac?
i?ioeane ?aaaia?aoe?? iiaeia iienaoe ?aaeoe?yie
2RNH3CI + CaO ( 2RNH2 + CaCI2 + H2O,
(5)
2 R2NH2CI + CaO ( 2R2NH + CaCI2 + H2O.
(6)
Anoaiiaeaii, ui iiaia ?aaaia?aoe?y IAA ? AeAA c ?o a?aei?aoeueiaaieo
?ic/ei?a a?aeaoaa?oueny i?e 150%-?e e?eueeino? ieneaeo eaeueoe?th a?ae
noao?iiao?e/ii? ii?ie. O aeiaaeeo ?aaaia?aoe?? noeueoaoai?niiai ?ic/eio
aaiii aeo?a/a?oueny ua ? ia inaaeaeaiiy noeueoao-?ii?a o aeaeyae?
ia?ic/eiiiai a?ino.
Aecia/aii ii?yaeie i?ioeano: ae?oaee – ca oei?eaeii iiiiaoaiieaiii?th,
ioeueiaee – ca ieneaeii eaeueoe?th. Ona?aaeiaia cia/aiiy eiinoaioe
oaeaeeino? aei??aith? 0,016 aei3/(iieue(n). Iioeiaeueia o?eaae?noue
i?ioeano ?aaaia?aoe?? noaiiaeoue 20…30 oa.
Ine?eueee ?ic/eiai? nie? nooo?ai ci?iththoue an? o?ceei-o?i?/i?
aeanoeaino? ooai?aii? a i?ioean? ?aaaia?aoe?? nenoaie
KCl-NaCl-CaCl2-IAA(AeAA)-I2I ii??aiyii c /enoith nenoaiith
aoaiieai?i-aiaea, a cia/aiiy oeeo ia?aiao??a a e?oa?aoo?? a?aenooi?,
aoee aeeiiai? niaoe?aeuei? aeine?aeaeaiiy aonoeie, a’yceino? oa aca?iii?
?ic/eiiino? a cacia/aieo nenoaiao. Anoaiiaeaii, ui a’yce?noue ? aonoeia
i?inoeo nenoai KCl-IAA(AeAA)-I2I ? NaCl-IAA(AeAA)-I2I ieaaii
ci?iththoueny c ?inoii eiioeaio?aoe?? aoaiieai?io ? oe? caeaaeiino?
aiaei(?/i? e?eaei iane/aiiy nenoai. Iaeaeaa ?ic/eiieee iathoue yne?aai
ae?aaeaio aeniethth/o ae?th ia aeine?aeaeai? nie?. Cieaeaiiy oaiia?aoo?e
oaae ni?ey? ciaioaiith ?ic/eiiino?. A oaa?ae?e oac? a aeine?aeaeaiiio
oaiia?aoo?iiio ?ioa?aae? a ??aiiaac? c ?ic/eiii ciaoiaeeoueny oaa?aea
oaca aacaiaeieo nieae. Aeiyoie noaiiaeoue nenoaia CaCl2-IAA-I2I, aeey
yei? caeaaeiino? aonoeie, a’yceino? ? ?ic/eiiino? a?ae neeaaeo iathoue
oa?aeoa?iee ceai. Oea na?ae/eoue i?i ooai?aiiy iiai? oaa?aei? oace a
nenoai?. Aeyaeaii, ui i?e cia/ieo eiioeaio?aoe?yo IAA (>58%) a ?ic/ei?
a?aeaoaa?oueny ?aaeoe?y, cai?ioia ca iai?yieii aei ?aaeoe?? ?aaaia?aoe??
(5), aiane?aeie /iai a oaa?aeo oaco aeae?ey?oueny Na(II)2. Iiea noi?nii?
e?enoae?caoe?? NaNl2(2H2O ? Na(II)2 caeia? cia/io /anoeio ae?aa?aie
?ic/eiiino?, a i?aeaeuaiiy oaiia?aoo?e i?ecaiaeeoue aei aeayeiai
ca?eueoaiiy oeueiai iiey. Ia i?aenoaa? aiae?co aieeao aoaeiae ?ic/eiieea
ia ?ic/eii?noue aeei?enoaieo nieae c?iaeaiee aeniiaie i?i ciaioaiiy
?ic/eiiino? oei?eaeo eaeueoe?th c? ca?eueoaiiyi iieueii? iane ai?io.
?ic/eiiino? ENl ? NaCl a?ae inoaiiuei? iaeaea ia caeaaeaoue. A
?cioa?i?/ieo ae?aa?aiao ?ic/eiiino? nenoaie KCl-NaCl-CaCl2-IAA-I2I i?e
80 ? 1000N iaea?eueoa iiea e?enoae?caoe?? iaeaaeeoue oei?eaeo eae?th.
C?noaaia c iei iiea e?enoae?caoe?? NaCl, oi/a aiii aeaui iaioa. Iaeiaioa
iiea e?enoae?caoe?? ia? CaCl2(2H2O.
Aeey ia(?oiooaaiiy ?icae?eaiiy nenoaie IAA-H2O aeeiiaee aeine?aeaeaiiy
??aiiaaaeiiai neeaaeo ??aeeie ? ia?e a oe?ieiio ae?aiacii? ci?ie oeneo
(29,42…98,66 eIa), ye? iieacaee, ui ciaioaiiy inoaiiueiai ia?aiao?a
i?ecaiaeeoue aei nooo?aiai cieaeaiiy oaiia?aoo?e eei?iiy ??aeeie ? aea?
ciiao ca?eueoeoe a?aeiinio eaoe?noue aiaeyieo ia??a. Iayai?noue
?ic/eiaieo nieae (KCl, NaCl, CaCl2) aeeeeea? a?ae/ooia ciaioaiiy
inoaiiuei? ii??aiyii c /enoith nenoaiith IAA-I2I. Iaea?eueoee aieea ia
a?aeiinio eaoe?noue aiaeyieo ia??a aeyaey? oei?eae eaeueoe?th, iaeiaioee
– oei?eae eae?th.
Iiaeaeueo? aeine?aeaeaiiy aoee ni?yiiaai? ia ?icae?eaiiy nenoai, ye?
ooai?ththoueny a i?ioean? ?aaaia?aoe??, c iaoith iaea?aeaiiy yeiiiaa
/eno?oiai inaaeaeoaa/a (IAA aai AeAA). Ia ia?oiio aoai? ?icae?eaiiy
nenoai cae?enithaaee aeia?thaaiiyi,?acoeueoaoe yeiai iiai?noth
i?aeoaa?aeeee iienai? aeua caeaaeiino? o?ceei-o?i?/ieo aeanoeainoae
?ic/eio a?ae eiai neeaaeo. Iieacaii, ui noia?ia e?euee?noue ?ic/eiaieo
nieae o aeia?aieo ?ic/eiao AeAA cia/ii ieae/a ii??aiyii c aeia?aieie
?ic/eiaie IAA. Caaa?iaiiy inoaii?o ia noaae?th inaaeaeaiiy a?ae?ieneaeo
ia(i?th iaaiei /eiii iia??oeei ye?noue e?ioeaaiai i?iaeoeoo, ai?no IgO a
yeiio ciaioeany aei 96,5…97,6% i?ioe 99,0…99,3% o aeiaaeeo
inaaeaeaiiy /enoei inaaeaeoaa/ai. A i?ioean? aeia?thaaiiy ooai?aia
ia?iaa oaca i?noeoue iaaio e?euee?noue ai?i?a. Iai?eeeaae, ca
iaeiaeiaeo oiia i?ioeano iaea?aeaiee ia?iaee eiiaeainao i?noeoue 80 a/e
IAA, a oie /an ye i?ney aeia?thaaiiy ?ic/ei?a AeAA – eeoa 2,2 a/e
i?aai?/iiai eiiiiiaioa.
Iaea?aeai? ?acoeueoaoe cana?ae/eee, ui ?icae?eaiiy ?aaaia?iaaieo
?ic/ei?a AeAA a?ae ?ic/eiaieo nieae iaea?eueo aeioe?eueii cae?enithaaoe
?o aaeooi-aeia?thaaiiyi. Aeia?thaaiiy ?aaaia?iaaieo ?ic/ei?a IAA
noi?iaiaeaeo?oueny cia/iei ia?aoiaeii i?aai?/iiai eiiiiiaioa a ia?iao
oaco ? aenieith ?ic/eii?noth nieae, iniaeeai, oei?eaeo eaeueoe?th a
??aee?e oac?, c /ei ca’ycai? cia/i? ao?aoe IAA a oeeee? ? a?ae/ooia
iia??oaiiy /enoioe i?iaeoeoo. Oiio a oeueiio aeiaaeeo iaiao?aeia
aeiaeaoeiaa ?icae?eaiiy iaea?aeaii? ia?iai? oace ?aeoeo?eaoe??th.
Aiane?aeie aeine?aeaeaiue ?aeoeo?eaoe?? nenoaie IAA-I2I, aeeiiaieo ia
eaai?aoi?i?e ?aeoeo?eaoe?ei?e eieiioe? ae?aiao?ii 15 ii c? neeyiith
ni??aeueiith ianaaeeith 2x2x0,2, aecia/ai? iioeiaeuei? ia?aiao?e
oeueiai i?ioeano: oene – aoiinoa?iee, /enei oa??eie a eieii? – 15 (7 –
aeey a?aeaiiii? ? 8 – aeey cae??iethth/i? /anoei) i?e e.e.ae. oa??eee
0,38 ? oeaaiiaiio /ene? 0,65. Cae?eniaiiy i?ioeano ca oeeo oiia iieacaei
iiaeeea?noue aeinyaiaiiy caaeaieo nooiai?a /enoioe IAA ? aiaee, ye?
a?aeiia?aeii noaiiaeee 99,70 ? 99,99 ian. %.
Ooai?aiee a i?ioean? aeia?thaaiiy inaae nieae caoiieth? 29…45% IAA. C
iaoith aeae?eaiiy inoaiiueiai aeeiiaee aeine?aeaeaiiy a?aeaiiee IAA ia
niaoe?aeuei?e eaai?aoi?i?e onoaiiaoe?, iniiaiei aeaiaioii yei? aoea i?/
c o?eueo?oth/ei oa?ii inaaeo. Nooeeueiei aaaioii neoaeeei aa?y/a
iia?o?y. Oaiia?aoo?a a oa?? iaoa??aeo noaiiaeea 1710N. Iaea?aeai?
?acoeueoaoe iieacaee iiaeeea?noue aeinyaiaiiy 97,7…99,0%-iai nooiaiy
a?aeaiiee IAA c inaaeo. Oea aeaei ciiao ooi/ieoe ao?aoe IAA c nieueiaei
caeeoeii o oeeee? ae?iaieoeoaa IgO.
I’yoee ?icae?e i?noeoue: ?acoeueoaoe aei?iaoaaiue ?ic?iaeaii? oaoiiei???
ieneaeo ia?i?th a aeine?aeii-i?iieneiaeo oiiaao; cia/aiiy iioeiaeueieo
oaoiiei??/ieo ia?aiao??a ? iieaciee?a i?ioeano; ?acoeueoaoe ?ic?aooieo
iaoa??aeueiiai aaeaino an?o noaae?e i?ioeano; ooieoe?iiaeueio ?
oaoiiei??/io noaie ae?iaieoeoaa oa ?o iien; oaoi?ei-aeiiii?/io ioe?ieo
aoaeoeaiino? cai?iiiiiaaii? oaoiiei???.
Iniiaieie aia?aoaie aeine?aeii-i?iieneiai? onoaiiaee aoee: noniaicaoi? –
ai?eciioaeueiee ?ii?niee aia?ao, iniauaiee aaaaoieiianiith i?oaeeith ia
ai?eciioaeueiiio aaeo, ia’?iii 0,3 i3; aa?aaaiiee aaeooi-o?eueo?
AIE-3-1,75 c iiaa?oiath o?eueo?oaaiiy 3 i2; ?aioeueiaoi?e – aa?oeeaeuei?
oeee?iae?e/i? aia?aoe c ?aiiith i?oaeeith ia’?iii 1 i3; aaeooi-aeia?iee
aia?ao c aeianaiith a??th/ith eaia?ith ieiuath 100 i2.
A oe?eiio ?acoeueoaoe ?iaioe aeine?aeii-i?iieneiai? onoaiiaee na?ae/aoue
i?i aenieo oaoiiei(?/i?noue i?ioeano, yeee ia iio?aao? neeaaeiiai aai
niaoe?aeueiiai iaeaaeiaiiy; iiaea cae?enithaaoeny a na??eieo a?o/eciyieo
aia?aoao; iiai?noth i?aeoaa?aeaeothoue aecia/ai? a eaai?aoi?ieo oiiaao
iioeiaeuei? oiiae cae?eniaiiy i?ioeano ? a?aeoai?thaai?noue
oa?aeoa?enoee iaea?aeaiiai ieneaeo ia(i?th.
