Кінетика розкладу вищих аліфатичних одноосновних пероксикислот у водних лужних розчинах та їх реакції з люмінолом: Автореф. дис… канд. хім. наук / І

EUeA?ANUeEEE AeA?AEAAIEE OI?AA?NEOAO

?iai? ?aaia O?aiea

CA??*IEE ?AI? IE?IIIAE*

OAeE 541.535

E?iaoeea ?iceeaaeo aeueo ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio o
aiaeieo eoaeieo ?ic/eiao

oa ?o ?aaeoe?? c ethi?iieii

02.00.04- o?ce/ia o?i?y

AAOI?AOA?AO

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?i?/ieo iaoe

EUeA?A — 1999

Aeena?oaoe?y ? ?oeiien.

?iaioa aeeiiaia ia eaoaae?? o?i?? oa o?ceee Euea?anueei? eiia?oe?eii?
aeaaeai??, Oeiiini?eea.

Iaoeiaee ea??aiee eaiaeeaeao o?i?/ieo iaoe, i?ioani?

Nei?iaiaaoee ss?ineaa Iao?iae/,

Euea?anueea eiia?oe?eia aeaaeai?y,

caa?aeoaa/ eaoaae?e o?i?? oa o?ceee

Io?oe?ei? iiiiaioe: aeieoi? o?i?/ieo iaoe, i?ioani?

Oo?ianueeee Aiaoie?e Aioiiiae/,

A?aeae?eaiiy o?ceei-o?i?? ? oaoiieia?? ai?th/eo

eiiaeei ?inoeoooo o?ce/ii? o?i??

?i. E. A. Iena?aeaanueeiai, caa?aeoaa/ a?aeae?eo

eaiaeeaeao o?i?/ieo iaoe, aeioeaio

Ae?a??aiee Aieiaeeie? Ieeieaeiae/,

Aea?aeaaiee oi?aa?neoao “Euea?anueea iie?oaoi?ea”,

aeioeaio eaoaae?e o?ce/ii? ? eiei?aeii? o?i??

I?ia?aeia onoaiiaa ?inoeooo o?ceei-i?aai?/ii? o?i?? ?
aoaeao?i??

?i. E. I. Eeoaeiaiea IAI Oe?a?ie, i. Aeiiaoeuee

Caoeno a?aeaoaeaoueny “ 16 ” aa?aniy 1999 ?ieo i 16 aiaeei? ia
can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee Ae 35.051.10 o Euea?anueeiio
aea?aeaaiiio oi?aa?neoao? ?iai? ?aaia O?aiea

( 290005, i. Euea?a, aoe. Ee?eea ? Iaoiae?y 6, o?i?/iee oaeoeueoao,
aoaeeoi??y N 2.)

C aeena?oaoe??th iiaeia iciaeiieoenue o iaoeia?e a?ae?ioaoe?
Euea?anueeiai aea?aeaaiiai oi?aa?neoaoo ?iai? ?aaia O?aiea ca aae?anith:
i. Euea?a, aoe. Ae?aaiiaiiaa, 5

Aaoi?aoa?ao ?ic?neaiee “ 12” na?iiy 1999 ?ieo

A/aiee nae?aoa?

niaoe?ae?ciaaii? a/aii? ?aaee
ss?aiei C. I.