Iai?aoeueiaaia ia aeine?aeii-i?iieneia?e onoaiiaoe? ia?o?y ieneaeo
ia(i?th, yeee ca nai?ie o?ceei-o?i?/ieie aeanoeainoyie a?aeiia?aeaa
aeuiio ni?oo AINO 844-79 (Iaaiacey aeae?iay oaoie/aneay(, i?ieoea
aei?iaoaaiiy a OeIAe? /i?ii? iaoaeo?a?? (i.Iineaa) ye oa?iino?eea
iie?eooy aeaeo?ioaoi?/ii? noae? c iiceoeaiei aeniiaeii i?i iiaeeea?noue
?? i?iieneiaiai aeei?enoaiiy.
Aeeiiaiee eiiieaen aenia?eiaioaeueieo oa aeine?aeii-i?iieneiaeo
aeine?aeaeaiue noaa iniiaith aeey ?ic?iaee oaoiiei(?/iiai ?aaeeio ?
oaoiiei(?/ii? noaie ae?iaieoeoaa ieneaeo ia(i?th iiiiaoaiieai?iiaei
niiniaii, yea cia?aaeaia ia ?en. 1.
Aeo?aeiee oei?eaeia(i?eiaee ?ic/ei /a?ac iai??iee aae 1 iiaea?oueny a
noniaicaoi? c ai?eciioaeueiith i?oaeeith 3. Nthaee ae c aaeo 2
iaaeoiaeeoue oee?eoeyoe?eiee IAA. Aeey eiiiainaoe?? ao?ao IAA
ia?aaeaa/a?oueny aaaaeaiiy a noaio /anoeie na?aeiai ?aa(aioa (0,86% a?ae
caaaeueii? e?eueeino?, ui iiaea?oueny ia inaaeaeaiiy). Ianiaa
ni?aa?aeiioaiiy i?ae 25%-ei ?ic/eiii oei?eaeo iaai?th ? IAA aei??aith?
1:1. Caaaeueia o?eaae?noue inaaeaeaiiy 20…30 oa. Ooai?aia noniaic?y
a?ae?ieneaeo ia(i?th iaaeoiaeeoue ia aa?aaaiiee aaeooi-o?eueo? (aai
o?eueo?oaaeueio oeaio?eooao) 4-1. Inaae caoiieth? c niaith aaeeeo
e?euee?noue iaoi/iiai ?ic/eio (ai?no ??aeei? oace a iueiio noaiiaeoue
78…84% i?ney aa?aaaiiiai aaeooi-o?eueo?a ? 70…73% i?ney
o?eueo?oaaeueii? oeaio?eooae). C iaoith ca?eueiaiiy inaaeo a?ae
iaoi/iiai ?ic/eio aeeiio?oueny 4-noaae?eia ?aioeueiaoe?eia i?ioeoa/?eia
i?iieaaiiy inaaeo, ca?aeii c yeei aiaea iiaea?oueny ia inoaiith
noaae?th i?iieaaiiy, cae?enithth/e cono??/iee ?oo a?aeiinii inaaeo.
I?iieaaiiy a?aeaoaa?oueny a eaneaae? iine?aeiaii i?aoethth/eo
?aioeueiaoi??a 5-1, 5-2, 5-3, 5-4, aea a?aeo?eueo?iaai? inaaee
ci?oothoueny c a?aeiia?aeiith i?iieaiith aiaeith. ?icae?eaiiy
noniaic?? i?ney i?iieaaiiy cae?enith?oueny ia aa?aaaiieo
aaeooi-o?eueo?ao (aai o?eueo?oaaeueieo oeaio?eooaao) 4-2, 4-3, 4-4, 4-5.
Ianiaa ni?aa?aeiioaiiy i?ae aieiaei inaaeii ? i?iieaiith aiaeith
noaiiaeoue 1:2,0…2,5. Aeey ciaioaiiy ao?ao IAA a oeeee? ae?iaieoeoaa,
cieaeaiiy ieeaaeianaiiy a i?ioean? i?iaea?thaaiiy inaaeo oa aeiiii??
iaeeaa noaiith ia?aaeaa/a?oueny oaaeaooaaiiy inaaeo. C oe??th
iaoith aieiaee i?iieoee inaae iiaea?oueny a oaaeaooaaeueio iaoeio
6, aea i?ae oeneii 30(105 Ia oi?iothoueny oaaeaoee. A?aeoeniaia
??aeeia no?ea? a ca??iee 13-5 ? ?acii c o?eueo?aoii i?ney /aoaa?oi?
noaae?? i?iieaaiiy iaaeoiaeeoue ia o?aoth noaae?th i?iieaaiiy. Oaaeaoee
a?ae?ieneaeo ia(i?th iiaeathoueny a nooeeueiee aa?aaai 7, aea
aenooothoueny aa?y/eie oiieiaeie aacaie, ye? iaaeoiaeyoue i?yiioa/??th c
ii/aoeiaith oaiia?aoo?ith 1100…12000N. Aenooaiee inaae a?ae?ieneaeo
ia(i?th c oaiia?aoo?ith 100…1100N ia?aaea?oueny a aa?aaaiio i?/
8, aea a?aeaoaa?oueny ?iceeaae a?ae?ieneaeo ia(i?th.
Oaiia?aoo?a i?iaeoeoo ia aeoiae? c ia/? ca oiiae iaea?aeaiiy
aenieiaeoeaiiai ieneaeo ia(i?th ia iiaeiia ia?aaeuoaaoe 5500N. Oiieia?
aace i/euathoueny a?ae caoiieaiiai ieeo i?iaeoeoo a oeeeeii? 9-1,
aaoa?aeiiio oeeeeii? 10 oa acaanoiaiio o?eueo?? 11. I?iaea?thaaiiy
a?ae?ieneaeo ia(i?th noi?iaiaeaeo?oueny cai?yiiyi caeeoeiaeo iaa?aeieoeo
c inaaeo i?aai?/ieo aeii?oie – IAA ? oei?eaeo IAA. Aeey i/euaiiy
a?aeo?aeieo oiieiaeo aac?a a?ae ooai?aiiai i?e cai?yii? oei?eaeo
aiaeith neoaeeoue i?iiee aani?aa? 12, yeee c?ioo?oueny aaiiyiith
aiaeith, ui iiaea?oueny ?c ca??ieea 13-8 ianinii 14-8. I?ney aani?aa?a
oiieia? aace aeeeaeathoueny a aoiinoa?o. Ieneae iaai?th c ia/? 8 ?
i/enii? aia?aoo?e 9-1, 10, 11 iiaea?oueny ia neeaae aioiai? i?iaeoeoe??.
Aaaeeeaith /anoeiith noaie, a?ae yei? nooo?ai caeaaeeoue
aeiiii?/i?noue ae?iaieoeoaa, ? ?aaaia?aoe?y IAA c a?aei?aoeueiaaieo
?ic/ei?a ? iiaa?iaiiy eiai ia noaae?th inaaeaeaiiy a?ae?ieneaeo ia(i?th.
Aeey oeueiai iaoi/iee ?ic/ei ? eiioeaio?iaaia i?iieaia aiaea i?ney
aaeooi-o?eueo??a (aai o?eueo?oaaeueieo oeaio?eooa) a?aeiia?aeii 4-1 ?
4-2 /a?ac ca??ieee 13-1 ? 13-2 a?aeoeaio?iaeie ianinaie 14-1 ? 14-2
iiiiothoueny a iai??iee aae 21, ca?aeee ci?oaiee ?ic/ei iaaeoiaeeoue ia
?aaaia?aoe?th, yea cae?enith?oueny ca aeiiiiiaith iaaaoaiiai aaiia. C
iaoith iiaiiai aeei?enoaiiy aaiia noaiith ia?aaeaa/a?oueny aeainoaae?eia
?aaaia?aoe?y, ca?aeii c yeith noi?o a?aei?aoeueiaaieo ?ic/ei?a IAA ?c
aaea 21 iaaeoiaeeoue a ?aaaia?aoi? ia?oi? noaae?? 15. Nthaee ae
aeaaaoi?ii 20 iiaea?oueny iai?i?aaaiaaia aaiii c ae?oai? noaae??
?aaaia?aoe??. Nooi?iue ?aaaia?aoe?? oei?eaeo iiiiaoaiieaiii?th ia ?
noaae?? noaiiaeoue 50%. *anoeiai ?aaaia?iaaiee ?ic/ei a?aenoith?oueny
a?ae oeaio o a?aeno?eieeo 16 ? iiaea?oueny ia ae?oao noaae?th
?aaaia?aoe?? a ?aaaia?aoi? 18. Caouaiee oeai i?ney ia?oi? noaae??
?aaaia?aoe?? a?aeo?eueo?iao?oueny ia aa?aaaiiiio aaeooi-o?eueo?? 4-6 ?
iiaea?oueny a nooeeueiee aa?aaai 24 aeey aeia?iaoaaiiy caoiieaiiai IAA.
Ina?oeaiee ?ic/ei c a?aeno?eieea 16 naiiieeiii ia?ao?ea? a ?aaaia?aoi?
ae?oai? noaae?? 18. Nthaee ae ?c ca??ieea 13-6 ianinii 14-6 iiiio?oueny
?ic/ei, a?aeae?eaiee ia aaeooi-o?eueo?? 4-6. C aoiea?a 17 a ?aaaia?aoi?
18 iaaeoiaeeoue iaaaoaia aaiii o noao?iiao?e/i?e e?eueeino?, yea
iaiao?aeia aeey ia?aoai?aiiy oei?eaeo iiiiaoaiieaiii?th o ii/aoeiaiio
a?aei?aoeueiaaiiio ?ic/ei? a IAA. Iaaeeeoie aaiia a?aeiinii ai?noo
oei?eaeo iiiiaoaiieaiii?th a ?ic/ei? a ?aaaia?aoi?? 18 aei??aith? 50%,
ui caaacia/o? 100%-ee nooi?iue ?aaaia?aoe??. Caaaeueia o?eaae?noue
i?ioeano ?aaaia?aoe?? noaiiaeoue 40 oa. ?aaaia?iaaiee ?ic/ei
a?aenoith?oueny a?ae iaaeeeoeo aaiia ? oeaio o a?aeno?eieeo 19,
o?eueo?o?oueny ia aa?aaaiiiio aaeooi-o?eueo?? 4-7, cae?a?oueny a
ca??ieeo 13-7 ? ianinii 14-7 /a?ac oaieiiai?iiee 26-1 iiiio?oueny o
aaeooi-aeia?iee aia?ao c aeianaiith a??th/ith eaia?ith ? i?eioniaith
oee?eoeyoe??th ?ic/eio 22. Aeeaeia aaeooio a aia?ao? noaiiaeoue
0,314(105 Ia, oene a??th/i? ia?e 0,485 IIa. Ai?no IAA o aeia?aiiio
?ic/ei? ia iiaeiai ia?aaeuoaaoe 61…63 ian.%, ui a?aeiia?aea? 40%-iio
nooiaith aeia?thaaiiy ?ic/eio. Aeia?aiee ?ic/ei, iane/aiee oei?eaeaie
eae?th, iao??th ? eaeueoe?th, no?ea? o aiaeyiee iiaa?oiaaee
e?enoae?caoi? 23, aea aiane?aeie ioieiaeaeaiiy aei 30…320N nie?
aeiaaeathoue a oaa?aeo oaco. Ooai?aiee inaae neeaaeo, ian.%: NaNl2.2H2O
-20,05; NaNl2.4H2O -24,36; NaNl2.6H2O – 4,06; KCl – 3,41; NaCl – 1,55;
IAA – 41,67; H2O -4,90 iaaeoiaeeoue a aa?aaaiio nooa?eo 24 aeey
a?aeaiiee c iueiai IAA. Nooa?ea i?aoeth? i?ae aoiinoa?iei oeneii.
I?ioeoa/??th aei oaa?aei? oace a nooa?eo iiaea?oueny aa?y/a iia?o?y c
ii/aoeiaith oaiia?aoo?ith 190…1950N ? e?i?eiith oaeaee?noth 0,88 i/n.
Aenooaiee inaae c nooa?ee 24 iiaea?oueny o a?aeaae (aai niiaeeaa/aa?).
Ia?i-iia?o?yia noi?o, yea aeoiaeeoue c nooa?ee 24, iiaea?oueny ia
i/euaiiy a?ae caoiieaiiai ieeo nieae a oeeeeii 9-2. Aeae? i/euaia a?ae
ieeo, yeee iiaa?oa?oueny a i?/, aaciaa noi?o iaaeoiaeeoue a
eiiaeainaoi? 26-3, aea aiane?aeie ioieiaeaeaiiy aei 30…400N ia?e IAA ?
/anoeiai aiaee eiiaeainothoueny. E?aie? eiiaeainaoo, caoiieai? iia?o?yi,
a?aeae?eythoueny a naia?aoi?? 28. ??aeeee IAA cae?a?oueny a ca??ieeo
13-12.
Ooai?aia o aaeooi-aeia?iiio aia?ao? 22 ia?iaa noi?o ?icae?ey?oueny a
?aeoeo?eaoe?ei?e eieii? 25 ia neeaaeia? eiiiiiaioe – aiaeo ?
iiiiaoaiieai?i. Ia?e aiaee, i?ioiaey/e aeaoeaaiaoi? 26-2,
eiiaeainothoueny ? no?eathoue a ?iciiae?ethaa/ oeaaie 27-1. Ooo aiaea
?iciiae?ey?oueny ia aeaa iioiee. Iaeei iiaa?oa?oueny a eieiio o
aeaeyae? oeaaie, ?ioee /a?ac ca??iee 13-11 ianinii 14-12 iiiio?oueny ia
i?iieaaiiy a?ae?ieneaeo ia(i?th a ?aioeueiaoi? 5-4. Cieco
?aeoeo?eaoe?eii? eieiie a?aeae?a?oueny ??aeeee IAA, yeee a?aeaea? naith
oaieioo a oaieiiai?iieeo 26-1 ? a ?iciiae?ethaa/? 27-2 oaeiae ae?eeoueny
ia aeaa iioiee. *anoeia IAA iiaa?oa?oueny a na?aaeith /anoeio eieiie 25,
a ?ioa eiai /anoeia /a?ac ca??iee 13-12 ianinii 14-13 iiaa?oa?oueny a
oeeee ae?iaieoeoaa MgO.
A i?ioean? ?aaaia?aoe?? a?aei?aoeueiaaieo ?ic/ei?a IAA ca aeaiith
oaoiiei(??th ooai?ththoueny cia/i? e?eueeino? oaa?aeiai, caa?oaeiaiiai
aeii?oeaie e?enoaeia?ae?aoo oei?eaeo eaeueoe?th (ia 1 o ieneaeo ia(i?th
i?eiaaea? 4,77 o oaa?aeiai caeeoeo). Oeae caeeoie, oi/a ? iiaea oe?iei
canoiniaoaaoeny a i?iieneiaino? oa ?ioeo noa?ao ainiiaea?noaa, a iao?e
e?a?i? aeei?enoiao?oueny a iacia/ieo ianyaao. Aa?o/e oea aei oaaae, iaie
aeeiiaiee eiiieaen oai?aoe/ieo oa aenia?eiaioaeueieo aeine?aeaeaiue ? ia
eiai i?aenoaa? ?ic?iaeaiee aoaeoeaiee oaoiiei(?/iee i?ioean ?aaaia?aoe??
a?aei?aoeueiaaieo ?ic/ei?a IAA, ni?yiiaaiee ia e?ea?aeaoe?th oaa?aeiai
caeeoeo, a yeiio cai?noue iaaaoaiiai aaiia aeei?enoiaoaaee
aeaeo?ie?oe/i? ?ic/eie ?aeeiai iao?o. Oaa?aeee caeeoie a oeueiio
aeiaaeeo yaey? niaith oei?eae iao??th c iaaaeeeeie aeii?oeaie oei?eaeo
eae?th (3…4%), ?aeeiai iao?o (5…5,5%) oa IAA (0,1…0,2 %) ? i?ney
i?iaea?thaaiiy iiaea aooe aeei?enoaiee aeey iaea?aeaiiy aeaeo?ie?oe/iiai
?ic/eio ?aeeiai iao?o. Oaoiiei(?/ia noaia i?ioeano iaea?aeaiiy ieneaeo
ia(i?th a oeueiio ?ac? a oe?eiio ? aiaeia?/iith iienai?e aeua c oith
??cieoeath, ui iaea?aeaiee aiane?aeie ?aaaia?aoe?? ?aeeei iao?ii ?ic/ei
IAA i?ney eiai aeia?thaaiiy i?aeoe/ii iiai?noth ca?eueiy?oueny a?ae
?ic/eiaieo a iueiio nieae, ye? aeiaaeathoue a oaa?aeo oaco. Ooai?aia a
i?ioean? aeia?thaaiiy noniaic?y ?icae?ey?oueny oeaio?eooaoaaiiyi c
iiaa?iaiiyi ??aeei? oace aaciina?aaeiuei ia noaae?th inaaeaeaiiy
a?ae?ieneaeo ia(i?th, a oaa?aeee caeeoie oei?eaeo iao??th i?ney eiai
noo?iiy ? ianooiiiai i?iaea?thaaiiy aeey ca?eueiaiiy a?ae caeeoe?a IAA
aeei?enoiao?oueny aeey iaea?aeaiiy iane/aiiai ?ic/eio c a?aeaaaeaiiyi
inoaiiueiai ia aeaeo?ie?c.
Iniiai? iieacieee i?ioean?a, aeo?aoe ne?iaeie oa aia?ai?ano?n?a ia 1 o
ieneaeo ia(i?th ia ae?th/eo ae?iaieoeoaao a iaaeao NIAe (aaiiyiee ?
niaeiaee niiniae) oa ca ei?aeiiii (oa?i?/iee niin?a – onoaiiaee o??ie
“Rutner”) ? a cai?iiiiiaai?e oaoiiei(?? iaaaaeai? a oaae.1.
Aeeiiaia oaoi?ei-aeiiii?/ia ioe?iea ia?aeiieeai aeiaiaeeoue
aoaeoeai?noue cai?iiiiiaaii? oaoiiei(??, ine?eueee aiia aea? ciiao
ia?a?iaeyoe aenieieiioeaio?iaai? ?ic/eie oei?eaeo ia(i?th aac ?o
iiia?aaeiueiai ?icaaaeaiiy, caaacia/o? aenieee nooi?iue aeei?enoaiiy
?ic/ei?a oei?eaeo ia(i?th oa aenieo /enoioo iaea?aeaiiai i?iaeoeoo.
Aeiiii?/i?noue aeaii? oaoiiei(?? i?aeoaa?aeaeo?oueny i?i?iaeueieie
ne?iaeiii-aia?aaoe/ieie aeo?aoaie ia ae?iaieoeoai 1o MgO.
Oinoee ?icae?e ?iaioe i?enay/aiee noai?aiith oaoiiei(?? eiiieaenii?
ia?a?iaee ??aeeeo a?aeoiae?a oainoinoiaeu c aeei?enoaiiyi i?aai?/ieo
?ic/eiiee?a. sse caaaeoaaeiny aeua, iayai?noue oeeo a?aeoiae?a ?
aaeeeith i?iaeaiith eae?eieo ae?iaieoeoa Oe?a?ie. A aeaiee /an ianya
iaeiie/aieo ? caneeaaeiaaieo a oainoinoiaeuao ?ic/ei?a aeinyaa? 7,5 iei.
i3 ? i?iaeiaaeo? noaa?eueii c?inoaoe.
Ia ii/aoeo ?icae?eo c?iaeaii aiae?c no/aniiai noaio i?iieneiaiai
cianoeueoa/aiiy a?aeo?aeieo ?ic/ei?a eae?eieo ae?iaieoeoa, aea c oe??th
iaoith aeei?enoiao?oueny ?ic/ei oei?eaeo eaeueoe?th, yeee ia?aoai?th?
?ic/eiai? noeueoaoe a ua iaeei oaa?aeee a?aeo?ae – a?in. I?ioean
cianoeueoa/aiiy ? aenieiaa?o?niei ? aeiaaio?eaaeei (14…18 aiae).
Aeeiiaiee aiae?c aea? i?aenoaao noaa?aeaeoaaoe i?i iaiao?aei?noue
naeaeoeaiiai aeae?eaiiy ?ii?a SO42- c ?ic/eio a oaa?aeo oaco ia?aaaaeii
o aeaeyae? noeueoaoo eae?th c iaoith iiaeaeueoiai aeei?enoaiiy
inoaiiueiai ye aeia?eaa. Iieacaii, ui oea caaaeaiiy iiaeia oni?oii
ae??oeoe ca aeiiiiiaith i?aai?/ieo ?ic/eiiee?a naeaeoeaii? ae??.
A aeine?aeaeaiiyo aeei?enoaee a?aeo?aeiee ?ic/ei Noaaieoeueeiai
oainoinoiaeua neeaaeo (a/e): Mg2+ 40,95; K+ 39,19; Na+ 61,73; SO42-
80,74; CI- 192,35; H2O 863,04 oa aeinooii? i?aai?/i? ?ic/eiieee c
iecueeith oaiia?aoo?ith eei?iiy aeey eaaeino? ?o ianooiii? aeenoeeyoe??
c i/euaiiai ?ic/eio, a naia: aoeaoii, ?cii?ii?eiaee nie?o, iaoaiie oa
aoaiie. Aecia/aii, ui iiaiioa inaaeaeaiiy ?ii?a eae?th ? noeueoaoo
ca?eueoo?oueny c ?inoii ni?aa?aeiioaiiy ia’?i?a inaaeaeoaa/:?ic/ei, i?e
oeueiio iioeiaeueiei ? ni?aa?aeiioaiiy 1:3…1:4. Inaaeaeoaaeueia
caeaoi?noue noiniaii noeueoao?a cieaeo?oueny a ?yaeo
aoaiie-iaoaiie-?cii?ii?eiaee nie?o-aoeaoii. Iaee?au? ?acoeueoaoe
aeeo/aiiy ?ii?a eae?th a oaa?aeo oaco aea? iaoaiie. Aeoyae E+ ? SO42-
i?e oeueiio aei??aiththoue a?aeiia?aeii 84,7…85,5% ? 97,0…99,6%.
I?ney a?aeaiiee aoaiieo aai iaoaiieo ?c cianoeueoa/aiiai ?ic/eio
eiioeaio?aoe?y SO42- a iueiio noaiiaeoue 0,02…0,14 ian.%. ?ic/ei
i?noeoue oei?eae ia(i?th (13,5…14,5%), oei?eae iao??th (4,15…6,66%)
oa iaaaeeeo e?euee?noue aeii?oie ENl ? MgSO4. Iieacaii, ui c oeueiai
?ic/eio aeia?thaaiiyi aeioe?eueii aeae?eeoe a oaa?aeo oaco oei?eae
iao??th, yeee i?ney a?aeieaaiiy ? aeiaeaoeiaei oiaa?iei i?iaeoeoii
??ciiai (aooieo a caeaaeiino? a?ae ni?aa?aeiioaiiy i?ae n?eeth ?
i?iieaiei ?ic/eiii. E?euee?noue iaea?aeaii? eooiiii? nie? noaiiaeoue
4,7…5,0% a?ae iane aeo?aeiiai ?ic/eio i?e nooiai? aeia?thaaiiy
40…42,5%, a aeoya – 80…85%. ?ic/ei i?ney a?aeae?eaiiy eooiiii? nie?
i?noeoue 25,8…26,0% MgCl2 ? ? oiaa?iei i?iaeoeoii. Eiai e?euee?noue
aei??aith? 46,5% a?ae iane ii/aoeiaiai ?ic/eio oainoinoiaeua.
Noeueoaoiee inaae, aeae?eaiee a oaa?aeo oaco ia noaae?? cianoeueoa/aiiy,
ui i?noeoue 15…30% Cl-, iiaeaaaee ia aeno?aaoaaiiy oei?eae?a c iueiai
ca aeiiiiiaith iaoaiiei-aiaeiiai ?ic/eiieea, iioeiaeueiee ianiaee neeaae
yeiai ? 60:40. Oea aeaei ciiao iaea?aeaoe aeia?eai neeaaeo (ian.%): E2I
31…37; MgO 1,1…3,5; Na2O 11,9…16,7; Cl- a?aenooi?e, a e?eueeino?
10,9…11,8% a?ae iane aeo?aeiiai ?ic/eio. Aeoyae E+ ? SO42- a aeia?eai
noaiiaeyoue a?aeiia?aeii 84…85% ? 97…99%. I?ney a?aeaiiee iaoaiieo
iaoi/iee ?ic/ei iiaoi?ii aeia?thaaee c iaea?aeaiiyi inaaeo oei?eaeo
iao??th. Caaaeueiee aeo?ae eooiiii? nie? noaiiaeoue 8,5…13% a?ae iane
ia?a?iaeaiiai ?ic/eio.
?acoeueoaoe aei?iaoaaiiy ia?a?iaee ?ic/eio oainoinoiaeua ia oe?oiiai?e
eaai?aoi?i?e onoaiiaoe? oa aecia/ai? iioeiaeuei? ia?aiao?e i?ioeano
iineoaeeee iniiaith aeey noai?aiiy ooieoe?iiaeueii? noaie i?ioeano,
iieacaii? ia ?en.2. E??i aeuaiienaieo noaae?e, noaia aeeth/a? ii/aoeia?
noaae?? o?eueo?oaaiiy ?ic/eio oa aaeni?aoe?? c iueiai ?ic/eiaieo
i?aai?/ieo ?a/iaei (aeueo ea?aiiiaeo eeneio oiui) oaa?aeei ni?aaioii
(aeoeaiaaiei aoa?eeyi), ui, ye iieacaii aeeiiaieie aeine?aeaeaiiyie,
aea? ciiao cieceoe ?o ai?no a iaea?aeai?e eooiii?e nie? c 1,2…1,3 aei
0,2…0,3 ian.%.