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeueiith i?iaeaiith no/aniiai i?aai?/iiai neioaco, iniaeeai c oi/ee
ci?o c?inoath/eo aeiiii?/ieo ? aeieia?/ieo aeiia, ? i?aeaeuaiiy
oaeaeeino? ? naeaeoeaiino? i?ioean?a ??aeeiii-oaciiai ieeneaiiy
i?aai?/ieo ?a/iaei. Ia oeyoo ?? ae??oaiiy ia?niaeoeaiei ? aeei?enoaiiy
ae?oaoe/ieo ia?ieneeeneio, ye ieenethaa/?a. Niaoeeo?/i?noue aoaeiae
iiiiia?ieneeeneio aeicaiey? i?iaiaeeoe ?aaeoe?? ca ?o o/anoth a ??cieo
?ic/eiieeao, a aeniea ieenethth/a caeaoi?noue ? naeaeoeai?noue c?iaeea
?o oi?aa?naeueieie ieenieeaie aoaeaaiaei?a, oaiie?a, ai?i?a oa ?o
iio?aeieo, a?ae?ieneethth/eie aaaioaie oa niaoeeo?/ieie oeo?aioaie aeey
e?euee?niiai aecia/aiiy iaiane/aieo, acio- ? n??eiai?nieo niieoe.

Aaaeeeaei iai?yieii ? aeei?enoaiiy ia?ieneeeneio ye ?i?oe?thth/eo
aaaio?a aeey ?aaeeeaeueieo i?ioean?a, ye ioaa?aeaeoth/eo aaaio?a oa
a?aea?ethaa/?a. E??i oeueiai, ui?ac a?eueoa aeooaeueiei noa? ieoaiiy i?i
?o a?ieia?/io ?ieue o aiaeieo ?icaaaeaieo ?ic/eiao ? ia iiaa?oi?
iaia?ai. Iaeiae, ia aeaiee /an, naia aiaei? ?ic/eie ia?ieneeeneio ?
iaeiaioa aea/aieie. Iecueea ?o no?ee?noue iaiaaeo? aeei?enoaiiy ia
i?aeoeoe?. Ciaiiy iaoai?cio ? e?iaoe/ieo caeiiii??iinoae ?iceeaaeo
ia?ieneeeneio a oeeo oiiaao aeicaieeei a ?aaoethaaoe oeae i?ioean. A
naith /a?ao, aeine?aeaeaiiy ye?niiai oa e?euee?niiai neeaaeo i?iaeoeo?a,
ui ooai?ththoueny i?e ?iceeaae? ia?ieneeeneioe, cia/ii ?icoe?eei a
iiiyooy i?i ieenethth/o caeaoi?noue ia?ieneeeneio, ca?eueoeei a
iiaeeeaino? aeei?enoaiiy ia?ieneeeneio, iineeeei a ?o aoaeoeai?noue a
oaea ?nioth/eo oaoiieia?/ieo i?ioeanao, oiiaeeeaeei a eiio?ieue ca
ieenethaaeueieie i?ioeanaie, ye? a?aeaoaathoueny i?e caa??aaii? oa?/iaeo
i?iaeoeo?a /e iaoieia?/ieo ci?iao a aeeaeo i?aai?ciao.

Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie. Aeaia ?iaioa ?
neeaaeiaith /anoeiith iaoeiaiai iai?yieo eaoaae?e o?i?? oa o?ceee
Euea?anueei? eiia?oe?eii? aeaaeai??. Aeeiiaiiy oe??? ?iaioe aoei
/anoeiai i?aeo?eiaia I?aeia?iaeiith Ni?in?anueeith i?ia?aiith i?aeo?eiee
ina?oe a aaeoc? oi/ieo iaoe (ISSEP).

Iaoa ? caaea/? ?iaioe. Ioe?ieoe noaa?euei?noue oa ieenethth/o
caeaoi?noue aeueo ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio ?yaeo N8-N13 o
aiaeieo eoaeieo ?ic/eiao. Aeey oeueiai:

· aea/eoe e?iaoeeo ?iceeaaeo ia?ieneeeneio, caeaaei?noue ?? a?ae ??cieo
oaeoi??a ? nai?eoe ia oe?e iniia? e?iaoe/io iiaeaeue ?iceeaaeo
ia?ieneeeneio a neaaeieoaeiiio na?aaeiaeu?.

· ?aeaioeo?eoaaoe i?iaeoeoe ?iceeaaeo ia?ieneeeneio, anoaiiaeoe
iiaeeea?noue ?o e?euee?nii? ioe?iee ca ia?aiao?aie oai?ethi?ianoeaioe??
a ?aaeoe?? c ethi?iieii.

· aeine?aeeoe ?aaeoe?? aeueo iiiiia?ieneeeneio a i?oeaey?iiio
na?aaeiaeu?.

Iaoeiaa iiaecia iaea?aeaieo ?acoeueoao?a. Aeyaeaii o?niee ca’ycie
ia?aiao??a oai?ethi?ianoeaioe?? a nenoai? ethi?iie – ia?ieneeeneioa c
e?iaoeeith ?iceeaaeo ia?ieneeeneio.

A ?acoeueoao? aeeiiaii? ?iaioe:

· Aia?oa aea/aia e?iaoeea ?iceeaaeo aeueo ae?oaoe/ieo iaeiiiniiaieo
ia?iene-eeneio ?yaeo N8-N13 i?e ??cieo oaiia?aoo?ao. Ca?aeii
cai?iiiiiaaii? e?iaoe/ii? noaie ciaeaeaii eiinoaioe oaeaeeino? ?aaeoe?e,
ye? i?ecaiaeyoue aei ?iceeaaeo ia?ieneeeneioe oa aeoeaaoe?ei? ia?aiao?e
?iceeaaeo.

· Aia?oa ciyoi niaeo?e ethi?ianoeaioe??, ui aeieea? i?e ieeneaii?
ethi?iieo aeueie iiiiia?ieneeeneioaie. Anoaiiaeaii iniiai? i?ii?aei?
i?iaeoeoe ?iceeaaeo ia?ieneeeneio. Aeine?aeaeaii aieea oaiia?aoo?e ia
ia?aiao?e oai?ethi?ianoeaioe??.

· Aia?oa aea/aii i?oeaey?i? aeanoeaino? aiaeieo ?ic/ei?a aeueo
ae?oaoe/ieo iiiiia?ieneeeneio.

Ia iniia? aeine?aeaeaiue aieeao i?oeaeiooai?aiiy ia e?iaoeeo ?iceeaaeo
iiiiia?ieneeeneio oa ?aaeoe?th c ethi?iieii ?ic?iaeaii
oai?ethi?ianoeaioio iaoiaeeeo aecia/aiiy ?o e?eoe/ii? eiioeaio?aoe??
i?oeaeiooai?aiiy.

I?aeoe/ia cia/aiiy iaea?aeaieo ?acoeueoao?a. Iaaaaeai? a ?iaio?
?acoeueoaoe aeine?aeaeaiiy e?iaoeee ? oa?iiaeeiai?ee aeoeaaoe??
?iceeaaeo aeueo ae?oaoe/ieo iiiiia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao
iiaeooue iaoe i?aeoe/iee ?ioa?an aeey o?i?? i?aai?/ieo ia?ieneaeieo
niieoe. Ciaiiy e?iaoeee ?iceeaaeo aeicaieeoue, aei aeayei? i??e,
ea?oaaoe i?ioeanii o aaaeaiiio iai?yieo. Aeyaeaii o?niee ca’ycie
ia?aiao??a oai?ethi?ianoeaioe?? a ?aaeoe?yo ieeneaiiy ethi?iieo
ia?ieneeeneioaie c e?iaoeeith ?o ?iceeaaeo, ui aea? ciiao ioe?ieoe ai?no
ei?ioeiaeeao/iai noia?ieneae ?ii-?aaeeeaeo a i?iaeoeoao ?iceeaaeo
ia?ieneeeneio. ?aeaioeo?eiaaii ai?oa? oai?ethi?ianoeaioe??. Ia iniia?
oai?ethi?ianoeaioe?? cai?iiiiiaaii oi?aa?naeueiee niin?a aecia/aiiy
e?eoe/ii? eiioeaio?aoe?? i?oeaeiooai?aiiy aeueo ae?oaoe/ieo
iaeiiiniiaieo ia?ieneeeneio, ui aeicaiey? aeine?aeeoe ?o
eiei?aeii-o?i?/i? aeanoeaino? o aiaeieo ?ic/eiao.