?ic?aooiie oiiaiiai aeiiii?/iiai aoaeoo, iaaaaeaiee a oaae.2, aea?
i?aenoaae aaaaeaoe ?ic?iaeaio oaoiiei(?th aoaeoeaiith oa
eiieo?aioiicaeaoiith.
A nueiiiio ?icae?e? iaaaaeai? ?acoeueoaoe aeine?aeaeaiue i?ioean?a
aeno?aeoe?? oei?eae?a c oaa?aeeo oei?eaeai?nieo iai?ai?iaeoeo?a eae?eieo
ae?iaieoeoa c iaoith iaea?aeaiiy eiiaeeoe?eieo uiaei ai?noo oei?-?iio
(ia a?eueoa 3%) eae?eieo aeia?ea.
A aeine?aeaeaiiyo aeei?enoiaoaaee iecueeioei?eaeiee oai?o Noaaieoeueeiai
AeAOI (Iie?i?ia?ae( ? aenieioei?eaeiee oai?o Eaeonueeiai AAO (I??aia(,
neeaae yeeo iaaaaeaiee a oaae.3.
sse aeno?aaaioe aeei?enoiaoaaee aiaeii-i?aai?/i? ?ic/eiieee ia iniia?
IAA. Aeey caiia?aaiiy aca?iiae?? c noeueoaoii ia(i?th, yeee i?noeoueny o
oai?o?, aiaei? ?ic/eie IAA iiia?aaeiuei iaeo?ae?coaaee i?ia?aeueieie
eeneioaie: oei?eaeiith, noeueoaoiith aai i?o?aoiith.
Ine?eueee naeaeoeai?noue aeno?aeoe?? aecia/a?oueny ni?eueiith
?ic/eii?noth neeaaeiaeo eiiiiiaio?a oai?oo o aea?aiiio ?ic/eiieeo, a a
e?oa?aoo?? oae? aeai? a?aenooi?, aea/aeany ?ic/eii?noue eNl, NaCl, MgSO4
i K2SO4 a ?ic/eiieeo RNH3Cl-H2O ?cioa?i?/iei iaoiaeii a oaiia?aoo?iiio
?ioa?aae? (20…50)0N. Anoaiiaeaii, ui iaeiaioo ?ic/eii?noue ?c
cacia/aieo nieae ia? noeueoao eae?th, ?ic/eii?noue ?ioeo nieae aeineoue
aeniea ? ni?ai??ia, ia /iio (?oioo?oueny ?o aea??eiaa aeno?aaoaaiiy a
??aeeo oaco.
Aenia?eiaioaeueieie aeine?aeaeaiiyie aeiaaaeaii, ui iaea?aeaiiy
aacoei?eaeiiai i?iaeoeoo (1,5% Nl-) c iecueeioei?eaeiiai oai?oo o
aiaeieo ?ic/eiao oei?eaeo iiiiaoaiieaiii?th a?aeaoaa?oueny c aeoiaeii
60…65% i?e oaeeo iioeiaeueieo ia?aiao?ao i?ioeano: eiioeaio?aoe?y IAA
o aeo?aeiiio ?ic/ei? 30 ian.%; O:?=1: (2,5…3,0). Aeno?aaaio aeey
iiaiiai iane/aiiy nieyie i?ney ia?oiai nooiaiy aeno?aaoaaiiy
aeei?enoiaoaaee aeey ia?iaee iiai? ii?oe?? oai?oo. Aeno?aeoe?y oei?eae?a
c aenieioei?eaeiiai oai?oo oeei aea ?ic/eiieeii iieacaea aiaeia?/i?
?acoeueoaoe. ??cieoey iieyaaea a caaaa/aii? aeia?eaa noeueoaoii iao??th,
ooai?aiiy yeiai a?aeaoaa?oueny a ??aee?e oac? ca ?aaeoe??th
2NaN? + IgSI4( Na2SI4 +IgN?2 (7)
c aeniethaaiiyi ooai?aiiai Na2SO4 a oaa?aeo oaco.
Aeei?enoaiiy aiaeieo ?ic/ei?a noeueoaoo IAA aeaei ciiao cieceoe ai?no
Nl- a e?ioeaaiio i?iaeoeo? aei 0,3…0,5% ? ca?eueoeoe aeo?ae i?iaeoeoo
ca noeueoaoii eae?th aei 98…99% ca ?aooiie ia?aa?ao ?aaeoe?e
(RNI3)2SI4 + 2EN? ( 2RNI3N? + E2SI4, (8)
IgSI4 + 2EN? ( E2SI4 + IgN?2.
(9)
Aeno?aeoe?y oei?eae?a ca aeiiiiiaith aiaeieo ?ic/ei?a i?o?aoo
iiiiaoaiieaiii?th noi?iaiaeaeo?oueny ?aaeoe??th
EN? + RNI3NI3 ( ENI3 + RNI3N?, (10)
aiane?aeie /iai iaea?aeo?oueny eiiieaenia i?o?aoii-noeueoaoia aeia?eai
neeaaeo (ian.%): K2O 28,2…29,4; MgO 5,3…5,8; SO42- 24,0…30,5; NO3-
20,0…25,4; Cl- 2,4…2,9, aea aeo?ae i?iaeoeoo ooo iaaenieee ? ia
ia?aaeuo? 30…40%.
Ia?aa?a i?ioeano o aeaio inoaii?o ?ic/eiieeao oneeaaeith?oueny
iaeiie/aiiyi a ??aee?e oac? ooai?aiiai ca ?aaeoe?yie eiiaa?n?? oei?eaeo
iiiiaoaiieaiii?th, a, ioaea, iaiao?aei?noth aeaaaeaiiy cia/ii? /anoeie
aeno?aaaioa c oeeeeo. Oiio aeey i?aeoe/iiai aeei?enoaiiy
?aeiiaiaeo?oueny naia aiaeiee ?ic/ei oei?eaeo iiiiaoaiieaiii?th.
A?aei?aoeueiaaiee, iane/aiee nieyie aeno?aaaio iiaeaaaee ia aaeooi-
aeia?thaaiiy aei nooiaiy 40…42%, i?e oeueiio ia?aaaaeia e?euee?noue
?ic/eiaieo nieae aeiaaeaea a inaae, yeee i?ney ooaoaaiiy iiaea aooe
aeei?enoaiee ye iecueeiye?nia eae?eii-i?o?aoia aeia?eai. Aeiaaaeaii, ui
iaea?aeaiee ?ic/ei iiaea iiaa?oaoeny ia aeno?aaoaaiiy oei?eae?a c
ii/aoeiaiai oai?oo.
Ia i?aenoaa? noeoiiino? iaea?aeaieo ?acoeueoao?a ?ic?aoiaaiee
iaoa??aeueiee aaeain i?ioeano oa ?ic?iaeai? oaoiiei(?/iee ?aaeei ?
i?eioeeiiaa oaoiiei(?/ia noaia iaea?aeaiiy aacoei?eaeieo eae?eieo
aeia?ea, cia?aaeaia ia ?en.3.
IAA (c? neeaaeo) ? eiiaeainao aiaeyii? ia?e iiaeathoueny a ci?ooaa/ 1
aeey iaea?aeaiiy 30%-iai ?ic/eio IAA. Iaeo?ae?caoe?y iaea?aeaiiai
?ic/eio nieyiith eeneioith a?aeaoaa?oueny a o?oa/aoiio iaeo?ae?caoi?? 2
c aiaeyiei ioieiaeaeaiiyi. Iaea?aeaiee aiaeiee ?ic/ei oei?eaeo IAA
iaaeoiaeeoue a aae 3. Nthaee ae ?c ca??ieea 19 ianinii 20 iiaea?oueny
oee?eoethth/ee ?ic/ei oei?eaeo IAA i?ney noaae?? aeia?thaaiiy ? aiaea
aeey eiai ?icaaaeaiiy. Ianiaa ni?aa?aeiioaiiy i?ae na?aeei,
oee?eoethth/ei ?ic/eiaie oei?eaeo IAA ? aiaeith noaiiaeoue 1:17:12. C
aaea 3 aeno?aaaio naiiieeaii iaaeoiaeeoue a aeno?aeoi? ia?oi? noaae??
aeno?aaoaaiiy 4-1, eoaee iiaea?oueny ii/aoeiaee aieiaee oai?o. Ianiaa
ni?aa?aeiioaiiy i?ae oacaie O:? noaiiaeoue 1:(2,5…3), o?eaae?noue
aeno?aaoaaiiy 45 oa. Ooai?aia noniaic?y ?icae?ey?oueny o a?aeno?eieeo
5-1 ? ia aa?aaaiiiio aaeooi-o?eueo?? 6-1. Iaoi/iee ?ic/ei i?ney ia?oi?
noaae?? aeno?aaoaaiiy ?c ca??ieea 7-1 ianinii 8-1 iiiio?oueny a
aeno?aeoi? ae?oai? noaae?? aeno?aaoaaiiy 4-2. Nthaee ae iiaea?oueny
ii/aoeiaee aieiaee oai?o a ianiaiio a?aeiioaii? aei aeno?aaaioa 1:2,5.
Noniaic?y i?ney ae?oai? noaae?? aeno?aaoaaiiy ?icae?ey?oueny o
a?aeno?eieeo 5-2 ? ia aa?aaaiiiio aaeooi-o?eueo?? 6-2.
A?aeo?eueo?iaai? inaaee i?ney aa?aaaiieo aaeooi-o?eueo??a 6-1 ? 6-2
iiaeathoueny o nooa?eo c inaaaeic??aeaeaiei oa?ii iaoa??aeo 9. Noo?iiy
iaoa??aeo cae?enith?oueny oiieiaeie aacaie c oaiia?aoo?ith 500…550iN.
Oaiia?aoo?a a oa?? – 150…160iN. Aenooaia aeia?eai iiaea?oueny ia
neeaae aioiai? i?iaeoeoe??. Aiii i?noeoue 27…28% E2I, 10…11% IgI,
0,17…0,18% N, ia a?eueoa 2% C?- ? ia a?eueoa 12% aieiae.
Aace i?ney nooa?ee 9 iaaeoiaeyoue a oeeeeii 11, aeae? – a aaoa?aeiee
oeeeeii 12, aea inaaeaeothoueny caoiieai? aacii oaa?ae? /anoeiee
aeia?eaa. I?ney aaoa?aeiiai oeeeeiia aace iiaeathoueny ia iie?a
i/euaiiy, a aeae? aeeeaeathoueny a aoiinoa?o. Iaoi/iee ?ic/ei ?c
ca??ieea 7-2 ianinii 8-2 iiaea?oueny o aaeooi-aeia?iee aia?ao 16 c
i?eioniaith oee?eoeyoe??th ?ic/eio, aea a?eueoa /anoeia nieae aeiaaea? a
inaae. Ooai?aia noniaic?y /a?ac i?ii?aeiee aae 17 iaaeoiaeeoue ia
oeaio?eooao 18. Iaea?aeaiee inaae i?noeoue 20…21% E2I, 10…11% IgI,
0,5% N ? aei 23% N?-, oiio iiaea aeei?enoiaoaaoeny ye a?aeia eae?eia
aeia?eai.
Aeia?aiee ?ic/ei, ca?eueiaiee a?ae iniiaii? iane ?ic/eiaieo a iueiio
nieae, i?ney oeaio?eooae 18 cae?a?oueny a ca??ieeo 19 ? ianinii 20
iiaa?oa?oueny a oeeee ae?iaieoeoaa.
C?iaeaiee ?ic?aooiie aoaeoeaiino? cai?iiiiiaaii? oaoiiei(?? iieacaa
iiaeeea?noue iaea?aeaiiy i/?eoaaiiai i?eaooeo a?eueoa 6 iei. a?i.
aiane?aeie ?aae?caoe?? 91 oen. o a ??e aacoei?eaeiiai
eae?eii-ia(i?eiaiai aeia?eaa.
Caaaeuei? aeniiaee
1. Ae?th/a oaoiiei??y ia?a?iaee iie?i?ia?aeueieo eae?eieo ?oae
I?eea?iaooy oa?aeoa?eco?oueny iecueeei aeoyaii ie?aieo eiiiiiaio?a
ne?iaeie, aaee/aciei ianyaii ??aeeeo ? oaa?aeeo a?aeoiae?a, aocueeei
ani?oeiaioii aioiaeo i?iaeoeo?a, iecueeith ye?noth eae?eieo aeia?ea.
Neacaia coiiaeth? aino?o iaiao?aei?noue a iiooeo ? ?ic?iaoe? i?eioeeiiai
iiaeo i?aeoiae?a aei oaoiiei??? ? ia?a?iaee oe??? ne?iaeie.
2. Aeei?enoaiiy i?aai?/ieo ?aa(aio?a ? ?ic/eiiee?a naeaeoeaii? ae?? a
oaoiiei??? eiiieaenii? ia?a?iaee eae?eieo iie?i?ia?aeueieo ?oae
I?eea?iaooy iiaea caaacia/eoe ?ioaineo?eaoe?th oaoiiei??/ieo i?ioean?a,
i?aeaeuaiiy yeino? ? ?icoe?aiiy ani?oeiaioo i?iaeoeoe??, ?ano?ni- oa
aia?aicaa?aaeaiiy, ae??oaiiy aaaaoueio aeieia?/ieo ieoaiue.
3. Aaaaoioiiaaei? a?aeo?aei? oei?eaeia?i?eia? ?ic/eie a?o/eciyieo
eae?eieo ae?iaieoeoa – oea aea?aeia c oaoiiei(?/ii?, aeiiii?/ii? oa
aeieia?/ii? oi/ee ci?o ne?iaeia aeey ae?iaieoeoaa aino?iaeao?oeeoiiai
ieneaeo ia?i?th (ia?iac??). O?aaeeoe?ei? oaoiiei??? ia?iac?? iathoue
aaaaoi ?noioieo iaaeie?e?a, ui coiiaeth? ?o iai?eaeaoi?noue aeey
ia?a?iaee cacia/aieo ?ic/ei?a.
4. Canoinoaaiiy aoaiieai?i?a caaacia/o? 95,5…98,5%-ee nooi?iue
aeeo/aiiy ?ii?a ia?i?th ?c eiioeaio?iaaieo oei?eaeiaai?eiaeo ?ic/ei?a (
~ 25% MgCl2), caa?oaeiaieo /eneaiieie aeii?oeaie eae?eieo oa ?ioeo
nieae. Aoaiieai?ie ? aeoeaieie ?aa?aioaie, aa?a?oth/eie ?a/iaeiaie oa
aeniethth/ei na?aaeiaeuai aeey a?ae?ieneaeo ia?i?th. Ca ia?a?aoiaaieie
iieacieeaie iiiiaoaiieai?i (IAA) ia?aaeuo? ae?aoaiieai?i.
5. I?ioean aca?iiae?? IAA c IgCl2 iieno?oueny e?iaoe/iei ??aiyiiyi
ae?oaiai ii?yaeeo. Aecia/ai? aiane?aeie aeine?aeaeaiue oeueiai i?ioeano
e?iaoe/i? oa?aeoa?enoeee (eiinoaioe oaeaeeino?, oaiia?aoo?iee
eiao?oe??io, aia?a?y aeoeaaoe??) aeaee ciiao cai?iiiioaaoe iaoai?ci
inaaeaeaiiy a?ae?ieneaeo ia?i?th.
6. I?ioeoa/?eia ?aioeueiaoe?eia i?iieaaiiy inaaeo a?ae?ieneaeo ia?i?th
aea? ciiao iaea?aeaoe i?iaeoeo iaiao?aeii? /enoioe, yea aecia/a?oueny
ianiaei ni?aa?aeiioaiiyi i?ae inaaeii ? i?iieaiith aiaeith (O:?) oa
/eneii noaae?e i?iieaaiiy. I?iaeoeo c ai?noii 97,7…98,8% IgI
iaea?aeo?oueny i?e O:? = 1:2…3 ? 4-noaae?ei?e noai? i?iieaaiiy.
7. A?oaiaeenia?nia no?oeoo?a inaaeaeaiiai a?ae?ieneaeo ia?i?th (?ici??
iaeeii/ieo /anoeiie 20…100 iei oa aa?aaao?a c ieo 1300…1700 iei)
coiiaeth? aenieo oaeaee?noue eiai o?eueo?oaaiiy (40…50 ea/i2(aiae),
yea ia?aaeuo? oeae iieaciee aeey o?aaeeoe?eieo iai?aai?/ieo
inaaeaeoaa/?a [Na(II)2, Na2NI3, NaII, NI4II oiui] a 1,7…10 ?ac?a.
8. A?ae?ieneae ia?i?th, iaea?aeaiee aoaiieai?iiaei niiniaii, ?
iecueeinoeneeaei, /ei coiiaeth?oueny eiai aeniea aieia?noue (aei 85%).
Canoinoaaiiy i?an-o?eueo?oaaiiy (oaaeaooaaiiy) i?iieoeo inaae?a i?ae
oeneii (30…40)(105 Ia aea? ciiao cieceoe aieia?noue aei 63…64%,
aia?aiaeo?aoe ia eiai noo?iiy a 2,5 ?ace ? ao?aoe IAA a oeeee? c 70…72
aei 37…39 ea ia 1 o IgI. Oeaio?eooaoaaiiy oeueiai inaaeo (oaeoi?
?icae?eaiiy 2000, o?eaae?noue 480 n) caaacia/o? cieaeaiiy ai?noo ??aeei?
oace ia 10…12 ian.%.
9. E?auei oeieoeyioii a?ae?ieneaeo ia?i?th c aeine?aeaeaieo (oi?iae?i,
iie?ae?eeai?ae ? e?ioiaeue) ? inoaii?e. I?e eiai eiioeaio?aoe?? a
?ic/ei? 0,04…0,05 ian.% oaeaee?noue o?eueo?oaaiiy ca?eueoo?oueny
iaeaea ao?e/?. Aoaeoeaiei caniaii i?enei?aiiy o?eueo?oaaiiy ? oaeiae
aeaeo?iia?iaea noniaic?? a?ae?ieneaeo ia?i?th i?ae oeoaiiaeie
aeaeo?iaeaie a iino?eiiio aeaeo?e/iiio iie? iai?oaith 20…60 A ?
aonoeiith no?oio 1,0…2,5 A/aei2 i?ioyaii 90…180 n.
10. Aeioe?eueiith oaiia?aoo?ith i?iaea?thaaiiy a?ae?ieneaeo ia?i?th ?
773…823 E, c i?aeaeuaiiyi oe??? oaiia?aoo?e aeoeai?noue i?iaeoeoo
??cei ciaioo?oueny (ca eeiiiiei /eneii c 20…30 aei 90…140 n).
11. Aenieee nooi?iue ?aaaia?aoe?? a?aei?aoeueiaaieo ?ic/ei?a IAA ( 100%)
aeinyaa?oueny ca aeiiiiiaith iaaaoaiiai aaiia i?e eiai aeo?ao? 150% a?ae
noao?iiao?e/ii? ii?ie. Oeae i?ioean iieno?oueny e?iaoe/iei ??aiyiiyi
ae?oaiai ii?yaeeo ca oei?eaeii iiiiaoaiieaiii?th ? ioeueiaiai – ca
ieneaeii eaeueoe?th.
12. Aoaiieai?ie iathoue neeueio aeniethth/o ae?th ia oei?eaee a
iine?aeiaiino? NaN?2>NaCl>EN?. Oey aeanoea?noue aeei?enoaia aeey
ia(?oiooaaiiy, noai?aiiy ? ?ic?aooieo aeae?eaiiy ?ic/eiaieo nieae ?c
?aaaia?iaaieo ?ic/ei?a aoaiieai?i?a i?e ?o aeia?iaoaaii?.
13. Aia?oa iaea?aeai? aeai? c ia?i-??aeeiii? ??aiiaaae a nenoai? IAA-I2I
a iaeano? oene?a, ieae/eo a?ae aoiinoa?iiai, oa aeyaeai? caeiiii??iino?
aieeao ?ic/eiaieo oei?eae?a eae?th, iao??th ? eaeueoe?th ia a?aeiinio
eaoe?noue aiaeyieo ia??a neeaee iniiao aeey ?ic?iaee iioeiaeueiiai
oaoiiei(?/iiai ?aaeeio ?aeoeo?eaoe?eiiai ?icae?eaiiy nenoaie ia
neeaaeia? eiiiiiaioe.
14. ?ic?iaeaia a eaai?aoi?ieo oiiaao ? aei?iaoaaia a
aeine?aeii-i?iieneiaeo ianooaaao oaoiiei??y ieneaeo ia?i?th
oa?aeoa?eco?oueny “eaa?aei?noth” oaoiiei??/iiai ?aaeeio, ia iio?aao?
niaoe?aeueiiai iaeaaeiaiiy, ia? aenie? oaoi?ei-aeiiii?/i? iieacieee, ?
eiieo?aioiicaeaoiith. Ia?iac?y, iaea?aeaia aeaiei niiniaii, ia? aenie?
oaoi?/i? oa?aeoa?enoeee, iiai?noth i?eaeaoia aeey oa?ii?cieyoe?eiiai
iie?eooy aeaeo?ioaoi?/ieo noaeae, ui cana?ae/aii OeIAe? /i?ii?
iaoaeo?a?? (i.Iineae).
15. Iaoaiie ? aoaeoeaiei cianoeueoa/oaa/ai a?aeo?aeieo ?ic/ei?a eae?eieo
ae?iaieoeoa, cie?aia, ?ic/ei?a oainoinoiaeu. I?e ia’?iiiio
ni?aa?aeiioaii? ?ic/ei:inaaeaeoaa/ = 1:4 nooi?iue cianoeueoa/aiiy
noaiiaeoue 99,3%, caeeoeiaa eiioeaio?aoe?y SI42- – 0,02 ian.%.
16. Cai?iiiiiaaiee ? ?ic?iaeaiee niin?a cianoeueoa/aiiy ca
?ioaineai?noth a 14…18 ?ac?a ia?aaeuo? ae?th/a oei?eaeeaeueoe?eiaa
i/euaiiy. Ia a?aei?io a?ae inoaiiueiai, aea oei?eae eaeueoe?th
aeo?a/a?oueny aaciiai?ioii, ooai?thth/e ua iaeei a?aeo?ae ae?iaieoeoaa –
a?in, ?ic?iaeaiee niin?a aea?aeii a?ae??ciy?oueny iiaeeea?noth ia?a?iaee
iaea?aeaiiai noeueoaoiiai inaaeo a aacoei?eaeia eae?eia aeia?eai c
ai?noii E2I aeua 30% aeno?aeoe??th oei?eae?a c iueiai ca aeiiiiiaith
aiaeii-iaoaiieiaiai ?ic/eiieea ianiaiai neeaaeo 1:1,5. Aeoyae ?ii?a E+ ?
SI42- a i?iaeoeo i?e oeueiio ia?aaeuothoue a?aeiia?aeii 85 ? 99%.
17. Cai?iiiiiaaia ? ?ic?iaeaia oaoiiei??y iiaii? ia?a?iaee ?ic/ei?a
oainoinoiaeu ?c canoinoaaiiyi iaoaiieo c iaea?aeaiiyi eooiiii? nie?,
aacoei?eaeiiai eae?eiiai aeia?eaa e eiiaeeoe?eiiai ?ic/eio oei?eaeo
ia?i?th ? i?inoith, ia?aaeaa/a? aeei?enoaiiy ?ic/eiieea a oeeee? ?
iaea?aeaiiy oiiaiiai aeiiii?/iiai aoaeoo 138,4 a?i. ia 1 o ii/aoeiaiai
?ic/eio.
18. Anoaiiaeaia iaie aeniethth/a ae?y oei?eaeo iiiiaoaiieaiii?th ia nie?
a iine?aeiaiino? IgSO4>KCl>NaCl>K2SO4 iineoaeeea i?aenoaaith aeey
?ic?iaee naeaeoeaiiai aeno?aeoe?eiiai aeeo/aiiy oei?eae?a eae?th ?
iao??th c oaa?aei? noi?o? – ae?iaie/iai oei?eaeai?niiai oai?oo – c
oeeee?/iei canoinoaaiiyi aeaiiai ?ic/eiieea.
19. Aeo?ae oa ye?noue iaea?aeaiiai aacoei?eaeiiai aeia?eaa caeaaeaoue
a?ae i?e?iaee aeno?aaaioa, eiai eiioeaio?aoe??, ni?aa?aeiioaiiy i?ae
?aa?aioaie, ia?aa?ao aoi?eiieo eiiaa?n?eieo ?aaeoe?e. Aiaei? ?ic/eie
IAA, iaeo?ae?ciaai? nieyiith eeneioith, aeathoue ciiao iaea?aeaoe
i?aeoe/ii aacoei?eaeia aeia?eai i?e eiioeaio?aoe?? iniiaii? ?a/iaeie a
iueiio 30,6% E2I. Aenieee aeo?ae aeia?eaa caaacia/o? i?aai?caoe?y
aeainoaae?eiiai aeno?aaoaaiiy oei?eae?a c iine?aeiaiei aeei?enoaiiyi
aeno?a?aioa ia eiaei?e noaae??.
20. Aeeiiai? oaoi?ei-aeiiii?/i? ?ic?aooiee ?ic?iaeaii? iiai? oaoiiei???
aacoei?eaeiiai eae?eiiai aeia?eaa ia aac? ae?iaie/iai oei?eaeai?niiai
oai?oo i?aeoaa?aeeee ?? nooo?ao ia?aaaao ? oaoi?ei-aeiiii?/io
aoaeoeai?noue. I/?eoaaiee aeiiii?/iee aoaeo a?ae ai?iaaaeaeaiiy oe???
oaoiiei??? noaiiaeoue 6,48 iei. a?i. i?e ??/iiio ianyao ae?iaieoeoaa a
91 oen. o aeia?eaa.