Iniaenoee aianie aaoi?a. Iinoaiiaea caaaeaiiy aeine?aeaeaiue
a?aeaoaaeanue ca aaciina?aaeiueith o/anoth aaoi?a. Iiooe ? ii?aoethaaiiy
e?oa?aoo?ieo aeaea?ae c aeine?aeaeoaaii? i?iaeaie, aenia?eiaioaeueia
?iaioa oa ?ioa?i?aoaoe?y io?eiaieo ?acoeueoao?a aeeiiai? aaoi?ii
iniaenoi.

Ai?iaaoe?y ?iaioe. Iaoa??aee aeena?oaoe?eii? ?iaioe aeiiia?aeaeeny oa
aoee iaaiai?ai? ia ?-iio neiiic?oi? o?i?/ii? eii?n?? iaoeiaiai
oiaa?enoaa ?i. O. Oaa/aiea, i?enay/aiiio iai’yo? aeaae. ?. Eo/a?a
(Euea?a, 18-20 aa?aciy 1993 ?.), iaoeia?e eiioa?aioe?? aei 150-??//y
“Euea?anueei? iie?oaoi?ee” (Euea?a, 17-19 o?aaiy 1994 ?.),
iaoeiai-i?aeoe/i?e eiioa?aioe?? “Euea?anuee? o?i?/i? /eoaiiy“,
i?enay/ai?e 50-??//th o?i?/iiai oaeoeueoaoo EAeO (Euea?a, 26 o?aaiy
1995 ?.).

Ioae?eaoe??. Iniiaiee ci?no aeena?oaoe?eii? ?iaioe aeeeaaeaii a 16
ae?oeiaaieo i?aoeyo, a oiio /ene? a naie iaoeiaeo noaooyo.

No?oeoo?a ? ia’?i ?iaioe. Aeena?oaoe?eia ?iaioa neeaaea?oueny ?c anooio,
i’yoe ?icae?e?a, aeniiae?a oa nieneo aeei?enoaieo e?oa?aoo?ieo aeaea?ae
(173 aeaea?aea). ?iaioa aeeeaaeaia ia 153 noi??ieao iaoeiiieniiai
oaenoo, i?noeoue 47 ?enoie?a oa 34 oaaeeoe?.

INIIAIEE CI?NO ?IAIOE

?ICAe?E 1. E?OA?AOO?IEE IAEssAe

Ocaaaeueiaii e?oa?aoo?i? aeai? i?i aeanoeaino? i?aai?/ieo ia?ieneeeneio
oa ?o iiaaae?ieo a ?ic/eiao, iaaaaeaii oa?aeoa?enoeeo caoaeaeaieo noai?a
iieaeoee eenith: neiaeaoiiai eenith ? noia?ieneae ?ii-?aaeeeaeo — ye
iiaeeeaeo aeoeaieo i?iaeoeo?a ?iceeaaeo aeueo ae?oaoe/ieo
iiiiia?ieneeeneio o aiaeiiio na?aaei-aeu?, iaaiai?aii o?i?ci aeieeiaiiy
oai?ethi?ianoeaioe?? i?e ieeneaii? ethi?iieo.

?ICAe?E 2. I*EUAIIss ?AAAAIO?A ? OAOI?EA AENIA?EIAIOO

Ia’?eoaie aeine?aeaeaiiy aoee aeu? ae?oaoe/i? iiiiia?ieneeeneioe ?yaeo
N8-N13. ?o neioacoaaee c a?aeiia?aeieo ea?aiiiaeo eeneio ? 30%
ia?ieneaeo aiaeith a n??/aiieeneiio na?aaeiaeu?. Ai?no iniiaii? ?a/iaeie
neeaaeaa ia iaioa 97%. Iaaaaeaii oa?aeoa?enoeeo ?ioeo aeo?aeieo ?a/iaei,
iaoiaeeee ?o iaea?aeaiiy /e iiia?aaeiuei? i/enoee.