Iniiaiee ci?no aeena?oaoe?? iioae?eiaaiee a ?iaioao:
1.Ia?aeoiei O.A. Eiiieaenia ia?a?iaea ??aeeeo a?aeoiae?a eae?eieo
ae?iaieoeoa c aeei?enoaiiyi i?aai?/ieo ?ic/eiiee?a //A?niee AeO
“Euea?anueea iie?oaoi?ea”, N316. Oai?y, oaoiieia?y ?a/iaei oa ?o
canoinoaaiiy. – Euea?a, 1997. – N. 181-183.
2. Ia?aeoiei O.A. Aeaye? aniaeoe aea/aiiy oai?cio inaaeaeaiiy
a?ae?ieneaeo ia?i?th c ?ic/ei?a oei?eaeo ia?i?th iiiiaoaiieai?iii// Oai
aea, N316. – Euea?a, 1997. – N. 178-181.
3.Ia?aeoiei O.A. Aea/aiiy ?ic/eiiino? oei?eae?a eae?th ? iao??th oa
noeueoao?a eae?th ? iaai?th o aiaeieo ?ic/eiao oei?eaeo
iiiiaoaiieaiii?th //A?niee AeO”Euea?a. iie?oaoi?ea” aei 125-??//y
o?i?ei-oaoiieia?/iiai oaeoeueoaoo. O?i?y, oaoiieia?y ?a/iaei oa ?o
canoinoaaiiy.- Euea?a, 1998.- N.35-39.
4. Ia?aeoiei O.A. Aei ieoaiiy aea/aiiy aeno?aaoth/i? caeaoiino?
?ic/eiiee?a ia iniia? iiiiaoaiieai?io aeey aeeo/aiiy oei?eae?a c
ae?iaie/iai oai?oo //Oai aea.- N. 39-40.
5. O.Ia?aeoiei. Ia?niaeoeae canoinoaaiiy i?aai?/ieo ?aaaaio?a ?
?ic/eiiee?a naeaeoeaii? ae?? a eiiieaeni?e ia?a?iaoe? iie?i?ia?aeueieo
eae?eieo ?oae I?eea?iaooy //AEo?iae Oe?a?inueeiai ?iaeaia?iiai
oiaa?enoaa “Oaoi?/i? a?no?. Technical News”.- Euea?a, 1998/1(6), 2(7).-
C.25-28.
6. Ia?aeoiei O.A. Enneaaeiaaiea i?ioeanna ?acaeaeaiey niane noeueoaoia
eaeey, iao?ey e iaaiey n i?eiaiaieai aeeaiieaieiia //Aanoiee Eueaia.
iieeoaoi. ei-oa, N149. Oeiey, oaoiieiaey aauanoa e eo i?eiaiaiea. –
Eueaia: Aeua oeiea, 1981.- N. 99-101.
7. Ia?aeoiei O.A., Aeaae?anueeee I.?., Iaeneiiae/ ?.?. Aeine?aeaeaiiy
i?ioeano ia?a?iaee aaioaoiieia?/ieo ?ic/ei?a, iaea?aeaieo i?ae /an
?ic/eiaiiy eae?eii? ?oaee ??ciiai neeaaeo // O?i. i?ii. Oe?a?ie. – 1996.
– N5. – N. 25-28.
8.Iaea?aeaiiy noeueoaoieo eae?eii-iaai??aeo aeia?ea ?c
eaiaaaei?oiai?nieo ?oae /A.O. ssai?nueeee, I.?. Aeaae?anueeee, ?.TH.
Eino?a, O.A. Ia?aeoiei //O?i. i?ii. Oe?a?ie. – 1995.- N2.- N.70-72.
9. Ia?aeoiei O.A., Iaoeianeee A.I., Aaaaneay A.A. Iieo/aiea aanoei?iuo
eaeeeiuo oaeia?aiee ec iooiaea yeaeo?ioeie/aneiai i?iecaiaenoaa iaaiey e
noeueoaoa iao?ey //Aanoiee Eueaia. iieeoaoi. ei-oa, N139. Oeiey,
oaoiieiaey aauanoa e eo i?eiaiaiea.- Eueaia: Aeua oeiea, 1980.- N.
89-91.
10. Ia?aeoiei O.A., Eeiaecaeueneay A.I. ?aaaia?aoeey aeeyoaiieaieia ec
io?aaioaiiiai ?anoai?a i?e iieo/aiee iaaiacee//Oai aea,
N171.-1983.-N.81-82.
11. Ia?aeoiei O.A., Aiaoi I.A. Enneaaeiaaiea i?ioeanna oeeueo?aoeee
noniaicee aeae?iieene iaaiey // Oai aea, N181. – 1984. – N. 79-80.
12. Ia?aeoiei O.A., Eiaaeueneee E.I., Iaeneiiae/ E.A. Enneaaeiaaiea
i?ioeanna i?ioeaioi/iie i?iiuaee aeae?ieneaea iaaiey, inaaeaeaiiiai
aeeyoaiieaieiii //Oai aea, N191.- 1986. – N. 64-65.
13. Aiaoi I.A., Ia?aeoiei O.A., Aa?o Y.N. Enneaaeiaaiea i?ioeanna
acaeiiaeaenoaey oei?eaea iiiiyoaiieaiiiiey n ieneaeii eaeueoeey//Oai
aea, N191.- 1985.- N. 64-67.
14. Ia?aeoiei O.A., Iaeneiiae/ E.A., Aeooaiiaa O.A. Eco/aiea i?ioeanna
yeaeo?ioeie/aneie ?aaaia?aoeee io?aaioaiiiai ?anoai?a iiiiyoaiieaieia //
Oai aea, N221.- 1988. – N. 68-70.
15. Ia?aeoiei O.A., Aeaaeeaneee I.E., Eiaaeueneee E.I. Aeeyiea oneiaee
iieo/aiey ieneaea iaaiey ia aai oeceei-oeie/aneea naienoaa // Oai aea,
N231.- 1989. – N. 72-74.
16. Aea/aiiy i?ioeano oaeaee?niiai a?aeieaaiiy oei?eae?a c ae?iaie/iai
oai?oo /O.A. Ia?aeoiei, I.?. Aeaae?anueeee, ?.?.Iaeneiiae/,
E.I.A?eaiueea // A?niee Euea?a. iie?oaoi. ?i-oo, N250. O?i?y, oaoiieia?y
?a/iaei oa ?o canoinoaaiiy.- Euea?a, 1991. – N. 54-56.
17. Ia?aeoiei O.A., Iaeneiiae/ ?.?., Aeaae?anueeee I.?. Aeine?aeaeaiiy
oaeaee?niiai a?aeieaaiiy oei?eae?a c aenieioei?eaeiiai oai?oo ?ic/eiaie
oei?eaeo iao??th //Oai aea, N285. – 1995. – N. 108-110.
18. ssai?nueeee A.O., Ia?aeoiei O.A., *i?iiienueea I.?. Aea/aiiy aieeao
?ioaineaiino? ia?ai?ooaaiiy ia e?iaoeeo ?ic/eiaiiy oei?enoiai iao??th a
aoeaoiii-aiaeiiio ?ic/eiieeo // Oai aea, N111. – 1977. – N. 80-83.
19. Ia?aeoiei O.A., Iaeneiiae/ ?.?., Aeaae?anueeee I.?. Aeine?aeaeaiiy
i?ioeano naeaeoeaii? aeno?aeoe?? oei?eae?a ca aeiiiiiaith aiaeieo
?ic/ei?a iiiiaoaiieai?io a oaoiieia?? eae?eieo aeia?ea//Oai aea, N260.-
1992.-N. 50-51.
20. ssai?nueeee A.O., Ia?aeoiei O.A., Aiaeae I.I. Aeine?aeaeaiiy oaciaeo
ia?aoai?aiue oei?eaeo eae?th a nenoai? EN?-IgSO4-oei?eae
iiiiaoaiieaiii?th-aiaea // Oai aea, N316. – 1997. – N. 140-142.
21. Ia?aeoiei O.A., Iaeneiiae/ ?.?., Aeaae?anueeee I.?. Aeine?aeaeaiiy
i?ioeano oia?thaaiiy ?ic/ei?a oainoinoiaeua Noaaieoeueeiai eae?eiiai
caaiaeo // Oai aea, N276. -1994. – N. 122-123.
22. Iioiaeaiei E.A., Ia?aeoiei O.A. E?iaoeea e?enoae?caoe?? noeueoaoo
eae?th c aiaeieo ?ic/ei?a i?e ??cieo oaiia?aoo?ao // Oai aea, N95.-
1975. – N. 136-139.
23. Ia?aeoiei O.A., Iaeneiiae/ ?.?., Aeaae?anueeee I.?. Aeine?aeaeaiiy
oeaio?eooaoaaiiy noniaic?? a i?ioean? aeaeo?io?i?/ii? ?aaaia?aoe??
iiiiaoaiieai?io //Oai aea, N241.- 1990. – N. 63-64.
24. ssai?nueeee A.O., Ia?aeoiei O.A., Iae?aei I.TH. Aea/aiiy
o?eueo?aoe?eieo aeanoeainoae a?ae?ieneaeo ia?i?th, inaaeaeaiiai c
?ic/ei?a noeueoaoo ia?i?th iiiiaoaiieai?iii // Oai aea, N298. -1996. –
N. 122-124.
25. ssai?neee A.O., Ia?aeoiei O.A., Eeiaecaeueneay A.I. Eco/aiea
i?ioeanna inaaeaeaiey aeae?ieneaea iaaiey ec oei?iaaieaauo ?anoai?ia
aeeyoaiieaieiii //AEIO. – 1986. – N2. – N. 418-421.
26. ssai?nueeee A.O., Ia?aeoiei O.A., Iae?aei I.TH. Aieea e?eueeino?
i?aai?/iiai inaaeaeoaa/a ia iieacieee i?ioeano inaaeaeaiiy iaai?th
a?ae?ieneaeo c ?ic/ei?a iaai?th noeueoaoo // A?niee AeO”Euea?a.
iie?oaoi?ea” aei 125-??//y o?i?ei-oaoiieia?/iiai oaeoeueoaoo. O?i?y,
oaoiieia?y ?a/iaei oa ?o canoinoaaiiy.- Euea?a, 1998.- N.3-4.
27. Ia?aeoiei O.A., Aiaeae I.I. Aei ieoaiiy aea/aiiy i?ioeano
iaea?aeaiiy aacoei?eaeiiai eae?eiiai aeia?eaa // Oai aea.- 1998.-
N.45-48.
28. ssai?nueeee A., Ia?aeoiei O. Noai ? ia?niaeoeae eiiieaeniiai
aeei?enoaiiy iie?i?ia?aeueieo eae?eieo ?oae I?eea?iaooy //A?no?
Aeaaeai?? ?iaeaia?ieo iaoe Oe?a?ie. – 1994. – N3.
29. ssai?neee A.O., Ia?aeoiei O.A., Iaoeue E.A. Eco/aiea ?anoai?eiinoe
oei?enoiai iao?ey e na?ienoiai aiaeae?eaea a aiaeiuo ?anoai?ao
aeeyoaiieaieia //AEIO. – 1983. -N9. – N.1963-1966.
30. ssai?neee A.O., Ia?aeoiei O.A., Iaoeue E.A. Eco/aiea ?anoai?eiinoe a
nenoaiao Na2S2O5-NaCl-AeYA-H2O //AEIO. -1984. – N1. – N.3-7.
31. Iioiaeaiei E.A., Ia?aeoiei O.A., AEa?ianeee E.A. Enneaaeiaaiea
aeeyiey ?anoai?eiuo ieia?aeueiuo i?eianae ia eeiaoeeo e?enoaeeecaoeee
nieae ec ?anoai?ia //OIOO. – 1975. – Oii. 9, N6. – N. 923-925.
32. Canoinoaaiiy i?aai?/ieo ?aa?aio?a aeey ?ioaineo?eaoe?? i?ioean?a
oaoiieia?? iai?aai?/ieo ?a/iaei /A.ssai?nueeee, O.Ia?aeoiei, E.Naa/oe oa
?i. //Iaoeia? caienee iaoeiaiai Oiaa?enoaa ?i. O.A.Oaa/aiea, 1997. – N.
283-291.
33. A.n. N1825772 NNN?, IEE N 05 D 1/02, 5/00. Niinia iieo/aiey
noeueoaoiiai eaeeeii-iaaieaaiai oaeia?aiey /A.O. ssai?neee, O.A.
Ia?aeoiei, I.E. Aeaaeeaneee e ae?. (NNN?). – N4883842/26; Cayae.
20.11.90; Iioae. 07.07.93, Athe. N25.
34. A.n. 967955 NNN?, IEE NI1 F 5/22; NI1 F 5/08. Niinia iieo/aiey ieene
iaaiey /A.A. Cueia, A.O. ssai?neee, E.E. Eiaaeeoei e O.A. Ia?aeoiei
(NNN?).- N3224847/23-26; Cayae. 17.11.80; Iioae. 23.10.82, Athe. N39.