I?e aea/aii? e?iaoeee ?iceeaaeo ia?ieneeeneio aeei?enoiaoaaee ia’?iiee
eiaeiiao?e/iee iaoiae. Aeey aecia/aiiy ia?ieneaeo aiaeith a ?aaeoe?ei?e
noi?o?, ui ooai?eany i?e a?ae?ie?c? ia?ieneeeneioe, aeei?enoiaoaaee
oeoaiiiao?e/iee iaoiae. Iioe/io aonoeio ?ic/ei?a aei??thaaee ia
oioieiei?eiao?? EOE-3, a niaeo?ioioiiao?e/i? aeine?aeaeaiiy i?iaiaeeee
ia niaeo?ioioiiao?ao Specord M40 ? NO-46. Cia/aiiy ?I ?ic/ei?a
aei??thaaee ia i?eeaae? ?I-150. Aeey oai?ethi?ian-oeaioieo
aeine?aeaeaiue canoiniaoaaee onoaiiaeo, ui neeaaeaeanue c
oioiaeaeo?e/iiai iiiiiaeoaa/a OYO-79 c iiae?ethaa/ai iai?oae, yeee
aeeaeoueny a?ae aenieiaieueoiiai noaa?e?caoi?a AN-22, aeaeo?iiiiai
i?aeneethaa/a iaeeo no?oi?a EIO-05, ?ioaa?aoi-?a E-02 ? naiiieoo/iai
iioaioe?iiao?a TZ 4620. Onoaiiaea aeicaiey? iaeii/anii iaea?aeaoe
e?iaoe/io e?eao oai?ethi?ianoeaioe?? ? noio na?oea ca iaaiee /an
aeniice-oe??. I?e aeine?aeaeaii? niaeo??a oai?ethi?ianoeaioe?? ?iceeaae
aei?ii?ithaaiiy cae?enithaaany ia iiiio?iiaoi?? IAe?-12 ? ?a?no?oaaany
oioiaeaeo?iiiei iiiiiaeoaa/ai OYO-100. Iooi?noue ?ic/ei?a ia?ieneeeneio
aecia/aee ia iaoaei-iao?? IOI c eooii ?icn?thaaiiy 1350, a iieaciee
caeiieaiiy — ia ?ao?aeoiiao?? E?O-23. An? ?ic/eie ?aaaaio?a
oa?iinoaooaaee c oi/i?noth wmetafile8? ??‰????????????
???????????yyy????.????1?????? ???????
?????&??yyyy?????Ayyy????A?????? ???&? ?MathType??
????u@y???????ICAe?E 3. CAEIIII??IINO? ?ICEEAAeO IIIIIA?IENEEENEIO
?ssAeO N8 — N13 O AIAeIEO EOAEIEO ?IC*EIAO