35. A.n. 1002243 NNN?, IEE NI1 F 5/14. Niinia iieo/aiey aeae?iieene
iaaiey / A.O. ssai?neee, E.E. Eiaaeeoei e O.A. Ia?aeoiei (NNN?).-
N3361296/23-26; Cayae. 05.12.81; Iioae. 07.03.83, Athe. N9.
36. A.n. 1111994 NNN?, IEE NI1 F 5/08; NI1 F 5/22. Niinia iieo/aiey
ieene iaaiey /A.O. ssai?neee, O.A. Ia?aeoiei, I.A. Aiaoi e E.E.
Eiaaeeoei (NNN?). – N3503829/23-26, Cayae. 25.10.82; Iioae. 07.09.84,
Athe. N33.
37. A.n. 1521717 NNN?, IEE N 01 F 5/08. Niinia iieo/aiey ieene
iaaiey /A.O. ssai?neee, O.A. Ia?aeoiei, E.A. Iaeneiiae/ (NNN?). –
N4281955/31-26; Cayae. 13.07.87; Iioae. 15.11.89, Athe. N42.
38. A.n. 1650585 NNN?, IEE N 01 F 5/14. Niinia iieo/aiey aeae?ieneaea
iaaiey /A.O.ssai?neee, O.A.Ia?aeoiei, I.E.Aeaaeeaneee (NNN?). –
N4427613/26; Cayae. 17.05.88; Iioae.23.05.91, Athe. N19.
39. A.n. 1368262 NNN?, IEE N 01 D 9/02. Niinia iieo/aiey ieo?aoa eaeey
/A.O.ssai?neee, O.A.Ia?aeoiei (NNN?). – N395849/31-26; Cayae. 30.09.85;
Iioae. 23.01.88, Athe. N3.
40. A.n.965995NNN?, IEE N 01 A 17/62.Niinia iieo/aiey ie?inoeueoeoa
iao?ey /A.O.ssai?neee, O.A.Ia?aeoiei, E.A.Iaoeue, E.E.Eiaaeeoei (NNN?).
– N3271200/23-26; Cayae. 26.03.81; Iioae. 15.10.1982, Athe. N38.
41. A.n. 1286519 NNN?, IEE N 01 F 5/30; N 01 F 11/46. Niinia i/enoee
oei?iaaieaauo ?anoai?ia io noeueoao-eiiia /?.A.Ia?onye, A.O.ssai?neee,
E.TH.Einoea, E.E.Ianoi?, E.E.Eiaaeeoei, O.A.Ia?aeoiei, I.I.Neiiothe,
E.E.Iooa, A.I.ss?ai/oe (NNN?). – N3941166/23-26; Cayae. 21.06.85; Iioae.
30.01.87, Athe. N4.
42. A.n. 622799 NNN?, IEE NI5 D 1/02. Niinia iieo/aiey aanoei?iiai
eaeeeniaea?aeauaai oaeia?aiey/E.A.Iioiaeaiei, O.A.Ia?aeoiei,
A.I.Iaoeianeee (NNN?). – N2437037/23-26; Cayae. 25.12.76; Iioae.
05.09.78, Athe. N33.
43. Iieo/aiea aanoei?eaeiiai noeueoaoiiai eaeeeii-iaaieaaiai oaeia?aiey
iooai ia?ae?enoaeeecaoeee i?iecaiaenoaaiiiai oaieoa / A.O.ssai?neee,
O.A.Ia?aeoiei, I.E.Aeaaeeaneee, E.A.Iaeneiiae/. – Aeai. a Oe?IEEIOE,
11.12.90. – 7 n. – N2029 – Oe 90.
44. Ia?aeoiei O.A., Aeaae?anueeee I.?., Iaeneiiae/ ?.?. Aeine?aeaeaiiy
i?ioeano e?enoae?caoe?? aaioaa?ae?aoa noeueoaoo iaai?th c ?ic/ei?a
oainoinoiaeua Noaaieoeueeiai eae?eiiai caaiaeo.-Aeai. a AeIOA
Oe?a?ie,6.12.93- 9n.-N2384-Oe93.
45. ssai?neee A.O., Ia?aeoiei O.A., Ieciaoeaaa A.A. ?anoai?eiinoue
noeueoaoia eaeey e iao?ey a aiaeiuo ?anoai?ao aeeyoaiieaieia. -Iineaa,
1995.- 9 n.- Aeai. a AEIEOE, N 2501-85.
46. Iioiaeaiei E.A., AEa?ianeee E.A., Ia?aeoiei O.A. Enneaaeiaaiea
i?ioeanna ?acaeaeaiey niane noeueoaoia e oei?eaeia eaeey, iao?ey e
iaaiey n i?eiaiaieai i?aaie/aneeo ?anoai?eoaeae. – Iineaa, 1975.- 12 n.-
Aeai. a AEIEOE, N1851-75.
47. Aeooaiiaa O.A., ssai?neee A.O., Ia?aeoiei O.A. Ecioa?iu
?anoai?eiinoe oei?eaeia iao?ey, eaeey e eaeueoeey a aiaeiuo ?anoai?ao
iiiiyoaiieaieia i?e iiauoaiiuo oaiia?aoo?ao. – Eeaa, 1988.- 8 n.- Aeai.
a Oe?IEEIOE, N2305-Oe 88.
48. Ia?aeoiei O.A., Iaeneiiae/ ?.?., Aeaae?anueeee I.?. Aeine?aeaeaiiy
oiia aeae?eaiiy oei?eaeo iao??th c ?ic/ei?a oainoinoiaeua Noaaieoeueeiai
eae?eiiai caaiaeo. – Aeai. a AeIOA 06.12.1993, N2385-Oe93.
49. Enneaaeiaaiea i?ioeanna ?anoai?aiey I?eea?iaoneeo eaeeeiuo ?oae e
ia?a?aaioee iieo/aiiuo aaioaoiieiae/aneeo ?anoai?ia /O.A.Ia?aeoiei,
A.E.Aeoiyeia, I.E. Aeaaeeaneee, E.A. Iaeneiiae/ // Oacenu aeiee. V
Iaaeaeoia?iaeiiai Ana?inneeneiai nieaaiai niaauaiey “I?iaeaiu
oi?ie?iaaiey e inaiaiey ianoi?iaeaeaiee iieaciuo eneiiaaiuo niea?iaeiuo
aannaeiia”. – Naieo-Iaoa?ao?a, 1994. – N. 97-98.
50. Ia?aeoiei O.A., Iaoeianeee A.I., Aaaee ss.I. Enneaaeiaaiea nei?inoe
eiiaa?nee oei?enoiai eaeey n noeueoaoii aiiiiey a aoeaoiii-aiaeiii
?anoai?eoaea //Oacenu aeieeaaeia XI Ananithciie iao/iie iaaeaocianeie
eiioa?aioeee ii oaoiieiaee iai?a. a-a e ieia?. oaeia?aiee.- *.I.-
Iiai/a?eanne, 1978.- N. 189-190.
51. Ia?aeoiei O.A., Aeaaeeaneee I.E., Iaeneiiae/ E.A. Iieo/aiea
aanoei?eaeiiai eaeeeiiai oaeia?aiey iooai ieceioaiia?aoo?iie
ia?ae?enoaeeecaoeee i?iiuoeaiiiai oaieoa //Oacenu aeiee. OV Ananithciie
eiio. ii oei. oaoiie. iai?a. a-a. – Eacaiue, 1991. – N. 151.
52. Ia?aeoiei O.A. ?anoai?eiinoue e oaciaua i?aa?auaiey oei?eaea
eaeueoeey a aiaeiuo ?anoai?ao yoaiieaieiia //Oai aea. – N. 151.
53. Ia?aeoiei O.A. Iieo/aiea oaeia?eoaeueiiai noeueoaoa eaeey ec niane
noeueoaoia eaeey, iaaiey e iao?ey n eniieueciaaieai i?aaie/aneeo
?anoai?eoaeae. //Iaoa?eaeu O?? Ananithciie iao/i.-oaoi. eiio.
“Oaoiieiaey iai?a. a-a e iei. oaeia?aiee”. – *.1. – *eieaio, 1981. – N.
14-16.
54. AEeaeeioaciua iaoa?eaeu ia iniiaa i?aaie/aneeo aieiia aeey
i?ioeannia ecae?aoaeueiie yeno?aeoeee i?eianae a oaoiieiaee eaeeeiuo
oaeia?aiee /A.O.ssai?neee, O.A.Ia?aeoiei, E.A.Iaeneiiae/, I.E.
Aeaaeeaneee //Oacenu aeiee. ? Ananithciie eiioa?aioeee “AEeaeeioaciua
iaoa?eaeu”. – Eaaiiai, 1990. – N. 227.
55. Enneaaeiaaiea i?ioeanna naeaeoeaiie yeno?aeoeee oei?eaeia aiaeiuie
?anoai?aie iiiiyoaiieaieia /A.O.ssai?neee, O.A.Ia?aeoiei,
E.A.Iaeneiiae/, I.E. Aeaaeeaneee //Oacenu aeiee. OV Ananithci. eiio. ii
oei. oaoiie. iai?a. a-a. – Eacaiue, 1991.- N. 151-152.
56. Ia?aeoiei O.A., Iaeneiiae/ ?.?., Aeaae?anueeee I.?. ?ic?iaea
i?ioeano iaea?aeaiiy noeueoaoiiai eae?eii-iaai?eiaiai aeia?eaa c
iecueeei ai?noii oei?eae?a //Oace aeiiia?aeae O??? Oe?a?inueei? eiio. c
iai?a. o?i??. – *. ??. – Oaeai?iae, 1992. – N. 223.
57. ssai?nueeee A., Ia?aeoiei O., Aiaeae I. Iaea?aeaiiy aacoei?eaeiiai
eae?eiiai aeia?eaa ia aac? aenieioei?eaeiiai oai?oo //Iaoeia? i?aoe?
oinoi? iaoeiai? eiioa?aioe?? “Euea?anuee? o?i?/i? /eoaiiy-97”. – Euea?a,
1977. – N. 214.
58. ?icae?eaiiy iiiiaoaiieai?ii-nieueiai? noniaic?? o ae?iaieoeoa?
ia?i?th
ieneaeo/?.Iaeneiiae/,A.ssai?nueeee,O.Ia?aeoiei,E.Aeaae?anueeee//Oai
aea.-N. 211.
59. Iae?aei I., ssai?nueeee A., Ia?aeoiei O. Aeine?aeaeaiiy i?ioeano
inaaeaeaiiy a?ae?ieneaeo iaai?th ?c noeueoaoai?nieo ?ic/ei?a
iiiiaoaiieai?iiaei niiniaii. // Oai aea. – N. 213.
60. ssai?neee A.O., Ia?aeoiei O.A. Ioeaiea yooaeoeaiinoe oaoiieiaee
iieo/aiey iaaiacee ec ioa?iniuo oei?iaaieaauo ?anoai?ia ia iniiaaiee
n?aaiaiey yia?aaoe/aneeo e oiieeaiuo cao?ao //Oacenu aeieeaaeia ia?aie
?anioae. iao/ii-oaoi. eiio. ii yeiiiiee oiieeaii-yia?aaoe/aneeo ?ano?nia
a oei., iaooaoei. e iaooaia?a?aaaouaathuae i?ii. Oe?aeiu.-
Eaaii-O?aieiane, 1982.- N. 48-49.
61. ssai?neee A.O., Ia?aeoiei O.A., Aiaoi I.A. Eco/aiea oeeueo?othueo
naienoa aeae?iieene iaaiey, inaaeaeaiiie ec ?anoai?a oei?enoiai iaaiey
yoaiieaieiii //Oacenu aeieeaaeia O??? Ananithciie eiioa?aioeee ii
oaoiieiaee iai?a. a-a e ieia?. oaeia?aiee. – *. ??. – Ai?ueeee, 1985. –
N. 13-14.
62. ssai?neee A.O., Ia?aeoiei O.A., Eeiaecaeueneay A.I. Enneaaeiaaiea
oneiaee inaaeaeaiey aeae?iieene iaaiey ec ioa?iniuo oei?iaaieaauo
?anoai?ia aeeyoaiieaieiii. – Oai aea. – N. 23-24.
63. ssai?neee A.O., Ia?aeoiei O.A., Iaeneiiae/ E.A. ?ac?aaioea
oaoiieiaee iieo/aiey ieneaea iaaiey ec ioa?iniuo oei?iaaieaauo ?anoai?ia
eaeeeiuo i?iecaiaenoa //Oacenu aeieeaaeia O?O Ananithciie iao/ii-oaoi.
eiio. ii oaoiieiaee iai?a. a-a e ieia?aeueiuo oaeia?aiee: A 3 /. –
*. 1. – Eueaia, 1988. – N. 92.
64. Ia?aeoiei O.A., Eiaaeueneee E.I. Eco/aiea iaeioi?uo
oeceei-oeie/aneeo naienoa ieneaea iaaiey a caaeneiinoe io oneiaee
inaaeaeaiey e i?ieaeeaaiey aeae?ieneaea iaaiey //Oai aea. – N. 94.
65. Ia?aeoiei O.A., Aeooaiiaa O.A. Aeeyiea aeaaeaiey ia eaoo/anoue
aiaeyiuo ia?ia a i?ioeanna ?aeoeoeeaoeee nenoaiu iiiiyoaiieaiei-aiaea. –
Oai aea. – N. 96.
66. Ia?aeoiei O.A., Iaeneiiae/ E.A. Eco/aiea ?anoai?eiinoe aeae?ieneaea
iao?ey a aiaeiuo ?anoai?ao iiiiyoaiieaieia i?e oaiia?aoo?ao 293, 353 e
373 E. – Oai aea. – N. 93.
67. Iaeneiiae/ E.A., ssai?neee A.O., Ia?aeoiei O.A. I aiciiaeiinoe
?acaeaeaiey nenoaiu iiiiyoaiieaiei-aiaea-oei?eae iao?ey-oei?eae
eaeey-aeae?ieneae iao?ey iaoiaeii ?acaiiee //Oacenu aeieeaaeia V??
?anioaeeeaineie eiioa?aioeee “Iiauoaiea yooaeoeaiinoe, niaa?oainoaiaaiea
i?ioeannia e aiia?aoia oeie/aneeo i?iecaiaenoa”: A 2 /. – *. ??. –
Eueaia, 1988. – N. 33-34.
68. Aeooaiiaa O.A., ssai?neee A.O., Ia?aeoiei O.A. Enneaaeiaaiea
i?ioeanna ?aeoeoeeaoeee aiaeiuo ?anoai?ia iiiiyoaiieaieia, niaea?aeaueo
oei?eaeu eaeueoeey, iao?ey e eaeey. – Oai aea. – N. 43.
69. I?eiaiaiea yoaiieaieiia a ea/anoaa ?aaaaioa e n?aaeu aeey
inaaeaeaiey aeae?ieneaea iaaiey /A.O. ssai?neee, O.A. Ia?aeoiei, E.A.
Iaeneiiae/, I.E.Aeaaeeaneee //Oacenu aeieeaaeia ?V Ananithciiai
niaauaiey “I?iaeaiu nieueaaoaoeee e eiiieaeniia?aciaaiey a ?anoai?ao”: A
3 /. – *. ???. – Eaaiiai, 1989.- N. 407.
70. Iiaay oaoiieiaey iieo/aiey ieneaea iaaiey iooai ooeeecaoeee
ioa?iniuo oei?iaaieaauo ?anoai?ia /A.O. ssai?neee, O.A. Ia?aeoiei, I.E.
Aeaaeeaneee, E.A.Iaeneiiae/ //Oacenu aeieeaaeia Ananithciie
iao/ii-oaoie/aneie eiioa?aioeee “Eioaineaiua e aaciooiaeiua oaoiieiaee e
iai?oaeiaaiea”: A 2 /. – *. 1. – Aieaia?aae, 1991. – N. 55.
71. Ia?aeoiei O.A., Aeooaiiaa O.A., Iaeneiiae/ E.A. Enneaaeiaaiea
i?ioeanna ?aaaia?aoeee iiiiyoaiieaieia a oeeeee/aneie noaia
i?iecaiaenoaa ieneaea iaaiey //Oacenu aeiee. ?V Ananithciiai niaauaiey
“I?iaeaiu nieueaaoaoeee e eiiieaeniia?aciaaiey a ?anoai?ao”: A 3 /. – *.
???. – Eaaiiai, 1989. – N. 407.
72. Iaeneiiae/ ?.?., Ia?aeoiei O.A. ?ic?iaea niiniao ?aaaia?aoe??
iiiiaoaiieai?io c eiai a?aei?aoeueiaaieo ?ic/ei?a o ae?iaieoeoa? ieneaeo
iaai?th //Oace iaoeiai? eiioa?aioe?? aei 150-??//y “Euea?anueei?
iie?oaoi?ee” “Noai ? ia?niaeoeae ?icaeoeo o?i?/ii? iaoee oa
i?iieneiaino? a Cao?aeiiio ?aa?ii? Oe?a?ie”. – Euea?a, 1994. – N. 177.
73. Aa?o Y.N., Ia?aeoiei O.A., Iaoeue E.A. Eco/aiea acaeiiaeaenoaey
oei?eaea iao?ey n aeeieneaeii na?u a aiaeii-i?aaie/aneii ?anoai?eoaea
i?e iieo/aiee noeueoeoa iao?ey //Oacenu aeieeaaeia O??? Ananithciie
eiio. ii oaoiieiaee iai?a. a-a e ieia?. oaeia?aiee. – *. ??. – Ai?ueeee,
1985. – N.14-15.
74. Oeceei-oeie/aneee aiaeec nenoai Na2SO3-AeYA-H2O, Na2S2O5-AeYA-H2O,
NaCl-Na2S2O5-H2O, NaCl-Na2S2O5-AeYA-H2O /A.O. ssai?neee, E.A. Iaoeue,
O.A.Ia?aeoiei, ?.?.Ieaiu/ //Oacenu aeiee. V??? Ananithciiai niaauaiey ii
oeceei-oeie/aneiio aiaeeco. – *. ??. – Na?aoia, 1994. – N.124.
75. ?ac?aaioea oaoiieiae/aneie noaiu iieo/aiey noeueoaoa eaeey ec niane
noeueoaoia e oei?eaeia eaeey, iao?ey e iaaiey / Iioiaeaiei E.A.,
AEa?ianeee E.A., Ia?aeoiei O.A. e ae?. //?aoa?ao. eioi?iaoeey i
caeii/aiiuo iao/ii-enneaae. ?aaioao a aocao ONN?. – Aui. 16. Oei. i?ii.
– Eeaa: Aeua oeiea, 1975. – N. 60-61.
76. Iioiaeaiei E.A., Ia?aeoiei O.A., AEa?ianeee E.A. Enneaaeiaaiea
aeeyiey eioaineaiinoe ia?aiaoeaaiey ?anoai?a ia eeiaoeeo e?enoaeeecaoeee
noeueoaoa eaeey //Oacenu aeiee. O Ananithciie iaaeaocianeie eiio. ii
oaoiieiaee iai?a. a-a e ieia?. oaeia?aiee.- Aeiai?iiao?iane, 1976. – N.
155-156.
Ia?aeoiei O.A. ?ioaineo?eaoe?y i?ioean?a eiiieaenii? ia?a?iaee
iie?i?ia?aeueieo eae?eieo ?oae I?eea?iaooy canoinoaaiiyi i?aai?/ieo
?aa(aio?a ? ?ic/eiiee?a. – ?oeiien.
Aeena?oaoe?y ia caeiaoooy a/aiiai nooiaiy aeieoi?a oaoi?/ieo iaoe ca
niaoe?aeuei?noth 05.17.01.- oaoiiei(?y iai?aai?/ieo ?a/iaei, Aea?aeaaiee
oi?aa?neoao (Euea?anueea iie?oaoi?ea(, Euea?a, 1998.
Caoeuathoueny ?acoeueoaoe oai?aoe/ieo oa aenia?eiaioaeueieo
aeine?aeaeaiue, aeeiiaieo aeey ?ic?iaee o?ueio i?eioeeiiai iiaeo
oaoiiei(?e ieneaeo ia(i?th c a?aeo?aeieo oei?eaeia(i?eiaeo ?ic/ei?a,
aacoei?eaeieo eae?eieo aeia?ea ia aac? oei?eaeai?niiai iai?ai?iaeoeoo
(oai?oo) ? iiaii? ia?a?iaee ?ic/ei?a oainoinoiaeu eae?eieo ae?iaieoeoa.
Ia(?oioiaaii iaoiaeieia?/i? i?eioeeie canoinoaaiiy i?aai?/ieo ?aa(aio?a
? ?ic/eiiee?a naeaeoeaii? ae??, ui aeaei iiaeeea?noue iaea?aeaoe
aenieiye?ni? e?ioeaa? i?iaeoeoe c aenieei aeoiaeii, caaacia/eoe ?ano?ni-
oa aia?aicaa?aaeaiiy, ae??oeoe ?yae ieoaiue ioi?iie aeiae?eey.
Cae?eniaii aei?iaoaaiiy cai?iiiiiaaieo oaoiiei(?e ia
aeine?aeii-i?iieneiaeo, aeine?aeieo ? eaai?aoi?ieo onoaiiaeao, iaaaaeaii
aeai? uiaei ?o aeiiii?/ii? aoaeoeaiino?.
Iaoa??aee aeena?oaoe?? aeeeaaeai? a 66 ae?oeiaaieo i?aoeyo ? 10
aaoi?nueeeo na?aeioeoaao.
Eeth/ia? neiaa: ieneae ia(i?th, iiiiaoaiieai?i, oei?eaeia(i?eiaee
?ic/ei, inaaeaeaiiy, ?aaaia?aoe?y, ?ic/ei oainoinoiaeua, iaoaiie,
aeenoeeyoe?y, oai?o, oei?eae iiiiaoaiieaiii?th, aeno?aeoe?y,
aacoei?eaeia eae?eia aeia?eai.
Ia?aeoiei O.A. Eioaineoeeaoeey i?ioeannia eiiieaeniie ia?a?aaioee
iieeieia?aeueiuo eaeeeiuo ?oae I?eea?iaouey iooai i?eiaiaiey
i?aaie/aneeo ?aaaaioia e ?anoai?eoaeae. – ?oeiienue.
Aeena?oaoeey ia nieneaiea o/aiie noaiaie aeieoi?a oaoie/aneeo iaoe ii
niaoeeaeueiinoe 05.17.01.-oaoiieiaey iai?aaie/aneeo aauanoa.
Ainoaea?noaaiiue oieaa?neoao (Eueaeanueea iieeoyoieea(, Eueaia, 1998.
Caueuathony ?acoeueoaou oai?aoe/aneeo e yenia?eiaioaeueiuo
enneaaeiaaiee, aeiieiaiiuo aeey ?ac?aaioee o?ao i?eioeeieaeueii iiauo
oaoiieiaee ieneaea iaaiey ec ioa?iniuo oei?iaaieaauo ?anoai?ia,
aacoei?eaeiuo eaeeeiuo oaeia?aiee ec oei?eaeniaea?aeauaai iieoi?iaeoeoa
(oaieoa) e iieiie ia?a?aaioee ?anoai?ia oainoio?aieeeu eaeeeiuo
i?iecaiaenoa. Iainiiaaii iaoiaeieiae/aneea i?eioeeiu i?eiaiaiey
i?aaie/aneeo ?aaaaioia e ?anoai?eoaeae naeaeoeaiiai aeaenoaey, /oi
iicaieeei iieo/eoue auniea/anoaaiiua eiia/iua i?iaeoeou n aunieei
auoiaeii, iaania/eoue ?ano?ni- e yia?ainaa?aaeaiea, ?aoeoue ?yae
aii?inia io?aiu ie?oaeathuae n?aaeu. Inouanoaeaii eniuoaiea
i?aaeeiaeaiiuo oaoiieiaee ia iiuoii-i?iiuoeaiiuo, iiuoiuo e eaai?aoi?iuo
onoaiiaeao, i?eaaaeaiu aeaiiua eo yeiiiie/aneie yooaeoeaiinoe.
Iaoa?eaeu aeenna?oaoeee eceiaeaiu a 66 ia/aoiuo ?aaioao e 10 aaoi?neeo
naeaeaoaeuenoaao.
Eeth/aaua neiaa: ieneae iaaiey, iiiiyoaiieaiei, oei?eaeiaaieaaue
?anoai?, inaaeaeaiea, ?aaaia?aoeey, ?anoai? oainoio?aieeeua, iaoaiie,
aeenoeeeyoeey, oaieo, oei?eae iiiiyoaiieaiiiiey, yeno?aeoeey,
aanoei?eaeiia eaeeeiia oaeia?aiea.
Perekupko T.V. Intensification of the processes of combined processing
of the Carpathian-region polymineral potassium ores by using organic
reagents and solvents.-Manuscript.
The Dissertation for a Doctor’s Degree of Engineering Sciences in
speciality 05.17.01.- Technology of Inorganic Substanses, State
University (Lvivska Polytechnica(, Lviv, 1998.
The results of theoretical and experimental investigations, which were
carried out for ellaboration of three principly new technologies such as
technology of magnesium oxide from wasted magnesium chloride solutions,
technology of unchloride potassium fertilizers from chloride-contains
semi-finished product (shoenite) and technology of combined processing
of waste stored potassium production solutions are defended. There have
been grounded the methodalogical principles for selective organic
reagents and solvents use, which made it possible to obtaine
high-quality final products with high yield, as well as to provide the
economy of resoures and energy and solve some environmental problems.
The proposed technologies were tested by use of industrial,
experimental and laboratory installations. The information of their
economic effectiveness is presented.
Presented dissertation material was published in 66 scientific works and
10 author’s evidences.
Key words: magnesium oxide, ethanolamine, magnesium chloride solution,
precipitation, regeneration, waste stored solution, methanol,
distillation, shoenite, ethanolamonium chloride, extraction, unchloride
potassium fertilizer.
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