Ae?oaoe/i? iiiiia?ieneea?aiiia? eeneioe (IE) o aiaeieo ?ic/eiao
naii/eiii iaiai?ioiuei ?iceeaaeathoueny. Iaie anoaiiaeaii, ui
oaeaee?noue ?o ?iceeaaeo caeaaeeoue a?ae i?e?iaee ia?ieneeeneioe,
eeneioiino? ? oaiia?aoo?e ?aaeoe?eiiai na?aaeiaeua. No?ee?noue
aeine?aeaeoaaieo IE o aiaeieo ?ic/eiao a ?yaeo N8-N13 ciaioo?oueny.
Caeaaei?noue oaeaeeino? ?iceeaaeo IE a?ae ?I na?aaeiaeua ia?
aeno?aiaeueiee oa?aeoa?. Aaee/eia ?I, i?e ye?e a ?cioa?i?/ieo oiiaao
aeinyaa?oueny iaea?eueoa oaeaee?noue, aeey an?o ia?ieneeeneio
iaaeeaea?oueny aei cia/aiiy ?o ?Ea, ui ocaiaeaeo?oueny c oyaeaiiyie i?i
?iciaae ia?ieneeeneio /a?ac i?ii?aeiee eiiieaen, yeee ooai?th?oueny i?e
aca?iiae?? iieaeoee IE c ?? ia?ieneai?iiii. Oey noaae?y ? e?i?ooth/ith,
oiio i?ioean ?iceeaaeo iiaeiai iienoaaoeny e?iaoe/iei ??aiyiiyi ae?oaiai
ii?yaeeo. Aeyaeaii, ui caaaeueiee ii?yaeie ?iceeaaeo ca IE
iaaeeaea?oueny aei aeaio o?eueee i?e ?I??Ea ia?ieneeeneioe, a i?e aeueo
cia/aiiyo ?I a?i ciaioo?oueny. Oea aeaco? ia ia?aeaeueia i?io?eaiiy a
?aaeoe?ei?e nenoai? ?ioeo i?ioean?a, ye? ni?eythoue ?iceeaaeo IE ?
iineeththoueny o eoaeiiio na?aaeiaeu?, cie?aia — ?aaeoe?? a?ae?ie?co
ia?ieneeeneio, a ?acoeueoao? yei? ooai?th?oueny ia?ieneae aiaeith. C
e?oa?aoo?iiai iaeyaeo a?aeiii, ui a neaaeieoaeiiio na?aaeiaeu? ?aaeoe?y
a?ae?ie?co IE iieno?oueny e?iaoe/iei ??aiyiiyi ia?oiai ii?yaeeo.
Aeine?aeaeaiiy e?iaoeee iaeiie/aiiy ia?ieneaeo aiaeith a ?aaeoe?ei?e
noi?o? i?e ?iceeaae? ia?ieneeeneio iieacaei, ui ?o caeaoi?noue aei
a?ae?ie?co a ?yae? N8-N13 c?inoa?. Iaie anoaiiaeaii oaeiae, ui iaa?oue
iacia/i? aeiaaaee ia?ieneaeo aiaeith (10-4-10-3 I) a ?aaeoe?eio noi?o
iii?oii ca?eueoothoue oaeaee?noue ?iceeaaeo ia?ieneeeneio. I/aaeaeii,
ia?ieneae aiaeith i?eeia? o/anoue a i?ioean? ?iceeaaeo, aca?iiae?th/e c
ai?iiii IE. Aeeaae oe??? ?aaeoe?? a caaaeueiee i?ioean ?iceeaaeo
ia?ieneeeneioe ca?eueoo?oueny c ?inoii cia/aiiy ?I. Anoaiiaeaii ia?oee
ii?yaeie ?aaeoe?? ca ia?ieneeeneioith.

Oaeei /eiii, i?ioean ?iceeaaeo aeine?aeaeoaaieo ia?ieneeeneio o eoaeiiio
na?aaeiaeu? ? aaaaoinoaae?eiee ? i?io?ea? ca o?ueiia iniiaieie
iai?yieaie iaeii/anii. Ca iniiao aeey e?iaoe/ieo ?ic?aooie?a acyee
ianooiio noaio i?ioeano.

O aiaeiiio eoaeiiio ?ic/ei? ia?ieneeeneioa aeenioe?th?:

? aeae? i?ioiaeeoue ?? ?iciaae c ooai?aiiyi i?ii?aeieo eiiieaen?a ca
??aiyiiyie:

wmetafile8? ??e???I??????? nG ???
h?I??&?‘MDLSK?????a??X????Y????
?Arialx????8?9?a?K?»?0????„ ?
??8?9?a?K?»?0??yy?d * ? * ? ?0????OAI¤
Q?M?ei/?2i/?”

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